journal article·2016-04

Transparent cellulose/Laponite nanocomposite films

Wentao Wu, Zhi Dong, Jiasong He, Jian Yu, Jun Zhang

Journal of Materials Science· Volume 51· Issue 8
Publisher page

Abstract

As a biorenewable resource, cellulose is widely used in our life in the form of films and fibers after dissolution-regeneration process. In this paper, cellulose/Laponite nanocomposite films were prepared from microcrystalline cellulose (MCC) and Laponite via a solution blending process by using a green solvent, 1-allyl-3-methylimidazolium chloride ionic liquid, to dissolve MCC effectively and disperse Laponite layers homogeneously. The dispersion of layered Laponite nanoparticles up to 5 wt% in MCC matrix was investigated by scanning electron microscopy, transmission electron microscopy, atomic force microscopy, X-ray diffraction, and Fourier-transform infrared spectroscopy. The results showed that the best dispersion was obtained for 1 wt% content of Laponite. The optical properties, tensile strength, and thermal stability of regenerated MCC/Laponite composite films depended on the dispersion of Laponite in MCC matrix. The MCC/Laponite film up to 3 wt% Laponite showed increased tensile strength, elongation at break, and thermal stability, retaining high transmittance above 80 % at 800 nm.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Advanced Cellulose Research Studies · Aerogels and thermal insulation · Nanocomposite Films for Food Packaging

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (30)

