journal article·2018-12Open access

Effect of high-pressure torsion on microstructure, mechanical properties and corrosion resistance of cast pure Mg

Donya Ahmadkhaniha, Yi Huang, Matias Jaskari, Antti Järvenpää, Mahmoud Heydarzadeh Sohi, Caterina Zanella, L. Pentti Karjalainen, Terence G. Langdon

Journal of Materials Science· Volume 53· Issue 24

Abstract

High-pressure torsion (HPT) processing was applied to cast pure magnesium, and the effects of the deformation on the microstructure, hardness, tensile properties and corrosion resistance were evaluated. The microstructures of the processed samples were examined by electron backscatter diffraction, and the mechanical properties were determined by Vickers hardness and tensile testing. The corrosion resistance was studied using electrochemical impedance spectroscopy in a 3.5% NaCl solution. The results show that HPT processing effectively refines the grain size of Mg from millimeters in the cast structure to a few micrometers after processing and also creates a basal texture on the surface. It was found that one or five turns of HPT produced no significant difference in the grain size of the processed Mg and the hardness was a maximum after one turn due to recovery in some grains. Measurements showed that the yield strength of the cast Mg increased by about seven times whereas the corrosion resistance was not significantly affected by the HPT processing.
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Research context

OpenAlex topics: Magnesium Alloys: Properties and Applications · Aluminum Alloys Composites Properties · Metal and Thin Film Mechanics

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References (42)

