A novel amorphous CoSx/NH2-MIL-125 composite for photocatalytic degradation of rhodamine B under visible light
Source abstract
Abstract
Metal–organic frameworks (MOFs) are a new type of porous crystal materials that have been widely used in various fields. Owing to their adjustable porous structure, MOF photocatalysts with high catalytic activity have become a research hotspot. In this study, NH2-MIL-125/CoSx samples were investigated as a novel visible light-responsive catalyst for the removal of organic dye. The NH2-MIL-125/CoSx-20 composites showed the best photodegradation efficiency, where photodegradation of the rhodamine B reached 95.4% in 45 min. CoSx was able to effectively extend the wavelength absorption range of NH2-MIL-125 and effectively separate the photogenerated electrons and holes and that could lead to the improved photocatalytic performance of the composites. The reactive superoxide radical (·O2−) was identified as the main active species using reactive species capture experiments, and a reasonable photocatalytic mechanism was proposed. This paper is intended to guide the development of organic–inorganic hybrid materials for environmental remediation.
Source: openaire · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Metal-Organic Frameworks: Synthesis and Applications · Advanced Photocatalysis Techniques · Covalent Organic Framework Applications
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (59)
Show source-provided references
1. Zhang YK, Xiong ZS, Yang LM, Ren Z, Shao PH, Shi H, Xiao X, Pavlostathis SG, Fang LL, Luo XB (2019) Successful isolation of a tolerant co-flocculating microalgae towards highly efficient nitrogen removal in harsh rare earth element tailings (REEs) wastewater. Water Res 166:11507610.1016/j.watres.2019.115076 ↗
2. Yang LM, Yi GP, Hou YN, Cheng HY, Luo XB, Pavlostathis SG, Luo SL, Wang AJ (2019) Building electrode with three-dimensional macroporous interface from biocompatible polypyrrole and conductive graphene nanosheets to achieve highly efficient microbial electrocatalysis. Biosens Bioelectron 141:11144410.1016/j.bios.2019.111444 ↗
3. Xiao JD, Jiang HL (2019) Metal-organic frameworks for photocatalysis and photothermal catalysis. Acc Chem Res 52:356–36610.1021/acs.accounts.8b00521 ↗
4. Xia W, Wu JC, Hu JC, Sun SS, Li MD, Liu HF, Lan MH, Wang F (2019) Highly efficient photocatalytic conversion of CO2 to CO catalyzed by surface-ligand-removed and Cd-Rich CdSe quantum dots. Chemsuschem 12:4617–462210.1002/cssc.201901633 ↗
5. Hu JC, Sun SS, Li MD, Wu X, Wu J, Liu HF, Wang F (2019) A biomimetic self-assembled cobaloxime@CdS/rGO hybrid for boosting photocatalytic H2 production. Chem Commun 55:14490–1449310.1039/C9CC08512B ↗
6. Hassan FU, Ahmed U, Muhyuddin M, Yasir M, Ashiq MN, Basit MA (2019) Tactical modification of pseudo-SILAR process for enhanced quantum-dot deposition on TiO2 and ZnO nanoparticles for solar energy applications. Mater Res Bull 120:11058810.1016/j.materresbull.2019.110588 ↗
7. Sridharan K, Jang E, Park JH, Kim JH, Lee JH, Park TJ (2015) Silver quantum cluster (Ag9)-grafted graphitic carbon nitride nanosheets for photocatalytic hydrogen generation and dye degradation. Chem Eur J 21:9126–913210.1002/chem.201500163 ↗
8. Ali L, Muhyuddin M, Mullani N, Kim DW, Basit MA, Park TJ (2020) Modernized H2S-treatment of TiO2 nanoparticles: Improving quantum-dot deposition for enhanced photocatalytic performance. Curr Appl Phys 20:384–39010.1016/j.cap.2019.12.006 ↗
9. Zhao JH, Liu LW, Li K, Li T, Liu FT (2019) Conductive Ti3C2 and MOF-derived CoSx boosting the photocatalytic hydrogen production activity of TiO2. CrystEngComm 21:2416–242110.1039/C8CE02050G ↗
