journal article·2019-05

Fabrication of dispersive α-Co(OH)2 nanosheets on graphene nanoribbons for boosting their oxygen evolution performance

Jingyun Wang, Yipeng Bao, Cao Cui, Zhenyu Zhang, Shumin Li, Jiami Pan, Yingying Zhang, Gaomei Tu, Jin Wang, Zhengquan Li

Journal of Materials Science· Volume 54· Issue 10
Publisher page

Abstract

Nanostructured α-Co(OH)2 materials are promising noble-metal-free electrocatalysts for oxygen evolution reaction (OER), but their performance is severally restrained by their poor conductivity. Combination of α-Co(OH)2 and carbon nanotubes (CNTs) can improve their conductivity, but it is difficult to build sufficient interface contact between them due to the mismatched hydrophobicity. Herein, we demonstrate a facile method to in situ grow α-Co(OH)2 nanosheets (NSs) on graphene nanoribbons (GNRs), an intriguing belt-like conductive material after oxidative unzipping of CNTs. Owing to the rich of functional groups, the GNRs can be utilized as substrate in solution to prepare dispersive α-Co(OH)2 nanosheets on their surface. The developed α-Co(OH)2 NSs are well contact with the conductive GNRs substrate and offer sufficient active surface area, showing obviously better OER performance than the α-Co(OH)2 and CNTs/Co(OH)2 prepared under the same condition. The composite electrocatalysts have been characterized by various apparatuses, and their OER activities are explored in detail.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Electrocatalysts for Energy Conversion · Electrochemical Analysis and Applications · Advanced battery technologies research

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References (45)

