journal article·2008-06Open access

Effect of particle size on kinetics crystallization of an iron-rich glass

M. Romero, M. Kovacova, J. Ma. Rincón

Journal of Materials Science· Volume 43· Issue 12

Abstract

The effect of glass particle size on the crystallization kinetics of an iron-rich glass from a nickel leaching waste has been investigated by means of differential thermal analysis (DTA). The results show that the crystallization of a pyroxene phase occurs by bulk nucleation from a constant number of nuclei. The crystallization mode and the dimensionality of crystals are strongly dependent of the glass particle size, being 100µm the critical size. Glass fractions with particle size >100µm show three-dimensional crystals growth controlled by diffusion whereas a particle size <100µm leads to an interface reaction mechanism with two-dimensional growth of crystals.
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Research context

OpenAlex topics: Glass properties and applications · Recycling and utilization of industrial and municipal waste in materials production · Nuclear materials and radiation effects

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

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