Barocaloric effect associated with magneto-structural transformation studied by an effectively indirect method for the Ni58.3Mn17.1Ga24.6 Heusler alloy
Source abstract
Abstract
In the present work, we report the dependence of magnetization on hydrostatic pressure for the non-stoichiometric Ni58.3Mn17.1Ga24.6 alloy, which undergoes the transformation from a paramagnetic austenite to a ferromagnetic martensite near room temperature. It is found that the application of pressure can push the martensitic transformation (MT) to a higher temperature at a rate of 4 K GPa−1. Considering the change of phase fraction under the isothermal condition caused by pressure-induced MT, we develop an indirect method based on magnetic data measured under various pressures to determine the barocaloric effect (BCE) for the studied alloy. When the change of the applied hydrostatic pressure reaches 1.05 GPa, the maximum isothermal entropy change $$ \Delta S_{\text{T}} $$ is calculated to be about −13.6 J kg−1 K−1, yielding a value of 2.8 K for the adiabatic temperature change $$ \Delta T_{\text{ad}} $$ near room temperature. These values are comparable to those obtained in many alloys of the same series by using superconducting magnets. Such a considerable BCE can be attributed to the fact that the MT can be driven more easily by the pressure-induced crystallographic change than by the magnetic field-induced spin–lattice coupling.
Source: openaire · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Shape Memory Alloy Transformations · Magnetic and transport properties of perovskites and related materials · Magnetic Properties and Applications
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (52)
Show source-provided references
1. Pecharsky VK, Gschneidner KA Jr (1997) Giant magnetocaloric effect in Gd5(Si2Ge2). Phys Rev Lett 78:4494–449710.1103/PhysRevLett.78.4494 ↗
2. Tegus O, Brück E, Buschow KHJ, de Boer FR (2002) Transition-metal-based magnetic refrigerants for room-temperature applications. Nature 415:150–15210.1038/415150a ↗
3. Tishin AM, Spichkin YI (2003) The magnetocaloric effect and its applications. Institute of Physics Publishing, Bristol10.1887/0750309229 ↗
4. Gschneidner KA Jr, Pecharsky VK, Tsokol AO (2005) Recent developments in magnetocaloric materials. Rep Prog Phys 68:1479–153910.1088/0034-4885/68/6/R04 ↗
5. de Oliveira NA, von Ranke PJ (2010) Theoretical aspects of the magnetocaloric effect. Phys Rep 489:89–15910.1016/j.physrep.2009.12.006 ↗
6. Liu J, Gottschall T, Skokov KP, Moore JD, Gutfleisch O (2012) Giant magnetocaloric effect driven by structural transitions. Nat Mater 11:620–62610.1038/nmat3334 ↗
7. Mischenko AS, Zhang Q, Whatmore RW, Scott JF, Mathur ND (2006) Giant electrocaloric effect in the thin film relaxor ferroelectric 0.9PbMg1/3Nb2/3O3–0.1PbTiO3 near room temperature. Appl Phys Lett 89:242912–1–242912–310.1063/1.2405889 ↗
8. Neese B, Chu BJ, Lu SG, Wang Y, Furman E, Zhang QM (2008) Large electrocaloric effect in ferroelectric polymers near room temperature. Science 321:821–82310.1126/science.1159655 ↗
9. Kaddoussi H, Gagou Y, Lahmar A, Allouche B, Dellis JL, Courty M, Khemakhem H, El Marssi M (2016) Ferroelectric phase changes and electrocaloric effects in Ba(Zr0.1Ti0.9)1−x Sn x O3 ceramics solid solution. J Mater Sci 51:3454–3462. doi: 10.1007/s10853-015-9663-z10.1007/s10853-015-9663-z ↗
