Mesoporous manganese oxide for the degradation of organophosphates pesticides
Source abstract
Abstract
Manganese(IV) oxide used for degradation of toxic organophosphorus compounds was prepared by homogeneous hydrolysis of potassium permanganate (KMnO4) with 2-chloroacetamide. The prepared sample was characterized by X-ray diffraction, scanning electron microscopy, high-resolution transmission electron microscopy, and nitrogen physisorption. The degradation efficiency was determined with parathion methyl (PM) as representative of organophosphate pesticides using high-performance liquid chromatography. For a comparison, the commercially obtained product and the two synthesized manganese(IV) oxides prepared by direct reaction of manganese(II) sulfate (MnSO4·H2O) and potassium permanganate (KMnO4) and potassium permanganate (KMnO4) with urea in aqueous solution were tested. The sample prepared by homogeneous hydrolysis of KMnO4 with 2-chloroacetamide showed the highest degradation efficacy. The reaction half-time in non-polar organic solvent (n-heptane) was around 0.9 min with the degradation efficiency of about 90 % within 2 h. It was shown that comparative samples of manganese(IV) oxides were variously effective in decomposition of PM by cleavage of the P–O-aryl bond in the pesticide molecule. The degradation mechanism for PM on the MnO2 surfaces was proposed.
Source: openaire · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Advanced oxidation water treatment · Radioactive element chemistry and processing · Catalytic Processes in Materials Science
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References (50)
Show source-provided references
1. Gunby P (1979) Toxicity of pesticides. J Am Med Assoc 242(7):596–59710.1001/jama.242.7.596 ↗
2. Ujváry I (2001) Handbook of pesticide toxicology. Academic Press, San Diego
3. Mathew SB, Pillai AK, Gupta VK (2007) A rapid spectrophotometric assay of some organophosphorus pesticide residues in vegetable samples. Spectrochim Acta A 67(5):1430–143210.1016/j.saa.2006.11.020 ↗
4. Tomlin C (2004) The pesticide manual, 13th edn, British Crop Protection Council, Farniham, Surey. BCPC Publications, Alton
5. Isbister GK, Mills K, Friberg LE, Hodge M, O’Connor E, Patel R, Abeyewardene M, Eddleston M (2007) Human methyl parathion poisoning. Clin Toxicol 45:956–96010.1080/15563650701232745 ↗
6. Matsudai M, Hunt G (2005) Nanotechnology and public health. Nihon Koshu Eisei Zasshi 52:923–927
7. Emerich DF, Thanos CG (2003) Nanotechnology and medicine. Expert Opin Biol Ther 3:655–66310.1517/14712598.3.4.655 ↗
8. Gleiter H (1995) Nanostructured materials: state of the art and perspectives. Nanostruct Mater 6:3–1410.1016/0965-9773(95)00025-9 ↗
9. Speier W, Szot K (1997) Physics and chemistry at oxide surfaces. By C Noguera (Ed), Cambridge university press, Cambridge, xv, 223 pp., hardcover, £40.00, ISBN 0-52147214-8. Adv Mater, 9(15):1192–1193
10. Vohs JM (1998) The surface science of metal oxides. AIChE J 44(2):502–50310.1002/aic.690440230 ↗
11. Gellings PJ, Bouwmeester HJM (1992) Ion and mixed conducting oxides as catalysts. Catal Today 12:1–10110.1016/0920-5861(92)80046-P ↗
12. Khaleel A, Li W, Klabunde KJ (1999) Nanocrystals as stoichiometric reagents with unique surface chemistry. New adsorbents for air purification. Nanostruct Mater 12:463–46610.1016/S0965-9773(99)00159-2 ↗
13. Štengl V, Bludská J, Opluštil F, Němec T (2011) Mesoporous titanium-manganese dioxide for sulphur mustard and soman decontamination. Mater Res Bull 46:2050–205610.1016/j.materresbull.2011.07.003 ↗
