journal article·2015-06

In situ random co-polycondensation for preparation of reduced graphene oxide/polyimide nanocomposites with amino-modified and chemically reduced graphene oxide

Wen-Qiu Chen, Quan-Tao Li, Peng-Hui Li, Quan-Yuan Zhang, Zu-Shun Xu, Paul K. Chu, Xian-Bao Wang, Chang-Feng Yi

Journal of Materials Science· Volume 50· Issue 11
Publisher page

Abstract

Reduced graphene oxide/polyimide (rGO/PI) nanocomposites are prepared via in situ random co-polycondensation of amino-modified and chemically reduced graphene oxide (rGO-NH2) with commercial diamine and dianhydrides. The chemical modification and reduction of graphene oxide (GO) endows rGO-NH2 with good solubility in organic solvents to prepare rGO/PI nanocomposites with high filler contents. rGO-NH2 is further used as a functional co-monomer to participate the polymerization of PI with full compatibility of the guest and host in molecular level. With the addition of rGO-NH2 at 2 wt% content, the thermal, mechanical properties, and hydrophobicities of rGO/PI nanocomposites are significantly enhanced with various indicators achieving or approaching the optimum. The positive or negative impacts of rGO-NH2 with various contents to the properties of the obtained nanocomposites are also illustrated incidentally from micromorphology. This effective approach provides a possibility for developing high-performance PI composites based on graphene for advanced engineering or functional materials.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Graphene research and applications · Graphene and Nanomaterials Applications · Synthesis and properties of polymers

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (42)

