journal article·2018-03

Controllable synthesis of Ho-doped In2O3 porous nanotubes by electrospinning and their application as an ethanol gas sensor

Haojie Duan, Yifang Wang, Shuo Li, Haiying Li, Li Liu, Liting Du, Yali Cheng

Journal of Materials Science· Volume 53· Issue 5
Publisher page

Abstract

Pure and Ho-doped In2O3 nanotubes (NTs) and porous nanotubes (PNTs) were successfully synthesized by conventional electrospinning process and the following calcination at different temperatures. X-ray diffractometry (XRD), thermogravimetric analysis (TGA), Raman spectrometer, energy-dispersive spectroscopy, scanning and transmission electron microscopy were carefully used to investigate the morphologies, structures and chemical compositions of these samples. Their sensing properties toward ethanol gas were studied. Compared with pure In2O3 NTs (response value is 17), pure In2O3 PNTs (response value is 20) demonstrated enhanced sensing characteristics. What’s more, the response of Ho-doped In2O3 PNTs sensors to 100 ppm ethanol was up to 60 at 240 °C, which increased three times more than that of the pure In2O3 PNTs. Additionally, the minimum concentration for ethanol was 200 ppb (response value is 2). The increased gas-sensing ability was attributed not only to the hollow and porous structure, but to the Ho dopant. Furthermore, Ho-doped In2O3 PNTs enable sensor to discriminate between ethanol and the other gas distinctly, particularly acetone that is usually indistinguishable from ethanol. Also, by analyzing XRD, TGA and Raman spectrometer, a possible formation mechanism of porous nanotubes and sensing mechanism were put forward.
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Research context

OpenAlex topics: Gas Sensing Nanomaterials and Sensors · Analytical Chemistry and Sensors · Advanced Chemical Sensor Technologies

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (50)

