journal article·2016-06

Magnetic properties and large magnetocaloric effect in Ho2Cu2In and Ho2Au2In compounds

Lingwei Li, Yalin Yi, Kunpeng Su, Yang Qi, Dexuan Huo, Rainer Pöttgen

Journal of Materials Science· Volume 51· Issue 11
Publisher page

Abstract

The magnetic and magnetocaloric properties of Ho2Cu2In and Ho2Au2In have been investigated. A second-order magnetic phase transition from a paramagnetic to a ferromagnetic state was observed for Ho2Cu2In and Ho2Au2In at Curie temperatures of TC ~ 30 and 21 K, respectively. An additional magnetic transition at 8 K was also observed for Ho2Au2In which is probably related to a spin reorientation phenomenon. A large reversible magnetocaloric effect was observed for both compounds. The maximum values of magnetic entropy change (−ΔSMmax) are 21.9 and 15.8 J/kg K under a field change of 0–7 T for Ho2Cu2In and Ho2Au2In, with the values of the relative cooling power of 638 and 490 J/kg, respectively.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Magnetic and transport properties of perovskites and related materials · Rare-earth and actinide compounds · Shape Memory Alloy Transformations

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (32)

Show source-provided references
1. de Oliveira NA, von Ranke PJ (2010) Theoretical aspects of the magnetocaloric effect. Phys Rep 489:89–15910.1016/j.physrep.2009.12.006 ↗
2. Franco V, Blázquez JS, Ingale B, Conde A (2012) The magnetocaloric effect and magnetic refrigeration near room temperature: materials and models. Ann Rev Mater Res 42:305–34210.1146/annurev-matsci-062910-100356 ↗
3. Moya X, Defay E, Heine V, Mathur ND (2015) Too cool to work. Nat Phys 11:202–20510.1038/nphys3271 ↗
4. Phan MH, Franco V, Chaturvedi A, Stefanoski S, Kirby H, Nolas GS, Srikanth H (2010) Magnetocaloric effect and refrigerant capacity in Sr-doped Eu8Ga16Ge30 type-I clathrates. J Appl Phys 107:09A910-1–09A910-3
5. Wagh AA, Suresh KG, Kumar PA, Elizabeth S (2015) Low temperature giant magnetocaloric effect in multiferroic GdMnO3 single crystals. J Phys D 48:135001-1–135001-7
6. Rubi K, Kumar P, Repaka DM, Chen R, Wang JS, Mahendiran R (2014) Giant magnetocaloric effect in magnetoelectric Eu1−xBaxTiO3. Appl Phys Lett 104:032407-1–032407-410.1063/1.4862981 ↗
7. Zhang YK, Hou L, Ren ZM, Li X, Wilde G (2016) Magnetic properties and magnetocaloric effect in TmZnAl and TmAgAl compounds. J Alloy Compd 565:635–63910.1016/j.jallcom.2015.10.026 ↗
8. Zhang YK, Yang BJ, Wilde G (2015) Magnetic properties and magnetocaloric effect in ternary REAgAl (RE = Er and Ho) intermetallic compounds. J Alloy Compd 619:12–1510.1016/j.jallcom.2014.08.235 ↗
9. Ma Z, Shang YF, Balfour EA, Wu YH, Fu H, Luo Y, Wang SF, Teng BH, Han MG (2016) Magnetic and magnetocaloric properties of GdNi xAl2−x (0.35 ≤ x ≤ 0.70) alloys with multiphase structure. J Mater Sci 51:2134–2140. doi: 10.1007/s10853-015-9523-x10.1007/s10853-015-9523-x ↗
10. Pöttgen R (1994) Er2Au2Sn and other ternary rare earth metal gold stannides with ordered Zr3Al2-Type structure. Z Naturforsch 49b:1309–131310.1515/znb-1994-1001 ↗
11. Rieger W, Nowotny H, Benesovsky F (1964) Die Kristallstruktur von Mo2FeB2. Monatsh Chem 95:1502–150310.1007/BF00901704 ↗
12. Lukachuk M, Pöttgen R (2003) Intermetallic compounds with ordered U3Si2 or Zr3Al2 type structure-crystal chemistry, chemical bonding and physical properties. Z Kristallogr 218:767–78710.1524/zkri.218.12.767.20545 ↗