10. Mao Q, Chen JM, Chen HR, Chen ZJ, Chen JY, Li YW (2019) Few-layered 1T-MoS2-modified ZnCoS solid-solution hollow dodecahedra for enhanced photocatalytic hydrogen evolution. J Mater Chem A 7:8472–848410.1039/C8TA12526K ↗
11. Chen F, Luo W, Mo YP, Yu HG, Cheng B (2018) In situ photodeposition of amorphous CoSx on the TiO2 towards hydrogen evolution. Appl Surf Sci 430:448–45610.1016/j.apsusc.2017.06.165 ↗
12. Fu JW, Bie CB, Cheng B, Yu JG, Zhang LY (2018) Hollow CoSx polyhedrons act as high-efficiency cocatalyst for enhancing the photocatalytic hydrogen generation of g-C3N4. ACS Sustain Chem Eng 6:2767–277910.1021/acssuschemeng.7b04461 ↗
13. Kornienko N, Resasco J, Becknell N, Jiang CM, Liu YS, Nie KQ, Sun XH, Guo JH, Leone SR, Yang PD (2015) Operando spectroscopic analysis of an amorphous cobalt sulfide hydrogen evolution electrocatalyst. J Am Chem Soc 137:7448–745510.1021/jacs.5b03545 ↗
14. Furukawa H, Cordova KE, O'Keeffe M, Yaghi OM (2013) The chemistry and applications of metal-organic frameworks. Science 341:123044410.1126/science.1230444 ↗
15. Zhang HB, Nai JW, Yu L, Lou XW (2017) Metal-organic-framework-based materials as platforms for renewable energy and environmental applications. Joule 1:77–10710.1016/j.joule.2017.08.008 ↗
16. Li BY, Chrzanowski M, Zhang YM, Ma SQ (2016) Applications of metal-organic frameworks featuring multi-functional sites. Coord Chem Rev 307:106–12910.1016/j.ccr.2015.05.005 ↗
17. Zhang T, Lin WB (2014) Metal-organic frameworks for artificial photosynthesis and photocatalysis. Chem Soc Rev 43:5982–599310.1039/C4CS00103F ↗
18. Abednatanzi S, Derakhshandeh PG, Depauw H, Coudert FX, Vrielinck H, Voort PVD, Leus K (2019) Mixed-metal metal-organic frameworks. Chem Soc Rev 48:2535–256510.1039/C8CS00337H ↗
19. Masoomi MY, Morsali A, Dhakshinamoorthy A, Garcia H (2019) Mixed-Metal MOFs: Unique Opportunities In Metal-Organic Framework (MOF) functionality and design. Angew Chem Int Ed 58:15188–1525010.1002/anie.201902229 ↗
20. Wang R, Xu HJ, Zhang K, Wei SY, Wu DY (2019) High-quality Al@Fe-MOF prepared using Fe-MOF as a micro-reactor to improve adsorption performance for selenite. J Hazard Mater 364:272–28010.1016/j.jhazmat.2018.10.030 ↗
21. Cao J, Yang Z, Xiong W, Zhou Y, Peng Y, Li X, Zhou C, Xu R, Zhang Y (2018) One-step synthesis of Co-doped UiO-66 nanoparticle with enhanced removal efficiency of tetracycline: Simultaneous adsorption and photocatalysis. Chem Eng J 353:126–13710.1016/j.cej.2018.07.060 ↗
22. Sheng Y, Wei Z, Miao H, Yao W, Li H, Zhu Y (2019) Enhanced organic pollutant photodegradation via adsorption/photocatalysis synergy using a 3D g-C3N4/TiO2 free-separation photocatalyst. Chem Eng J 370:287–29410.1016/j.cej.2019.03.197 ↗
23. Ren Y, Li T, Zhang W, Wang S, Shi M, Shan C, Zhang W, Guan X, Lv L, Hua M, Pan B (2019) MIL-PVDF blend ultrafiltration membranes with ultrahigh MOF loading for simultaneous adsorption and catalytic oxidation of methylene blue. J Hazard Mater 365:312–32110.1016/j.jhazmat.2018.11.013 ↗
24. Nandasiri MI, Jambovane SR, McGrail BP, Schaef HT, Nune SK (2016) Adsorption, separation, and catalytic properties of densified metal-organic frameworks. Coord Chem Rev 311:38–5210.1016/j.ccr.2015.12.004 ↗
25. Li H, Li L, Lin RB, Zhou W, Zhang Z, Xiang S, Chen B (2019) Porous metal-organic frameworks for gas storage and separation: status and challenges. EnergyChem 1:10000610.1016/j.enchem.2019.100006 ↗
26. Li H, Wang K, Sun Y, Lollar CT, Li J, Zhou H (2018) Recent advances in gas storage and separation using metal-organic frameworks. Mater Today 21:108–12110.1016/j.mattod.2017.07.006 ↗
27. Das S, Xu S, Ben T, Qiu S (2018) Chiral recognition and separation by chirality-enriched metal-organic frameworks. Angew Chem Int Ed 57:8629–863310.1002/anie.201804383 ↗