10. Nikitin SA, Myalikgulyev G, Annaorazov MP, Tyurin AL, Myndyev RW, Akopyan SA (1992) Giant elastocaloric effect in FeRh alloy. Phys Lett A 171:234–23610.1016/0375-9601(92)90432-L ↗
11. Bonnot E, Romero R, Mañosa L, Vives E, Planes A (2008) Elastocaloric effect associated with the martensitic transition in shape-memory alloys. Phys Rev Lett 100:125901–1–125901–410.1103/PhysRevLett.100.125901 ↗
12. Sun W, Liu J, Lu BF, Li Y, Yan A (2016) Large elastocaloric effect at small transformation strain in Ni45Mn44Sn11 metamagnetic shape memory alloys. Scr Mater 114:1–410.1016/j.scriptamat.2015.11.021 ↗
13. Strässle Th, Furrer A, Müller KA (2000) Cooling by adiabatic application of pressure-the barocaloric effect. Phys B 276–278:944–94510.1016/S0921-4526(99)01288-0 ↗
14. de Oliveira NA (2007) Entropy change upon magnetic field and pressure variations. Appl Phys Lett 90:052501–1–052501–310.1063/1.2434154 ↗
15. Mañosa L, González-Alonso D, Planes A, Bonnot E, Barrio M, Tamarit J-L, Aksoy S, Acet M (2010) Giant solid-state barocaloric effect in the Ni–Mn–In magnetic shape-memory alloy. Nat Mater 9:478–48110.1038/nmat2731 ↗
16. Mañosa L, González-Alonso D, Planes A, Barrio M, Tamarit J-L, Titov IS, Acet M, Bhattacharyya A, Majumdar S (2011) Inverse barocaloric effect in the giant magnetocaloric La–Fe–Si–Co compound. Nat Commun 2:595–1–595–510.1038/ncomms1606 ↗
17. Yuce S, Barrio M, Emre B, Stern-Taulats E, Planes A, Tamarit J-L, Mudryk Y, Gschneidner KA Jr, Pecharsky VK, Mañosa L (2012) Barocaloric effect in the magnetocaloric prototype Gd5Si2Ge2. Appl Phys Lett 101:071906–1–071906–510.1063/1.4745920 ↗
18. Moya X, Kar-Narayan S, Mathur ND (2014) Caloric materials near ferroic phase transitions. Nat Mater 13:439–45010.1038/nmat3951 ↗
19. Wu RR, Bao LF, Hu FX, Wu H, Huang QZ, Wang J, Dong XL, Li GN, Sun JR, Shen FR, Zhao TY, Zheng XQ, Wang LC, Liu Y, Zuo WL, Zhao YY, Zhang M, Wang XC, Jin CQ, Rao GH, Han XF, Shen BG (2015) Giant barocaloric effect in hexagonal Ni2In-type Mn–Co–Ge–In compounds around room temperature. Sci Rep 5:18027–1–18027–10
20. Matsunami D, Fujita A, Takenaka K, Kano M (2015) Giant barocaloric effect enhanced by the frustration of the antiferromagnetic phase in Mn3GaN. Nat Mater 14:73–1–73–610.1038/nmat4117 ↗
21. Lloveras P, Stern-Taulats E, Barrio M, Tamarit J-L, Crossley S, Li W, Pomjakushin V, Planes A, Mañosa L, Mathur ND, Moya X (2015) Giant barocaloric effects at low pressure in ferrielectric ammonium sulphate. Nat Commun 6:8801–1–8801–610.1038/ncomms9801 ↗
22. Ullakko K, Huang JK, Kantner C, O’Handley RC, Kokorin VV (1996) Large magnetic-field-induced strains in Ni2MnGa single crystals. Appl Phys Lett 69:1966–196810.1063/1.117637 ↗
23. Hu FX, Shen BG, Sun JR (2000) Magnetic entropy change in Ni515Mn227Ga258 alloy. Appl Phys Lett 76:3460–346210.1063/1.126677 ↗
24. Barandiarán JM, Chernenko VA, Lázpita P, Gutiérrez J, Feuchtwanger J (2009) Effect of martensitic transformation and magnetic field on transport properties of Ni–Mn–Ga and Ni–Fe–Ga Heusler alloys. Phys Rev B 80:104404–1–104404–710.1103/PhysRevB.80.104404 ↗
25. Vasil’ev AN, Bozhko AD, Khovailo VV, Dikshtein IE, Shavrov VG, Buchelnikov VD, Matsumoto M, Suzuki S, Takagi T, Tani J (1999) Structural and magnetic phase transitions in shape-memory alloys Ni2+x Mn1−x Ga. Phys Rev B 59:1113–112010.1103/PhysRevB.59.1113 ↗