Show source-provided references
1. Staiger MP, Pietak AM, Huadmai J, Dias G (2006) Magnesium and its alloys as orthopedic biomaterials: a review. Biomaterials 27:1728–173410.1016/j.biomaterials.2005.10.003 ↗
2. Witte F (2010) The history of biodegradable magnesium implants: a review. Acta Biomater 6:1680–169210.1016/j.actbio.2010.02.028 ↗
3. Song G (2007) Control of biodegradation of biocompatable magnesium alloys. Corros Sci 49:1696–170110.1016/j.corsci.2007.01.001 ↗
4. Li L, Gao J, Wang Y (2004) Evaluation of cyto-toxicity and corrosion behavior of alkali-heat-treated magnesium in simulated body fluid. Surf Coat Technol 185:92–9810.1016/j.surfcoat.2004.01.004 ↗
5. Wang Y, Wei M, Gao J (2009) Improve corrosion resistance of magnesium in simulated body fluid by dicalcium phosphate dihydrate coating. Mater Sci Eng C 29:1311–131610.1016/j.msec.2008.09.051 ↗
6. Hornberger H, Virtanen S, Boccaccini AR (2012) Biomedical coatings on magnesium alloys—a review. Acta Biomater 8:2442–245510.1016/j.actbio.2012.04.012 ↗
7. Hänzi AC, Gerber I, Schinhammer M, Löffler JF, Uggowitzer PJ (2010) On the in vitro and in vivo degradation performance and biological response of new biodegradable Mg–Y–Zn alloys. Acta Biomater 6:1824–183310.1016/j.actbio.2009.10.008 ↗
8. Zong Y, Yuan G, Zhang X, Mao L, Niu J, Ding W (2012) Comparison of biodegradable behaviors of AZ31 and Mg–Nd–Zn–Zr alloys in Hank’s physiological solution. Mater Sci Eng B 177:395–40110.1016/j.mseb.2011.09.042 ↗
9. Abidin NIZ, Rolfe B, Owen H, Malisano J, Martin D, Hofstetter J, Uggowitzer PJ, Atrens A (2013) The in vivo and in vitro corrosion of high-purity magnesium and magnesium alloys WZ21 and AZ91. Corros Sci 75:354–36610.1016/j.corsci.2013.06.019 ↗
10. Han H, Minghui Y, Seok H, Byun J, Cha P, Yang S, Kim YC (2013) The modification of microstructure to improve the biodegradation and mechanical properties of a biodegradable Mg alloy. J Mech Behav Biomed Mater 20:54–6010.1016/j.jmbbm.2012.12.007 ↗
11. op’t Hoog C, Birbilis N, Estrin Y (2008) Corrosion of pure Mg as a function of grain size and processing route. Adv Eng Mater 10:579–58210.1002/adem.200800046 ↗
12. Huang Y, Figueiredo RB, Baudin T, Langdon TG (2012) Evolution of strength and homogeneity in a magnesium AZ31 alloy processed by high-pressure torsion at different temperatures. Adv Eng Mater 14:1018–102610.1002/adem.201200016 ↗
13. Kawasaki M, Figueiredo RB, Huang Y, Langdon TG (2014) Interpretation of hardness evolution in metals processed by high-pressure torsion. J Mater Sci 49:6586–6596. https://doi.org/10.1007/s10853-014-8262-810.1007/s10853-014-8262-8 ↗
14. Lee H, Ahn B, Kawasaki M, Langdon TG (2015) Evolution in hardness and microstructure of ZK60A magnesium alloy processed by high-pressure torsion. J Mater Res Technol 4:18–2510.1016/j.jmrt.2014.10.015 ↗
15. Edalati K, Yamamoto A, Horita Z, Ishihara T (2011) High-pressure torsion of pure magnesium: evolution of mechanical properties, microstructures and hydrogen storage capacity with equivalent strain. Scripta Mater 64:880–88310.1016/j.scriptamat.2011.01.023 ↗
16. Figueiredo RB, Cetlin PR, Langdon TG (2011) Using finite element modeling to examine the flow processes in quasi-constrained high-pressure torsion. Mater Sci Eng A 528:8198–820410.1016/j.msea.2011.07.040 ↗
17. Figueiredo RB, Pereira PHR, Aguilar MTP, Cetlin PR, Langdon TG (2012) Using finite element modeling to examine the temperature distribution in quasi-constrained high-pressure torsion. Acta Mater 60:3190–319810.1016/j.actamat.2012.02.027 ↗
18. Edalati K, Horita Z, Langdon TG (2009) The significance of slippage in processing by high-pressure torsion. Scripta Mater 60:9–1210.1016/j.scriptamat.2008.08.042 ↗
19. Loucif A, Figueiredo RB, Kawasaki M, Langdon TG (2012) Effect of aging on microstructural development in an Al–Mg–Si alloy processed by high-pressure torsion. J Mater Sci 47:7815–7820. https://doi.org/10.1007/s10853-012-6400-810.1007/s10853-012-6400-8 ↗
20. Bonarski BJ, Schafler E, Mingler B, Skrotzki W, Mikulowski B, Zehetbauer MJ (2008) Texture evolution of Mg during high-pressure torsion. J Mater Sci 43:7513–7518. https://doi.org/10.1007/s10853-008-2794-810.1007/s10853-008-2794-8 ↗
21. Čížek J, Procházka I, Smola B, Stulíková I, Kužel R, Matěj Z, Cherkaska V, Islamgaliev RK, Kulyasova O (2007) Microstructure and thermal stability of ultra fine grained Mg-based alloys prepared by high-pressure torsion. Mater Sci Eng A 462:121–12610.1016/j.msea.2006.01.177 ↗
22. Kawasaki M, Figueiredo RB, Langdon TG (2011) An investigation of hardness homogeneity throughout disks processed by high-pressure torsion. Acta Mater 59:308–31610.1016/j.actamat.2010.09.034 ↗
