Recent advances in the modification of polyacrylate latexes
Source abstract
Abstract
Polyacrylate latexes present good film-forming property, and therefore are used in a wide range of applications including coatings, adhesives, additives for paper, textiles, wood, and leather. However, some drawbacks, such as poor elasticity and low hardness have restricted their applications. This review summarizes recent development of polyacrylate latexes modified by polyurethane, organic fluorine, and inorganic nanoparticles, separately, which most often exhibit superior properties to those of their individual components. For each modification method, a comment is given based on our knowledge and related research experience. At last, some perspectives on the future research and development of modification of polyacrylate latexes are concluded.
Source: openaire · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Surface Modification and Superhydrophobicity · Silicone and Siloxane Chemistry · Advanced Polymer Synthesis and Characterization
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (100+)
Show source-provided references
1. Samyn P, Deconinck M, Schoukens G, Stanssens D, Vonck L, Abbeele HV (2010) Modifications of paper and paperboard surfaces with a nanostructured polymer coating. Prog Org Coat 69:442–45410.1016/j.porgcoat.2010.08.008 ↗
2. Nuessle AC, Kine BB (1953) Acrylic resins in textile processing. Ind Eng Chem 45:1287–129310.1021/ie50522a037 ↗
3. Rodrıguez R, Alarcon CH, Ekanayake P, McDonald PJ, Keddie JL, Barandiaran MJ, Asua JM (2008) Correlation of silicone incorporation into hybrid acrylic coatings with the resulting hydrophobic and thermal properties. Macromolecules 41:8537–854610.1021/ma8006015 ↗
4. Zou M, Zhao Q, Zhang Z (2007) Preparation and characterization of polysiloxane–polyacrylates composite lattices by two seeded emulsion polymerization and their film properties. J Appl Polym Sci 103:1406–141110.1002/app.24843 ↗
5. Zou M, Huang F, Nie J, Zhang Z, Ge X (2005) Preparation and characterization of polysiloxane–polyacrylates composite latices and their film properties. Polym Int 54:861–86910.1002/pi.1759 ↗
6. Tamai T, Watanabe M (2006) Acrylic polymer/silica hybrids prepared by emulsifier-free emulsion polymerization and the sol–gel process. J Polym Sci A 44:273–28010.1002/pola.21155 ↗
7. Watanabe M, Tamai T (2006) Acrylic polymer/silica organic–inorganic hybrid emulsions for coating materials: role of the silane coupling agent. J Polym Sci A 44:4736–474210.1002/pola.21574 ↗
8. Peruzzo PJ, Anbinde PS, Pardini OR, Vega J, Costa CA, Galembeck F, Amalvy JI (2011) Waterborne polyurethane/acrylate: comparison of hybrid and blend systems. Prog Org Coat 72:429–43710.1016/j.porgcoat.2011.05.016 ↗
9. Lin M, Chu F, Guyot A, Putaux J, Bourgeat-Lami E (2005) Silicone–polyacrylate composite latex particles. Particles formation and film properties. Polymer 46:1331–133710.1016/j.polymer.2004.11.063 ↗
10. Guyot A, Landfester K, Schork FJ, Wang C (2007) Hybrid polymer latexes. Prog Polym Sci 32:1439–146110.1016/j.progpolymsci.2007.07.003 ↗
11. Zou H, Wu S, Shen J (2008) Polymer/silica nanocomposites: preparation, characterization, properties, and applications. Chem Rev 108:3893–395710.1021/cr068035q ↗
12. Imae T (2003) Fluorinated polymers. Curr Opin Colloid Interf Sci 8:307–31410.1016/S1359-0294(03)00050-5 ↗
