Evolution of ω phase during heating of metastable β titanium alloy Ti–15Mo
Source abstract
Abstract
Evolution of $$\omega $$ phase during heating of metastable $$\beta $$ titanium alloy Ti–15Mo was investigated in situ during heating by electrical resistance measurements and accompanied by transmission electron microscopy. Different heating rates were employed aiming to determine kinetics of occurring phase transformations. Sharp change of temperature dependence of electrical resistance caused by complete dissolution of $$\omega $$ phase was observed at 560 $$\circ \hbox {C}$$ independently of heating rate. Majority of $$\omega _{\mathrm{iso}}$$ particles revert back to $$\beta $$ phase at 560 $$\circ \hbox {C}$$ ; therefore, they are not direct precursors of $$\alpha $$ precipitation during continuous heating.
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Research context
OpenAlex topics: Titanium Alloys Microstructure and Properties · Intermetallics and Advanced Alloy Properties · Hydrogen embrittlement and corrosion behaviors in metals
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References (47)
Show source-provided references
1. Lütjering G, Williams JC (2007) Titanium. Engineering materials, processes. Springer, Berlin, pp 1–39. doi:10.1007/978-3-540-73036-110.1007/978-3-540-73036-1 ↗
2. Maeshima T, Nishida M (2004) Shape memory and mechanical properties of biomedical Ti–Sc–Mo alloys. Mater Trans 45(4):1101–1105. doi:10.2320/matertrans.45.110110.2320/matertrans.45.1101 ↗
3. Duraccio D, Mussano F, Faga MG (2015) Biomaterials for dental implants: current and future trends. J Mater Sci 50(14):4779–4812. doi:10.1007/s10853-015-9056-310.1007/s10853-015-9056-3 ↗
4. Duerig TW, Williams JC (1984) In: Boyer RR, Rosenberg HW (eds) Beta-Titanium Alloys in the 1980’s. The Metallurgical Society of AIME, pp 19–69
5. Wang CH, Yang CD, Liu M, Li X, Hu PF, Russell AM, Cao GH (2016) Martensitic microstructures and mechanical properties of as-quenched metastable $$\beta $$-type Ti–Mo alloys. J Mater Sci 51(14):6886–6896. doi:10.1007/s10853-016-9976-610.1007/s10853-016-9976-6 ↗
6. Duerig TW, Albrecht J, Richter D, Fischer P (1982) Formation and reversion of stress induced martensite in Ti–10V–2Fe–3Al. Acta Metall 30(12):2161–2172. doi:10.1016/0001-6160(82)90137-710.1016/0001-6160(82)90137-7 ↗
7. Tang X, Ahmed T, Rack HJ (2000) Phase transformations in Ti–Nb–Ta and Ti–Nb–Ta–Zr alloys. J Mater Sci 35(7):1805–1811. doi:10.1023/A:100479292215510.1023/A:1004792922155 ↗
8. Frost PD, Parris WM, Hirsch LL, Doig JR, Schwartz CM (1954) Isothermal transformation of titanium–chromium alloys. Trans Am Soc Met 46:231
9. Zheng Y, Williams RE, Sosa JM, Alam T, Wang Y, Banerjee R, Fraser HL (2016) The indirect influence of the $$\omega $$ phase on the degree of refinement of distributions of the $$\alpha $$ phase in metastable $$\beta $$-titanium alloys. Acta Mater 103:165–173. doi:10.1016/j.actamat.2015.09.05310.1016/j.actamat.2015.09.053 ↗
10. Zheng Y, Williams RE, Sosa JM, Wang Y, Banerjee R, Fraser HL (2016) The role of the $$\omega $$ phase on the non-classical precipitation of the $$\alpha $$ phase in metastable $$\beta $$-titanium alloys. Scripta Mater 111:81–84. doi:10.1016/j.scriptamat.2015.08.01910.1016/j.scriptamat.2015.08.019 ↗
11. Sikka SK, Vohra YK, Chidambaram R (1982) Omega phase in materials. Prog Mater Sci 27(3):245. doi:10.1016/0079-6425(82)90002-010.1016/0079-6425(82)90002-0 ↗
12. Hickman BS (1969) The formation of omega phase in titanium and zirconium alloys: a review. J Mater Sci 4(6):55410.1007/BF00550217 ↗
13. Banerjee S, Mukhopadhyay P (2007) Phase transformations: examples from titanium and zirconium alloys. No. 12 in Pergamon materials seriesv. Elsevier, Pergamon
14. Šmilauerová J, Harcuba P, Stráský J, Stráská J, Janeček M, Pospíšil J, Kužel R, Brunátová T, Holý V, Ilavský J (2014) Ordered array of $$\omega $$ particles in $$\beta $$-Ti matrix studied by small-angle X-ray scattering. Acta Mater 81:71–82. doi:10.1016/j.actamat.2014.06.04210.1016/j.actamat.2014.06.042 ↗