Show source-provided references
1. Klemm D, Heublein B, Fink HP, Bohn A (2005) Cellulose: fascinating biopolymer and sustainable raw material. Angew Chem Int Edit 44:3358–339310.1002/anie.200460587 ↗
2. Swatloski RP, Spear SK, Holbrey JD, Rogers RD (2002) Dissolution of cellose with ionic liquids. J Am Chem Soc 124:4974–497510.1021/ja025790m ↗
3. Wu J, Zhang J, Zhang H, He JS, Ren Q, Guo M (2004) Homogeneous acetylation of cellulose in a new ionic liquid. Biomacromolecules 5:266–26810.1021/bm034398d ↗
4. Zhang H, Wu J, Zhang J, He JS (2005) 1-allyl-3-methylimidazolium chloride room temperature ionic liquid: a new and powerful nonderivatizing solvent for cellulose. Macromolecules 38:8272–827710.1021/ma0505676 ↗
5. El Seoud OA, Koschella A, Fidale LC, Dorn S, Heinze T (2007) Applications of ionic liquids in carbohydrate chemistry: a window of opportunities. Biomacromolecules 8:2629–264710.1021/bm070062i ↗
6. Wang H, Gurau G, Rogers RD (2012) Ionic liquid processing of cellulose. Chem Soc Rev 41:1519–153710.1039/c2cs15311d ↗
7. Welton T (1999) Room-temperature ionic liquids. Solvents for synthesis and catalysis. Chem Rev 99:2071–208310.1021/cr980032t ↗
8. Cao Y, Li HQ, Zhang Y, Zhang J, He JS (2010) Structure and properties of novel regenerated cellulose films prepared from cornhusk cellulose in room temperature ionic liquids. J Appl Polym Sci 116:547–55410.1002/app.31273 ↗
9. Kosan B, Michels C, Meister F (2008) Dissolution and forming of cellulose with ionic liquids. Cellulose 15:59–6610.1007/s10570-007-9160-x ↗
10. Mahmoudian S, Wahit MU, Ismail AF, Yussuf AA (2012) Preparation of regenerated cellulose/montmorillonite nanocomposite films via ionic liquids. Carbohydr Polym 88:1251–125710.1016/j.carbpol.2012.01.088 ↗
11. Turner MB, Spear SK, Holbrey JD, Rogers RD (2004) Production of bioactive cellulose films reconstituted from ionic liquids. Biomacromolecules 5:1379–138410.1021/bm049748q ↗
12. Xu SS, Zhang J, He AH, Li JX, Zhang H, Han CC (2008) Electrospinning of native cellulose from nonvolatile solvent system. Polymer 49:2911–291710.1016/j.polymer.2008.04.046 ↗
13. Zhang H, Wang ZG, Zhang ZN, Wu J, Zhang J, He JS (2007) Regenerated-cellulose/multiwalled-carbon-nanotube composite fibers with enhanced mechanical properties prepared with the ionic liquid 1-allyl-3-methylimidazolium chloride. Adv Mater 19:698–70410.1002/adma.200600442 ↗
14. Soheilmoghaddam M, Wahit MU, Yussuf AA, Al-Saleh MA, Whye WT (2014) Characterization of bio regenerated cellulose/sepiolite nanocomposite films prepared via ionic liquid. Polym Test 33:121–13010.1016/j.polymertesting.2013.11.011 ↗
15. Hanid NA, Wahit MU, Guo QP, Mahmoodian S, Soheilmoghaddam M (2014) Development of regenerated cellulose/halloysites nanocomposites via ionic liquids. Carbohydr Polym 99:91–9710.1016/j.carbpol.2013.07.080 ↗
16. Kumar ASK, Kalidhasan S, Rajesh V, Rajesh N (2012) Application of cellulose-clay composite biosorbent toward the effective adsorption and removal of chromium from industrial wastewater. Ind Eng Chem Res 51:58–6910.1021/ie201349h ↗
17. Qi HS, Liu JW, Gao SL, Mader E (2013) Multifunctional films composed of carbon nanotubes and cellulose regenerated from alkaline-urea solution. J Mat Chem A 1:2161–216810.1039/C2TA00882C ↗
18. Soheilmoghaddam M, Wahit MU, Mahmoudian S, Hanid NA (2013) Regenerated cellulose/halloysite nanotube nanocomposite films prepared with an ionic liquid. Mater Chem Phys 141:936–94310.1016/j.matchemphys.2013.06.029 ↗
19. Yang QL, Saito T, Isogai A (2013) Transparent, flexible, and high-strength regenerated cellulose/saponite nanocomposite films with high gas barrier properties. J Appl Polym Sci 130:3168–317410.1002/app.39564 ↗
20. Avery RG, Ramsay JDF (1986) Colloidal properties of synthetic hectorite clay dispersions. 2. Light and samll-angle neutron-scattering. J Colloid Interface Sci 109:448–45410.1016/0021-9797(86)90322-X ↗
21. Thompson DW, Butterworth JT (1992) The nature of Laponite and its aqueous dispersions. J Colloid Interface Sci 151:236–24310.1016/0021-9797(92)90254-J ↗
22. Loginov M, Lebovka N, Vorobiev E (2012) Laponite assisted dispersion of carbon nanotubes in water. J Colloid Interface Sci 365:127–13610.1016/j.jcis.2011.09.025 ↗
23. Cao Y, Wu J, Zhang J, Li H, Zhang Y, He J (2009) Room temperature ionic liquids (RTILs): a new and versatile platform for cellulose processing and derivatization. Chem Eng J 147:13–2110.1016/j.cej.2008.11.011 ↗
24. Lv YX, Wu J, Zhang JM, Niu YH, Liu CY, He JS, Zhang J (2012) Rheological properties of cellulose/ionic liquid/dimethylsulfoxide (DMSO) solutions. Polymer 53:2524–253110.1016/j.polymer.2012.03.037 ↗
25. Rein DM, Khalfin R, Szekely N, Cohen Y (2014) True molecular solutions of natural cellulose in the binary ionic liquid-containing solvent mixtures. Carbohydr Polym 112:125–13310.1016/j.carbpol.2014.05.059 ↗
26. Sun LF, Chen JY, Jiang W, Lynch V (2015) Crystalline characteristics of cellulose fiber and film regenerated from ionic liquid solution. Carbohy Polym 118:150–15510.1016/j.carbpol.2014.11.008 ↗
27. Palkova H, Madejova J, Zimowska M, Serwicka EM (2010) Laponite-derived porous clay heterostructures: II. FTIR study of the structure evolution. Microporous Mesoporous Mat 127:237–24410.1016/j.micromeso.2009.07.012 ↗
28. Oh SY, Yoo DI, Shin Y, Seo G (2005) FTIR analysis of cellulose treated with sodium hydroxide and carbon dioxide. Carbohydr Res 340:417–42810.1016/j.carres.2004.11.027 ↗
29. Yuan ZW, Fan QR, Dai XN, Zhao C, Zhang JJ, Xu GY, Qin MH (2014) Cross-linkage effect of cellulose/laponite hybrids in aqueous dispersions and solid films. Carbohydr Polym 102:431–43710.1016/j.carbpol.2013.11.051 ↗
30. Hedicke-Hochstotter K, Lim GT, Altstadt V (2009) Novel polyamide nanocomposites based on silicate nanotubes of the mineral halloysite. Composite Sci Tech 69:330–33410.1016/j.compscitech.2008.10.011 ↗