journal article·2016-09

Quantifying structural and electromagnetic interference (EMI) shielding properties of thermoplastic polyurethane–carbon nanofiber/magnetite nanocomposites

Zehra Durmus, Ali Durmus, M. Yunus Bektay, Huseyin Kavas, Ibrahim Saim Unver, Bekir Aktas

Journal of Materials Science· Volume 51· Issue 17
Publisher page

Abstract

In this study, mixed-structure carbon–magnetite nanocomposites were prepared by decorating of carbon nanofiber (CNF) surfaces with magnetite (Fe3O4) nanoparticles synthesized via reflux method and characterized. The compositions of CNF–Fe3O4 nanocomposites were varied using different amounts of CNF into the Fe3O4 synthesis medium as 25/75, 50/50, and 75/25 (w/w). These nanocomposites were then used as functional fillers to prepare flexible, thermoplastic polyurethane (TPU)-based electromagnetic interference (EMI) shielding composites by solution mixing method. Structural features of fillers, morphological, and electromagnetic properties of flexible composites were studied. It was found that the magnetite nanoparticles with the average size of 8–10 nm were formed and successfully covered the oxidized CNF surfaces. It was also found that the resulting CNF–Fe3O4 nanocomposites exhibited sufficiently high saturation magnetization (Ms) values compared to Fe3O4. These CNF–Fe3O4 nanocomposites were embedded into TPU phase by employing the weight percent of 20 wt%. The flexible TPU–CNF–Fe3O4 nanocomposite having the composition of 80–5–15 wt% showed the reflection loss (RL) value of −32 dB which signified that the composite material could absorb the 97 % of an incident electromagnetic wave at around 12.14 GHz.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Electromagnetic wave absorption materials · Advanced Antenna and Metasurface Technologies

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (31)