Show source-provided references
1. Guo L, Shen X, Zhu G, Chen K (2011) Sens Actuators B Chem 155:752. https://doi.org/10.1016/j.snb.2011.01.04210.1016/j.snb.2011.01.042 ↗
2. Wagner T, Haffer S, Weinberger C, Klaus D, Tiemann M (2013) Chem Soc Rev 42:4036. https://doi.org/10.1039/C2CS35379B10.1039/C2CS35379B ↗
3. Katoch A, Abideen ZU, Kim J-H, Kim SS (2016) Sens Actuators B Chem 232:698. https://doi.org/10.1016/j.snb.2016.04.01310.1016/j.snb.2016.04.013 ↗
4. Katoch A, Choi S-W, Kim SS (2014) Nanotechnology 25:455504. https://doi.org/10.1088/0957-4484/25/45/45550410.1088/0957-4484/25/45/455504 ↗
5. Espinosa EH, Ionescu R, Bittencourt C et al (2007) Thin Solid Films 515:8322. https://doi.org/10.1016/j.tsf.2007.03.01710.1016/j.tsf.2007.03.017 ↗
6. Kaniyoor A, Imran Jafri R, Arockiadoss T, Ramaprabhu S (2009) Nanoscale 1:382. https://doi.org/10.1039/b9nr00015a10.1039/b9nr00015a ↗
7. Qian LH, Wang K, Li Y, Fang HT, Lu QH, Ma XL (2006) Mater Chem Phys 100:82. https://doi.org/10.1016/j.matchemphys.2005.12.00910.1016/j.matchemphys.2005.12.009 ↗
8. Feng C, Li W, Li C et al (2012) Sens Actuators B Chem 166–167:83. https://doi.org/10.1016/j.snb.2011.12.08310.1016/j.snb.2011.12.083 ↗
9. Okamoto A, Shibasaki I (2003) J Cryst Growth 251:560. https://doi.org/10.1016/S0022-0248(02)02448-X10.1016/S0022-0248(02)02448-X ↗
10. Bloor LG, Manzi J, Binions R et al (2012) Chem Mater 24:2864. https://doi.org/10.1021/cm300596c10.1021/cm300596c ↗
11. Chikhale LP, Patil JY, Rajgure AV, Shaikh FI, Mulla IS, Suryavanshi SS (2014) Ceram Int 40:2179. https://doi.org/10.1016/j.ceramint.2013.07.13610.1016/j.ceramint.2013.07.136 ↗
12. Habibzadeh S, Khodadadi AA, Mortazavi Y (2010) Sens Actuators B Chem 144:131. https://doi.org/10.1016/j.snb.2009.10.04710.1016/j.snb.2009.10.047 ↗
13. Qin W, Xu L, Song J, Xing R, Song H (2013) Sens Actuators B Chem 185:231. https://doi.org/10.1016/j.snb.2013.05.00110.1016/j.snb.2013.05.001 ↗
14. Che G, Lakshmi BB, Martin CR, Fisher ER, Ruoff RS (1998) Chem Mater 10:26010.1021/cm970412f ↗
15. Tao X, Sun L, Li Z, Zhao Y (2009) Nanoscale Res Lett 5:383. https://doi.org/10.1007/s11671-009-9493-510.1007/s11671-009-9493-5 ↗
16. Lakshmi BB, Patrissi CJ, Martin CR (1997) Chem Mater 9:2544. https://doi.org/10.1021/cm970268y10.1021/cm970268y ↗
17. Xu L, Song H, Dong B, Wang Y, Chen J, Bai X (2010) Inorg Chem 49:10590. https://doi.org/10.1021/ic101602a10.1021/ic101602a ↗
18. Xu L, Dong B, Wang Y, Bai X, Liu Q, Song H (2010) Sens Actuators B Chem 147:531. https://doi.org/10.1016/j.snb.2010.04.00310.1016/j.snb.2010.04.003 ↗
19. Huang Z-M, Zhang YZ, Kotaki M, Ramakrishna S (2003) Compos Sci Technol 63:2223. https://doi.org/10.1016/S0266-3538(03)00178-710.1016/S0266-3538(03)00178-7 ↗
20. Azhari SJ, Diab MA (1998) Polym Degrad Stab 60:253. https://doi.org/10.1016/S0141-3910(97)00073-610.1016/S0141-3910(97)00073-6 ↗
21. Chen W-S, Huang D-A, Chen H-C et al (2009) Cryst Growth Des 9:4070. https://doi.org/10.1021/cg900297q10.1021/cg900297q ↗
22. Enhanced acetone sensing properties of Eu-In2O3 nanotubes with bumps (2016) Institution of Engineering and Technology, http://digital-library.theiet.org/content/journals/10.1049/mnl.2016.0235
23. Kumar M, Singh VN, Singh F, Lakshmi KV, Mehta BR, Singh JP (2008) Appl Phys Lett 92:171907. https://doi.org/10.1063/1.291050110.1063/1.2910501 ↗
24. Olivia MB, Ariano DR, Cleocir JD, Alexandre JCL, Edson RL, Adenilson JC (2010) J Phys D Appl Phys 43:04540110.1088/0022-3727/43/4/045401 ↗
