journal article·2018-06

Ultrathin nanosheets-assembled CuO flowers for highly efficient electrocatalytic water oxidation

Qianqian Zhou, Ting-Ting Li, Wei Xu, Hong-Lin Zhu, Yue-Qing Zheng

Journal of Materials Science· Volume 53· Issue 11
Publisher page

Abstract

Integration of water oxidation catalysts on conductive support without polymer binder is an appealing strategy to improve the catalytic activity for electrochemical oxygen evolution reaction. Herein, the hierarchical CuO dandelion-like materials assembled from numerous ultrathin nanosheets are directly grown on Cu foil to produce a 3D oxygen evolution anode (CuO NSDs/CF). As a result of its integrated configuration and high electrocatalytic active sites, the anode exhibits superior electrocatalytic water oxidation activity in 1.0 M NaOH solution, associated with a small overpotential of 370 mV at 10 mA cm−2 and a low Tafel slope of 41 mV dec−1. Furthermore, the anode can maintain a relatively stable current density at 1.65 V versus RHE for at least 24 h, and a high Faradaic efficiency of 98% is also achieved.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Electrocatalysts for Energy Conversion · Advanced battery technologies research · Copper-based nanomaterials and applications

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (43)

Show source-provided references
1. Cook TR, Dogutan DK, Reece SY, Surendranath Y, Teets TS, Nocera DG (2010) Solar energy supply and storage for the legacy and nonlegacy worlds. Chem Rev 110:6474–650210.1021/cr100246c ↗
2. Li TT, Zheng YQ (2016) Electrocatalytic water oxidation using a chair-like tetranuclear copper(II) complex in a neutral aqueous solution. Dalton Trans 45:12685–1269010.1039/C6DT01891B ↗
3. Fang Y, Liu Z (2010) Mechanism and Tafel lines of electro-oxidation of water to oxygen on RuO2 (110). J Am Chem Soc 132:18214–1822210.1021/ja1069272 ↗
4. Chen H, Yan J, Wu H, Zhang Y, Liu S (2016) One-pot fabrication of NiFe2O4 nanoparticles on α-Ni(OH)2 nanosheet for enhanced water oxidation. J Power Sources 324:499–50810.1016/j.jpowsour.2016.05.075 ↗
5. Okamura M, Kondo M, Kuga R, Kurashige Y, Yanai T, Hayami S, Praneeth VKK, Yoshida M, Yoneda K, Kawata V, Masaoka S (2016) A pentanuclear iron catalyst designed for water oxidation. Nature 530:465–46810.1038/nature16529 ↗
6. Fan K, Ji Y, Zou H, Zhang J, Zhu B, Chen H, Daniel Q, Luo Y, Yu JG, Sun L (2017) Hollow iron-vanadium composite spheres: a highly efficient iron-based water oxidation electrocatalyst without the need for nickel or cobalt. Angew Chem Int Ed 56:3289–329310.1002/anie.201611863 ↗
7. Najafpour MM, Renger G, Hołyńska M, Moghaddam AN, Aro EM, Carpentier R, Nishihara H, Eaton-Rye JJ, Shen JR, Allakhverdiev SI (2016) Manganese compounds as water-oxidizing catalysts: from the natural water-oxidizing complex to nanosized manganese oxide structures. Chem Rev 116:2886–293610.1021/acs.chemrev.5b00340 ↗
8. Ma T, Dai S, Jaroniec M, Qiao S (2014) Metal-organic framework derived hybrid Co3O4-carbon porous nanowire arrays as reversible oxygen evolution electrodes. J Am Chem Soc 136:13925–1393110.1021/ja5082553 ↗
9. Chen Z, Kang P, Zhang M, Stoner BR, Meyer TJ (2013) Cu(II)/Cu(0) electrocatalyzed CO2 and H2O splitting. Energy Environ Sci 6:813–81710.1039/c3ee24487c ↗
10. Zhao Q, Hao G, Yuan W, Ma N, Li J (2015) Novel copper oxides oxygen evolving catalyst in situ for electrocatalytic water splitting. Electrochim Acta 152:280–28510.1016/j.electacta.2014.11.079 ↗
