journal article·2019-04

Template-free method for fabricating carbon nanotube combined with thin N-doped porous carbon composite for supercapacitor

Yixin Zhang, Lei Liu, Lili Zhang, Yifeng Yu, Haijun Lv, Aibing Chen

Journal of Materials Science· Volume 54· Issue 8
Publisher page

Abstract

Carbon nanotube (CNT) has been intensively studied as supercapacitor electrode materials due to their high mechanical strength and excellent electrical conductivity. However, CNT with limited accessible surface area has low specific capacitance, which limits its application and development in supercapacitor. Herein, we have designed a thin N-doped porous carbon layer-modified CNT nanocomposite by template-free method. In this process, 3-aminophenol and formaldehyde rapidly self-assemble on the CNT in the presence of cationic surfactant CTAB, forming the composite of 3-aminophenol/formaldehyde (3-AF) resin and CNT. Due to the different polymerization degree of inside 3-AF resin, the soluble 3-AF resin oligomer was removed by acetone to form porous 3-AF resin and CNT@N-doped porous carbon (CNT@N-PC) was obtained by annealing process. The CNT@N-PC exhibited abundant porous structure, high specific surface area of 940 m2 g−1, excellent specific capacitance value of 224 F g−1 at 1 A g−1 and good cycle stability, demonstrating its potential as supercapacitor electrode materials.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Supercapacitor Materials and Fabrication · Conducting polymers and applications · Electrospun Nanofibers in Biomedical Applications

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (38)

