journal article·2014-10

Synthesis of acetone reduced graphene oxide/Fe3O4 composite through simple and efficient chemical reduction of exfoliated graphene oxide for removal of dye from aqueous solution

Kaushal R. Parmar, Isha Patel, Shaik Basha, Z. V. P. Murthy

Journal of Materials Science· Volume 49· Issue 19
Publisher page

Abstract

A simple and effective technique for reduction of graphene oxide at low temperature (70 C) using acetone was reported for the first time. Magnetically recoverable acetone reduced graphene oxide (ARGO)/Fe3O4 composite was synthesized by uniformly decorating Fe3O4 on ARGO. The synthesized ARGO/Fe3O4 composite was character- ized by the powder X-ray diffraction, scanning electron microscopy, transmission electron microscopy, Fourier transform-infrared spectroscopy and thermogravimetric analysis. An organic dye rhodamine 6G was used as an adsorbate for investigating the adsorption characteristics of the composite. The adsorption kinetic data were best described by the pseudo-second-order model, and equilib- rium was achieved within 2 h. Dye adsorption was favored in basic conditions (pH 9-11) and governed by intraparticle diffusion process. The maximum dye adsorption on the composite was 93.37 mg/g at 293 K, and it followed the Langmuir-Freundlich model. The calculated thermodynamic parameters (DG, DH and DS) showed that the dye adsorption onto composite was feasible, spontaneous and exothermic. The ARGO/Fe3O4 composite was easily con- trolled in magnetic field for desired separation, leading to an easy removal of the dye from wastewater, which holds great potential for dye decontamination.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Graphene research and applications · Graphene and Nanomaterials Applications · Nanomaterials for catalytic reactions

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (58)