26. Jiang CB, Muhammad Y, Deng LF, Wu W, Xu HB (2004) Composition dependence on the martensitic structures of the Mn-rich NiMnGa alloys. Acta Mater 52:2779–278510.1016/j.actamat.2004.02.024 ↗
27. Pasquale M, Sasso CP, Lewis LH, Giudici L, Lograsso T, Schlagel D (2005) Magnetostructural transition magnetocaloric effect in Ni55Mn20Ga25 single crystals. Phys Rev B 72:094435–1–094435–510.1103/PhysRevB.72.094435 ↗
28. Long Y, Zhang ZY, Wen D, Wu GH, Ye RC, Chang YQ, Wan FR (2005) Phase transition processes and magnetocaloric effects in the Heusler alloys NiMnGa with concurrence of magnetic and structural phase transition. J Appl Phys 98:046102–1–046102–310.1063/1.1991995 ↗
29. Stadler S, Khan M, Mitchell J, Ali N, Gomes AM, Dubenko I, Takeuchi AY, Guimarães AP (2006) Magnetocaloric properties of Ni2Mn1−x Cu x Ga. Appl Phys Lett 88:192511–1–192511–310.1063/1.2202751 ↗
30. Li ZB, Sánchez Llamazares JL, Sánchez-Valdés CF, Zhang YD, Esling C, Zhao X, Zuo L (2012) Microstructure and magnetocaloric effect of melt-spun Ni52Mn26Ga22 ribbon. Appl Phys Lett 100:174102–1–174102–4
31. Li ZB, Zhang YD, Sánchez-Valdés CF, Sánchez Llamazares JL, Esling C, Zhao X, Zuo L (2014) Giant magnetocaloric effect in melt-spun Ni–Mn–Ga ribbons with magneto-multistructural transformation. Appl Phys Lett 104:044101–1–044101–5
32. Li Z, Yang HM, Xu K, Zhang YL, Zheng D, Jing C (2016) Magnetocaloric and negative thermal expansion effects for Ni55.5Mn19.5Ga25 Heusler alloy with magneto-structural transition. Mater Chem Phys 180:156–16010.1016/j.matchemphys.2016.05.056 ↗
33. Kamarád J, Albertini F, Arnold Z, Casoli F, Pareti L, Paoluzi A (2005) Effect of hydrostatic pressure on magnetization of Ni2+x Mn1−x Ga alloys. J Magn Magn Mater 290–291:669–67210.1016/j.jmmm.2004.11.332 ↗
34. Albertini F, Kamaraád J, Arnold Z, Pareti L, Villa E, Righi L (2007) Pressure effects on the magnetocaloric properties of Ni-rich and Mn-rich Ni2MnGa alloys. J Magn Magn Mater 316:364–36710.1016/j.jmmm.2007.03.020 ↗
35. Mandal K, Pal D, Scheerbaum N, Lyubina J, Gutfleisch O (2009) Effect of pressure on the magnetocaloric properties of nickel-rich Ni–Mn–Ga Heusler alloys. J Appl Phys 105:073509–1–073509–6
36. Devarajan U, Esakki Muthu S, Arumugam Sanjay Singh S, Barman SR (2013) Investigation of the influence of hydrostatic pressure on the magnetic and magnetocaloric properties of Ni2–x Mn1–x Ga (x = 0, 0.15) Heusler alloys. J Appl Phys 114:053906–1–053906–610.1063/1.4817250 ↗
37. Mañosa L, Planesa A, Acet M (2013) Advanced materials for solid-state refrigeration. J Mater Chem A 1:4925–493610.1039/c3ta01289a ↗
38. Stern-Taulats E, Planes A, Lloveras P, Barrio M, Tamarit J-L, Pramanick S, Majumdar S, Yüce S, Emre B, Frontera C, Mañosa L (2015) Tailoring barocaloric and magnetocaloric properties in low–hysteresis magnetic shape memory alloys. Acta Mater 96:324–33210.1016/j.actamat.2015.06.026 ↗
39. Mañosa L, Stern-Taulats E, Planes A, Lloveras P, Barrio M, Tamarit J-L, Emre B, Yüce S, Fabbrici S, Albertini F (2014) Barocaloric effect in metamagnetic shape memory alloys. Phys Status Solidi B 251:2114–211910.1002/pssb.201350371 ↗