13. Castelvetro V, Vita CD (2004) Nanostructured hybrid materials from aqueous polymer dispersions. Adv Colloid Interf Sci 108–109:167–18510.1016/j.cis.2003.10.017 ↗
14. Lee SK, Kim BK (2009) High solid and high stability waterborne polyurethanes via ionic groups in soft segments and chain termini. J Colloid Interf Sci 336:208–21410.1016/j.jcis.2009.03.028 ↗
15. Yen MS, Tsai PY, Hong PD (2006) The solution properties and membrane properties of polydimethylsiloxane waterborne polyurethane blended with the waterborne polyurethanes of various kinds of soft segments. Colloids Surf A 279:1–910.1016/j.colsurfa.2005.09.027 ↗
16. Kuan HC, Su HY, Ma CCM (2005) Synthesis and characterization of polysilicic acid nanoparticles/waterborne polyurethane nanocomposite. J Mater Sci 40:6063–6070. doi: 10.1007/s10853-005-1302-710.1007/s10853-005-1302-7 ↗
17. Li CY, Chiu WY, Don TM (2005) Preparation of polyurethane dispersions by miniemulsion polymerization. J Polym Sci, Part A 43:4870–488110.1002/pola.20959 ↗
18. Barrère M, Landfester K (2003) High molecular weight polyurethane and polymer hybrid particles in aqueous miniemulsion. Macromolecules 36:5119–512510.1021/ma025981+ ↗
19. Okamoto Y, Hasegawa Y, Yoshino F (1996) Urethane/acrylic composite polymer emulsions. Prog Org Coat 29:175–18210.1016/S0300-9440(96)00660-1 ↗
20. Athawale VD, Kulkarni MA (2009) Preparation and properties of urethane/acrylate composite by emulsion polymerization technique. Prog Org Coat 65:392–40010.1016/j.porgcoat.2009.03.004 ↗
21. Wang C, Chu F, Graillat C, Guyot A (2005) Hybrid acrylicpolyurethane polymer latexes. II.Mechanical properties. Polym Advan Technol 16:139–14510.1002/pat.557 ↗
22. Kukanja D, Golob J, Valant AZ, Krajnc M (2000) Structure and properties of acrylic-polyurethane hybrid emulsions and comparison with physical blends. J Appl Polym Sci 78:67–8010.1002/1097-4628(20001003)78:1<67::AID-APP100>3.0.CO;2-4 ↗
23. Wu L, You B, Li D (2002) Synthesis and characterization of urethane/acrylate composite latex. J Appl Polym Sci 84:1620–162810.1002/app.10526 ↗
24. Hirose M, Kadowaki F, Zhou J (1997) The structure and properties of core-shell type acrylic-polyurethane hybrid aqueous emulsions. Prog Org Coat 31:157–16910.1016/S0300-9440(97)00032-5 ↗
25. Dong A, An Y, Feng S, Sun D (1999) Preparation and morphology studies of core-shell type waterborne polyacrylate–polyurethane microspheres. J Colloid Interf Sci 214:118–12210.1006/jcis.1999.5847 ↗
26. Hirose M, Zhou J, Nagai K (2000) The structure and properties of acrylic-polyurethane hybrid emulsions. Prog Org Coat 38:27–3410.1016/S0300-9440(99)00081-8 ↗
27. Li M, Daniels ES, Dimonie V, Sudol ED, El-Aasser MS (2005) Preparation of polyurethane/acrylic hybrid nanoparticles via a miniemulsion polymerization process. Macromolecules 38:4183–419210.1021/ma048141z ↗
28. Schork FJ, Luo Y, Smulders W, Russum JP, Butte A, Fontenot K (2005) Miniemulsion polymerization. Polym Part Adv Polym Sci 175:129–25510.1007/b100115 ↗
29. Landfester K, Bechthold N, Forster S, Antonietti M (1999) Evidence for the preservation of the particle identity in miniemulsion polymerization. Macromol Rapid Commun 20:81–8410.1002/(SICI)1521-3927(19990201)20:2<81::AID-MARC81>3.0.CO;2-G ↗
30. Gooch JW, Dong H, Schork FJ (2000) Waterborne oil-modified polyurethane coatings via hybrid miniemulsion polymerization. J Appl Polym Sci 76:105–11410.1002/(SICI)1097-4628(20000404)76:1<105::AID-APP14>3.0.CO;2-8 ↗