28. Hou QQ, Wu Y, Zhou S, Wei Y, Caro J, Wang H (2019) Ultra-tuning of the aperture size in stiffened ZIF-8_Cm frameworks with mixed-linker strategy for enhanced CO2/CH4 separation. Angew Chem Int Ed 58:327–33110.1002/anie.201811638 ↗
29. Ye YX, Ma Z, Lin RB, Krishna R, Zhou W, Lin Q, Zhang Z, Xiang S, Chen B (2019) Pore space partition within a metal-organic framework for highly efficient C2H2/CO2 separation. J Am Chem Soc 141:4130–413610.1021/jacs.9b00232 ↗
30. Wang S, McGuirk CM, d'Aquino A, Mason JA, Mirkin CA (2018) Metal-Organic Framework Nanoparticles. Adv Mater 30:180020210.1002/adma.201800202 ↗
31. Dhakshinamoorthy A, Li Z, Garcia H (2018) Catalysis and photocatalysis by metal organic frameworks. Chem Soc Rev 47:8134–817210.1039/C8CS00256H ↗
32. Sun D, Li Z (2017) Robust Ti- and Zr-Based Metal-Organic Frameworks for Photocatalysis. Chin J Chem 35:135–14710.1002/cjoc.201600647 ↗
33. Shen K, Chen XD, Chen JY, Li YW (2016) Development of MOF-derived carbon-based nanomaterials for efficient catalysis. ACS Catal 6:5887–590310.1021/acscatal.6b01222 ↗
34. Zhang ZS, Zhao K, Li XG, Li SL, Li H (2020) The engineering of surface plasmon resonance and up-conversion to improve the photocatalytic performance of MIL-53(Fe) over the full solar spectrum. J Mater Sci 55:997–1011. https://doi.org/10.1007/s10853-019-03995-710.1007/s10853-019-03995-7 ↗
35. Mohaghegh N, Kamrani S, Tasviri M, Elahifard M, Gholami M (2015) Nanoporous Ag2O photocatalysts based on copper terephthalate metal–organic frameworks. J Mater Sci 50(13):4536–4546. https://doi.org/10.1007/s10853-015-9003-310.1007/s10853-015-9003-3 ↗
36. Chi WS, Roh DK, Lee CS, Kim JH (2015) A shape- and morphology-controlled metal organic framework template for high-efficiency solid-state dye-sensitized solar cells. J Mater Chem A 3:21599–2160810.1039/C5TA06731F ↗
37. Basit MA, Rashid M, Khan TF, Muhyuddin M, Butt S (2019) Simplistic thermal transformation of MIL-125 to TiO2 nano-coins and nano-diamonds for efficient quantum-dot sensitized solar cells. Mat Sci Semicon Proc 104:10466310.1016/j.mssp.2019.104663 ↗
38. Wang ZQ, Li X, Xu H, Yang Y, Cui YJ, Pan HG, Wang ZY, Chen BL, Qian GD (2014) J Mater Chem A 2:12571–1257510.1039/C4TA02029D ↗
39. Su Y, Li S, He D, Yu D, Liu F, Shao N, Zhang Z (2018) MOF-Derived Porous ZnO Nanocages/rGO/Carbon sponge-based photocatalytic microreactor for efficient degradation of water pollutants and hydrogen evolution. ACS Sustain Chem Eng 6:11989–1199810.1021/acssuschemeng.8b02287 ↗
40. Zhang B, Zhang J, Tan X, Shao D, Shi J, Zheng L, Zhang J, Yang G, Han B (2018) MIL-125-NH2@TiO2 core-shell particles produced by a post-solvothermal route for high-performance Photocatalytic H2 production. ACS Appl Mater Interfaces 10:16418–1642310.1021/acsami.8b01462 ↗
41. Zhang F, Zhang B, Feng J, Tan X, Liu L, Liu L, Han B, Zheng L, Zhang J, Tai J, Zhang J (2019) Highly mesoporous Ru-MIL-125-NH2 produced by supercritical fluid for efficient photocatalytic hydrogen production. ACS Appl Energy Mater 2:4964–497010.1021/acsaem.9b00649 ↗
42. Chen YF, Tan LL, Liu JM, Qin S, Xie ZQ, Huang JF, Xu YW, Xiao LM, Su CY (2017) Calix [4] arene based dye-sensitized Pt@UiO-66-NH2 metal-organic framework for efficient visible-light photocatalytic hydrogen production. Appl Catal B Environ 206:426–43310.1016/j.apcatb.2017.01.040 ↗
43. He J, Wang J, Chen Y, Zhang J, Duan D, Wang Y, Yan Z (2014) A dye-sensitized Pt@UiO-66(Zr) metal-organic framework for visible-light photocatalytic hydrogen production. Chem Commun 50:7063–706610.1039/C4CC01086H ↗
44. Zlotea C, Phanon D, Mazaj M, Heurtaux D, Guillerm V, Serre C, Horcajada P, Devic T, Magnier E, Cuevas F, Ferey G, Llewellyn PL, Latroche M (2011) Effect of NH2 and CF3 functionalization on the hydrogen sorption properties of MOFs. Dalton Trans 40:4879–488110.1039/c1dt10115c ↗