Show source-provided references
1. Shi YM, Zhang B (2016) Recent advances in transition metal phosphide nanomaterials: synthesis and applications in hydrogen evolution reaction. Chem Soc Rev 45:1529–154110.1039/C5CS00434A ↗
2. Zhang HB, Nai JW, Yu L, Lou XW (2017) Metal-organic-framework-based materials as platforms for renewable energy and environmental applications. Joule 1:77–10710.1016/j.joule.2017.08.008 ↗
3. Montoya JH, Seitz LC, Chakthranont P, Vojvodic A, Jaramillo TF, Nørskov JK (2016) Materials for solar fuels and chemicals. Nat Mater 16:70–8110.1038/nmat4778 ↗
4. McCrory CCL, Jung S, Ferrer IM, Chatman SM, Peters JC, Jaramillo TF (2015) Benchmarking hydrogen evolving reaction and oxygen evolving reaction electrocatalysts for solar water splitting devices. J Am Chem Soc 137:4347–435710.1021/ja510442p ↗
5. Yan CZ, Wu HB, Xie Y, Lou XW (2014) Mixed transition-metal oxides: design, synthesis, and energy-related applications. Angew Chem Int Ed 53:1488–150410.1002/anie.201303971 ↗
6. Yu YF, Shi YM, Zhang B (2018) Synergetic transformation of solid inorganic-organic hybrids into advanced nanomaterials for catalytic water splitting. Acc Chem Res 51:1711–172110.1021/acs.accounts.8b00193 ↗
7. Zhao SL, Wang Y, Dong JC, He CT, Yin HJ, An PF, Zhao K, Zhang XF, Gao C, Zhang LJ, Lv JW, Wang JX, Zhang JQ, Khattak AM, Khan NA, Wei ZX, Zhang J, Liu ZY (2016) Ultrathin metal-organic framework nanosheets for electrocatalytic oxygen evolution. Nat Energy 1:16184–1619310.1038/nenergy.2016.184 ↗
8. Gerken JB, McAlpin JG, Chen JY, Rigsby ML, Casey WH, Britt RD, Stahl SS (2011) Electrochemical water oxidation with cobalt-based electrocatalysts from pH 0–14: the thermodynamic basis for catalyst structure, stability, and activity. J Am Chem Soc 133:14431–1444210.1021/ja205647m ↗
9. Zheng Y, Jiao Y, Zhu YH, Li LH, Han Y, Chen Y, Du AJ, Jaroniec M, Qiao SZ (2014) Hydrogen evolution by a metal-free electrocatalyst. Nat Commun 5:3783–379010.1038/ncomms4783 ↗
10. McCrory CCL, Jung S, Peters JC, Jaramillo TF (2013) Benchmarking heterogeneous electrocatalysts for the oxygen evolution reaction. J Am Chem Soc 135:16977–1698710.1021/ja407115p ↗
11. Burke MS, Enman LJ, Batchellor AS, Zou SH, Boettcher SW (2015) Oxygen evolution reaction electrocatalysis on transition metal oxides and (oxy)hydroxides: activity trends and design principles. Chem Mater 27:7549–755810.1021/acs.chemmater.5b03148 ↗
12. Nong HN, Gan L, Willinger E, Teschner D, Strasser P (2014) IrOx core–shell nanocatalysts for cost-and energy-efficient electrochemical water splitting. Chem Sci 5:2955–296310.1039/C4SC01065E ↗
13. Chang SH, Danilovic N, Chang KC, Subbaraman R, Paulikas AP, Fong DD, Highland MJ, Baldo PM, Stamenkovic VR, Freeland JW, Eastman JA, Markovic NM (2014) Functional links between stability and reactivity of strontium ruthenate single crystals during oxygen evolution. Nat Commun 5:4191–419910.1038/ncomms5191 ↗
14. Nong HN, Oh HS, Reier T, Willinger E, Willinger MG, Petkov V, Teschner D, Strasser P (2015) Oxide-supported IrNiOx core–shell particles as efficient, cost-effective, and stable catalysts for electrochemical water splitting. Angew Chem Int Ed 54:2975–297910.1002/anie.201411072 ↗
15. Zhan Y, Du GJ, Yang SL, Xu CH, Lu MH, Liu ZL, Lee JY (2015) Development of cobalt hydroxide as a bifunctional catalyst for oxygen electrocatalysis in alkaline solution. ACS Appl Mater Interfaces 7:12930–1293610.1021/acsami.5b02670 ↗
16. Liu PF, Yang S, Zheng LR, Zhang B, Yang HG (2016) Electrochemical etching of acobalt hydroxide for improvement of oxygen evolution reaction. J Mater Chem A 4:9578–958410.1039/C6TA04078K ↗
17. Wang JY, Cui C, Lin RB, Xu CH, Wang J, Li ZQ (2018) Hybrid cobalt-based electrocatalysts with adjustable compositions for electrochemical water splitting derived from Co2+-loaded MIL-53(Fe) particles. Electrochim Acta 286:397–40510.1016/j.electacta.2018.08.046 ↗
18. Liu ZP, Ma RZ, Osada M, Takada K, Sasaki T (2005) Selective and controlled synthesis of α-and β-cobalt hydroxides in highly developed hexagonal platelets. J Am Chem Soc 127:13869–1387410.1021/ja0523338 ↗
19. Lei W, Zhi HD, Zheng GW, Feng XZ, Jian J (2013) Layered α-Co(OH)2 nanocones as electrode materials for pseudocapacitors: understanding the effect of interlayer space on electrochemical activity. Adv Funct Mater 23:2758–276410.1002/adfm.201202786 ↗
20. Guo P, Wu J, Li XB, Luo J, Lau WM, Liu H, Sun XL, Liu LM (2018) A highly stable bifunctional catalyst based on 3D Co(OH)2@NCNTs@NF towards overall water-splitting. Nano Energy 47:96–10410.1016/j.nanoen.2018.02.032 ↗
21. Jagadale AD, Jamadade VS, Pusawale SN, Lokhande CD (2012) Effect of scan rate on the morphology of potentiodynamically deposited β-Co(OH)2 and corresponding supercapacitive performance. Electrochim Acta 78:92–9710.1016/j.electacta.2012.05.137 ↗
22. Xia XH, Tu JP, Zhang YQ, Mai YJ, Wang XL, Gu CD, Zhao XB (2011) Three-dimentional porous nano-Ni/Co(OH)2 nanoflake composite film: a pseudocapacitive material with superior performance. J Phys Chem C 115:22662–2266810.1021/jp208113j ↗
23. Zhang BX, Zhang JL, Tan XN, Tan DX, Shi JB, Zhang FY, Liu LF, Su ZZ, Han BX, Zheng LR, Zhang J (2018) One-step synthesis of ultrathin α-Co(OH)2 nanomeshes and their high electrocatalytic activity toward the oxygen evolution reaction. Chem Commun 54:4045–404810.1039/C8CC01724G ↗