Show source-provided references
1. Liaw D-J, Wang K-L, Huang Y-C, Lee K-R, Lai J-Y, Ha C-S (2012) Advanced polyimide materials: syntheses, physical properties and applications. Prog Polym Sci 37:907–97410.1016/j.progpolymsci.2012.02.005 ↗
2. Zhang Q-H, Dai M, Ding M-X, Chen D-J, Gao L-X (2004) Mechanical properties of BPDA-ODA polyimide fibers. Eur Polym J 40:2487–249310.1016/j.eurpolymj.2004.06.020 ↗
3. Liu Y, Xing Y, Zhang Y, Guan S, Zhang H, Wang Y, Wang Y, Jiang Z (2010) Novel soluble fluorinated poly(ether imide)s with different pendant groups: synthesis, thermal, dielectric, and optical properties. J Polym Sci A 48:3281–328910.1002/pola.24111 ↗
4. Hasegawa M, Hirano D, Fujii M, Haga M, Takezawa E, Yamaguchi S, Ishikawa A, Kagayama T (2013) Solution-processable colorless polyimides derived from hydrogenated pyromellitic dianhydride with controlled steric structure. J Polym Sci A 51:575–59210.1002/pola.26407 ↗
5. Halim A, Gurr PA, Blencowe A, Bryant G, Kentish SE, Qiao GG (2013) Synthesis and self-assembly of polyimide/poly(dimethylsiloxane) brush triblock copolymers. Polymer 54:520–52910.1016/j.polymer.2012.12.027 ↗
6. Jia X, Zhang Q, Zhao M-Q, Xu G-H, Huang J-Q, Qian W, Lu Y, Wei F (2012) Dramatic enhancements in toughness of polyimide nanocomposite via long-CNT-induced long-range creep. J Mater Chem 22:7050–705610.1039/c2jm15359a ↗
7. Chen D, Liu T, Zhou X, Tjiu WC, Hou H (2009) Electrospinning fabrication of high strength and toughness polyimide nanofiber membranes containing multiwalled carbon nanotubes. J Phys Chem B 113:9741–974810.1021/jp9025128 ↗
8. Delozier DM, Watson KA, Smith JG Jr, Clancy TC, Connell JW (2006) Investigation of aromatic/aliphatic polyimides as dispersants for single wall carbon nanotubes. Macromolecules 39:1731–173910.1021/ma051826u ↗
9. Gunasekaran SG, Rajakumar K, Alagar M, Dharmendirakumar M (2014) Siloxane core dianhydride modified ether linked cyclohexyl diamine based multi-walled carbon nanotube reinforced polyimide (MWCNT/PI) nanocomposites. J Polym Res 21:34210.1007/s10965-013-0342-y ↗
10. Loh KP, Bao Q, Anga PK, Yang J (2010) The chemistry of graphene. J Mater Chem 20:2277–228910.1039/b920539j ↗
11. Yang SY, Ma CCM, Teng CC, Huang YW, Liao SH, Huang YL, Tien HW, Lee TM, Chiou KC (2010) Effect of functionalized carbon nanotubes on the thermal conductivity of epoxy composites. Carbon 48:592–60310.1016/j.carbon.2009.08.047 ↗
12. Stankovich S, Dikin DA, Dommett GHB, Kohlhaas KM, Zimney EJ, Stach EA, Piner RD, Nguyen SBT, Ruoff RS (2006) Graphene-based composite materials. Nature 442:282–28610.1038/nature04969 ↗
13. Bai H, Li C, Shi G (2011) Functional composite materials based on chemically converted graphene. Adv Mater 23:1089–111510.1002/adma.201003753 ↗
14. Dreyer DR, Park S, Bielawski CW, Ruoff RS (2010) The chemistry of graphene oxide. Chem Soc Rev 39:228–24010.1039/B917103G ↗
15. Gao W, Alemany LB, Ci L, Ajayan PM (2009) New insights into the structure and reduction of graphite oxide. Nat Chem 1:403–40810.1038/nchem.281 ↗
16. Chen D, Zhu H, Liu T (2010) In situ thermal preparation of polyimide nanocomposite films containing functionalized grapheme sheets. ACS Appl Mater Interfaces 2:3702–370810.1021/am1008437 ↗
17. Huang T, Lu R, Su C, Wang H, Guo Z, Liu P, Huang Z, Chen H, Li T (2012) Chemically modified graphene/polyimide composite films based on utilization of covalent bonding and oriented distribution. ACS Appl Mater Interfaces 4:2699–270810.1021/am3003439 ↗
18. Luong ND, Hippi U, Korhonen JT, Soininen AJ, Ruokolainen J, Johansson L-S, Nam J-D, Sinh LH, Seppälä J (2011) Enhanced mechanical and electrical properties of polyimide film by grapheme sheets via in situ polymerization. Polymer 52:5237–524210.1016/j.polymer.2011.09.033 ↗
19. Qian Y, Lan Y-F, Xu J-P, Ye F-C, Dai S-Z (2014) Fabrication of polyimide-based nanocomposites containing functionalized graphene oxide nanosheets by in situ polymerization and their properties. Appl Surf Sci 314:991–99910.1016/j.apsusc.2014.06.130 ↗
20. Liu H, Li Y, Wang T, Wang Q (2012) In situ synthesis and thermal, tribological properties of thermosetting polyimide/graphene oxide nanocomposites. J Mater Sci 47:1867–1874. doi: 10.1007/s10853-011-5975-910.1007/s10853-011-5975-9 ↗
21. Kim GY, Choi M-C, Lee D, Ha C-S (2012) 2D-Aligned graphene sheets in transparent polyimide/graphene nanocomposite films based on noncovalent interactions between poly(amic acid) and graphene carboxylic acid. Macromol Mater Eng 297:303–31110.1002/mame.201100211 ↗
