Rodlike CeO2/carbon nanocomposite derived from metal–organic frameworks for enhanced supercapacitor applications
Source abstract
Abstract
The rod-shaped CeO2@C architectures have been synthesized by novel and facile methods initially from metal–organic frameworks (MOFs). The MOF-derived material showed a pseudocapacitance of 1102 F g−1 at 2 A g−1 and 418 F g−1 at a high current density of 20 A g−1 and had excellent cyclic stability of about 2.3% decrease after 5000 cycles. Results revealed that favorable effects of dispersed partially graphitic carbon in the CeO2@C composite could improve electronic conductivity, which made this product be an alternative high-performance electrode for supercapacitors.
Source: openaire · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Supercapacitor Materials and Fabrication · Advancements in Battery Materials · Conducting polymers and applications
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (43)
Show source-provided references
1. Wang F et al (2017) Latest advances in supercapacitors: from new electrode materials to novel device designs. Chem Soc Rev 46:6816–685410.1039/C7CS00205J ↗
2. Wang G, Zhang L, Zhang J (2012) A review of electrode materials for electrochemical supercapacitors. Chem Soc Rev 41:797–82810.1039/C1CS15060J ↗
3. Zhang LL, Zhao X (2009) Carbon-based materials as supercapacitor electrodes. Chem Soc Rev 38:2520–253110.1039/b813846j ↗
4. Chen T, Dai L (2013) Carbon nanomaterials for high-performance supercapacitors. Mater Today 16:272–28010.1016/j.mattod.2013.07.002 ↗
5. Li Y et al (2017) A facile method for the preparation of three-dimensional CNT sponge and a nanoscale engineering design for high performance fiber-shaped asymmetric supercapacitors. J Mater Chem A 5:22559–2256710.1039/C7TA06722D ↗
6. Li Y et al (2018) A three-dimensional reticulate CNT-aerogel for a high mechanical flexibility fiber supercapacitor. Nanoscale 10:9360–936810.1039/C8NR01991F ↗
7. Augustyn V, Simon P, Dunn B (2014) Pseudocapacitive oxide materials for high-rate electrochemical energy storage. Energy Environ Sci 7:1597–161410.1039/c3ee44164d ↗
8. Sharma P, Bhatti T (2010) A review on electrochemical double-layer capacitors. Energy Convers Manag 51:2901–291210.1016/j.enconman.2010.06.031 ↗
9. Yu G, Xie X, Pan L, Bao Z, Cui Y (2013) Hybrid nanostructured materials for high-performance electrochemical capacitors. Nano Energy 2:213–23410.1016/j.nanoen.2012.10.006 ↗
10. Wang Y, Song Y, Xia Y (2016) Electrochemical capacitors: mechanism, materials, systems, characterization and applications. Chem Soc Rev 45:5925–595010.1039/C5CS00580A ↗
11. Li Y et al (2016) Fiber-shaped asymmetric supercapacitors with ultrahigh energy density for flexible/wearable energy storage. J Mater Chem A 4:17704–1771010.1039/C6TA07163E ↗
12. Kang Z et al (2018) Facile synthesis of NiCo2S4 nanowire arrays on 3D graphene foam for high-performance electrochemical capacitors application. J Mater Sci 53:10292–10301. https://doi.org/10.1007/s10853-018-2251-210.1007/s10853-018-2251-2 ↗
13. González A, Goikolea E, Barrena JA, Mysyk R (2016) Review on supercapacitors: technologies and materials. Renew Sustain Energy Rev 58:1189–120610.1016/j.rser.2015.12.249 ↗
14. Zhi M, Xiang C, Li J, Li M, Wu N (2013) Nanostructured carbon–metal oxide composite electrodes for supercapacitors: a review. Nanoscale 5:72–8810.1039/C2NR32040A ↗
15. Eftekhari A, Mohamedi M (2017) Tailoring pseudocapacitive materials from a mechanistic perspective. Mater Today Energy 6:211–22910.1016/j.mtener.2017.10.009 ↗
16. Maheswari N, Muralidharan G (2016) Hexagonal CeO2 nanostructures: an efficient electrode material for supercapacitors. Dalton Trans 45:14352–1436210.1039/C6DT03032G ↗
17. Maheswari N, Muralidharan G (2015) Supercapacitor behavior of cerium oxide nanoparticles in neutral aqueous electrolytes. Energy Fuels 29:8246–825310.1021/acs.energyfuels.5b02144 ↗
18. Padmanathan N, Selladurai S (2014) Shape controlled synthesis of CeO2 nanostructures for high performance supercapacitor electrodes. RSC Adv 4:6527–653410.1039/c3ra43339k ↗
19. Aravinda L, Bhat KU, Bhat BR (2013) Nano CeO2/activated carbon based composite electrodes for high performance supercapacitor. Mater Lett 112:158–16110.1016/j.matlet.2013.09.009 ↗
20. Vanitha M, Cao P, Balasubramanian N (2015) Ag nanocrystals anchored CeO2/graphene nanocomposite for enhanced supercapacitor applications. J Alloys Compd 644:534–54410.1016/j.jallcom.2015.03.221 ↗
21. Wang Y, Guo CX, Liu J, Chen T, Yang H, Li CM (2011) CeO2 nanoparticles/graphene nanocomposite-based high performance supercapacitor. Dalton Trans 40:6388–639110.1039/c1dt10397k ↗
