Catalytic conversion of Kraft lignin to bio-multilayer graphene materials under different atmospheres
Source abstract
Abstract
Kraft lignin was catalytic graphitized by iron at 1000 °C in argon, hydrogen, CO2, methane, and natural gas atmospheres, respectively. The effect of atmospheric agent types on product distribution (gas, liquid, and solid carbon yields) was analyzed. The solid products were characterized by scanning electron microscopy, Raman, high-resolution transmission electron microscopy, and X-ray diffraction. Experimental results have shown that the degree of graphitization of Kraft lignin depends not only on the highest temperature, but also the type of ambient gas phase during heat treatment. Methane and natural gas in the ambient gas phase seem to accelerate the formation of multilayer graphene materials with a range of 2–30 layers, and hydrogen and carbon dioxide have an etching effect on solid carbon species during the catalytic graphitization process, while multilayer graphene-encapsulated iron nanoparticles were the main products in the case of argon.
Source: openaire · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Lignin and Wood Chemistry · Thermochemical Biomass Conversion Processes · Catalysis for Biomass Conversion
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (30)
Show source-provided references
1. Ōya A, Marsh H (1982) Phenomena of catalytic graphitization. J Mater Sci 17(2):309–322. https://doi.org/10.1007/BF0059146410.1007/BF00591464 ↗
2. Noda Tokiti, Inagaki Michio (1964) Effect of gas phase on graphitization of carbon. Carbon 2:127–13010.1016/0008-6223(64)90052-1 ↗
3. Noda T, Inagaki M, Sekiya T (1965) Kinetic studies of the graphitization process—I effect of ambient gas phase on the rate of graphitization. Carbon 3:175–18010.1016/0008-6223(65)90045-X ↗
4. Yan Q, Toghiani H, Yu F, Cai Z, Zhang J (2011) Effects of pyrolysis conditions on yield of bio-chars from pine chips. For Prod J 61(5):367–371
5. Okazaki S, Yamaguchi K, Sakamoto A, Ogi T, Okuyama K (2014) Effect of gas atmosphere on graphitization of carbon powder. Kagaku Kogaku Ronbunshu 40(1):12–1710.1252/kakoronbunshu.40.12 ↗
6. Bachmatiuk A, Boeckl J, Smith H, Ibrahim I, Gemming T, Oswald S, Kazmierczak W, Makarov D, Schmidt OG, Eckert J, Fu LH, Rummeli MH (2015) Vertical graphene growth from amorphous carbon films using oxidizing gases. J Phys Chem C 119(31):17965–1797010.1021/acs.jpcc.5b05167 ↗
7. Son IH, Park JH, Kwon S, Choi JW, Rümmeli MH (2016) Graphene coating of silicon nanoparticles with CO2—enhanced chemical vapor deposition. Small 12:658–667. https://doi.org/10.1002/smll.20150288010.1002/smll.201502880 ↗
8. Hata Kenji, Futaba Don N, Mizuno Kohei, Namai Tatsunori, Yumura Motoo, Iijima Sumio (2004) Water-assisted highly efficient synthesis of impurity-free single-walled carbon nanotubes. Science 306(5700):1362–136410.1126/science.1104962 ↗
9. Vlassiouk I, Regmi M, Fulvio P, Dai S, Datskos P, Eres G, Smirnov S (2011) Role of hydrogen in chemical vapor deposition growth of large single-crystal graphene. ACS Nano 5:6069–6076. https://doi.org/10.1021/nn201978y10.1021/nn201978y ↗
10. Son IH, Song HJ, Kwon S, Bachmatiuk A, Lee SJ, Benayad A, Park JH, Choi J-Y, Chang H, Rümmeli MH (2014) CO2 enhanced chemical vapor deposition growth of few-layer graphene over NiOx. ACS Nano 8:9224–9232. https://doi.org/10.1021/nn504342e10.1021/nn504342e ↗
11. Mitchel WC, Boeckl J, Tomlin D, Lu W, Rigueur J, Reynolds J (2005) Growth of carbon nanotubes by sublimation of silicon carbide substrates. In: Razeghi M, Brown GJ (eds) International Society for Optics and Photonics, p 77. https://doi.org/10.1117/12.59045610.1117/12.590456 ↗
12. Lu W, Boeckl JJ, Mitchel WC (2010) A critical review of growth of low-dimensional carbon nanostructures on SiC (0 0 0 1): impact of growth environment. J Phys D Appl Phys 43:374004. https://doi.org/10.1088/0022-3727/43/37/37400410.1088/0022-3727/43/37/374004 ↗