Show source-provided references
1. Lu HY, Li QW, Guo JH, Song AX, Gong CH, Zhang JW, Zhang JW (2018) Hierarchically porous carbon with high-speed ion transport channels for high performance supercapacitors. Appl Surf Sci 427:992–99910.1016/j.apsusc.2017.09.065 ↗
2. Zhang JL, Zhang WF, Han MF, Pang J (2018) One pot synthesis of nitrogen-doped hierarchical porous carbon derived from phenolic formaldehyde resin with sodium citrate as activation agent for supercapacitors. J Mater Sci Mater Electron 29:4639–464810.1007/s10854-017-8415-z ↗
3. Choi BG, Hong J, Hong WH, Hammond PT, Park HS (2011) Facilitated ion transport in all-solid-state flexible supercapacitors. ACS Nano 5:7205–721310.1021/nn202020w ↗
4. Huang JY, Chen LD, Dong HW, Zeng Y, Hu H, Zheng MT, Liu YL, Xiao Y, Liang YR (2017) Hierarchical porous carbon with network morphology derived from natural leaf for superior aqueous symmetrical supercapacitors. Electrochim Acta 258:504–51110.1016/j.electacta.2017.11.092 ↗
5. Staaf LGH, Lundgren P, Enoksson P (2014) Present and future supercapacitor carbon electrode materials for improved energy storage used in intelligent wireless sensor systems. Nano Energy 9:128–14110.1016/j.nanoen.2014.06.028 ↗
6. Wei L, Yushin G (2012) Nanostructured activated carbons from natural precursors for electrical double layer capacitors. Nano Energy 1:552–56510.1016/j.nanoen.2012.05.002 ↗
7. Cao XH, Yin ZY, Zhang H (2014) Three-dimensional graphene materials: preparation, structures and application in supercapacitors. Energy Environ Sci 7:1850–186510.1039/C4EE00050A ↗
8. Qie L, Chen WM, Xu HH, Xiong XQ, Jiang Y, Zou F, Hu XL, Xin Y, Zhang ZL, Huang YH (2013) Synthesis of functionalized 3D hierarchical porous carbon for high-performance supercapacitors. Energy Environ Sci 6:2497–250410.1039/c3ee41638k ↗
9. Zhang LL, Zhou R, Zhao XS (2010) Graphene-based materials as supercapacitor electrodes. J Mater Chem 20:5983–599210.1039/c000417k ↗
10. Peng C, Zhang SW, Jewell D, Chen GZ (2008) Carbon nanotube and conducting polymer composites for supercapacitors. Prog Nat Sci 18:777–78810.1016/j.pnsc.2008.03.002 ↗
11. Ko JM, Kim KM (2009) Electrochemical properties of MnO2/activated carbon nanotube composite as an electrode material for supercapacitor. Mater Chem Phys 114:837–84110.1016/j.matchemphys.2008.10.047 ↗
12. Borenstien A, Noked M, Okashy S, Aurbach D (2013) Composite carbon nano-tubes (CNT)/activated carbon electrodes for non-aqueous super capacitors using organic electrolyte solutions. J Electrochem Soc 160:A1282–A128510.1149/2.103308jes ↗
13. Frackowiak E, Delpeux S, Jurewicz K, Szostak K, Cazorla-Amoros D, Beguin F (2002) Enhanced capacitance of carbon nanotubes through chemical activation. Chem Phys Lett 361:35–4110.1016/S0009-2614(02)00684-X ↗
14. Bi RR, Wu XL, Cao FF, Jiang LY, Gu YG, Wan LJ (2010) Highly dispersed RuO2 nanoparticles on carbon nanotubes: facile synthesis and enhanced supercapacitance performance. J Phys Chem C 114:2448–245110.1021/jp9116563 ↗
15. Jiang H, Li CZ, Sun T, Ma J (2012) A green and high energy density asymmetric supercapacitor based on ultrathin MnO2 nanostructures and functional mesoporous carbon nanotube electrodes. Nanoscale 4:807–81210.1039/C1NR11542A ↗
16. Cai F, Kang YR, Chen HY, Chen MH, Li QW (2014) Hierarchical CNT@NiCo2O4 core–shell hybrid nanostructure for high-performance supercapacitors. J Mater Chem A 2:11509–1151510.1039/C4TA01235F ↗
17. Yu YJ, Ouyang C, Gao Y, Si ZH, Chen W, Wang ZQ, Xue G (2005) Synthesis and characterization of carbon nanotube/polypyrrole core–shell nanocomposites via in situ inverse microemulsion. J Polym Sci Part A Polym Chem 43:6105–611510.1002/pola.21114 ↗
18. Czerw R, Terrones M, Charlier JC, Blase X, Foley B, Kamalakaran R, Grobert N, Terrones H, Tekleab D, Ajayan PM, Blau W, Ruhle M, Carroll DL (2001) Identification of electron donor states in N-doped carbon nanotubes. Nano Lett 1:457–46010.1021/nl015549q ↗
19. Sahoo NG, Rana S, Cho JW, Li L, Chan SH (2010) Polymer nanocomposites based on functionalized carbon nanotubes. Prog Polym Sci 35:837–86710.1016/j.progpolymsci.2010.03.002 ↗
