journal article·2014-03

Enhanced novel orange red emission in LiSr4−x (BO3)3:xSm3+ by K+

Zhi-wei Zhang, You-shun Peng, Xi-hai Shen, Jian-ping Zhang, Shi-tao Song, Qi Lian

Journal of Materials Science· Volume 49· Issue 6
Publisher page

Abstract

LiSr4−x(BO3)3:xSm3+ and LiSr3.985−x(BO3)3:0.015Sm3+, xK+ phosphors were prepared by solid-state reactions. The phases and luminescent properties of the obtained phosphors were characterized. The results demonstrate that the phosphors particles emit an intensive reddish orange light emission under excitation at 403 nm. LiSr4−x(BO3)3:xSm3+ phosphor can be efficiently excited by ultraviolet and blue light, and the emission spectrum consists of three emission peaks at 564, 601 and 647 nm. The introduction of the charge compensator K+ into the LiSr4−x(BO3)3:xSm3+ phosphor matrix promotes the increase of the emission intensity, as well as the decrease of the Eg value. Results suggest that LiSr3.97(BO3)3:0.015Sm3+, 0.015 K+ is a promising orange–red emitting phosphor for UV LED applications.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Luminescence Properties of Advanced Materials · Ammonia Synthesis and Nitrogen Reduction · Advanced Photocatalysis Techniques

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (41)