15. Bagaryatskiy A, Yu I, Nosova G (1962) Phys Met Metallogr 13(3):92
16. De Fontaine D, Paton NE, Williams JC (1971) The omega phase transformation in titanium alloys as an example of displacement controlled reactions. Acta Metall 19(11):1153. doi:10.1016/0001-6160(71)90047-210.1016/0001-6160(71)90047-2 ↗
17. Zháňal P, Harcuba P, Šmilauerová J, Stráský J, Janeček M, Smola B, Hájek M (2015) Phase transformations in Ti–15Mo investigated by in situ electrical resistance. Acta Phys Pol A 128(4):779. doi:10.12693/APhysPolA.128.77910.12693/APhysPolA.128.779 ↗
18. Nejezchlebová J, Janovská M, Seiner H, Sedlák P, Landa M, Šmilauerová J, Stráský J, Harcuba P, Janeček M (2016) The effect of athermal and isothermal $$\omega $$ phase particles on elasticity of $$\beta $$-Ti single crystals. Acta Mater 110:185–191. doi:10.1016/j.actamat.2016.03.03310.1016/j.actamat.2016.03.033 ↗
19. Froes F, Staff AI (2015) Titanium: physical metallurgy processing and applications. ASM International, New York10.31399/asm.tb.tpmpa.9781627083188 ↗
20. Šmilauerová J, Harcuba P, Pospíšil J, Matěj Z, Holý V (2013) Growth of $$\omega $$ inclusions in Ti alloys: an X-ray diffraction study. Acta Mater 61(17):6635–6645. doi:10.1016/j.actamat.2013.07.05910.1016/j.actamat.2013.07.059 ↗
21. Ohmori Y, Ogo T, Nakai K, Kobayashi S (2001) Effects of $$\omega $$-phase precipitation on $$\beta \rightarrow \alpha $$, $$\alpha $$” transformations in a metastable $$\beta $$ titanium alloy. Mater Sci Eng A 312(1):182. doi:10.1016/S0921-5093(00)01891-810.1016/S0921-5093(00)01891-8 ↗
22. Williams JC, Blackburn MJ (1969) The influence of Misfit on the morphology and stability of the omega phase in titanium–transition metal alloys. Trans Met Soc AIME 245:2352–2355
23. Nag S, Banerjee R, Srinivasan R, Hwang JY, Harper M, Fraser HL (2009) $$\omega $$-Assisted nucleation and growth of $$\alpha $$ precipitates in the Ti–5Al–5Mo–5V–3Cr–0.5Fe $$\beta $$ titanium alloy. Acta Mater 57(7):2136. doi:10.1016/j.actamat.2009.01.00710.1016/j.actamat.2009.01.007 ↗
24. Li T, Kent D, Sha G, Stephenson LT, Ceguerra AV, Ringer SP, Dargusch MS, Cairney JM (2016) New insights into the phase transformations to isothermal $$\omega $$ and $$\omega $$-assisted $$\alpha $$ in near $$\beta $$-Ti alloys. Acta Mater 106:353–366. doi:10.1016/j.actamat.2015.12.04610.1016/j.actamat.2015.12.046 ↗
25. Prima F, Vermaut P, Texier G, Ansel D, Gloriant T (2006) Evidence of $$\alpha $$-nanophase heterogeneous nucleation from $$\omega $$ particles in a $$\beta $$-metastable Ti-based alloy by high-resolution electron microscopy. Scripta Mater 54(4):645. doi:10.1016/j.scriptamat.2005.10.02410.1016/j.scriptamat.2005.10.024 ↗
26. Ho JC, Collings EW (1972) Anomalous electrical resistivity in titanium–molybdenum alloys. Phys Rev B 6(10):372710.1103/PhysRevB.6.3727 ↗
27. Luhman TS, Taggart R, Polonis DH (1968) A resistance anomaly in beta stabilized Ti–Cr alloys. Scr Metall 2(3):169. doi:10.1016/0036-9748(68)90219-610.1016/0036-9748(68)90219-6 ↗
28. Hake RR, Leslie DH, Berlincourt TG (1961) Electrical resistivity, Hall effect and superconductivity of some b.c.c. titanium–molybdenum alloys. J Phys Chem Solids 20(3):177. doi:10.1016/0022-3697(61)90002-610.1016/0022-3697(61)90002-6 ↗
29. Komatsu SY, Ikeda M, Sugimoto T, Kamei K, Maesaki O, Kojima MA (1996) Aging behaviour of Ti15Mo5Zr and Ti15Mo5Zr3Al alloy up to 573 K. Mater Sci Eng A 213(1—-2):61–65. doi:10.1016/0921-5093(96)10228-810.1016/0921-5093(96)10228-8 ↗
30. Sun F, Prima F, Gloriant T (2010) High-strength nanostructured Ti–12Mo alloy from ductile metastable beta state precursor. Mater Sci Eng A 527(16–17):4262–4269. doi:10.1016/j.msea.2010.03.04410.1016/j.msea.2010.03.044 ↗
31. Hill MA, Polonis DH (1987) Influence of beta phase decomposition on the temperature coefficient of resistivity of titanium alloys. J Mater Sci 22(6):2181–2184. doi:10.1007/BF0113295710.1007/BF01132957 ↗
