Magnetically hyper-cross-linked polymers with well-developed mesoporous: a broad-spectrum and highly efficient adsorbent for water purification
Source abstract
Abstract
A novel magnetically hyper-cross-linked polymer (Fe3O4@HCP-NH2) was prepared in this study, which combined the advantage of the amino-modified HCP-NH2 and the magnetic Fe3O4 nanoparticles. The Fe3O4@HCP-NH2 composite has a high specific surface area (532.62 m2 g−1), well-developed mesoporous (0.3786 cm3 g−1) and good magnetic property. This Fe3O4@HCP-NH2 composite exhibits excellent adsorption ability for tetracycline, and the maximum adsorption capacity calculated by Langmuir model at 298 K is up to 694 mg g−1. The adsorption mechanisms could be attributed to the complexation interactions, hydrogen bonding and cation exchange, and the dominant interaction was the surface complexation which was elucidated by X-ray photoelectron spectroscopy analysis. In addition, the composite can be rapidly separated and maintains high adsorption performance after five regeneration cycles. More importantly, it can be used as a broad-spectrum and highly efficient adsorbent for organic contaminants including methyl orange, methylene blue, bisphenol A and 2,4-dichlorophenol removal from contaminated water. This work demonstrated that the Fe3O4@HCP-NH2 composite would be the most promising candidates for application in the adsorption of organic pollutants.
Source: openaire · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Adsorption and biosorption for pollutant removal · Covalent Organic Framework Applications · Membrane Separation and Gas Transport
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
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