Characterization of amino-crosslinked hypromellose and its adsorption characteristics for methyl orange from water
Source abstract
Abstract
The adsorption behavior and mechanism of amino-crosslinked hypromellose (AHM) adsorbent crosslinked with epichlorohydrin and modified with diethylenetriamine were studied. This material is unprecedented, and the modification method used to obtain it is relatively simple. The parameters affecting the adsorption of methyl orange (MO) dye by AHM such as pH, adsorbent dosage, contact time, initial concentration, and temperature were investigated. The experimental results show that the optimal adsorption time and dosage were 30 min and 3.6 g L−1, respectively. It was found that the pseudo-second-order kinetic model and the Langmuir isotherm adsorption model provide a good description of the adsorption process, indicating that the adsorption of MO by AHM is mainly controlled by the chemical bonding interactions. Analysis of the thermodynamic parameters showed that the process of MO adsorption on AHM is spontaneous and endothermic. The morphology, surface chemical bonding, crystal structure, specific surface area, and temperature stability of AHM were characterized by SEM, FTIR, XRD, BET, and TGA measurements. The results showed that the AHM materials had large pores, which is favorable for adsorption. AHM may also have an increased content of amino-functional groups that are beneficial for adsorption. The maximum MO adsorption capacities of AHM were 15.56 mg g−1, whereas the maximum adsorption capacity of the unmodified hypromellose was 2.12 mg g−1. It is important to note that the adsorption efficiency of AHM remained above 62% after five adsorption–desorption experiments. Therefore, AHM can be used as an efficient and environmentally friendly adsorbent material for the removal of MO from water.
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Research context
OpenAlex topics: Adsorption and biosorption for pollutant removal · Mesoporous Materials and Catalysis · Supercapacitor Materials and Fabrication
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References (53)
Show source-provided references
1. Zheng Y, Cheng B, You W, Yu J, Ho W (2019) 3D hierarchical graphene oxide-NiFe LDH composite with enhanced adsorption affinity to Congo red, methyl orange and Cr(VI) ions. J Hazard Mater 369:214–22510.1016/j.jhazmat.2019.02.013 ↗
2. Sutirman ZA, Sanagi MM, Abd Karim KJ, Naim AAbu, Wan Ibrahim WA, (2019) Enhanced removal of Orange G from aqueous solutions by modified chitosan beads: Performance and mechanism. Int J Biol Macromol 133:1260–126710.1016/j.ijbiomac.2019.04.188 ↗
3. Bai L, Wang S, Wang Z, Hong E, Wang Y, Xia C, Wang B (2019) Kinetics and mechanism of photocatalytic degradation of methyl orange in water by mesoporous Nd-TiO2-SBA-15 nanocatalyst. Environ Pollut 248:516–52510.1016/j.envpol.2019.02.052 ↗
4. Yoon S, Bae S (2019) Novel synthesis of nanoscale zerovalent iron from coal fly ash and its application in oxidative degradation of methyl orange by Fenton reaction. J Hazard Mater 365:751–75810.1016/j.jhazmat.2018.11.073 ↗
5. Peng HH, Chen J, Jiang Y, Li M, Feng L, Losic D, Dong F, Zhang YX (2016) Synergistic effect of manganese dioxide and diatomite for fast decolorization and high removal capacity of methyl orange. J Colloid Interface Sci 484:1–910.1016/j.jcis.2016.08.057 ↗
6. Ni C, Wang J, Guan Y, Jiang B, Meng X, Luo S, Guo S, Wang L (2019) Self-powered peroxi-coagulation for the efficient removal of p-arsanilic acid: pH-dependent shift in the contributions of peroxidation and electrocoagulation, Chemical Engineering Journal 12349510.1016/j.cej.2019.123495 ↗
7. Hou D, Lu L, Ren ZJ (2016) Microbial fuel cells and osmotic membrane bioreactors have mutual benefits for wastewater treatment and energy production. Water Res 98:183–18910.1016/j.watres.2016.04.017 ↗