32. Yoshida S, Tsuya Y (1956) The temperature dependence of the electrical resistivity of the $$\beta $$-phase titanium–molybdenum alloys. J Phys Soc Jpn 11(11):1206. doi:10.1143/JPSJ.11.120610.1143/JPSJ.11.1206 ↗
33. Prima F, Debuigne J, Boliveau M, Ansel D (2000) Control of omega phase volume fraction precipitated in a beta titanium alloy: development of an experimental method. J Mater Sci Lett 19(24):221910.1023/A:1006708420478 ↗
34. Hájek M, Veselý J, Cieslar M (2007) Precision of electrical resistivity measurements. Mater Sci Eng A 462(1–2):339–342. doi:10.1016/j.msea.2006.01.17510.1016/j.msea.2006.01.175 ↗
35. Gloriant T, Texier G, Sun F, Thibon I, Prima F, Soubeyroux J (2008) Characterization of nanophase precipitation in a metastable $$\beta $$ titanium-based alloy by electrical resistivity, dilatometry and neutron diffraction. Scripta Mater 58(4):271. doi:10.1016/j.scriptamat.2007.10.00710.1016/j.scriptamat.2007.10.007 ↗
36. Settefrati A, Aeby-Gautier E, Dehmas M, Geandier G, Appolaire B, Audion S, Delfosse J (2011) Precipitation in a near beta titanium alloy on ageing: influence of heating rate and chemical composition of the beta-metastable phase. Solid State Phenom 172–174:760–765. doi:10.4028/www.scientific.net/SSP.172-174.76010.4028/www.scientific.net/SSP.172-174.760 ↗
37. Boeckels H (2012) Phase transformations in titanium–molybdenum–oxygen. Ph.D. thesis, Clemson University
38. Barriobero-Vila P, Requena G, Warchomicka F, Stark A, Schell N, Buslaps T (2015) Phase transformation kinetics during continuous heating of a $$\beta $$-quenched Ti–10V–2Fe–3Al alloy. J Mater Sci 50(3):1412–1426. doi:10.1007/s10853-014-8701-610.1007/s10853-014-8701-6 ↗
39. Donachie M (1988) Titanium: a technical guide. AMS International, New York
40. Gemelli E, Camargo NHA (2007) Oxidation kinetics of commercially pure titanium. Matéria (Rio de Janeiro) 12(3):525–531. doi:10.1590/S1517-7076200700030001410.1590/S1517-70762007000300014 ↗
41. Prima F, Vermaut P, Thibon I, Ansel D, Debuigne J, Gloriant T (2002) Nanostructured metastable $$\beta $$-titanium based alloy. J Metastab Nanocrystal Mater 13:307. doi:10.4028/www.scientific.net/JMNM.13.30710.4028/www.scientific.net/JMNM.13.307 ↗
42. Takemoto Y, Hida M, Sakakibara A (1993) Mechanism of $$\omega \rightarrow \alpha $$ transformation in $$\beta $$-Ti alloy. J Jpn Inst Met 57(3):261–26710.2320/jinstmet1952.57.3_261 ↗
43. Devaraj A, Nag S, Srinivasan R, Williams R, Banerjee S, Banerjee R, Fraser H (2012) Experimental evidence of concurrent compositional and structural instabilities leading to $$\omega $$ precipitation in titanium–molybdenum alloys. Acta Mater 60(2):596. doi:10.1016/j.actamat.2011.10.00810.1016/j.actamat.2011.10.008 ↗
44. Schryvers D, Tanner L (1990) High resolution electron microscopy observations of athermal omega phase in Ti–Mo alloys. Mater Sci Forum 56–58:329. doi:10.4028/www.scientific.net/MSF.56-58.32910.4028/www.scientific.net/MSF.56-58.329 ↗
45. Zháňal P, Harcuba P, Janeček M, Smilauerová J, Veselý J, Smola B, Zimina M (2016) In: Venkatesh V, Pilchak AL, Allison JE, Ankem S, Boyer R, Christodoulou J, Fraser HL, Imam MA, Kosaka Y, Rack HJ, Chatterjee A, Woodfield A (eds) Proceedings of the 13th world conference on titanium, TMS (The Minerals, Metals & Materials Society), pp 431–436
46. Furuhara T, Makino T, Idei Y, Ishigaki H, Takada A, Maki T (1998) Morphology and crystallography of $$\alpha $$ precipitates in $$\beta $$ Ti–Mo binary alloys. Mater Trans JIM 39(1):31–39. doi:10.2320/matertrans1989.39.3110.2320/matertrans1989.39.31 ↗
47. Zheng Y, Williams REA, Wang D, Shi R, Nag S, Kami P, Sosa JM, Banerjee R, Wang Y, Fraser HL (2016) Role of $$\omega $$ phase in the formation of extremely refined intragranular $$\alpha $$ precipitates in metastable $$\beta $$-titanium alloys. Acta Mater 103:850–858. doi:10.1016/j.actamat.2015.11.02010.1016/j.actamat.2015.11.020 ↗