22. Pramoda KP, Mya KY, Lin TT, Lu X, He C (2012) Investigation of thermomechanical properties and matrix-filler interaction on polyimide/graphene oxide composites. Polym Eng Sci 52:2530–253610.1002/pen.23208 ↗
23. Tseng IH, Chang J-C, Huang S-L, Tsai M-H (2012) Enhanced thermal conductivity and dimensional stability of flexible polyimide nanocomposite film by addition of functionalized graphene oxide. Polym Int 62:827–83510.1002/pi.4375 ↗
24. Dong J, Yin C, Zhao X, Li Y, Zhang Q (2012) High strength polyimide fibers with functionalized grapheme. Polymer 54:6415–642410.1016/j.polymer.2013.09.035 ↗
25. Wang J-Y, Yang S-Y, Huang Y-L, Tien H-W, Chin W-K, Ma C-M (2011) Preparation and properties of graphene oxide/polyimide composite films with low dielectric constant and ultrahigh strength via in situ polymerization. J Mater Chem 21:13569–1357510.1039/c1jm11766a ↗
26. Zhang L-B, Wang J-Q, Wang H-G, Xu Y, Wang Z-F, Li Z-P, Mi Y-J, Yang S-R (2012) Preparation, mechanical and thermal properties of functionalized graphene/polyimide nanocomposites. Compos A 43:1537–154510.1016/j.compositesa.2012.03.026 ↗
27. Cao L, Sun Q-Q, Wang H-X, Zhang X-X, Shi H-F (2015) Enhanced stress transfer and thermal properties of polyimide composites with covalent functionalized reduced graphene oxide. Compos A 68:140–14810.1016/j.compositesa.2014.10.007 ↗
28. Yoonessi M, Shi Y, Scheiman DA, Lebron-Colon M, Tigelaar DM, Weiss RA, Meador MA (2012) Graphene polyimide nanocomposites; thermal, mechanical, and high-temperature shape memory effects. ACS Nanotechnol 6:7644–7655
29. Kong J-Y, Choi M-C, Kim GY, Park JJ, Selvaraj M, Han M, Ha C-S (2012) Preparation and properties of polyimide/graphene oxide nanocomposite films with Mg ion crosslinker. Eur Polym J 48:1394–140510.1016/j.eurpolymj.2012.05.015 ↗
30. Park S, Ruoff RS (2009) Chemical methods for the production of graphenes. Nat Nanotechnol 4:217–22410.1038/nnano.2009.58 ↗
31. Paredes JI, Villar-Rodil S, Martinez-Alonso A, Tascon JMD (2008) Graphene oxide dispersions in organic solvents. Langmuir 24:10560–1056410.1021/la801744a ↗
32. Stankovich S, Dikin DA, Piner RD, Kohlhaas KA, Kleinhammes A, Jia Y, Wu Y, Nguyen ST, Ruoff RS (2007) Synthesis of graphene-based nanosheets via chemical reduction of exfoliated graphite oxide. Carbon 45:1558–156510.1016/j.carbon.2007.02.034 ↗
33. Wang J-C, Wang X-B, Wan L, Yang Y-K, Wang S-M (2010) An effective method for bulk obtaining graphene oxide solids. Chin J Chem 28:1935–194010.1002/cjoc.201090322 ↗
34. Yang H, Li F, Shan C, Han D, Zhang Q, Niu L, Ivaska A (2009) Covalent functionalization of chemically converted graphene sheets via silane and its reinforcement. J Mater Chem 19:4632–463810.1039/b901421g ↗
35. Stankovich S, Piner RD, Chen X, Wu N, Nguyen ST, Ruoff RS (2006) Stable aqueous dispersions of graphitic nanoplatelets via the reduction of exfoliated graphite oxide in the presence of poly(sodium 4-styrenesulfonate). J Mater Chem 16:155–15810.1039/B512799H ↗
36. Zhu YW, Murali S, Cai WW, Li XS, Suk JW, Potts JR, Ruoff RS (2010) Graphene and graphene oxide: synthesis, properties, and applications. Adv Mater 22:3906–392410.1002/adma.201001068 ↗
37. Luong ND, Pahimanolis N, Hippi U, Korhonen JT, Ruokolainen J, Johansson LS, Nam JD, Seppälä J (2011) Graphene/cellulose nanocomposite paper with high electrical and mechanical performances. J Mater Chem 21:13991–1399810.1039/c1jm12134k ↗
38. Yang D, Velamakanni A, Bozoklu G, Park S, Stoller M, Piner RD, Stankovich S, Jung I, Field DA, Ventrice CA Jr, Ruoff RS (2009) Chemical analysis of graphene oxide films after heat and chemical treatments by X-ray photoelectron and micro-raman spectroscopy. Carbon 47:145–15210.1016/j.carbon.2008.09.045 ↗
39. Ferrari AC (2007) Raman spectroscopy of graphene and graphite: disorder, electron-phonon coupling, doping and nonadiabatic effects. Solid State Commun 143:47–5710.1016/j.ssc.2007.03.052 ↗
40. Ha HW, Choudhury A, Kamal T, Kim D-H, Park S-Y (2012) Effect of chemical modification of graphene on mechanical, electrical, and thermal properties of polyimide/graphene nanocomposites. ACS Appl Mater Interfaces 4:4623–463010.1021/am300999g ↗
41. Zhao X, Zhang Q, Chen D, Lu P (2010) Enhanced mechanical properties of graphene-based poly(vinyl alcohol) composites. Macromolecules 43:2357–236310.1021/ma902862u ↗
42. Zhang X, Wan S, Pu J, Wang L, Liu X (2011) Highly hydrophobic and adhesive performance of graphene films. J Mater Chem 21:12251–1225810.1039/c1jm12087e ↗