14. Štengl V, Houšková V, Bakardjieva S, Murafa N, Maříková M, Opluštil F, Němec T (2010) Zirconium doped nano-dispersed oxides of Fe, Al and Zn for destruction of warfare agents. Mater Charact 61(11):1080–108810.1016/j.matchar.2010.06.021 ↗
15. Zhang CC, Zhang FS (2014) Recovery of triphenyl phosphate from waste printed circuit boards by solvothermal process. Chem Eng J 240:10–1510.1016/j.cej.2013.11.048 ↗
16. Wang S, Peng Y (2010) Natural zeolites as effective adsorbents in water and wastewater treatment. Chem Eng J 156(1):11–2410.1016/j.cej.2009.10.029 ↗
17. Lei Z, Shi F, Lu L (2012) Incorporation of MnO2-coated carbon nanotubes between graphene sheets as supercapacitor electrode. ACS Appl Mater Interfaces 4:1058–106410.1021/am2016848 ↗
18. Qu J, Shi L, He C, Gao F, Li B, Zhou Q, Hu H, Shao G, Wang X, Qiu J (2014) Highly efficient synthesis of graphene/MnO2 hybrids and their application for ultrafast oxidative decomposition of methylene blue. Carbon N Y 66:485–49210.1016/j.carbon.2013.09.025 ↗
19. Xiao W, Wang D, Lou XW (2010) Shape-controlled synthesis of MnO2 nanostructures with enhanced electrocatalytic activity for oxygen reduction. J Phys Chem C 114:1694–170010.1021/jp909386d ↗
20. Yan D, Yan PX, Yue GH, Liu JZ, Chang JB, Yang Q, Qu DM, Geng ZR, Chen JT, Zhang GA, Zhuo RF (2007) Self-assembled flower-like hierarchical spheres and nanobelts of manganese oxide by hydrothermal method and morphology control of them. Chem Phys Lett 440:134–13810.1016/j.cplett.2007.04.027 ↗
21. Wang X, Wang X, Huang W, Sebastian PJ, Gamboa S (2005) Sol-gel template synthesis of highly ordered MnO2 nanowire arrays. J Power Sources 140:211–21510.1016/j.jpowsour.2004.07.033 ↗
22. Rao CNR, Govindaraj A, Vivekchand SRC (2006) Inorganic nanomaterials: current status and future prospects. Annu Rep Sect A Inorg Chem. 102:2010.1039/b516174f ↗
23. Lin HY, Sun YP, Weng BJ, Yang CT, Suen NT, Liao KH, Huang YC, Ho JY, Chong NS, Tang HY (2007) Factors influencing the structure of electrochemically prepared α-MnO2 and γ-MnO2 phases. Electrochim Acta 52:6548–655310.1016/j.electacta.2007.04.095 ↗
24. Štengl V, Králová D, Opluštil F, Němec T (2012) Mesoporous manganese oxide for warfare agents degradation. Microporous Mesoporous Mater 156:224–23210.1016/j.micromeso.2012.02.031 ↗
25. Kumagai N, Sasaki T, Oshitari S, Komaba S (2006) Characterization and lithium insertion characteristics of hollandite-type Ky(Mn1−xMx)O2 for rechargeable lithium battery electrodes. J New Mater Electrochem Syst 9:175–180
26. McKenzie RM (1971) The synthesis of birnessite, cryptomelane, and some other oxides and hydroxides of manganese. Miner Mag 38:493–50210.1180/minmag.1971.038.296.12 ↗
27. Iyer A, Del-Pilar J, King’ondu CK, Kissel E, Garces HF, Huang H, El-Sawy AM, Dutta PK, Suib SL (2012) Water oxidation catalysis using amorphous manganese oxides, octahedral molecular sieves (OMS-2), and octahedral layered (OL-1) manganese oxide structures. J Phys Chem C 116:6474–648310.1021/jp2120737 ↗
28. Shih Y-J, Huang R-L, Huang Y-H (2015) Adsorptive removal of arsenic using a novel akhtenskite coated waste goethite. J Clean Prod 87:897–90510.1016/j.jclepro.2014.10.065 ↗
29. Thackeray MM, Rossouw MH, Gummow RJ, Liles DC, Pearce K, De Kock A, David WIF, Hull S (1993) Ramsdellite-MnO2 for lithium batteries: the ramsdellite to spinel transformation. Electrochim Acta 38:1259–126710.1016/0013-4686(93)80056-6 ↗
30. Reddy RN, Reddy RG (2004) Synthesis and electrochemical characterization of amorphous MnO2 electrochemical capacitor electrode material. J Power Sources 132:315–32010.1016/j.jpowsour.2003.12.054 ↗
31. Segal SR, Cao L, Suib SL, Tang X, Satyapal S (2001) Thermal decomposition of dimethyl methylphosphonate over manganese oxide catalysts. J Catal 198(1):66–7610.1006/jcat.2000.3126 ↗