24. Wu D, Wei YC, Ren X, Ji XQ, Liu YW, Guo XD, Liu Z, Asiri AM, Wei Q, Sun XP (2018) Co(OH)2 nanoparticle-encapsulating conductive nanowires array: room-temperature electrochemical preparation for high-performance water oxidation electrocatalysis. Adv Mater 30:1705366–170537210.1002/adma.201705366 ↗
25. Jiang YM, Li X, Wang TX, Wang CM (2016) Enhanced electrocatalytic oxygen evolution of α-Co(OH)2 nanosheets on carbon nanotube/polyimide films. Nanoscale 8:9667–967510.1039/C6NR00614K ↗
26. Jiang DF, Chu ZY, Peng JM, Luo JY, Mao YY, Yang PQ, Jin WQ (2018) One-step synthesis of three-dimensional Co(OH)2/rGO nano-flowers as enzyme-mimic sensors for glucose detection. Electrochim Acta 270:147–15510.1016/j.electacta.2018.03.066 ↗
27. Rahimi SA, Norouzi P, Ganjali MR (2018) One-step cathodic electrodeposition of a cobalt hydroxide–graphene nanocomposite and its use as a high performance supercapacitor electrode material. RSC Adv 8:26818–2682710.1039/C8RA04105A ↗
28. Liu PF, Li X, Yang S, Zu MY, Liu P, Zhang B, Zheng LR, Zhao H, Yang HG (2017) Ni2P(O)/Fe2P(O) interface can boost oxygen evolution electrocatalysis. ACS Energy Lett 2:2257–226310.1021/acsenergylett.7b00638 ↗
29. Cai JM, Ruffieux P, Jaafar R, Bieri M, Braun T, Blankenburg S, Muoth M, Seitsonen AP, Saleh M, Feng XL, Müllen K, Fasel R (2010) Atomically precise bottom-up fabrication of graphene nanoribbons. Nature 466:470–47310.1038/nature09211 ↗
30. Yan QM, Huang B, Yu J, Zheng FW, Zang J, Wu J, Gu BL, Liu F, Duan WH (2007) Intrinsic current-voltage characteristics of graphene nanoribbon transistors and effect of edge doping. Nano Lett 7:1469–147310.1021/nl070133j ↗
31. Li PP, Zheng YP, Shi T, Wang YD, Li MZ, Chen C, Zhang JX (2016) A solvent-free graphene oxide nanoribbon colloid as filler phase for epoxy-matrix composites with enhanced mechanical, thermal and tribological performance. Carbon 96:40–4810.1016/j.carbon.2015.09.035 ↗
32. Zehtab YA, Chizari K, Jalilov AS, Tour J, Sundararaj U (2015) Helical and dendritic unzipping of carbon nanotubes: a route to nitrogen-doped graphene nanoribbons. ACS Nano 9:5833–584510.1021/acsnano.5b02197 ↗
33. John R, Shinde DB, Liu L, Ding F, Xu Z, Vijayan C, Pillai VK, Pradeep T (2014) Sequential electrochemical unzipping of single-walled carbon nanotubes to graphene ribbons revealed by in situ raman spectroscopy and imaging. ACS Nano 8:234–24210.1021/nn403289g ↗
34. Higginbotham AL, Kosynkin DV, Alexander S, Zhengzong S, Tour JM (2010) Lower-defect graphene oxide nanoribbons from multiwalled carbon nanotubes. ACS Nano 4:2059–206910.1021/nn100118m ↗
35. Dimiev AM, Khannanov A, Vakhitov I, Kiiamov A, Shukhina K, Tour JM (2018) Revisiting the mechanism of oxidative unzipping of multiwall carbon nanotubes to graphene nanoribbons. ACS Nano 12:3985–399310.1021/acsnano.8b01617 ↗
36. Fortunato GV, Lima FD, Maia G (2016) Oxygen-reduction reaction strongly electrocatalyzed by Pt electrodeposited onto graphene or graphene nanoribbons. J Power Sources 302:247–25810.1016/j.jpowsour.2015.10.069 ↗
37. Long JL, Xie XQ, Xu J, Gu Q, Chen LM, Wang XX (2012) Nitrogen-doped graphene nanosheets as metal-free catalysts for aerobic selective oxidation of benzylic alcohols. ACS Catal 2:622–63110.1021/cs3000396 ↗
38. Xie H, Tang SC, Gong ZL, Vongehr S, Fang F, Li M, Meng XK (2014) 3D nitrogen-doped graphene/Co(OH)2-nanoplate composites for high-performance electrochemical pseudocapacitors. RSC Adv 4:61753–6175810.1039/C4RA10333E ↗
39. Liu ZP, Ma RZ, Osada M, Takada K, Sasaki T (2005) Selective and controlled synthesis of α-and β-cobalt hydroxides in highly developed hexagonal platelets. J Am Chem Soc 127:13869–1387410.1021/ja0523338 ↗
40. Yang ZB, Liu MK, Zhang C, Tjiu WW, Liu TX, Peng HS (2013) Carbon nanotubes bridged with graphene nanoribbons and their use in high-efficiency dye-sensitized solar cells. Angew Chem Int Ed 52:3996–399910.1002/anie.201209736 ↗
41. Wu ZL, Li CK, Yu JG, Chen XQ (2017) MnO2/reduced graphene oxide nanoribbons: facile hydrothermal preparation and their application in amperometric detection of hydrogen peroxide. Sens Actuators, B 239:544–55210.1016/j.snb.2016.08.062 ↗
42. Aghazadeh M, Shiri HM, Barmi AAM (2013) Uniform Co(OH)2 disc-like nanostructures prepared by low-temperature electrochemical rout as an electrode material for supercapacitors. Appl Surf Sci 273:237–24210.1016/j.apsusc.2013.02.021 ↗
43. Chen S, Qiao SZ (2013) Hierarchically porous nitrogen-doped graphene-NiCo2O4 hybrid paper as an advanced electrocatalytic water-splitting material. ACS Nano 7:10190–1019610.1021/nn404444r ↗
44. Fan XB, Peng WC, Li Y, Li XY, Wang SL, Zhang GL, Zhang FB (2010) Deoxygenation of exfoliated graphite oxide under alkaline conditions: a green route to graphene preparation. Adv Mater 20:4490–449310.1002/adma.200801306 ↗
45. Zhang LJ, Zheng R, Li S, Liu BK, Wang DJ, Wang LL, Xie TF (2014) Enhanced photocatalytic H2 generation on cadmium sulfide nanorods with cobalt hydroxide as cocatalyst and insights into their photogenerated charge transfer properties. ACS Appl Mater Interfaces 6:13406–1341210.1021/am501216b ↗