11. Cheng N, Xue Y, Liu Q, Tian J, Zhang L, Asiri A, Sun X (2015) Cu/(Cu(OH)2–CuO) core/shell nanorods array: in situ growth and application as an efficient 3D oxygen evolution anode. Electrochim Acta 163:102–10610.1016/j.electacta.2015.02.099 ↗
12. Liu X, Cui S, Sun Z, Du P (2015) Copper oxide nanomaterials synthesized from simple copper salts as active catalysts for electrocatalytic water oxidation. Electrochim Acta 160:202–20810.1016/j.electacta.2015.01.123 ↗
13. Hou C, Fu W, Chen Y (2016) Self-supported Cu-based nanowire arrays as noble-metal-free electrocatalysts for oxygen evolution. Chemsuschem 9:2069–207310.1002/cssc.201600592 ↗
14. Huan T, Rousse G, Zanna S, Lucas I, Xu X, Menguy N, Mougel V, Fontecave M (2017) A dendritic nanostructured copper oxide electrocatalyst for the oxygen evolution reaction. Angew Chem Int Ed 56:4792–479610.1002/anie.201700388 ↗
15. Li TT, Cao S, Yang C, Chen Y, Lv X, Fu W (2015) Electrochemical water oxidation by in situ-generated copper oxide film from [Cu(TEOA)(H2O)2][SO4] complex. Inorg Chem 54:3061–306710.1021/acs.inorgchem.5b00266 ↗
16. Liu X, Cui S, Sun Z, Ren Y, Zhang X, Du P (2016) Self-supported copper oxide electrocatalyst for water oxidation at low overpotential and confirmation of its robustness by Cu K-edge X-ray absorption spectroscopy. J Phys Chem C 120:831–84010.1021/acs.jpcc.5b09818 ↗
17. Handoko AD, Deng S, Deng Y, Cheng A, Chan K, Tan H, Pan Y, Tok ES, Sow CH, Yeo BS (2016) Enhanced activity of H2O2-treated copper(II) oxide nanostructures for the electrochemical evolution of oxygen. Catal Sci Technol 6:269–27410.1039/C5CY00861A ↗
18. Cui S, Liu X, Sun Z, Du P (2016) Noble metal-free copper hydroxide as an active and robust electrocatalyst for water oxidation at weakly basic pH. ACS Sustain Chem Eng 4:2593–260010.1021/acssuschemeng.6b00067 ↗
19. Li TT, Qian J, Zheng YQ (2016) Facile synthesis of porous CuO polyhedron from Cu-based metal organic framework (MOF-199) for electrocatalytic water oxidation. RSC Adv 6:77358–7736510.1039/C6RA18781A ↗
20. Deng Y, Handoko AD, Du Y, Xi S, Yeo BS (2016) In situ Raman spectroscopy of copper and copper oxide surfaces during electrochemical oxygen evolution reaction: identification of CuIII oxides as catalytically active species. ACS Catal 6:2473–248110.1021/acscatal.6b00205 ↗
21. Liu Y, Cheng H, Lyu M, Fan S, Liu Q, Zhang W, Zhi Y, Wang C, Xiao C, Wei S, Ye B, Xie Y (2014) Low overpotential in vacancy-rich ultrathin CoSe2 nanosheets for water oxidation. J Am Chem Soc 136:15670–1567510.1021/ja5085157 ↗
22. Sun Y, Sun Z, Gao S, Cheng H, Liu Q, Piao J, Yao T, Wu C, Hu S, Wei S, Xie Y (2012) Fabrication of flexible and freestanding zinc chalcogenide single layers. Nat Commun 3:1057–106310.1038/ncomms2066 ↗
23. Joya KS, de Groot HJM (2016) Controlled surface-assembly of nanoscale leaf-type Cu-oxide electrocatalyst for high activity water oxidation. ACS Catal 6:1768–177110.1021/acscatal.5b02950 ↗
24. Du X, Huang J, Feng Y, Ding Y (2016) Flower-like 3D CuO microsphere acting as photocatalytic water oxidation catalyst. Chin J Catal 37:123–13410.1016/S1872-2067(15)61012-9 ↗
25. Yu M, Jiang L, Yang H (2015) Ultrathin nanosheets constructed CoMoO4 porous flowers with high activity for electrocatalytic oxygen evolution. Chem Commun 51:14361–1436410.1039/C5CC05511C ↗
26. Gao X, Zhang H, Li Q, Yu X, Hong Z, Zhang X, Liang C, Lin Z (2016) Hierarchical NiCo2O4 hollow microcuboids as bifunctional electrocatalysts for overall water-splitting. Angew Chem Int Ed 55:6290–629410.1002/anie.201600525 ↗