32. Mahato TH, Prasad GK, Singh B, Batra K, Ganesan K (2010) Mesoporous manganese oxide nanobelts for decontamination of sarin, sulphur mustard and chloro ethyl ethyl sulphide. Microporous Mesoporous Mater 132(1–2):15–2110.1016/j.micromeso.2009.05.035 ↗
33. Prasad GK, Mahato TH, Pandey P, Singh B, Suryanarayana MVS, Saxena A, Shekhar K (2007) Reactive sorbent based on manganese oxide nanotubes and nanosheets for the decontamination of 2-chloro-ethyl ethyl sulphide. Microporous Mesoporous Mater 106:256–26110.1016/j.micromeso.2007.03.004 ↗
34. Janos P, Kuran P, Kormunda M, Stengl V, Grygar TM, Dosek M, Stastny M, Ederer J, Pilarova V, Vrtoch L (2014) Cerium dioxide as a new reactive sorbent for fast degradation of parathion methyl and some other organophosphates. J Rare Earths 32(4):360–37010.1016/S1002-0721(14)60079-X ↗
35. Gordon L, Salesin ED (1963) Precipitation from homogeneous solution. J Chem Educ 40(4):A30610.1021/ed040pA306.1 ↗
36. Refat M, Sadeek S (2005) A novel method for synthesis of Cr2O3, MnO2, MoO3 and WO3. Maced J Chem Chem Eng 24(2):153–155
37. Glover ED (1977) Characterization of a marine birnessite. Am Miner 62:278–285
38. Auerbach SM, Carrado KA, Dutta PK (2004) Handbook of layered materials. CRC Press, Boca Raton10.1201/9780203021354 ↗
39. Bish DL (2013) Parallels and distinctions between clay minerals and zeolites, vol 5. Elsevier, New York
40. Rajagopalan S, Koper O, Decker S, Klabunde KJ (2002) Nanocrystalline metal oxides as destructive adsorbents for organophosphorus compounds at ambient temperatures. Chem A Eur J 8:2602–260710.1002/1521-3765(20020603)8:11<2602::AID-CHEM2602>3.0.CO;2-3 ↗
41. Wagner GW, Koper OB, Lucas E, Decker S, Klabunde KJ (2000) Reactions of VX, GD, and HD with nanosize CaO: autocatalytic dehydrohalogenation of HD. J Phys Chem B 104:5118–512310.1021/jp000101j ↗
42. Štengl V, Maříková M, Bakardjieva S, Šubrt J, Opluštil F, Olšanská M (2005) Reaction of sulfur mustard gas, soman and agent VX with nanosized anatase TiO2 and ferrihydrite. J Chem Technol Biotechnol 80(7):754–75810.1002/jctb.1218 ↗
43. Sharma N, Kakkar R (2013) Recent advancements on warfare agents/metal oxides surface chemistry and their simulation study. Adv Mater 4(7):508–521
44. Janoš P, Hladík T, Kormunda M, Ederer J, Šťastný M (2014) Thermal treatment of cerium oxide and its properties: adsorption ability versus degradation efficiency. Adv Mater Sci Eng 2014:1–1210.1155/2014/706041 ↗
45. Kung HH (1989) Transition metal oxides—surface chemistry and catalysis, vol 45. Elsevier, New York
46. Lee SJ, Huang CH, Shian S, Sandhage KH (2007) Rapid hydrolysis of organophosphorous esters induced by nanostructured, fluorine-doped titania replicas of diatom frustules. J Am Ceram Soc 90(5):1632–163610.1111/j.1551-2916.2007.01571.x ↗
47. Mitchell MB, Sheinker VN, Mintz EA (1997) Adsorption and decomposition of dimethyl methylphosphonate on metal oxides. J Phys Chem B 101(51):11192–1120310.1021/jp972724b ↗
48. Li YX, Koper O, Maher A, Klabunde KJ (1992) Adsorption and decomposition of organophosphorus compounds on nanoscale metal oxid particles. In situ GC-MS studies of pulsed microreactions over magnesium oxide. Chem Mater 4:323–33010.1021/cm00020a019 ↗
49. Narske RM, Klabunde KJ, Fultz S (2002) Solvent effects on the heterogeneous adsorption and reactions of (2-chloroethyl) ethyl sulfide on nanocrystalline magnesium oxide. Langmuir 18:4819–482510.1021/la020195j ↗
50. Meng Q, Doetschman DC, Rizos AK, Lee M-H, Schulte JT, Spyros A, Kanyi CW (2011) Adsorption of organophosphates into microporous and mesoporous NaX zeolites and subsequent chemistry. Environ Sci Technol 45(7):3000–300510.1021/es1030678 ↗