Show source-provided references
1. Kim JS, Jeon PE, Choi JC, Park HL, Mho SI, Kim GC (2004) Warm-white-light emitting diode utilizing a single-phase full-color Ba3MgSi2O8:Eu2+, Mn2+ phosphor. Appl Phys Lett 84:293110.1063/1.1695441 ↗
2. Dobrowolska A, Zych E (2012) Spectroscopic characterization of Ca3Y2Si3O12:Eu2+, Eu3+ powders in VUV-UV−Vis region. J Phys Chem C 116:2549310.1021/jp306764f ↗
3. Mueller AH, Petruska MA, Achermann M, Werder DJ, Akhadov EA, Koleske DD, Hoffbauer MA, Klimov VI (2005) Multicolor light-emitting diodes based on semiconductor nanocrystals encapsulated in GaN charge injection layers. Nanoletters 5:103910.1021/nl050384x ↗
4. Dorman JA, Choi JH, Kuzmanich G, Chang JP (2012) High-quality white light using core–shell RE3+:LaPO4(RE = Eu, Tb, Dy, Ce) phosphors. J Phys Chem C 116:1285410.1021/jp300858z ↗
5. Song X, Fu R, Agathopoulos S, He H, Zhao X, Yu X (2011) Synthesis of BaSi2O2N2:Ce3+, Eu2+ phosphors and determination of their luminescence properties. J Am Ceram Soc 94:50110.1111/j.1551-2916.2010.04092.x ↗
6. Krishna RH, Nagabhushana BM, Kuzmanich G, Nagabhushana H, Murthy NS, Sharma SC, Shivakumara C, Chakradhar RPS (2013) Effect of calcination temperature on structural, photoluminescence, and thermoluminescence properties of Y2O3:Eu3+ nanophosphor. J Phys Chem C 117:191510.1021/jp309684b ↗
7. Rack PD, Naman A, Holloway PH, Sun SS, Tuenge RT (1996) Materials used in electroluminescent displays. MRS Bull 21:4910.1557/S0883769400036137 ↗
8. Nakano H, Ozono K, Hayashi H, Fujihara S (2012) Synthesis and luminescent properties of a new Eu3+-doped Li1+x (Ta1−z Nb z )1−x Ti x O3 red phosphor. J Am Ceram Soc 95:279510.1111/j.1551-2916.2012.05372.x ↗
9. Bandi VR, Grandhe BK, Jang K, Lee HS, Yi SS, Jeong JH (2011) Citric based sol-gel synthesis and photoluminescence properties of un-doped and Sm3+ doped Ca3Y2Si3O12 phosphors. Ceram Int 37:200110.1016/j.ceramint.2011.02.026 ↗
10. Sun JY, Zeng JH, Sun YN, Zhu JC, Du HY (2013) Synthesis and luminescence properties of novel Y2Si4N6C:Sm3+ carbonitride phosphor. Ceram Int 39:109710.1016/j.ceramint.2012.07.032 ↗
11. Wang ZJ, Li PL, Yang ZP, Guo QL (2009) A novel red phosphor BaZn2(PO4)2:Sm3+, R+ (R=Li, Na, K). J Lumin 132:194410.1016/j.jlumin.2012.03.022 ↗
12. Chen Y, Wang J, Liu C, Kuang XJ, Su Q (2011) A host sensitized reddish-orange Gd2MoO6:Sm3+ phosphor for light emitting diodes. Appl Phys Lett 98:08191710.1063/1.3557065 ↗
13. Li PL, Wang ZJ, Yang ZP, Guo QL, Li X (2009) Emission features of LiBaBO3:Sm3+ red phosphor for white LED. Mater Lett 63:75110.1016/j.matlet.2008.12.041 ↗
14. Vengala RB, Rambabu U, Buddhudu S (2007) Emission analysis of Sm3+:Ca4GdO(BO3)3 powder phosphor. Mater Lett 61:286810.1016/j.matlet.2007.01.042 ↗
15. Dotsenko VP, Berezovskaya IV, Efryushina NP, Voloshinovskii AS, Stryganyuk GB (2010) Luminescence properties and electronic structure of Sm3+-doped YAl3B4O12. J Mater Sci 45:1469. doi: 10.1007/s10856-009-3879-x10.1007/s10853-009-4104-5 ↗
16. Yang Z, Han Y, Song Y, Zhao Q, Zhou D, Liu Y (2012) Preparation and luminescence properties of Ba2–x B2O5:xSm3+ red-emitting phosphor. J Chin Ceram Soc 40:031
17. Wu L, Chen XL, Li H, He M, Xu YP, Li XZ (2005) Structure determination and relative properties of novel cubic borates MM′4(BO3)3 (M = Li, M′ = Sr; M = Na, M′ = Sr, Ba). Inorg Chem 44:640910.1021/ic050299s ↗
18. Guo C, Ding X, Seo HJ, Ren Z, Bai J (2011) Luminescent properties of UV excitable blue emitting phosphors MSr4(BO3)3:Ce3+ (M=Li and Na). J Alloy Compd 509:487110.1016/j.jallcom.2011.01.194 ↗
19. Zhang XM, Lang HY, Seo HJ (2011) On the luminescence of Ce3+, Eu3+, and Tb3+ in novel borate LiSr4(BO3)3. J Fluoresc 21:111110.1007/s10895-010-0786-y ↗