40. Krenke T, Duman E, Acet M, Wassermann EF, Moya X, Mañosa L, Planes A (2005) Inverse magnetocaloric effect in ferromagnetic Ni–Mn–Sn alloys. Nat Mater 4:450–45410.1038/nmat1395 ↗
41. Khan M, Ali N, Stadler S (2007) Inverse magnetocaloric effect in ferromagnetic Ni50Mn37+x Sb13−x Heusler. J Appl Phys 101:053919–1–053919–310.1063/1.2710779 ↗
42. Krenke T, Duman E, Acet M, Wassermann EF, Moya X, Mañosa L, Planes A, Suard E, Ouladdiaf B (2007) Magnetic superelasticity and inverse magnetocaloric effect in Ni–Mn–In. Phys Rev B 75:104414–1–104414–610.1103/PhysRevB.75.104414 ↗
43. Khovaylo VV, Skokov KP, Gutfleisch O, Miki H, Takagi T, Kanomata T, Koledov VV (2010) Peculiarities of the magnetocaloric properties in Ni–Mn–Sn ferromagnetic shape memory alloys. Phys Rev B 81:214406–1–214406–610.1103/PhysRevB.81.214406 ↗
44. Amano ME, Betancourt I, Sánchez Llamazares JL, Huerta L, Sánchez-Valdés CF (2014) Mixed-valence La0.80(Ag1–x Sr x )0.20MnO3 manganites with magnetocaloric effect. J Mater Sci 49:633–641. doi: 10.1007/s10853-013-7743-510.1007/s10853-013-7743-5 ↗
45. Cherif R, Hlil EK, Ellouze M, Elhalouani F, Obbade S (2014) Study of magnetic and magnetocaloric properties of La0.6Pr0.1Ba0.3MnO3 and La0.6Pr0.1Ba0.3Mn0.9Fe0.1O3 perovskite-type manganese oxides. J Mater Sci 49:8244–8251. doi: 10.1007/s10853-014-8533-410.1007/s10853-014-8533-4 ↗
46. Sasso CP, Pasquale M, Giudici L, Besseghini S, Villa E, Lewis LH, Lograsso TA, Schlagel DL (2006) Magnetostructural transitions and adiabatic temperature variation in polycrystal and single-crystal Ni2MnGa alloys. J Appl Phys 99:08K905–1–08K905–310.1063/1.2162335 ↗
47. Pasquale M, Sasso CP, Giudici L, Lograsso T, Schlagel D (2007) Field-driven structural phase transition and sign–switching magnetocaloric effect in Ni–Mn–Sn. Appl Phys Lett 91:131904–1–131904–310.1063/1.2790829 ↗
48. Khovaylo VV, Skokov KP, Koshkid’ko YS, Koledov VV, Shavrov VG, Buchelnikov VD, Taskaev SV, Miki H, Takagi T, Vasiliev AN (2008) Adiabatic temperature change at first-order magnetic phase transitions: Ni2.19Mn0.81Ga as a case study. Phys Rev B 78:060403–1–060403–410.1103/PhysRevB.78.060403 ↗
49. Buchelnikov VD, Sokolovskiy VV, Taskaev SV, Khovaylo VV, Aliev AA, Khanov LN, Batdalov AB, Entel P, Miki H, Takagi T (2011) Monte Carlo simulations of the magnetocaloric effect in magnetic Ni–Mn–X (X = Ga, In) Heusler alloys. J Phys D Appl Phys 44:064012–1–064012–1410.1088/0022-3727/44/6/064012 ↗
50. Kazakov AP, Prudnikov VN, Granovsky AB, Zhukov AP, Gonzalez J, Dubenko I, Pathak AK, Stadler S, Ali N (2011) Direct measurements of field-induced adiabatic temperature changes near compound phase transitions in Ni–Mn–In based Heusler alloys. Appl Phys Lett 98:131911–1–131911–310.1063/1.3574088 ↗
51. Porcari G, Fabbrici S, Pernechele C, Albertini F, Buzzi M, Paoluzi A, Kamarad J, Arnold Z, Solzi M (2012) Reverse magnetostructural transformation and adiabatic temperature change in Co- and In-substituted Ni–Mn–Ga alloys. Phys Rev B 85:024414–1–024414–710.1103/PhysRevB.85.024414 ↗
52. Porcari G, Cugini F, Fabbrici S, Pernechele C, Albertini F, Buzzi M, Mangia M, Solzi M (2012) Convergence of direct and indirect methods in the magnetocaloric study of first order transformations: the case of Ni–Co–Mn–Ga Heusler alloys. Phys Rev B 86:104432–1–104432–510.1103/PhysRevB.86.104432 ↗