13. Lu WJ, Boeckl J, Mitchel WC, Rigueur J, Collins WE (2006) Role of oxygen in growth of carbon nanotubes on SiC. Mater Sci Forum 527–529:1575–1578. https://doi.org/10.4028/www.scientific.net/MSF.527-529.157510.4028/www.scientific.net/MSF.527-529.1575 ↗
14. Bystrzejewski M, Schönfelder R, Cuniberti G, Lange H, Huczko A, Gemming T, Pichler T, Büchner B, Rümmeli M (2008) Exposing multiple roles of H2O in high-temperature enhanced carbon nanotube synthesis. Chem Mater 20:6586–6588. https://doi.org/10.1021/cm802067610.1021/cm8020676 ↗
15. Nomura T, Katsura M, Sano T (1973) Graphitization of free carbon precipitating due to the reaction of UC with N2. J Nucl Mater 47:58–64. https://doi.org/10.1016/0022-3115(73)90186-410.1016/0022-3115(73)90186-4 ↗
16. Gao L, Ren W, Zhao J, Ma L-P, Chen Z, Cheng H-M (2010) Efficient growth of high-quality graphene films on Cu foils by ambient pressure chemical vapor deposition. Appl Phys Lett 97(18):18310910.1063/1.3512865 ↗
17. Losurdo M, Giangregorio MM, Capezzuto P, Bruno G (2011) Graphene CVD growth on copper and nickel: role of hydrogen in kinetics and structure. Phys Chem Chem Phys 13(46):20836–2084310.1039/c1cp22347j ↗
18. Zhang Y, Li Z, Kim P, Zhang L, Zhou C (2012) Anisotropic hydrogen etching of chemical vapor deposited graphene. ACS Nano 6(1):126–13210.1021/nn202996r ↗
19. Kong J, Cassell AM, Dai H (1998) Chemical vapor deposition of methane for single-walled carbon nanotubes. Chem Phys Lett 292(4–6):567–57410.1016/S0009-2614(98)00745-3 ↗
20. Nikolaev P, Bronikowski MJ, Bradley RK, Rohmund F, Colbert DT, Smith KA, Smalley RE (1999) Gas-phase catalytic growth of single-walled carbon nanotubes from carbon monoxide. Chem Phys Lett 313(1–2):91–9710.1016/S0009-2614(99)01029-5 ↗
21. Xu F, Liu X, Stephen DT (2006) Synthesis of carbon nanotubes on metal alloy substrates with voltage bias in methane inverse diffusion flames. Carbon 44(3):570–57710.1016/j.carbon.2005.07.043 ↗
22. Sun Z, Yan Z, Yao J, Beitler E, Zhu Y, Tour JM (2010) Growth of graphene from solid carbon sources. Nature 468:549–552. https://doi.org/10.1038/nature0957910.1038/nature09579 ↗
23. Liu X, Fu L, Liu N, Gao T, Zhang Y, Liao L, Liu Z (2011) Segregation growth of graphene on Cu–Ni alloy for precise layer control. J Phys Chem C 115:11976–11982. https://doi.org/10.1021/jp202933u10.1021/jp202933u ↗
24. Zheng M, Takei K, Hsia B, Fang H, Zhang X, Ferralis N, Ko H, Chueh Y-L, Zhang Y, Maboudian R, Javey A (2010) Metal-catalyzed crystallization of amorphous carbon to graphene. Appl Phys Lett 96:63110. https://doi.org/10.1063/1.331826310.1063/1.3318263 ↗
25. Kwak J, Chu JH, Choi J-K, Park S-D, Go H, Kim SY, Park K, Kim S-D, Kim Y-W, Yoon E, Kodambaka S, Kwon S-Y (2012) Near room-temperature synthesis of transfer-free graphene films. Nat. Commun 3:645. https://doi.org/10.1038/ncomms165010.1038/ncomms1650 ↗
26. Xie WG, Chen J, Chen J, Ming WW, Deng SZ, Xu NS (2009) Study on effect of hydrogen treatment on amorphous carbon film using scanning probe microscopy. Ultramicroscopy 109(5):451–45610.1016/j.ultramic.2008.10.019 ↗
27. Nasibulin AG, Brown DP, Queipo P, Gonzalez D, Jiang H, Kauppinen EI (2006) An essential role of CO2 and H2O during single-walled CNT synthesis from carbon monoxide. Chem Phys Lett 417:179–18410.1016/j.cplett.2005.10.022 ↗
28. Pimenta MA, Dresselhaus G, Dresselhaus MS, Cançado LG, Jorio A, Saito R (2007) Studying disorder in graphite-based systems by Raman spectroscopy. Phys Chem Chem Phys 9:1276–129010.1039/B613962K ↗
29. Abdelaziz Omar Y, Brink Daniel P, Prothmann Jens, Ravi Krithika, Sun Mingzhe, García-Hidalgo Javier, Sandahl Margareta, Hulteberg Christian P, Turner Charlotta, Lidén Gunnar, Gorwa-Grauslun Marie F (2016) Biological valorization of low molecular weight lignin. Biotechnol Adv 34(8):1318–134610.1016/j.biotechadv.2016.10.001 ↗
30. Fengel D, Wegener G (1984) Wood (Chemistry, Ultrastructure, Reactions). Walter de Gruyter, New York