31. Wang C, Chu F, Graillat C, Guyot A (2003) Hybrid acrylic-polyurethane latexes by miniemulsion polymerization. Polym React Eng 11:541–56210.1081/PRE-120024425 ↗
32. Wang C, Chu F, Graillat C, Guyot A, Gauthier C, Chapel JP (2005) Hybrid polymer latexes: acrylics–polyurethane from miniemulsion polymerization: properties of hybrid latexes versus blends. Polymer 46:1113–112410.1016/j.polymer.2004.11.051 ↗
33. Wang C, Chu F, Guyot A, Gauthier C, Boisson F (2006) Hybrid acrylic-polyurethane latexes: emulsion versus miniemulsion polymerization. J Appl Polym Sci 101:3927–394110.1002/app.22889 ↗
34. Wang C, Chu F (2006) Mechanical properties of films from hybrid acrylic-polyurethane polymer colloids. J Disper Sci Technol 27:325–33010.1080/01932690500358030 ↗
35. Lee JR, Jin FL, Park SJ, Park JM (2004) Study of new fluorine-containing epoxy resin for low dielectric constant. Surf Coat Technol 180–181:650–654
36. Ha JW, Park IJ, Lee SB (2005) Hydrophobicity and sliding behavior of liquid droplets on the fluorinated latex films. Macromolecules 38:736–74410.1021/ma0488764 ↗
37. Morent R, DeGeyter N, Verschuren J, DeClerck K, Kiekens P, Leys C (2008) Non-thermal plasma treatment of textiles. Surf Coat Technol 202:3427–344910.1016/j.surfcoat.2007.12.027 ↗
38. Zhang C, Chen Y (2005) Investigation of fluorinated polyacrylate latex with core–shell structure. Polym Int 54:1027–103310.1002/pi.1803 ↗
39. Saïdi S, Guittard F, Guimon C, Geribaldi S (2006) Synthesis and characterization of copolymers based on styrene and partially fluorinated acrylates. Eur Polym J 42:702–71010.1016/j.eurpolymj.2005.09.012 ↗
40. Timperley CM, Arbon RE, Bird M (2003) Bis(fluoroalkyl) acrylic and methacrylic phosphate monomers, their polymers and some of their properties. J Fluor Chem 121:23–3110.1016/S0022-1139(02)00314-7 ↗
41. Malshe VC, Sangaj NS (2005) Fluorinated acrylic copolymers (I) study of clear coatings. Prog Org Coat 91:512–516
42. Linemann RF, Malner TE, Brandsch R, Bar G, Ritter W, Mulhaupt R (1999) Latex blends of fluorinated and fluorine-free acrylates: emulsion polymerization and tapping mode atomic force microscopy of film formation. Macromolecules 32:1715–172110.1021/ma981580b ↗
43. Zhang K, Feng H, Pan Z, Liu D (2001) Synthesis and properties of polyacrylate emulsions modified by fluorine-containing emulsion. J Tsinghua Univ 41:50–52
44. Hu Y, Zhang C, Chen Y, Liu X, Lv M, Hu L (2010) Preparation and structure of fluorinated/non-fluorinated polyacrylate gradient emulsion blend film. Mater Lett 64:2091–209310.1016/j.matlet.2010.06.048 ↗
45. Chen Y, Cheng S, Wang Y (2006) Chemical components and properties of cor-shell acrylate latex containing fluorine in the shell and their films. J Appl Polym Sci 99:107–11410.1002/app.22460 ↗
46. Peng S, Zhao L, Wu L (2007) Surface properties of fluorinated acrylate polymer latex. Acta Phys Chim Sin 23:531–53610.1016/S1872-1508(07)60034-5 ↗
47. Chen Y, Zhang C, Chen X (2006) Emulsifier-free latex of fluorinated acrylate copolymer. Eur Polym J 42:694–70110.1016/j.eurpolymj.2005.08.012 ↗
48. Huang P, Chao Y, Liao Y (2007) Enhancement of water repellency durability of the fabrics treated by fluorinated nanocopolymer emulsions. J Appl Polym Sci 104:2451–245710.1002/app.24736 ↗
49. Ma J, Lu J, Bao Y (2012) Preparation and properties of functionalized fluorine-containing acrylate copolymer. J Funct Mater 43:1336–1340
50. Park IJ, Lee SB, Choi CK (1998) Surface properties of the fluorine-containing graft copolymer of poly((perfluoroalkyl)ethyl methacrylate)-g-poly(methyl methacrylate). Macromolecules 31:7555–755810.1021/ma970262u ↗