45. Hu Q, Di J, Wang B, Ji M, Chen Y, Xia J, Li H, Zhao Y (2019) In-situ preparation of NH2-MIL-125(Ti)/BiOCl composite with accelerating charge carriers for boosting visible light photocatalytic activity. Appl Surf Sci 466:525–53410.1016/j.apsusc.2018.10.020 ↗
46. Emam HE, Abdelhameed RM (2017) Anti-UV radiation textiles designed by embracing with Nano-MIL (Ti, In)-metal organic framework. ACS Appl Mater Interfaces 9:28034–2804510.1021/acsami.7b07357 ↗
47. Wang H, Yuan X, Wu Y, Zeng G, Chen X, Leng L, Wu Z, Jiang L, Li H (2015) Facile synthesis of amino-functionalized titanium metal-organic frameworks and their superior visible-light photocatalytic activity for Cr (VI) reduction. J Hazard Mater 286:187–19410.1016/j.jhazmat.2014.11.039 ↗
48. Meng XQ, Sun H, Zhu JW, Bi HP, Han QF, Liu XH, Wang X (2016) Graphene-based cobalt sulfide composite hydrogel with enhanced electrochemical properties for supercapacitors. New J Chem 40:2843–284910.1039/C5NJ03423J ↗
49. He WH, Ifraemov R, Raslin A, Hod I (2018) Room-temperature electrochemical conversion of metal-organic frameworks into porous amorphous metal sulfides with tailored composition and hydrogen evolution activity. Adv Funct Mater 28:170724410.1002/adfm.201707244 ↗
50. Ao D, Zhang J, Liu H (2018) Visible-light-driven photocatalytic degradation of pollutants over Cu-doped NH2-MIL-125(Ti). J Photochem Photobiol A 364:524–53310.1016/j.jphotochem.2018.06.044 ↗
51. Qiu B, Zhu Q, Du M, Fan L, Xing M, Zhang J (2017) Efficient solar light harvesting CdS/Co9S8 hollow cubes for Z-Scheme photocatalytic water splitting. Angew Chem Int Ed 56:2684–268810.1002/anie.201612551 ↗
52. Wu Z, Yuan X, Wang H, Wu Z, Jiang L, Wang H, Zhang L, Xiao Z, Chen X, Zeng G (2017) Facile synthesis of a novel full-spectrum-responsive Co2.67S4 nanoparticles for UV-, vis- and NIR-driven photocatalysis. Appl Catal B Environ 202:104–11110.1016/j.apcatb.2016.08.064 ↗
53. Fu J, Zhu B, You W, Jaroniec M, Yu J (2018) A flexible bio-inspired H2-production photocatalyst. Appl Catal B Environ 220:148–16010.1016/j.apcatb.2017.08.034 ↗
54. Sha Z, Chan HS, Wu J (2015) Ag2CO3/UiO-66(Zr) composite with enhanced visible-light promoted photocatalytic activity for dye degradation. J Hazard Mater 299:132–14010.1016/j.jhazmat.2015.06.016 ↗
55. Wang H, Yuan X, Wu Y, Zeng G, Chen X, Leng L, Li H (2015) Synthesis and applications of novel graphitic carbon nitride/metal-organic frameworks mesoporous photocatalyst for dyes removal. Appl Catal B Environ 174–175:445–45410.1016/j.apcatb.2015.03.037 ↗
56. Wang Q, Wang W, Zhong L, Liu D, Cao X, Cui F (2018) Oxygen vacancy-rich 2D/2D BiOCl-g-C3N4 ultrathin heterostructure nanosheets for enhanced visible-light-driven photocatalytic activity in environmental remediation. Appl Catal B Environ 220:290–30210.1016/j.apcatb.2017.08.049 ↗
57. Yu D, Wu M, Hu Q, Wang L, Lv C, Zhang L (2019) Iron-based metal-organic frameworks as novel platforms for catalytic ozonation of organic pollutant: efficiency and mechanism. J Hazard Mater 367:456–46410.1016/j.jhazmat.2018.12.108 ↗
58. Gong Y, Zhao X, Zhang H, Yang B, Xiao K, Guo T, Zhang J, Shao H, Wang Y, Yu G (2018) MOF-derived nitrogen doped carbon modified g-C3N4 heterostructure composite with enhanced photocatalytic activity for bisphenol A degradation with peroxymonosulfate under visible light irradiation. Appl Catal B Environ 233:35–4510.1016/j.apcatb.2018.03.077 ↗
59. He S, Rong Q, Niu H, Cai Y (2019) Platform for molecular-material dual regulation: a direct Z-scheme MOF/COF heterojunction with enhanced visible-light photocatalytic activity. Appl Catal B Environ 247:49–5610.1016/j.apcatb.2019.01.078 ↗