22. Luo Y, Yang T, Zhao Q, Zhang M (2017) CeO2/CNTs hybrid with high performance as electrode materials for supercapacitor. J Alloys Compd 729:64–7010.1016/j.jallcom.2017.09.165 ↗
23. Enterría M, Gonçalves A, Pereira MFR, Martins JI, Figueiredo JL (2016) Electrochemical storage mechanisms in non-stoichiometric cerium oxide/multiwalled carbon nanotube composites. Electrochim Acta 209:25–3510.1016/j.electacta.2016.05.036 ↗
24. Sun J-K, Xu Q (2014) Functional materials derived from open framework templates/precursors: synthesis and applications. Energy Environ Sci 7:2071–210010.1039/c4ee00517a ↗
25. Cao X, Tan C, Sindoro M, Zhang H (2017) Hybrid micro-/nano-structures derived from metal–organic frameworks: preparation and applications in energy storage and conversion. Chem Soc Rev 46:2660–267710.1039/C6CS00426A ↗
26. Valentino KY, Jing T, Rahul SR, Xuchuan J, Aibing Y, Kevin C-WW, Yusuke Y (2017) Nanoarchitectured design of porous materials and nanocomposites from metal–organic frameworks. Adv Mater. https://doi.org/10.1002/adma.20160489810.1002/adma.201604898 ↗
27. Lee KJ, Lee JH, Jeoung S, Moon HR (2017) Transformation of metal–organic frameworks/coordination polymers into functional nanostructured materials: experimental approaches based on mechanistic insights. Acc Chem Res 50:2684–269210.1021/acs.accounts.7b00259 ↗
28. Salunkhe RR, Kaneti YV, Yamauchi Y (2017) Metal–organic framework-derived nanoporous metal oxides toward supercapacitor applications: progress and prospects. ACS Nano 11:5293–530810.1021/acsnano.7b02796 ↗
29. Xie Z, Xu W, Cui X, Wang Y (2017) Recent progress in metal–organic frameworks and their derived nanostructures for energy and environmental applications. ChemSusChem 10:1645–166310.1002/cssc.201601855 ↗
30. Zheng S et al (2017) Transition-metal (Fe Co, Ni) based metal–organic frameworks for electrochemical energy storage. Adv Energy Mater. https://doi.org/10.1002/aenm.20160273310.1002/aenm.201602733 ↗
31. Maiti S, Pramanik A, Mahanty S (2014) Extraordinarily high pseudocapacitance of metal organic framework derived nanostructured cerium oxide. Chem Commun 50:11717–1172010.1039/C4CC05363J ↗
32. Zeng G, Chen Y, Chen L, Xiong P, Wei M (2016) Hierarchical cerium oxide derived from metal–organic frameworks for high performance supercapacitor electrodes. Electrochim Acta 222:773–78010.1016/j.electacta.2016.11.035 ↗
33. Liu K et al (2009) Hierarchically nanostructured coordination polymer: facile and rapid fabrication and tunable morphologies. Cryst Growth Des 10:790–79710.1021/cg901170j ↗
34. Wen Y, Cheng J, Feng Y, Zhang J, Li Z, Yao Y (2005) Synthesis and crystal structure of [La (BTC)(H2O)6]n. Chin J Struct Chem 24:1440–1444
35. Prestipino C et al (2006) Local structure of framework Cu(II) in HKUST-1 metallorganic framework: spectroscopic characterization upon activation and interaction with adsorbates. Chem Mater 18:1337–134610.1021/cm052191g ↗
36. Schilling C, Hofmann A, Hess C, Ganduglia-Pirovano MV (2017) Raman spectra of polycrystalline CeO2: a density functional theory study. J Phys Chem C 121:20834–2084910.1021/acs.jpcc.7b06643 ↗
37. Nakajima A, Yoshihara A, Ishigame M (1994) Defect-induced Raman spectra in doped CeO2. Phys Rev B 50:13297–1330710.1103/PhysRevB.50.13297 ↗
38. Weber W, Hass K, McBride J (1993) Raman study of CeO2: second-order scattering, lattice dynamics, and particle-size effects. Phys Rev B 48:178–18510.1103/PhysRevB.48.178 ↗
39. Babitha K, Sreedevi A, Priyanka K, Sabu B, Varghese T (2015) Structural characterization and optical studies of CeO2 nanoparticles synthesized by chemical precipitation. Indian J Pure Appl Phys 53:596–603
40. Sadezky A, Muckenhuber H, Grothe H, Niessner R, Pöschl U (2005) Raman microspectroscopy of soot and related carbonaceous materials: spectral analysis and structural information. Carbon 43:1731–174210.1016/j.carbon.2005.02.018 ↗
41. Chen XY, He YY, Song H, Zhang ZJ (2014) Structure and electrochemical performance of highly nanoporous carbons from benzoate–metal complexes by a template carbonization method for supercapacitor application. Carbon 72:410–42010.1016/j.carbon.2014.02.040 ↗
42. Chu PK, Li L (2006) Characterization of amorphous and nanocrystalline carbon films. Mater Chem Phys 96:253–27710.1016/j.matchemphys.2005.07.048 ↗
43. Su L-H, Zhang X-G, Mi C-H, Gao B, Liu Y (2009) Improvement of the capacitive performances for Co–Al layered double hydroxide by adding hexacyanoferrate into the electrolyte. Phys Chem Chem Phys 11:2195–220210.1039/b814844a ↗