8. Heo JN, Do JY, Son N, Kim J, Kim YS, Hwang H, Kang M (2019) Rapid removal of methyl orange by a UV Fenton-like reaction using magnetically recyclable Fe-oxalate complex prepared with rice husk. J Ind Eng Chem 70:372–37910.1016/j.jiec.2018.10.038 ↗
9. Pava-Gómez B, Vargas-Ramírez X, Díaz-Uribe C (2018) Physicochemical study of adsorption and photodegradation processes of methylene blue on copper-doped TiO2 films. J Photochem Photobiol, A 360:13–2510.1016/j.jphotochem.2018.04.022 ↗
10. Gao J, Jiang B, Ni C, Qi Y, Zhang Y, Oturan N, Oturan MA (2019) Non-precious Co3O4-TiO2/Ti cathode based electrocatalytic nitrate reduction: Preparation, performance and mechanism. Appl Catal B 254:391–40210.1016/j.apcatb.2019.05.016 ↗
11. Zhang Z, Hao C, Qu H, Sun R (2019) Studied on the dynamic adsorption process of Lycium barbarum polysaccharide in the POPC/DPPC monolayers. Colloids Surf B Biointerfaces 178:38–4310.1016/j.colsurfb.2019.02.046 ↗
12. Pargoletti E, Pifferi V, Falciola L, Facchinetti G, Re Depaolini A, Davoli E, Marelli M, Cappelletti G (2019) A detailed investigation of MnO2 nanorods to be grown onto activated carbon. High efficiency towards aqueous methyl orange adsorption/degradation. Appl Surf Sci 472:118–12610.1016/j.apsusc.2018.03.170 ↗
13. Mobarak M, Mohamed EA, Selim AQ, Mohamed FM, Sellaoui L, Bonilla-Petriciolet A, Seliem MK (2019) Statistical physics modeling and interpretation of methyl orange adsorption on high-order mesoporous composite of MCM-48 silica with treated rice husk. J Mol Liq 285:678–68710.1016/j.molliq.2019.04.116 ↗
14. Gao J, Jiang B, Ni C, Qi Y, Bi X (2020) Enhanced reduction of nitrate by noble metal-free electrocatalysis on P doped three-dimensional Co3O4 cathode: Mechanism exploration from both experimental and DFT studies. Chem Eng J 382:12303410.1016/j.cej.2019.123034 ↗
15. Qu W, He D, Guo Y, Tang Y, Shang J, Zhou L, Zhu R, Song R-J (2019) Modified Water Hyacinth Functionalized with Citric Acid as an Effective and Inexpensive Adsorbent for Heavy Metal Ions Removal. Ind Eng Chem Res 58:18508–1851810.1021/acs.iecr.9b03401 ↗
16. Yao M, Wang Z, Liu Y, Yang G, Chen J (2019) Preparation of dialdehyde cellulose graftead graphene oxide composite and its adsorption behavior for heavy metals from aqueous solution. Carbohydr Polym 212:345–35110.1016/j.carbpol.2019.02.052 ↗
17. Tang J, Song Y, Zhao F, Spinney S, Silva Bernardes J, Tam KC (2019) Compressible cellulose nanofibril (CNF) based aerogels produced via a bio-inspired strategy for heavy metal ion and dye removal. Carbohydr Polym 208:404–41210.1016/j.carbpol.2018.12.079 ↗
18. Dai H, Zhang Y, Ma L, Zhang H, Huang H (2019) Synthesis and response of pineapple peel carboxymethyl cellulose-g-poly (acrylic acid-co-acrylamide)/graphene oxide hydrogels. Carbohydr Polym 215:366–37610.1016/j.carbpol.2019.03.090 ↗
19. Sun B, Yuan Y, Li H, Li X, Zhang C, Guo F, Liu X, Wang K, Zhao XS (2019) Waste-cellulose-derived porous carbon adsorbents for methyl orange removal. Chem Eng J 371:55–6310.1016/j.cej.2019.04.031 ↗
20. Manzar MS, Waheed A, Qazi IW, Blaisi NI, Ullah N (2019) Synthesis of a novel epibromohydrin modified crosslinked polyamine resin for highly efficient removal of methyl orange and eriochrome black T. Journal of the Taiwan Institute of Chemical Engineers 97:424–43210.1016/j.jtice.2019.01.027 ↗
21. Jiang Y, Liu B, Xu J, Pan K, Hou H, Hu J, Yang J (2018) Cross-linked chitosan/beta-cyclodextrin composite for selective removal of methyl orange: Adsorption performance and mechanism. Carbohydr Polym 182:106–11410.1016/j.carbpol.2017.10.097 ↗
22. Ptaszkowska-Koniarz M, Goscianska J, Pietrzak R (2018) Synthesis of carbon xerogels modified with amine groups and copper for efficient adsorption of caffeine. Chem Eng J 345:13–2110.1016/j.cej.2018.03.132 ↗
