journal article·2020-02

Hierarchical NiCo2S4 nanosheets grown on graphene to catalyze the oxygen evolution reaction

Chao Shuai, Zunli Mo, Xiaohui Niu, Xing Yang, Guigui Liu, Jia Wang, Nijuan Liu, Ruibin Guo

Journal of Materials Science· Volume 55· Issue 4
Publisher page

Abstract

Efficient transition metal-based electrocatalysts for oxygen evolution reaction (OER) are vital for water splitting to make H2 fuel. Here, the hierarchical NiCo2S4 nanosheets/reduced graphene oxide (NiCo2S4/RGO) architecture composite was designed and synthesized. The constitution and morphology of NiCo2S4/RGO composites were characterized by X-ray diffraction, X-ray photoelectron spectroscopy, scanning electron microscope and transmission electron microscope. Then, the electrochemical performance of as-prepared NiCo2S4/RGOs for OER was studied. The optimal composite (NiCo2S4/RGO-2) exhibited the best improved compared to raw NiCo2S4 on OER performance, which afforded a small overpotential (366 mV at current density of 10 mA cm−2) and a low Tafel slope of 65 mV dec−1 and good stability in 1.0 M KOH electrolyte. The hierarchical architecture of the NiCo2S4/RGO system endows more active sites and enhances charge transfer. This work provided a general strategy to design more efficient NiCo-based chalcogenide OER electrocatalysts.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Electrocatalysts for Energy Conversion · Advanced battery technologies research · Fuel Cells and Related Materials

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

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