27. Hen B, Qing C, Wang H, Sun D, Wang B, Tang Y (2015) Facile synthesis of Fe-incorporated CuO nanoarrays with enhanced electrochemical performance for lithium ion full batteries. Alloys Compd 649:899–90510.1016/j.jallcom.2015.07.192 ↗
28. Song F, Hu X (2014) Ultrathin cobalt-manganese layered double hydroxide as an efficient oxygen evolution catalyst. J Am Chem Soc 136:16481–1648410.1021/ja5096733 ↗
29. Xu P, Miao C, Cheng K, Ye K, Yin J, Cao D, Pan Z, Wang G, Zhang X (2016) High electrochemical energy storage performance of controllable synthesis of nanorod Cu1.92S accompanying nanoribbon CuS directly grown on copper foam. Electrochim Acta 214:276–28510.1016/j.electacta.2016.08.049 ↗
30. Zhang W, Wen X, Yang S (2003) Controlled reactions on a copper surface: synthesis and characterization of nanostructured copper compound films. Inorg Chem 42:5005–501410.1021/ic0344214 ↗
31. Zhang W, Ding S, Yang Z, Liu A, Qian Y, Tang S, Yang S (2006) Growth of novel nanostructured copper oxide (CuO) films on copper foil. J Cryst Growth 291:479–48410.1016/j.jcrysgro.2006.03.015 ↗
32. Xu S, Ng J, Du A, Liu J, Sun D (2011) Highly efficient TiO2 nanotube photocatalyst for simultaneous hydrogen production and copper removal from water. Int J Hydrog Energy 36:6538–654310.1016/j.ijhydene.2011.03.047 ↗
33. Ghijsen J, Tjeng LH, Elp J, Eskes H, Westerink J, Sawatzky GA, Czyzyk MT (1998) Electronic structure of Cu2O and CuO. Phys Rev B 38:11322–1133010.1103/PhysRevB.38.11322 ↗
34. Dong G, Du B, Liu L, Zhang W, Liang Y, Shi H, Wang W (2017) Synthesis and their enhanced photoelectrochemical performance of ZnO nanoparticle-loaded CuO dandelion heterostructures under solar light. Appl Surf Sci 399:86–9410.1016/j.apsusc.2016.12.024 ↗
35. Guerrero-Araque D, Acevedo-Peña P, Ramírez-Ortega D, Lartundo-Rojas L, Gómez R (2017) SnO2–TiO2 structures and the effect of CuO, CoO metal oxide on photocatalytic hydrogen production. J Chem Technol Biotechnol 92:1531–153910.1002/jctb.5273 ↗
36. Devaraj M, Deivasigamani RK, Jeyadevan S (2013) Enhancement of the electrochemical behavior of CuO nanoleaves on MWCNTs/GC composite film modified electrode for determination of norfloxacin. Colloids Surf B 102:554–56110.1016/j.colsurfb.2012.08.051 ↗
37. Liu X, Zheng H, Sun Z, Han A, Du P (2015) Earth-abundant copper-based bifunctional electrocatalyst for both catalytic hydrogen production and water oxidation. ACS Catal 5:1530–153810.1021/cs501480s ↗
38. Harzandi AM, Tiwari JN, Lee HS, Jeon H, Cho WJ, Lee G, Baik J, Kwak JH, Kim KS (2017) Efficient CO oxidation by 50-facet Cu2O nanocrystals coated with CuO nanoparticles. ACS Appl Mater Interfaces 9:2495–249910.1021/acsami.6b13843 ↗
39. Peng S, Li L, Zhang J, Tan TL, Zhang T, Ji D, Han X, Cheng F, Ramakrishna S (2017) Engineering Co9S8/WS2 array films as bifunctional electrocatalysts for efficient water splitting. J Mater Chem A 5:23361–2336810.1039/C7TA08518D ↗
40. Du J, Chen Z, Ye S, Wiley BJ, Meyer TJ (2015) Copper as a robust and transparent electrocatalyst for water oxidation. Angew Chem Int Ed 54:2073–207810.1002/anie.201408854 ↗
41. Chen H, Gao Y, Sun L (2017) Highly active three-dimensional NiFe/Cu2O nanowires/Cu foam electrode for water oxidation. ChemSusChem 10:1475–148110.1002/cssc.201601884 ↗
42. Man IC, Su HY, Calle-Vallejo F, Hansen HA, Martínez JI, Inoglu NG, Kitchin J, Jaramillo TF, Nørskov JK, Rossmeisl J (2011) Universality in oxygen evolution electrocatalysis on oxide surfaces. ChemCatChem 3:1159–116510.1002/cctc.201000397 ↗
43. Rossmeisl J, Qu ZW, Zhu H, Kroes GJ, Nørskov JK (2007) Electrolysis of water on oxide surfaces. J Electroanal Chem 607:83–8910.1016/j.jelechem.2006.11.008 ↗