23. Dragan ES, Dinu MV (2018) Spectacular Selectivity in the Capture of Methyl Orange by Composite Anion Exchangers with the Organic Part Hosted by Daisogel Microspheres. ACS Appl Mater Interfaces 10(24):20499–2051110.1021/acsami.8b04498 ↗
24. Liu X, Zong E, Hu W, Song P, Wang J, Liu Q, Ma Z, Fu S (2018) Lignin-Derived Porous Carbon Loaded with La(OH)3 Nanorods for Highly Efficient Removal of Phosphate. ACS Sustainable Chemistry & Engineering 7(1):758–76810.1021/acssuschemeng.8b04382 ↗
25. Dong C, Lu J, Qiu B, Shen B, Xing M, Zhang J (2018) Developing stretchable and graphene-oxide-based hydrogel for the removal of organic pollutants and metal ions. Appl Catal B 222:146–15610.1016/j.apcatb.2017.10.011 ↗
26. Huang H, He D, Tang Y, Guo Y, Li P, Qv W, Deng F, Lu F (2018) Adsorption of Hexavalent Chromium from an Aqueous Phase by Hydroxypropyl Methylcellulose Modified with Diethylenetriamine. J Chem Eng Data 64(1):98–10610.1021/acs.jced.8b00607 ↗
27. Liu S, Li J, Xu S, Wang M, Zhang Y, Xue X (2019) A modified method for enhancing adsorption capability of banana pseudostem biochar towards methylene blue at low temperature. Bioresour Technol 282:48–5510.1016/j.biortech.2019.02.092 ↗
28. Qu W, He D, Guo Y, Tang Y, Song R (2019) Characterization of modified Alternanthera philoxeroides by diethylenetriamine and its application in the adsorption of copper(II) ions in aqueous solution. Environ Sci Pollut Res Int 26(21):21189–2120010.1007/s11356-019-05472-9 ↗
29. Shen H, Pan S, Zhang Y, Huang X, Gong H (2012) A new insight on the adsorption mechanism of amino-functionalized nano-Fe3O4 magnetic polymers in Cu(II), Cr(VI) co-existing water system. Chem Eng J 183:180–19110.1016/j.cej.2011.12.055 ↗
30. Dai H, Zhang Y, Ma L, Zhang H, Huang H (2019) Synthesis and response of pineapple peel carboxymethyl cellulose-g-poly (acrylic acid-co-acrylamide)/graphene oxide hydrogels. Carbohyd Polym 215:366–37610.1016/j.carbpol.2019.03.090 ↗
31. Qu W, He D, Guo Y, Tang Y, Shang J, Zhou L, Zhu R, Song R-J (2019) Adsorption of Ni2+ and Pb2+ from water using diethylenetriamine-grafted Spirodela polyrhiza: Behavior and mechanism studies. Environ Sci Pollut Res Int 26:34562–3457410.1007/s11356-019-06558-0 ↗
32. Huang D, Wu J, Wang L, Liu X, Meng J, Tang X, Tang C, Xu J (2019) Novel insight into adsorption and co-adsorption of heavy metal ions and an organic pollutant by magnetic graphene nanomaterials in water. Chem Eng J 358:1399–140910.1016/j.cej.2018.10.138 ↗
33. Zhang W, Li Q, Mao Q, He G (2019) Cross-linked chitosan microspheres: An efficient and eco-friendly adsorbent for iodide removal from waste water. Carbohydr Polym 209:215–22210.1016/j.carbpol.2019.01.032 ↗
34. Huang D, Xu B, Wu J, Brookes PC, Xu J (2019) Adsorption and desorption of phenanthrene by magnetic graphene nanomaterials from water: Roles of pH, heavy metal ions and natural organic matter. Chem Eng J 368:390–39910.1016/j.cej.2019.02.152 ↗
35. Shu D, Feng F, Han H, Ma Z (2017) Prominent adsorption performance of amino-functionalized ultra-light graphene aerogel for methyl orange and amaranth. Chem Eng J 324:1–910.1016/j.cej.2017.04.136 ↗
36. Pu W, Song Z, Yan J, Xu H, Ji H, Yuan S, Li H (2019) Preparation of oxygen-deficient 2D WO3-x nanoplates and their adsorption behaviors for organic pollutants: equilibrium and kinetics modeling. J Mater Sci 54:12463–1247510.1007/s10853-019-03780-6 ↗
37. Xiao D, Ding W, Zhang J, Ge Y, Wu Z, Li Z (2019) Fabrication of a versatile lignin-based nano-trap for heavy metal ion capture and bacterial inhibition. Chem Eng J 358:310–32010.1016/j.cej.2018.10.037 ↗
38. Li M, Liu H, Chen T, Dong C, Sun Y (2019) Synthesis of magnetic biochar composites for enhanced uranium(VI) adsorption. Sci Total Environ 651:1020–102810.1016/j.scitotenv.2018.09.259 ↗