13. Rodewald ChU, Chevalier B, Pöttgen R (2007) Rare earth-transition metal-magnesium compounds-An overview. J Solid State Chem 180:1720–173610.1016/j.jssc.2007.03.007 ↗
14. Tappe F, Pöttgen R (2011) Rare earth-transition metal-cadmium intermetallics—crystal chemistry and physical properties. Rev Inorg Chem 31:5–2510.1515/revic.2011.007 ↗
15. Heying B, Rodewald Ch U, Chevalier B, Pöttgen R (2013) The stannides RE2Ni2Sn (RE = Pr, Ho, Er, Tm)—structural transition from the W2B2Co to the Mo2B2Fe type as a function of the rare earth size. Z Naturforsch 68b:10–1610.5560/znb.2013-2296 ↗
16. Fisher IR, Islam Z, Canfield PC (1999) Magnetic and transport properties of single-crystal R2Cu2In (R = Gd-Tm, Lu). J Magn Magn Mater 202:1–1010.1016/S0304-8853(99)00383-2 ↗
17. Pöttgen R, Kremer RK, Rayaprol S, Heying B, Hoffmann DR (2007) Magnetic and electrical properties of the intermetallic compounds RE2Au. Z Naturforsch 62b:169–17210.1515/znb-2007-0205 ↗
18. Schappacher FM, Hermes W, Pöttgen R (2009) Structure and magnetic properties of RE2Cu2Cd. J Solid State Chem 182:265–27210.1016/j.jssc.2008.10.033 ↗
19. Rayaprol S, Pöttgen R (2006) Gd2Au2Cd: a Mo2FeB2-type intermetallic with ferromagnetic ordering and spin glass anomalies. Phys Rev B 73:214403–1–214403-810.1103/PhysRevB.73.214403 ↗
20. Matar SF, Pöttgen R, Chevalier B (2014) Electronic and magnetic structures and bonding properties of Ce2T2X (T = d element; X = Mg, Cd, Pb or Sn) intermetallics from first principles. Intermetallics 51:18–2310.1016/j.intermet.2014.02.018 ↗
21. Hulliger F (1996) On tetragonal M2Au2In and related compounds. J Alloy Compd 232:160–16410.1016/0925-8388(95)01925-1 ↗
22. Banerjee BK (1964) On a generalised approach to first and second order magnetic transitions. Phys Lett 12:16–1710.1016/0031-9163(64)91158-8 ↗
23. Chen J, Shen BG, Dong QY, Hu FX, Sun JR (2009) Large reversible magnetocaloric effect caused by two successive magnetic transitions in ErGa compound. Appl Phys Lett 95:132504-1–132504-3
24. Li L, Namiki T, Huo D, Qian Z, Nishimura K (2013) Two successive magnetic transitions induced large refrigerant capacity in HoPdIn compound. Appl Phys Lett 103:222405–1–222405-4
25. Chaturvedi A, Stefanoski S, Phan MH, Nolas GS, Srikanth H (2011) Table-like magnetocaloric effect and enhanced refrigerant capacity in Eu8Ga16Ge30-EuO composite materials. Appl Phys Lett 99:162513-1–162513-310.1063/1.3654157 ↗
26. Dong QY, Chen J, Shen J, Sun JR, Shen BG (2011) Magnetic properties and magnetocaloric effects in R3Ni2 (R = Ho and Er) compounds. Appl Phys Lett 99:132504–1–132504-4
27. Shen J, Wu JF (2011) Magnetocaloric effect and magnetic phase transition in Ho3Co. J Appl Phys 109:07A931-1–07A931-3
28. Kim MS, Sung NH, Son Y, Ko MS, Cho BK (2011) Giant reversible anisotropic magnetocaloric effect in an antiferromagnetic EuFe2As2 single crystal. Appl Phys Lett 98:172509–1–172509-3
29. Wang JL, Campbell SJ, Cadogan JM, Studer A, Zeng R, Dou SX (2011) Magnetocaloric effect in layered NdMn2Ge0.4Si1.6. Appl Phys Lett 98:232509–1–232509-3
30. Zimm C, Jastrab A, Sternberg A, Pecharsky VK, Geschneidner KA Jr et al (1998) Description and performance of near-room temperature magnetic refrigerator. Adv Cryog Eng 43:1759–196610.1007/978-1-4757-9047-4_222 ↗
31. Smaïli A, Chahine R (1998) Thermodynamic investigations of optimum active magnetic regenerators. Cryogenics 38:247–25210.1016/S0011-2275(97)00140-9 ↗
32. Smaïli A, Chahine R (1997) Composite materials for Ericsson-like magnetic refrigeration cycle. J Appl Phys 81:824–82910.1063/1.364166 ↗