Show source-provided references
1. Hai FI, Yamamoto K, Fukushi K (2007) Hybrid treatment systems for dye wastewater. Crit Rev Environ Sci Technol 37:315–37710.1080/10643380601174723 ↗
2. Mohanty K, Naidu JT, Meikap BC et al (2006) Removal of crystal violet from wastewater by activated carbons prepared from rice husk. Ind Eng Chem Res 45:5165–517110.1021/ie060257r ↗
3. RaoCNR SoodAK, Subrahmanyam KS et al (2009) Graphene: the new two-dimensional nanomaterial. Angew Chem Int Ed 48:7752–777710.1002/anie.200901678 ↗
4. Ramesh GK, Vijaya Kumar A, Muralidhar HB et al (2011) Graphene and graphene oxide as effective adsorbents toward anionic and cationic dyes. Colloid Interface Sci 361:270–27710.1016/j.jcis.2011.05.050 ↗
5. Fan L, Luo C, Sun M et al (2012) Synthesis of graphene oxide decorated with magnetic cyclodextrin for fast chromium removal. J Mater Chem 22:24577–2458310.1039/c2jm35378d ↗
6. Liu F, Chung S, Oh G et al (2012) Three-dimensional graphene oxide nanostructure for fast and efficient water-soluble dye removal. ACS Appl Mater Interface 4:922–92710.1021/am201590z ↗
7. Luo B, Liu S, Zhi L (2012) Chemical approaches toward graphene-based nanomaterials and their applications in energy-related areas. Small 8:630–64610.1002/smll.201101396 ↗
8. Deng H, Li XL, Peng Q et al (2005) Monodisperse magnetic single-crystal ferrite microspheres. Angew Chem Int Ed 44:2782–278510.1002/anie.200462551 ↗
9. Yang X, Zhang X, Ma Y et al (2009) Superparamagnetic graphene oxide–Fe3O4 nanoparticles hybrid for controlled targeted drug carriers. J Mater Chem 19:2710–271410.1039/b821416f ↗
10. Ma X, Tao H, Yang K et al (2012) A functionalized graphene oxide-iron oxide nanocomposite for magnetically targeted drug delivery, photothermal therapy, and magnetic resonance imaging. Nano Res 5:199–21210.1007/s12274-012-0200-y ↗
11. Kemp KC, Seema H, Saleh M et al (2013) Environmental applications using graphene composites: water remediation and gas adsorption. Nanoscale 5:3149–317110.1039/c3nr33708a ↗
12. Sun HM, Cao LY, Lu LH (2011) Magnetite/reduced graphene oxide nanocomposites: one step solvothermal synthesis and use as a novel platform for removal of dye pollutants. Nano Res 4:550–56210.1007/s12274-011-0111-3 ↗
13. Zhou KF, Zhu YH, Yang XL (2010) One-pot preparation of graphene/Fe3O4 composites by a solvothermal reaction. New J Chem 34:2950–295510.1039/c0nj00283f ↗
14. Zhang Y, Chen B, Zhang L et al (2011) Controlled assembly of Fe3O4 magnetic nanoparticles on graphene oxide. Nanoscale 3:1446–145010.1039/c0nr00776e ↗
15. Marcano DC, Kosynkin DV, Berlin JM et al (2010) Improved synthesis of graphene oxide. ACS Nano 4:4806–481410.1021/nn1006368 ↗
16. Xu C, Wang X (2009) Fabrication of flexible metal-nanoparticle films using graphene oxide sheets as substrates. Small 5:2212–221710.1002/smll.200900548 ↗
17. Moon IK, Lee J, Ruoff RS et al (2010) Reduced graphene oxide by chemical graphitization. Nat Commun 1:73–7910.1038/ncomms1067 ↗
18. Zhang J, Srivastava RS, Misra RDK (2007) Core-Shell Magnetite nanoparticles surface encapsulated with smart stimuli-responsive polymer: synthesis, characterization, and LCST of viable drug-targeting delivery system. Langmuir 23:6342–635110.1021/la0636199 ↗
19. Adireddy S, Lin C, Palshin V et al (2009) Size-controlled synthesis of quasi-monodisperse transition-metal ferrite nanocrystals in fatty alcohol solutions.J. Phys Chem C113:20800–20811
20. McAllister MJ, Li JL, Adamson DH et al (2007) Single sheet functionalized graphene by oxidation and thermal expansion of graphite. Chem Mater 19:4396–440410.1021/cm0630800 ↗
21. Stankovich S, Dikin DA, Piner RD et al (2007) Synthesis of graphene-based nanosheets via chemical reduction of exfoliated graphite oxide. Carbon 45:1558–156510.1016/j.carbon.2007.02.034 ↗
22. Morrison RT, Boyd RN (1992) Organic chemistry, 6th edn. Prentice Hall, NJ, p 798
23. Feng H, Cheng R, Zhao X et al (2013) A low-temperature method to produce highly reduced graphene oxide. Nat Commun 4:153910.1038/ncomms2555 ↗
24. Singh DK, Iyer PK, Giri PK (2012) Role of molecular interactions and structural defects in the efficient fluorescence quenching by carbon nanotubes. Carbon 50:4495–450510.1016/j.carbon.2012.05.030 ↗
25. Kim BT, Lee HK, Moon H et al (1995) Adsorption of radionuclides from aqueous solutions by inorganic adsorbents. Sep Purif Technol 30:3165–3182
26. Helfferich F (1962) Ion exchange. McGraw Hill, New York
27. Annadurai G, Juang RS, Lee DJ (2001) Adsorption of rhodamine 6G from aqueous solutions on activated carbon. J Environ Sci Health A Tox Hazard Subst Environ Eng 36:715–72510.1081/ESE-100103755 ↗
28. Shukla NB, Madras G (2012) Kinetics of adsorption of methylene blue and rhodamine 6G on acrylic acid-based superabsorbents. J Appl Polym Sci 126:463–47210.1002/app.36717 ↗
29. Gemeay AH (2002) Adsorption characteristics and the kinetics of the cation exchange of rhodamine-6G with Na + -montmorillonite. J Colloid Interface Sci 251:235–24110.1006/jcis.2002.8410 ↗
30. Senturk HB, Ozdes C (2010) Biosorption of rhodamine 6G from aqueous solutions onto almond shell (Prunus dulcis) as a low cost biosorbent. Desalination 252:81–8710.1016/j.desal.2009.10.021 ↗
31. Wu Q, Feng C, Wang C et al (2013) A facile one-pot solvothermal method to produce superparamagnetic graphene-Fe3O4 nanocomposite and its application in the removal of dye from aqueous solution. Colloids Surf B Biointerface 101:210–21410.1016/j.colsurfb.2012.05.036 ↗