39. Lu Y, He D, Lei H, Hu J, Huang H, Ren H (2018) Adsorption of Cu(II) and Ni(II) from aqueous solutions by taro stalks chemically modified with diethylenetriamine. Environ Sci Pollut Res Int 25:17425–1743310.1007/s11356-018-1932-3 ↗
40. Xu X, Zou J, Teng J, Liu Q, Jiang XY, Jiao FP, Yu JG, Chen XQ (2018) Novel high-gluten flour physically cross-linked graphene oxide composites: Hydrothermal fabrication and adsorption properties for rare earth ions. Ecotoxicol Environ Saf 166:1–1010.1016/j.ecoenv.2018.09.062 ↗
41. Ahmed S, Guo Y, Li D, Tang P, Feng Y (2018) Superb removal capacity of hierarchically porous magnesium oxide for phosphate and methyl orange. Environ Sci Pollut Res Int 25(25):24907–2491610.1007/s11356-018-2565-2 ↗
42. Wang J, Dang M, Duan C, Zhao W, Wang K (2017) Carboxymethylated Cellulose Fibers as Low-Cost and Renewable Adsorbent Materials. Ind Eng Chem Res 56(51):14940–1494810.1021/acs.iecr.7b03697 ↗
43. Li B, Wang Q, Guo JZ, Huan WW (2018) Liu L (2018) Sorption of methyl orange from aqueous solution by protonated amine modified hydrochar. Bioresour Technol 268:454–45910.1016/j.biortech.2018.08.023 ↗
44. Jiang X, Xiang X, Peng S, Hou L (2019) Facile preparation of nitrogen-doped activated mesoporous carbon aerogel from chitosan for methyl orange adsorption from aqueous solution. Cellulose 26(7):4515–452710.1007/s10570-019-02368-2 ↗
45. Darwish AAA, Rashad M, Al-Aoh HA (2019) Methyl orange adsorption comparison on nanoparticles: Isotherm, kinetics, and thermodynamic studies. Dyes Pigm 160:563–57110.1016/j.dyepig.2018.08.045 ↗
46. Mittal A, Malviya A, Kaur D, Mittal J, Kurup L (2007) Studies on the adsorption kinetics and isotherms for the removal and recovery of Methyl Orange from wastewaters using waste materials. J Hazard Mater 148:229–24010.1016/j.jhazmat.2007.02.028 ↗
47. Zhu HY, Jiang R, Xiao L, Zeng GM (2010) Preparation, characterization, adsorption kinetics and thermodynamics of novel magnetic chitosan enwrapping nanosized gamma-Fe2O3 and multi-walled carbon nanotubes with enhanced adsorption properties for methyl orange. Bioresour Technol 101(14):5063–506910.1016/j.biortech.2010.01.107 ↗
48. Macedo JS, da Costa Ju´nior NB, Almeida LE, da Silva Vieira EF, Cestari AR, Gimenez IF, Carren˜o NLV, Barreto LS (2006) Kinetic and calorimetric study of the adsorption of dyes on mesoporous activated carbon prepared from coconut coir dust. J Colloid Interface Sci 298:515-52210.1016/j.jcis.2006.01.021 ↗
49. Falaki F, Fakhri A (2013) Study of the adsorption of methyl orange from aqueous solution using nickel oxide nanoparticles: equilibrium and Kinetics Studies. J Phys Theor Chem 10:117–124
50. Polepalli S, Rao CP (2018) Drum Stick Seed Powder as Smart Material for Water Purification: Role of Moringa oleifera Coagulant Protein-Coated Copper Phosphate Nanoflowers for the Removal of Heavy Toxic Metal Ions and Oxidative Degradation of Dyes from Water. ACS Sustainable Chemistry & Engineering 6(11):15634–1564310.1021/acssuschemeng.8b04138 ↗
51. Molavi H, Hakimian A, Shojaei A, Raeiszadeh M (2018) Selective dye adsorption by highly water stable metal-organic framework: Long term stability analysis in aqueous media. Appl Surf Sci 445:424–43610.1016/j.apsusc.2018.03.189 ↗
52. Mohammadi A, Doctorsafaei AH, Zia KM (2018) Alginate/calix arenes modified graphene oxide nanocomposite beads: Preparation, characterization, and dye adsorption studies. Int J Biol Macromol 120:1353–136110.1016/j.ijbiomac.2018.09.136 ↗
53. Hu ZH, Omer AM, Ouyang XK, Yu D (2018) Fabrication of carboxylated cellulose nanocrystal/sodium alginate hydrogel beads for adsorption of Pb(II) from aqueous solution. Int J Biol Macromol 108:149–15710.1016/j.ijbiomac.2017.11.171 ↗