51. Guo T, Tang D, Song M, Zhang B (2007) Copolymerizations of butyl methacrylate and fluorinated methacrylates via RAFT miniemulsion polymerization. J Polym Sci, Part A 45:5067–507510.1002/pola.22249 ↗
52. Chen L, Wu F (2011) Effect of different surfactants on colloidal and polymer properties of fluorinated acrylate latex. J Saudi Chem Soc. doi: 10.1016/j.jscs.2011.10.025
53. Yang W, Chen Y, Han D, Zhu L (2013) Synthesis and characterization of the fluorinated acrylic latex: effect of fluorine-containing surfactant on properties of the latex film. J Fluor Chem 149:8–1210.1016/j.jfluchem.2013.02.005 ↗
54. Chen L, Shi H, Wu H, Xiang J (2010) Study on the double fluorinated modification of the acrylate latex. Colloids Surf A 368:148–15310.1016/j.colsurfa.2010.07.032 ↗
55. Marion P, Beinert G, Juhueı D, Lang J (1997) Core-shell latex particles containing a fluorinated polymer in the shell. 2. Internal structure studied by fluorescence nonradiative energy transfer. Macromolecules 30:123–12910.1021/ma960392n ↗
56. Ito F, Ma G, Nagai M, Omi S (2003) Study on preparation of irregular shaped particle in seeded emulsion polymerization accompanied with regulated electrostatic coagulation by counter-ion species. Colloids Surf A 216:109–12210.1016/S0927-7757(02)00541-1 ↗
57. Richar RT, Douglas RA, William FG, Michael JD, Bryan BS, Katherine MS, Dennis GS (1997) Preparation and surface properties of acrylic polymers containing fluoined monomers. Macromolecules 30:2883–289010.1021/ma9618686 ↗
58. Cheng S, Chen Y, Chen Z (2002) Core–shell latex fluorinated polymer rich in shell. J Appl Polym Sci 85:1147–115310.1002/app.10622 ↗
59. Xiao X, Liu J (2008) Synthesis and characterization of fluorine-containing polyacrylate emulsion with core-shell structure. Chinese J Chem Eng 16:626–63010.1016/S1004-9541(08)60131-7 ↗
60. Thomas RR, Glaspey DF, DuBois DC, Kirchner JR, Anton DR, Lloyd KG, Stika KM (2000) Solution properties of partially fluorinated unsaturated esters and surface properties of polyester coatings containing partially fluorinated unsaturated esters as cross-linkers. Langmuir 16:6898–690510.1021/la0003600 ↗
61. Xiang M, Li X, Ober CK, Char K, Genzer J, Sivaniah E, Kramer EJ, Fischer DA (2006) Surface stability in liquid-crystalline block copolymers with semifluorinated monodendron side groups. Macromolecules 33:6106–611910.1021/ma992111s ↗
62. Schmidt DL, Brady RF, Lam K, Schmidt DC, Chaudhury MK (2004) Contact angle hysteresis, adhesion, and marine biofouling. Langmuir 20:2830–283610.1021/la035385o ↗
63. Cheng X, Chen Z, Shi T, Wang H (2007) Synthesis and characterization of core-shell LIPN-fluorine-containing polyacrylate latex. Colloids Surf A 292:119–12410.1016/j.colsurfa.2006.06.006 ↗
64. Cui X, Zhong S, Gao Y, Wang H (2008) Preparation and characterization of emulsifier-free core–shell interpenetrating polymer network-fluorinated polyacrylate latex particles. Colloids Surf A 324:14–2110.1016/j.colsurfa.2008.03.018 ↗
65. Cui X, Zhong S, Wang H (2007) Emulsifier-free core-shell polyacrylate latex nanoparticles containing fluorine and silicon in shell. Polymer 48:7241–724810.1016/j.polymer.2007.10.019 ↗
66. Zhang Q, Zhan X, Chen F (2007) Miniemulsion polymerization of a fluorinated acrylate copolymer: kinetic studies and nanolatex morphology characterization. J Appl Polym Sci 104:641–64710.1002/app.25639 ↗