25. Gan J, Lu X, Wu J et al (2013) Sci Rep 3:1021. https://doi.org/10.1038/srep0102110.1038/srep01021 ↗
26. Dayal P, Kyu T (2006) J Appl Phys 100:04351210.1063/1.2259812 ↗
27. Cho JS, Kang YC (2015) Small 11:467310.1002/smll.201500940 ↗
28. Tu KN, Gösele U (2005) Appl Phys Lett 86:09311110.1063/1.1873044 ↗
29. Yanping L, Zhihong L, Yuhu L, Zhiyong L, Qihou L (2014) Chin J Nonferrous Metals 24:221
30. Shaalan NM, Rashad M, Abdel-Rahim MA (2016) Mater Sci Semicond Process 56:260. https://doi.org/10.1016/j.mssp.2016.09.00710.1016/j.mssp.2016.09.007 ↗
31. Lim SK, Hwang S-H, Chang D, Kim S (2010) Sens Actuators B Chem 149:28. https://doi.org/10.1016/j.snb.2010.06.03910.1016/j.snb.2010.06.039 ↗
32. Gao L, Cheng Z, Xiang Q, Zhang Y, Xu J (2015) Sens Actuators B Chem 208:436. https://doi.org/10.1016/j.snb.2014.11.05310.1016/j.snb.2014.11.053 ↗
33. Zhang L-h, Wang S-l, Liu F-h (2015) J Electron Mater 44:3408. https://doi.org/10.1007/s11664-015-3905-310.1007/s11664-015-3905-3 ↗
34. Guo X, Zhang J, Ni M, Liu L, Lian H, Wang H (2016) J Mater Sci Mater Electron 27:11262. https://doi.org/10.1007/s10854-016-5247-110.1007/s10854-016-5247-1 ↗
35. Yu F, Wu Y, Ma J, Zhang C (2013) J Environ Sci 25:195. https://doi.org/10.1016/S1001-0742(12)60023-010.1016/S1001-0742(12)60023-0 ↗
36. Zhao C, Zhang G, Han W et al (2013) Cryst Eng Commun 15:6491. https://doi.org/10.1039/C3CE40962G10.1039/C3CE40962G ↗
37. Bagheri M, Khodadadi AA, Mahjoub AR, Mortazavi Y (2015) Sens Actuators B Chem 220:590. https://doi.org/10.1016/j.snb.2015.06.00710.1016/j.snb.2015.06.007 ↗
38. Anand K, Kaur J, Singh RC, Thangaraj R (2017) Chem Phys Lett 670:37. https://doi.org/10.1016/j.cplett.2016.12.05710.1016/j.cplett.2016.12.057 ↗
39. Montazeri A, Jamali-Sheini F (2017) Sens Actuators B Chem 242:778. https://doi.org/10.1016/j.snb.2016.09.18110.1016/j.snb.2016.09.181 ↗
40. Navale ST, Bandgar DK, Nalage SR et al (2013) Ceram Int 39:6453. https://doi.org/10.1016/j.ceramint.2013.01.07410.1016/j.ceramint.2013.01.074 ↗
41. Sun P, Cai Y, Du S et al (2013) Sens Actuators B Chem 182:336. https://doi.org/10.1016/j.snb.2013.03.01910.1016/j.snb.2013.03.019 ↗
42. Franke ME, Koplin TJ, Simon U (2006) Small 2:36. https://doi.org/10.1002/smll.20050026110.1002/smll.200500261 ↗
43. Singh S, Singh A, Yadav BC, Dwivedi PK (2013) Sens Actuators B Chem 177:730. https://doi.org/10.1016/j.snb.2012.11.09610.1016/j.snb.2012.11.096 ↗
44. Hamedani NF, Mahjoub AR, Khodadadi AA, Mortazavi Y (2012) Sens Actuators B Chem 169:67. https://doi.org/10.1016/j.snb.2012.02.07410.1016/j.snb.2012.02.074 ↗
45. Miller DR, Akbar SA, Morris PA (2014) Sens Actuators B Chem 204:250. https://doi.org/10.1016/j.snb.2014.07.07410.1016/j.snb.2014.07.074 ↗
46. Anand K, Kaur J, Singh RC, Thangaraj R (2016) Ceram Int 42:10957. https://doi.org/10.1016/j.ceramint.2016.03.23310.1016/j.ceramint.2016.03.233 ↗
47. An W, Wu X, Zeng XC (2008) J Phys Chem C 112:5747. https://doi.org/10.1021/jp711105d10.1021/jp711105d ↗
48. Cheng JP, Wang BB, Zhao MG, Liu F, Zhang XB (2014) Sens Actuators B Chem 190:78. https://doi.org/10.1016/j.snb.2013.08.09810.1016/j.snb.2013.08.098 ↗
49. Belmonte JC, Manzano J, Arbiol J et al (2006) Sens Actuators B Chem 114:881. https://doi.org/10.1016/j.snb.2005.08.00710.1016/j.snb.2005.08.007 ↗
50. Prabhu E, Gnanasekar KI, Ravindran TR, Jayaraman V, Gnanasekaran T (2014) J Electrochem Soc 161:B176. https://doi.org/10.1149/2.0451409jes10.1149/2.0451409jes ↗