journal article·2019-08

Hydrothermal synthesis of a graphene/magnetite/montmorillonite nanocomposite and its ultrasonically assisted methylene blue adsorption

Bo Zhang, Tailiang Zhang, Zhidong Zhang, Mingyuan Xie

Journal of Materials Science· Volume 54· Issue 16
Publisher page

Abstract

A graphene/magnetite/montmorillonite nanocomposite (GQDs/Fe3O4/MMT) was synthesized via a simple green hydrothermal method. The effects of pH, temperature, contact time, adsorbent quality, dye concentration and ultrasonication on the adsorption performance of methylene blue (MB) were investigated. For ultrasonic-assisted adsorption, the adsorption rate of GQDs/Fe3O4/MMT can reach 10 s. Ultrasound strongly affected the adsorption equilibrium time but did not affect the maximum adsorption capacity. The main reason for ultrasonic-assisted dyes ultrafast adsorption is cavitation that graphene quantum dots (GQDs) promote nucleation. By adjusting the amount of surface charge, the adsorbent has excellent selective ultrasonic-assisted ultrafast adsorption properties of mixed dyes. The adsorption performance of the GQDs/Fe3O4/MMT was weakly affected by temperature. The theoretical and experimental maximum adsorption capacities were 429.4 mg/g and 225.0 mg/g, respectively. The adsorption kinetics and adsorption isotherms agree well with the pseudo-second-order equation and the Langmuir equation, respectively. After six adsorption/desorption cycles, the adsorption and desorption efficiency of the dye decreased slightly. The results indicated that the GQDs/Fe3O4/MMT nanosorbent has strong potential for removing the cationic dye MB from wastewater.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Carbon and Quantum Dots Applications · Adsorption and biosorption for pollutant removal · Graphene and Nanomaterials Applications

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (51)