20. Zhang ZW, Sun XY, Liu L, Peng YS, Shen XH, Zhang WG, Wang DJ (2013) Synthesis and luminescence properties of novel LiSr4(BO3)3:Dy3+ phosphors. Ceram Int 39:172310.1016/j.ceramint.2012.08.017 ↗
21. Wang Q, Deng DW, Hua YJ, Huang LH, Wang HP, Zhao SL, Jia GH, Li CX, Xu SQ (2012) Potential tunable white-emitting phosphor LiSr4(BO3)3:Ce3+, Eu2+ for ultraviolet light-emitting diodes. J Lumin 132:43410.1016/j.jlumin.2011.09.003 ↗
22. Ding XM, Liang HB, Hou DJ, Jia SC, Su Q, Sun SS, Tao Y (2012) Site occupancy and luminescence of Ce3+ in NaSr4(BO3)3. J Phys D Appl Phys 45:36530110.1088/0022-3727/45/36/365301 ↗
23. Guo CF, Ding X, Seo HJ, Ren ZY, Bai JT (2011) Double emitting phosphor NaSr4(BO3)3:Ce3+, Tb3+ for near-UV light-emitting diodes. Opt Laser Technol 43:135110.1016/j.optlastec.2011.04.006 ↗
24. Zhang XM, Seo HJ (2011) Luminescence properties of novel NaBa4(BO3)3:Ce3+, Eu3+ phosphors. Phys B 406:7710.1016/j.physb.2010.10.021 ↗
25. Zhang XM, Qiao XB, Seo JS (2011) Luminescence properties of novel Ce3+, Mn2+ doped NaSr4(BO3)3 phosphors. Curr Appl Phys 11:44210.1016/j.cap.2010.08.017 ↗
26. Jiang LH, Zhang YL, Li CY, Hao JQ, Su Q (2009) Synthesis, photoluminescence, thermoluminescence and dosimetry properties of novel phosphor KSr4(BO3)3:Ce3+. J Alloy Compd 482:31310.1016/j.jallcom.2009.04.009 ↗
27. Zhang Y, Wu L, Ji MY, Wang B, Kong YF, Xu JJ (2012) Structure and photoluminescence properties of KSr4(BO3)3:Eu3+ red-emitting phosphor. Opt Mater 2:9210.1364/OME.2.000092 ↗
28. Bajaj NS, Omanwar SK (2013) Combustion synthesis and characterization of phosphor KSr4(BO3)3:Dy3+. Opt Mater 35:122210.1016/j.optmat.2013.01.025 ↗
29. Wu L, Zhang Y, Gui MY, Lu PZ, Zhao LX, Tian S, Kong YF, Xu JJ (2012) Luminescence and energy transfer of a color tunable phosphor: Dy3+-, Tm3+-, and Eu3+-coactivated KSr4(BO3)3 for warm white UV LEDs. J Mater Chem 22:646310.1039/c2jm15506k ↗
30. Zhang XM, Seo HJ (2010) Photoluminescence and concentration quenching of NaCa4(BO3)3:Eu3+ phosphor. J Alloy Compd 30:L1410.1016/j.jallcom.2010.04.242 ↗
31. Zhang XM, Zhang Z, Seo HJ (2011) Luminescence properties of novel NaBa4(BO3)3:Ce3+, Eu3+ phosphors. J Alloy Compd 509:487510.1016/j.jallcom.2011.01.195 ↗
32. Zhang XM, Seo HJ (2011) Luminescence properties of novel NaBa4(BO3)3:Ce3+, Eu3+ phosphors. Phys B 406:7710.1016/j.physb.2010.10.021 ↗
33. Sun XY, Liang WL, Wang WF, Zhang JC (2011) White-light emission from Li2Sr1−3x/2Dy x SiO4 phosphors. Appl Phys A 104:8310.1007/s00339-011-6380-6 ↗
34. Jung SH, Kang DS, Jeon DY (2011) Effect of substitution of nitrogen ions to red-emitting Sr3B2O6−3/2x N x :Eu2+ oxy-nitride phosphor for the application to white LED. J Cryst Growth 326:11610.1016/j.jcrysgro.2011.01.074 ↗
35. Lin X, Qiao XS, Fan XP (2011) Synthesis and luminescence properties of a novel red SrMoO4:Sm3+, R+ phosphor. Solid State Sci 13:57910.1016/j.solidstatesciences.2010.12.029 ↗
36. Huang SH, Lou LR (1990) Concentration dependence of sensitizer fluorescence intensity in energy transfer. Chin J Lumin 11:1
37. Zhang WF, Yin Z, Zhang MS (2000) Study of photoluminescence and electronic states in nanophase strontium titanate. Appl Phys A 70:9310.1007/s003390050018 ↗
38. Zhang Q, Wang J, Zhang M, Ding W, Su Q (2007) Enhanced photoluminescence of Ca2Al2SiO7:Eu3+ by charge compensation method. Appl Phys A 88:80510.1007/s00339-007-4090-x ↗
39. Liu G, Jacquier B (2005) Spectroscopic properties of rare earths in optical materials. Springer, Berlin, p 195
40. Puchalska M, Zych E (2012) The effect of charge compensation by means of Na+ ions on luminescence behavior of Sm3+-doped CaAl4O7. J Lumin 132:82610.1016/j.jlumin.2011.11.015 ↗
41. Li PL, Wang ZJ, Yang ZP, Guo QL, Li X (2009) Emission features of LiBaBO3:Sm3+ red phosphor for white LED. Mater Lett 63:75110.1016/j.matlet.2008.12.041 ↗