20. Qian XF, Lv YY, Li W, Xia YY, Zhao DY (2011) Multiwall carbon nanotube@mesoporous carbon with core–shell configuration: a well-designed composite-structure toward electrochemical capacitor application. J Mater Chem 21:13025–1303110.1039/c1jm12082d ↗
21. Liu C, Wang J, Li JS, Zeng ML, Luo R, Shen JY, Sun XY, Han WQ, Wang LJ (2016) Synthesis of N-doped hollow-structured mesoporous carbon nanospheres for high-performance supercapacitors. ACS Appl Mater Interfaces 8:7194–720410.1021/acsami.6b02404 ↗
22. Ni M, Huang ZH, Zhang XL, Liu JP, Qiao L, Yang W (2017) Hierarchical design of nitrogen-doped porous carbon nanorods for use in high efficiency capacitive energy storage. RSC Adv 7:22447–2245310.1039/C7RA02425H ↗
23. Chen LF, Zhang XD, Liang HW, Kong MG, Guan QF, Chen P, Wu ZY, Yu SH (2012) Synthesis of nitrogen-doped porous carbon nanofibers as an efficient electrode material for supercapacitors. ACS Nano 6:7092–710210.1021/nn302147s ↗
24. Liu B, Liu YJ, Chen HB, Yang M, Li HM (2017) Oxygen and nitrogen co-doped porous carbon nanosheets derived from Perilla frutescens for high volumetric performance supercapacitors. J Power Sources 341:309–31710.1016/j.jpowsour.2016.12.022 ↗
25. Chen L, Ji T, Mu LW, Zhu JH (2017) Cotton fabric derived hierarchically porous carbon and nitrogen doping for sustainable capacitor electrode. Carbon 111:839–84810.1016/j.carbon.2016.10.054 ↗
26. Du J, Liu L, Hu ZP, Yu YF, Zhang Y, Hou SL, Chen AB (2018) Raw-cotton-derived N-doped carbon fiber aerogel as an efficient electrode for electrochemical capacitors. ACS Sustain Chem Eng 6:4008–401510.1021/acssuschemeng.7b04396 ↗
27. Luo GS, Huang HF, Lei CL, Chen ZZ, Wu XS, Tang SL, Du YW (2016) Facile synthesis of porous graphene as binder-free electrode for supercapacitor application. Appl Surf Sci 366:46–5210.1016/j.apsusc.2016.01.015 ↗
28. Rana M, Subramani K, Sathish M, Gautam UK (2017) Soya derived heteroatom doped carbon as a promising platform for oxygen reduction, supercapacitor and CO2 capture. Carbon 114:679–68910.1016/j.carbon.2016.12.059 ↗
29. Béguin F, Szostak K, Lota G, Frackowiak E (2005) A self-supporting electrode for supercapacitors prepared by one-step pyrolysis of carbon nanotube/polyacrylonitrile blends. Adv Mater 17:2380–238410.1002/adma.200402103 ↗
30. Han JP, Xu GY, Ding B, Pan J, Dou H, MacFarlane DR (2014) Porous nitrogen-doped hollow carbon spheres derived from polyaniline for high performance supercapacitors. J Mater Chem A 2:5352–535710.1039/C3TA15271E ↗
31. Chen AB, Xia KC, Zhang LS, Yu YF, Li YT, Sun HX, Wang YY, Li YQ, Li SH (2016) Fabrication of nitrogen-doped hollow mesoporous spherical carbon capsules for supercapacitors. Langmuir 32:8934–894110.1021/acs.langmuir.6b02250 ↗
32. Liu XH, Zhou L, Zhao YQ, Bian L, Feng XT, Pu QS (2013) Hollow, spherical nitrogen-rich porous carbon shells obtained from a porous organic framework for the supercapacitor. ACS Appl Mater Interfaces 5:10280–1028710.1021/am403175q ↗
33. Liu YZ, Li YF, Su FY, Xie LJ, Kong QQ, Li XM, Ga JG, Chen CM (2016) Easy one-step synthesis of N-doped graphene for supercapacitors. Energy Storage Mater 2:69–7510.1016/j.ensm.2015.09.006 ↗
34. Wang B, Qiu JH, Feng HX, Sakaia E, Komiyama T (2016) KOH-activated nitrogen doped porous carbon nanowires with superior performance in supercapacitors. Electrochim Acta 190:229–23910.1016/j.electacta.2016.01.038 ↗
35. Jiang M, Zhang JL, Xing LB, Zhou J, Cui HY, Si WJ, Zhuo SP (2016) KOH-activated porous carbons derived from chestnut shell with superior capacitive performance. Chin J Chem 34:1093–110210.1002/cjoc.201600320 ↗
36. Guo HL, Gao QM (2009) Boron and nitrogen co-doped porous carbon and its enhanced properties as supercapacitor. J Power Sources 186:551–55610.1016/j.jpowsour.2008.10.024 ↗
37. Zhang L, Xu L, Zhang YG, Zhou X, Zhang LT, Yasin A, Wang LL, Zhi KK (2018) Facile synthesis of bio-based nitrogen-and oxygen-doped porous carbon derived from cotton for supercapacitors. RSC Adv 8:3869–387710.1039/C7RA11475C ↗
38. Wang Q, Yan J, Wang YB, Ning GQ, Fan ZJ, Wei T, Cheng J, Zhang ML, Jing XY (2013) Template synthesis of hollow carbon spheres anchored on carbon nanotubes for high rate performance supercapacitors. Carbon 52:209–21810.1016/j.carbon.2012.09.022 ↗