67. Xie K, Hou A, Shi Y (2008) Synthesis of fluorine-containing acrylate copolymer and application as resins on dyed polyester microfiber fabric. J Appl Polym Sci 108:1778–178210.1002/app.27723 ↗
68. Zhang S, Zhao J, Chu G, Zhang L, Xu A, Li H, Geng B (2011) Synthesis, characterization and properties of a novel fluorinated methacrylate polymer. J Fluor Chem 132:915–91910.1016/j.jfluchem.2011.07.004 ↗
69. Xiao X, Wang Y (2009) Emulsion copolymerization of fluorinated acrylate in the presence of a polymerizable emulsifier. Colloids Surf A 348:151–15610.1016/j.colsurfa.2009.07.006 ↗
70. Xu W, An Q, Hao L, Zhang D, Zhang M (2013) Synthesis and characterization of self-crosslinking fluorinated polyacrylate soap-free latices with core–shell structure. Appl Surf Sci 268:373–38010.1016/j.apsusc.2012.12.104 ↗
71. Zhou J, Zhang L, Ma J (2013) Fluorinated polyacrylate emulsifier-free emulsion mediated by poly(acrylic acid)-b-poly(hexafluorobutyl acrylate) trithiocarbonate via ab initio RAFT emulsion polymerization. Chem Eng J 223:8–1710.1016/j.cej.2013.02.117 ↗
72. Adams J, Hardin A, Vounatsos F (2006) Microwave-assisted synthesis of new polysubstituted dienaminoesters and their cyclization to 3-bromo-2(1H)-pyridinones. J Org Chem 71:9895–989810.1021/jo0618526 ↗
73. Samaroo D, Soll CE, Todaro LJ, Drain CM (2006) Efficient microwave-assisted synthesis of amine-substituted tetrakis(pentafluorophenyl)porphyrin. Org Lett 8:4985–498810.1021/ol060946z ↗
74. Bremner WS, Organ MG (2007) Multicomponent Reactions to form heterocycles by microwave-assisted continuous flow organic synthesis. J Comb Chem 9:14–1610.1021/cc060130p ↗
75. Xiong S, Guo X, Li L, Wu S, Chu P, Xu Z (2010) Preparation and characterization of fluorinated acrylate copolymer latexes by miniemulsion polymerization under microwave irradiation. J Fluor Chem 131:417–42510.1016/j.jfluchem.2009.12.015 ↗
76. Li J, Wang Q, Su C, Chen Q (2007) Preparation and characterization of fluorine-containing acrylate copolymers by 60Co γ-ray radiation co-polymerization. Eur Polym J 43:2928–293410.1016/j.eurpolymj.2007.04.028 ↗
77. Chen Z, Cui X, Jiang W, Cheng X, Wang H (2006) Synthesis and characterization of fluoropolymer modified polyacrylate in emulsion polymerization. J Appl Polym Sci 99:558–56210.1002/app.22490 ↗
78. Yilmaz O, Cheaburu CN, Durraccio D, Gulumser G, Vasile C (2010) Preparation of stable acrylate/montmorillonite nanocomposite latex via in situ batch emulsion polymerization: effect of clay types. Appl Clay Sci 49:288–29710.1016/j.clay.2010.06.007 ↗
79. Bonnefond A, Paulis M, Leiza JR (2011) Kinetics of the emulsion copolymerization of MMA/BA in the presence of sodium montmorillonite. Appl Clay Sci 51:110–11610.1016/j.clay.2010.11.011 ↗
80. Hub C, Harton SE, Hunt MA, Fink R, Ade H (2007) Influence of sample preparation and processing on observed glass transition temperatures of polymer nanocomposites. J Polym Sci, Part B 45:2270–227610.1002/polb.21249 ↗
81. Li B, Zhang S, Xu Q, Wang B (2009) Preparation of composite polyacrylate latex particles with in situ-formed methylsilsesquioxane cores. Polym Adv Technol 20:1190–119410.1002/pat.1371 ↗
82. Jiang L, Pan K, Dan Y (2006) Synthesis and characterization of well-defined poly(methyl methacrylate)/CaCO3/SiO2 three-component composite particles via reverse atom transfer radical polymerization. Colloid Polym Sci 285:65–7410.1007/s00396-006-1535-2 ↗