23. Figueiredo RB, Aguilar MTP, Cetlin PR, Langdon TG (2011) Deformation heterogeneity on the cross-sectional planes of a magnesium alloy processed by high-pressure torsion. Metall Mater Trans A 42A:3013–302110.1007/s11661-011-0609-z ↗
24. Al-Zubaydi A, Figueiredo RB, Huang Y, Langdon TG (2013) Structural and hardness inhomogeneities in Mg–Al–Zn alloys processed by high-pressure torsion. J Mater Sci 48:4661–4670. https://doi.org/10.1007/s10853-013-7176-110.1007/s10853-013-7176-1 ↗
25. Qiao XG, Zhao YW, Gan WM, Chen Y, Wu K, Gao M, Starink MJ (2014) Hardening mechanism of commercially pure Mg processed by high pressure torsion at room temperature. Mater Sci Eng A 619:95–10610.1016/j.msea.2014.09.068 ↗
26. Ahmadkhaniha D, Järvenpää A, Jaskari M, Sohi MH, Zarei-Hanzaki A, Fedel M, Deflorian F, Karjalainen LP (2016) Microstructural modification of pure Mg for improving mechanical and biocorrosion properties. J Mech Behav Biomed Mater 61:360–37010.1016/j.jmbbm.2016.04.015 ↗
27. Kawasaki M (2014) Different models of hardness evolution in ultrafine-grained materials processed by high-pressure torsion. J Mater Sci 49:18–34. https://doi.org/10.1007/s10853-013-7687-910.1007/s10853-013-7687-9 ↗
28. Huang Y, Figueiredo RB, Baudin T, Helbert AL, Brisset F, Langdon TG (2013) Microstructure and texture evolution in a magnesium alloy during processing by high-pressure torsion. Mater Res 16:577–58510.1590/S1516-14392013005000025 ↗
29. Valiev RZ, Alexandrov IV, Zhu YT, Lowe TC (2002) Paradox of strength and ductility in metals processed by severe plastic deformation. J Mater Res 17:5–810.1557/JMR.2002.0002 ↗
30. Biswas S, Dhinwal SS, Suwas S (2010) Room-temperature equal channel angular extrusion of pure magnesium. Acta Mater 58:3247–326110.1016/j.actamat.2010.01.051 ↗
31. Song GL, Xu Z (2012) Effect of microstructure evolution on corrosion of different crystal surfaces of AZ31 Mg alloy in a chloride containing solution. Corros Sci 54:97–10510.1016/j.corsci.2011.09.005 ↗
32. Ascencio M, Pekguleryuz M, Omanovic S (2014) An investigation of the corrosion mechanisms of WE43 Mg alloy in a modified simulated body fluid solution: the influence of immersion time. Corros Sci 87:489–50310.1016/j.corsci.2014.07.015 ↗
33. Yamashita A, Horita Z, Langdon TG (2001) Improving the mechanical properties of magnesium and a magnesium alloy through severe plastic deformation. Mater Sci Eng A 300:142–14710.1016/S0921-5093(00)01660-9 ↗
34. Figueiredo RB, Cetlin PR, Langdon TG (2007) The processing of difficult-to-work alloys by ECAP with an emphasis on magnesium alloys. Acta Mater 55:4769–477910.1016/j.actamat.2007.04.043 ↗
35. Cetlin PR, Aguilar MTP, Figueiredo RB, Langdon TG (2010) Avoiding cracks and inhomogeneities in billets processed by ECAP. J Mater Sci 45:4561–4570. https://doi.org/10.1007/s10853-010-4384-910.1007/s10853-010-4384-9 ↗
36. Horita Z, Matsubara K, Makii K, Langdon TG (2002) A two-step processing route for achieving a superplastic forming capability in dilute magnesium alloys. Scripta Mater 47:255–26010.1016/S1359-6462(02)00135-5 ↗
37. Lee HJ, Lee SK, Jung KH, Lee GA, Ahn B, Kawasaki M, Langdon TG (2015) Evolution of hardness and texture of a ZK60A magnesium alloy processed by high-pressure torsion. Mater Sci Eng A 630:90–9810.1016/j.msea.2015.02.011 ↗
38. Torbati-Sarraf SA, Sabbaghianrad S, Figueiredo RB, Langdon TG (2017) Orientation imaging microscopy and microhardness in a ZK60 magnesium alloy processed by high-pressure torsion. J Alloys Compd 712:185–19310.1016/j.jallcom.2017.04.054 ↗
39. Sabbaghianrad S, Torbati-Sarraf SA, Langdon TG (2018) An investigation of the limits of grain refinement after processing by a combination of severe plastic deformation techniques: a comparison of Al and Mg alloys. Mater Sci Eng A 712:373–37910.1016/j.msea.2017.11.090 ↗
40. Silva CLP, Oliveira AC, Costa CGF, Figueiredo RB, MdeF Leite, Pereira MM, Lins VFC, Langdon TG (2017) Effect of severe plastic deformation on the biocompatibility and corrosion rate of pure magnesium. J Mater Sci 52:5992–6003. https://doi.org/10.1007/s10853-017-0835-x10.1007/s10853-017-0835-x ↗
41. Xin R, Luo Y, Zuo A, Gao J, Liu Q (2012) Texture effect on corrosion behavior of AZ31 Mg alloy in simulated physiological environment. Mater Lett 72:1–410.1016/j.matlet.2011.11.032 ↗
42. Nie M, Wang CT, Qu M, Gao N, Wharton JA, Langdon TG (2014) The corrosion behavior of commercial purity titanium processed by high-pressure torsion. J Mater Sci 49:2824–2831. https://doi.org/10.1007/s10853-013-7988-z10.1007/s10853-013-7988-z ↗