32. Kyzas GZ, Travlou NA, Kalogirou O et al (2013) Magnetic graphene oxide: effect of preparation route on reactive black 5 adsorption. Materials 6:1360–137610.3390/ma6041360 ↗
33. Yao Y, Miao S, Liu S et al (2012) Synthesis, characterization, and adsorption properties of magnetic Fe3O4 @graphene nanocomposite. Chem Eng J 184:326–33210.1016/j.cej.2011.12.017 ↗
34. Deng J-H, Zhang X-R, Zeng G-M et al (2013) Simultaneous removal of Cd(II) and ionic dyes from aqueous solution using magnetic graphene oxide nanocomposite as an adsorbent. Chem Eng J 226:189–20010.1016/j.cej.2013.04.045 ↗
35. Wang X, Liu Z, Zhong H et al (2014) A facile one-step approach to functionalized graphene oxide-based hydrogels used as effective adsorbents toward anionic dyes. Appl Surf Sci. doi: 10.1016/j.apsusc.2014.04.103
36. Wang S, Wei J, Lv S et al (2013) Removal of organic dyes in environmental water onto magnetic-sulfonic graphene nanocomposite. Clean: Soil, Air, Water 00(0):1–1010.1016/j.jclepro.2013.09.038 ↗
37. Xie G, Xi P, Liu H et al (2012) A facile chemical method to produce superparamagnetic graphene oxide–Fe3O4 hybrid composite and its application in the removal of dyes from aqueous solution. J Mater Chem 22:1033–103910.1039/C1JM13433G ↗
38. Geng Z, Lin Y, Yu X et al (2012) Highly efficient dye adsorption and removal: a functional hybrid of reduced graphene oxide–Fe3O4 nanoparticles as an easily regenerative adsorbent. J Mater Chem 22:3527–353510.1039/c2jm15544c ↗
39. Fan W, Gao W, Zhang C et al (2012) Hybridization of graphene sheets and carbon-coated Fe3O4 nanoparticles as a synergistic adsorbent of organic dyes. J Mater Chem 22:25108–2511510.1039/c2jm35609k ↗
40. Liu J, Cao H, Xiong J et al (2012) Ferromagnetic hematite@ graphene nanocomposites for removal of rhodamine B dye molecules from water. Cryst Eng Commun 14:5140–514410.1039/c2ce25578b ↗
41. Sun H, Cao L, Lu L (2011) Magnetite/reduced graphene oxide nanocomposites: one step solvothermal synthesis and use as a novel platform for removal of dye pollutants. Nano Res 4:550–56210.1007/s12274-011-0111-3 ↗
42. Li C, Dong D, Yang J et al (2014) Modified nano-graphite/Fe3O4 composite as efficient adsorbent for the removal of methyl violet from aqueous solution. J Mol Liq 196:348–35610.1016/j.molliq.2014.04.010 ↗
43. Hamad S, Sanchez-Valencia JR, Barranco A et al (2009) Molecular dynamics simulation of the effect of pH on the adsorption of rhodamine laser dyes on TiO2 hydroxylated surfaces. Mol Simul 35:1140–115110.1080/08927020903108083 ↗
44. Sreelatha G, Ageetha V, Parmar J et al (2011) Equilibrium and kinetic studies on reactive dye adsorption using palm shell powder (an agrowaste) and chitosan. J Chem Eng Data 56:35–4210.1021/je1007263 ↗
45. Crini G (2008) Kinetic and equilibrium studies on the removal of cationic dyes from aqueous solution by adsorption onto a cyclodextrin polymer. Dyes Pigm 77:415–42610.1016/j.dyepig.2007.07.001 ↗
46. Sadhasivam S, Savitha S, Swaminathan K (2007) Exploitation of Trichoderma harzianum mycelial waste for the removal of rhodamine 6G from aqueous solution. J Environ Manage 85:155–16110.1016/j.jenvman.2006.08.010 ↗
47. Duran C, Ozdes D, Gundogdu A et al (2011) Kinetics and isotherm analysis of basic dyes adsorption onto almond shell (Prunus dulcis) as a low cost adsorbent. J Chem Eng Data 56:2136–214710.1021/je101204j ↗
48. Ugurlu M, Karaoglu MH (2011) Adsorption of ammonium from an aqueous solution by fly ash and sepiolite: isotherm, kinetic and thermodynamic analysis. Microporous Mesoporous Mater 139:173–17810.1016/j.micromeso.2010.10.039 ↗
49. Hameed BH, Mahmoud DK, Ahmad AL (2008) Equilibrium modeling and kinetic studies on the adsorption of basic dye by a low-cost adsorbent: coconut (Cocos nucifera) bunch waste. J Hazard Mater 158:65–7210.1016/j.jhazmat.2008.01.034 ↗
50. Rudzinski W, Panczyk T (2002) The Langmuirian adsorptionkinetics revised. Adsorption 8:23–3410.1023/A:1015214406179 ↗
51. Dotto GL, Pinto LA (2011) Adsorption of food dyes acid blue 9 and food yellow 3 onto chitosan: stirring rate effect in kinetics and mechanism. J Hazard Mater 187:164–17010.1016/j.jhazmat.2011.01.016 ↗
52. Kumar D, Gaur JP (2011) Chemical reaction- and particle diffusion-based kinetic modeling of metal biosorption by a Phormidium sp.-dominated cyanobacterial mat. Bioresour Technol 102:633–64010.1016/j.biortech.2010.08.014 ↗
53. Dizge N, Aydiner C, Demirbas E et al (2008) Adsorption of reactive dyes from aqueous solutions by fly ash: kinetic and equilibrium studies. J Hazard Mater 150:737–74610.1016/j.jhazmat.2007.05.027 ↗
54. Ponnusami V, Rajan KS, Srivastava SN (2010) Application of film-pore diffusion model for methylene blue adsorption onto plant leaf powders. Chem Eng J 163:236–24210.1016/j.cej.2010.07.052 ↗
55. Khraisheh MA, Al-Degs YS, Allen SJ et al (2002) Elucidation of controlling steps of reactive dye adsorption on activated carbon. Ind Eng Chem Res 141:1651–165710.1021/ie000942c ↗
56. Sontheimer H, Crittenden JC, Summers RS (1988) Activated carbon for water treatment. DVGW Forschungsstelle am Engler-Bunte-Institut der Universitat Karlsruhe (TH), AWWA Research Foundation, Karlsruhe, Denver
57. Xu J, Wang L, Zhu Y (2012) Decontamination of bisphenol A from aqueous solution by graphene adsorption. Langmiur 28:8418–842510.1021/la301476p ↗
58. Zhao G, Li J, Ren X et al (2011) Few-layered graphene oxide nanosheets as superior sorbents for heavy metal ion pollution management. Environ Sci Technol 45:10454–1046210.1021/es203439v ↗