83. Burunkova JA, Denisyuk IY, Semina SA (2011) Self-organization of ZnO nanoparticles on UV-curable acrylate nanocomposites J Nanotechnol 1–610.1155/2011/951036 ↗
84. Liu H, Ye H, Lin T, Zhou T (2008) Synthesis and characterization of PMMA/Al2O3 composite particles by in situ emulsion polymerization. Particuology 6:207–21310.1016/j.partic.2008.01.003 ↗
85. Song X, Zhao Y, Wang H, Do Q (2009) Fabrication of polymer microspheres using titania as a photocatalyst and pickering stabilizer. Langmuir 25:4443–444910.1021/la8039237 ↗
86. Ma J, Zhang Z, Liu L, Hu J (2006) Application of acrylic resin coating agent modified by nano SiO2. J Soc Leather Technol Chem 90:188–192
87. Ma J, Hu J, Zhang Z (2006) The acrylic resin leather coating agent modified by nano-SiO2. J Compos Mater 40:2189–220110.1177/0021998306062314 ↗
88. Ma J, Hu J, Yang Z, Liu L (2007) Preparation of acrylic resin/modified nano-SiO2 via sol-gel method for leather finishing agent. J Sol–Gel Sci Technol 41:209–21610.1007/s10971-006-1506-6 ↗
89. Ma J, Hu J, Yang Z (2007) Preparation of acrylic resin/nano-SiO2 for leather finishing agent. Mater Manuf Process 22:782–78610.1080/10426910701385465 ↗
90. Liu J, Ma J, Bao Y, Zhu Z, Zhang J, Ma Y (2011) Effect of long-chain acrylate on the properties of polyacrylate/nano-SiO2 composite leather finishing agent. Polym-Plast Technol Eng 50:1546–155110.1080/03602559.2011.603782 ↗
91. Ma J, Hu J, Zhang Z (2007) Polyacrylate/silica nanocomposite materials prepared by sol–gel process. Eur Polym J 43:4169–417710.1016/j.eurpolymj.2007.06.051 ↗
92. Hu J, Ma J, Deng W (2008) Properties of acrylic resin/nano-SiO2 leather finishing agent prepared via emulsifier-free emulsion polymerization. Mater Lett 62:2931–293410.1016/j.matlet.2008.01.127 ↗
93. Huang S, Chin W, Yang W (2004) Viscosity, particle size distribution, and structural investigation of tetramethyloxysilane/2-hydroxyethyl methacrylate sols during the sol–gel process with acid and base catalysts. J Polym Sci, Part B 42:3476–348610.1002/polb.20224 ↗
94. Ni K, Shan G, Weng Z (2005) Synthesis of hybrid core − shell nanoparticles by emulsion (co)polymerization of styrene and γ-methacryloxypropyltrimethoxysilane. Macromolecules 38:7321–732910.1021/ma050334e ↗
95. Watanabe M, Tamai T (2007) Sol − gel reaction in acrylic polymer emulsions: the effect of particle surface charge. Langmuir 23:3062–306610.1021/la062999v ↗
96. Tong X, Tang T, Zhu N, Feng Z, Huang B (2002) Preparation of polymer/silica nanoscale hybrids through sol-gel method involving emulsion polymers(PMMA/SiO2). Chem J Chin Univ 23:306–309
97. Tong X, Tang T, Zhang Q, Feng Z, Huang B (2002) Polymer/silica nanoscale hybrids through sol–gel method involving emulsion polymers. I. Morphology of poly(butyl methacrylate)/SiO2. J Appl Polym Sci 83:46–5410.1002/app.2230 ↗
98. Tong X, Tang T, Feng Z, Huang B (2002) Preparation of polymer/silica nanoscale hybrids through sol-gel method involving emulsion polymers. II. Poly(ethyl acrylate)/SiO2. J Appl Polym Sci 86:3532–353610.1002/app.11152 ↗
99. Chang C, Oyang T, Hwang F, Chen C, Cheng L (2012) Preparation of polymer/silica hybrid hard coatings with enhanced hydrophobicity on plastic substrates. J Non-Cryst Solids 358:72–7610.1016/j.jnoncrysol.2011.08.024 ↗
100. Hashemi-Nasab R, Mirabedini SM (2013) Effect of silica nanoparticles surface treatment on in situ polymerization of styrene–butyl acrylate latex. Prog Org Coat 76:1016–102310.1016/j.porgcoat.2013.02.016 ↗