Show source-provided references
1. Abbas SM, Chandra M, Verma A, Chatterjee R, Goel TC (2006) Complex permittivity and microwave absorption properties of a composite dielectric absorber. Composites A 37:2148–215410.1016/j.compositesa.2005.11.006 ↗
2. Das S, Nayak GC, Sahu SK, Routray PC, Roy AK, Baskey H (2015) Microwave absorption properties of double-layer composites using CoZn/NiZn/MnZn-ferrite and titanium dioxide. J Magnet Magnet Mater 377:111–11610.1016/j.jmmm.2014.10.059 ↗
3. Heo J., Choi D., Hong J., Layer-by-Layer self-assembled ferrite multilayer nanofilms for microwave absorption, J Nanomater. (2015) Article ID 16461910.1155/2015/164619 ↗
4. Tyagi S, Baskey HB, Agarwala RC, Agarwala V, Shami TC (2011) Development of hard/soft ferrite nanocomposite for enhanced microwave absorption. Ceram Int 37:2631–264110.1016/j.ceramint.2011.04.012 ↗
5. Della Pina C, Falletta E, Ferretti AM, Ponti A, Gentili GG, Verri V, Nesti R (2015) Microwave characterization of magnetically hard and soft ferrite nanoparticles in K-band. J Appl Phys 116:15430610.1063/1.4898138 ↗
6. Jacobo SE, Bercoff PG, Herme CA, Vives LA (2015) Sr hexaferrite/Ni ferrite nanocomposites: magnetic behavior and microwave absorbing properties in the X-band. Mater Chem Phys 157:124–12910.1016/j.matchemphys.2015.03.026 ↗
7. Ghodake JS, Kambale RC, Shinde TJ, Maskar PK, Suryavanshi SS (2016) Magnetic and microwave absorbing properties of Co2+ substituted nickel-zinc ferrites with the emphasis on initial permeability studies. J Magnet Magnet Mater 401:938–94210.1016/j.jmmm.2015.11.009 ↗
8. Gama AM, Rezende MC (2013) Complex permeability and permittivity variation of radar absorbing materials based on MnZn ferrite in microwave frequencies. Mater Res 16:997–100110.1590/S1516-14392013005000077 ↗
9. Durmus Z, Durmus A, Kavas H (2015) Synthesis and characterization of structural and magnetic properties of graphene/hard ferrite nanocomposites as microwave-absorbing material. J Mater Sci 50:1201–1213. doi: 10.1007/s10853-014-8676-310.1007/s10853-014-8676-3 ↗
10. Durmus Z, Kavas H, Durmus A, Aktas B (2015) Synthesis and micro-structural characterization of graphene/strontium hexaferrite (SrFe12O19) nanocomposites. Mater Chem Phys 163:439–44510.1016/j.matchemphys.2015.07.063 ↗
11. Verma M, Singh AP, Sambyal P, Singh BP, Dhawan SK, Choudhary V (2015) Barium ferrite decorated reduced graphene oxide nanocomposite for effective electromagnetic interference shielding. Chem Phys Phys Chem 17:1610–161810.1039/C4CP04284K ↗
12. Zhang Q, Zhu M, Zhang Q, Li Y, Wang H (2009) The formation of magnetite nanoparticles on the sidewalls of multi-walled carbon nanotubes. Comp Sci Tech 69:633–63810.1016/j.compscitech.2008.12.011 ↗
13. Zhang T, Huang D, Yang Y, Kanga F, Gub J (2013) Fe3O4/carbon composite nanofiber absorber with enhanced microwave absorption performance. Mater Sci Eng B 178:1–910.1016/j.mseb.2012.06.005 ↗
14. Chen D, Quan H, Huang Z, Luo S, Luo X, Deng F (2014) Electromagnetic and microwave absorbing properties of RGO@hematite core-shell nanostructure/PVDF composites. Comp Sci Tech 102:126–13110.1016/j.compscitech.2014.06.018 ↗
15. Yang R-B, Reddy PM, Chang C-J, Chen P-A, Chen J-K, Chang C-C (2016) Synthesis and characterization of Fe3O4/polypyrrole/carbon nanotube composites with tunable microwave absorption properties: role of carbon nanotube and polypyrrole content. Chem Eng J 285:497–50710.1016/j.cej.2015.10.031 ↗
16. Luo J, Xu Y, Yao W, Jiang C, Xu J (2015) Synthesis and microwave absorption properties of reduced graphene oxide-magnetic porous nanospheres-polyaniline composites. Comp Sci Tech 117:315–32110.1016/j.compscitech.2015.07.008 ↗
17. Stout DA (2015) Recent advancements in carbon nanofiber and carbon nanotube applications in drug delivery and tissue engineering. Current Pharm Design 21:2037–204410.2174/1381612821666150302153406 ↗
18. Adabi M, Saber R, Naghibzadeh M, Faridbod F, Faridi-Majidi R (2015) Parameters affecting carbon nanofiber electrodes for measurement of cathodic current in electrochemical sensors: an investigation using artificial neural network. RSC Adv 5:81243–8125210.1039/C5RA15541J ↗
19. Wang CJ, Chen TC, Lin J-H, Huang PR, Tsai HJ, Chen CS (2015) One-step preparation of hydrophilic carbon nanofiber containing magnetic Ni nanoparticles materials and their application in drug delivery. J Colloid Inter Sci 440:179–18810.1016/j.jcis.2014.10.073 ↗
20. Song MJ, Kim T, Kim YB, Shin MW (2015) Self-standing, binder-free electrospun Co3O4/carbon nanofiber composites for non-aqueous Li-air batteries. Electrochim Acta 182:289–29610.1016/j.electacta.2015.09.100 ↗
21. Bayat M, Yang H, Ko FK, Michelson D, Mei A (2014) Electromagnetic interference shielding effectiveness of hybrid multifunctional Fe3O4/carbon nanofiber composite. Polymer 55:936–94310.1016/j.polymer.2013.12.042 ↗
22. Panels JE, Lee J, Park KY, Kang SY, Marquez M, Wiesner U, Joo YL (2008) Synthesis and characterization of magnetically active carbon nanofiber/iron oxide composites with hierarchical pore structures. Nanotechnology 19:45561210.1088/0957-4484/19/45/455612 ↗
23. Pardavi-Horvath M (2000) Microwave applications of soft ferrites. J Magn Magn Mater 215–216:171–18310.1016/S0304-8853(00)00106-2 ↗
24. Özgür Ü, Alivov Y, Morkoç H (2009) Microwave ferrites, Part 1: fundamental properties. J Mater Sci-Mater Electron 20:789–83410.1007/s10854-009-9923-2 ↗
25. Peddis D, Cannas C, Musinu A, Ardu A, Orru F, Fiorani D, Lauretti S, Rinaldi D, Muscas G, Concas G, Piccaluga G (2013) Beyond the effect of particle size: influence of CoFe2O4 nanoparticle arrangements on magnetic properties. Chem Mater 25:2005–201310.1021/cm303352r ↗
26. Deraz NM (2010) Size and crystallinity-dependent magnetic properties of copper ferrite nano-particles. J Alloys Compd 501:317–32510.1016/j.jallcom.2010.04.096 ↗
27. Chia CH, Zakaria S, Yusoff M, Goh SC, Haw CY, Ahmadi Sh, Huang NM, Lim HN (2010) Size and crystallinity-dependent magnetic properties of CoFe2O4 nanocrystals. Ceramic Int 36:605–60910.1016/j.ceramint.2009.10.001 ↗
28. Raghavender AT, Zadro K, Pajic D, Skoko Z, Biliskov N (2010) Effect of grain size on the neel temperature of nanocrystalline nickel ferrite. Mater Let 64:1144–114610.1016/j.matlet.2010.02.031 ↗
29. Liu J, Zeng M, Yu R, Liu X, Zhu M (2014) Size influence to the high-frequency properties of granular magnetite nanoparticles. IEEE Trans Magn 50:2801304
30. Choudhury A, Kar P (2011) Doping effect of carboxylic acid group functionalized multi-walled carbon nanotube on polyaniline. Composites B 42:1641–164710.1016/j.compositesb.2011.04.005 ↗
31. Wejrzanowski T, Pielaszek R, Opalinska A, Matysiak H, Lojkowski W, Kurzydlowski KJ (2006) Quantitative methods for nanopowders characterization. Appl Surf Sci 253:204–20810.1016/j.apsusc.2006.05.089 ↗