Show source-provided references
1. Banerjee S, Benjwal P, Singh M, Kar KK (2018) Graphene oxide (rGO)-metal oxide (TiO2/Fe3O4) based nanocomposites for the removal of methylene blue. Appl Surf Sci 439:560–56810.1016/j.apsusc.2018.01.085 ↗
2. Li Z, Sun Y, Xing J, Xing Y, Meng A (2018) One step synthesis of Co/Cr-codoped ZnO nanoparticle with superb adsorption properties for various anionic organic pollutants and its regeneration. J Hazard Mater 352:204–21410.1016/j.jhazmat.2018.03.049 ↗
3. Mirzaei A, Chen Z, Haghighat F, Yerushalmi L (2017) Enhanced adsorption of anionic dyes by surface fluorination of zinc oxide: a straightforward method for numerical solving of the ideal adsorbed solution theory (IAST). Chem Eng J 330:407–41810.1016/j.cej.2017.07.035 ↗
4. Duman O, Tunç S, Polat TG, Bozoğlan BK (2016) Synthesis of magnetic oxidized multiwalled carbon nanotube-κ-carrageenan-Fe3O4 nanocomposite adsorbent and its application in cationic methylene blue dye adsorption. Carbohydr Polym 147:79–8810.1016/j.carbpol.2016.03.099 ↗
5. Zhang YR, Wang SQ, Shen SL, Zhao BX (2013) A novel water treatment magnetic nanomaterial for removal of anionic and cationic dyes under severe condition. Chem Eng J 233:258–26410.1016/j.cej.2013.07.009 ↗
6. Zhao R, Wang Y, Li X, Sun B, Wang C (2015) Synthesis of β-cyclodextrin-based electrospun nanofiber membranes for highly efficient adsorption and separation of methylene blue. ACS Appl Mater Interfaces 7:26649–2665710.1021/acsami.5b08403 ↗
7. Zhao F, Liu L, Yang F, Ren N (2013) E-Fenton degradation of MB during filtration with Gr/PPy modified membrane cathode. Chem Eng J 230:491–49810.1016/j.cej.2013.06.117 ↗
8. Yu RF, Lin CH, Chen HW, Cheng WP, Kao MC (2013) Possible control approaches of the Electro-Fenton process for textile wastewater treatment using on-line monitoring of DO and ORP. Chem Eng J 218:341–34910.1016/j.cej.2012.12.061 ↗
9. Yao J, Li L, Li P, Yang M (2017) Quantum dots: from fluorescence to chemiluminescence, bioluminescence, electrochemiluminescence, and electrochemistry. Nanoscale 9:l1336410.1039/C7NR05233B ↗
10. Li LL, Ji J, Fei R, Wang CZ, Lu Q, Zhang JR, Jiang LP, Zhu JJ (2012) A facile microwave avenue to electrochemiluminescent two-color graphene quantum dots. Adv Funct Mater 22:2971–297910.1002/adfm.201200166 ↗
11. Li L, Wu G, Yang G, Peng J, Zhao J, Zhu JJ (2013) Focusing on luminescent graphene quantum dots: current status and future perspectives. Nanoscale 5:4015–403910.1039/c3nr33849e ↗
12. Dong Y, Chen JC, Li HR, Wang Y, Chi X, Gchen L (2012) Blue luminescent graphene quantum dots and graphene oxide prepared by tuning the carbonization degree of citric acid. Carbon 50:4738–474310.1016/j.carbon.2012.06.002 ↗
13. Henry B (2014) Preparation and characterization of graphene quantum dots-Fe3O4 nanocomposite as an efficient adsorbent in magnetic solid phase extraction: application to determination of Bisphenol A in water samples. Anal Methods 6:8413–841910.1039/C4AY01633E ↗
14. Shi B, Su Y, Zhang L, Huang M, Li X, Zhao S (2016) Facilely prepared Fe3O4/nitrogen-doped graphene quantum dot hybrids as a robust nonenzymatic catalyst for visual discrimination of phenylenediamine isomers. Nanoscale 8:10814–1082210.1039/C6NR02725C ↗
15. Yao Q, Wang S, Shi WY, Lu C, Liu G (2017) Graphene quantum dots in two dimensional confined and hydrophobic space for enhanced adsorption of nonionic organic adsorbates. Ind Eng Chem Res 56:583–59010.1021/acs.iecr.6b02389 ↗
16. Sani HA, Ahmad MB, Hussein MZ, Ibrahim NA, Musa A, Saleh TA (2017) Nanocomposite of ZnO with montmorillonite for removal of lead and copper ions from aqueous solutions. Proc Safe Environ Prot 109:97–10510.1016/j.psep.2017.03.024 ↗
17. Chang J, Ma J, Ma Q, Zhang D, Qiao N, Hu M, Ma H (2015) Adsorption of methylene blue onto Fe3O4/activated montmorillonite nanocomposite. Appl Clay Sci 119:132–14010.1016/j.clay.2015.06.038 ↗
18. Bakandritsos A, Steriotis T, Petridis D (2004) High surface area montmorillonite—carbon composites and derived carbons. Chem Mater 16:1551–155910.1021/cm0350030 ↗
19. Mu B, Tang J, Zhang L, Wang A (2016) Preparation, characterization and application on dye adsorption of a well-defined two-dimensional superparamagnetic clay/polyaniline/Fe3O4 nanocomposite. Appl Clay Sci 132–133:7–1610.1016/j.clay.2016.06.005 ↗
20. Benítezmartínez S, Valcárcel M (2015) Fluorescent determination of graphene quantum dots in water samples. Anal Chim Acta 896:78–8410.1016/j.aca.2015.09.019 ↗
21. Sricharoen P, Limchoowong N, Areerob Y, Nuengmatcha PT, Echawongstien S, Chanthai S (2017) Fe3O4/hydroxyapatite/graphene quantum dots as a novel nano-sorbent for preconcentration of copper residue in Thai food ingredients: optimization of ultrasound-assisted magnetic solid phase extraction. Ultrason Sonochem 37:83–9310.1016/j.ultsonch.2016.12.037 ↗
22. Zhou JB, Wu PX, Dang Z, Zhu NW, Li P, Wu JH, Wang XD (2010) Polymeric Fe/Zr pillared montmorillonite for the removal of Cr(VI) from aqueous solutions. Chem Eng J 162:1035–104410.1016/j.cej.2010.07.016 ↗
23. Wu P, Dai Y, Long H, Zhu N, Li P, Wu J, Dang Z (2012) Characterization of organo-montmorillonites and comparison for Sr(II) removal: equilibrium and kinetic studies. Chem Eng J 191:288–29610.1016/j.cej.2012.03.017 ↗
24. Ryu J, Suh YW, Dong JS, Dong JA (2010) Hydrothermal preparation of carbon microspheres from mono-saccharides and phenolic compounds. Carbon 48:1990–199810.1016/j.carbon.2010.02.006 ↗
25. Chen Q, Wu Q (2015) Preparation of carbon microspheres decorated with silver nanoparticles and their ability to remove dyes from aqueous solution. J Hazard Mater 283:193–20110.1016/j.jhazmat.2014.09.024 ↗
26. Baccile N, Laurent G, Babonneau F, Fayon F, Titirici MM, Antonietti M (2009) Structural characterization of hydrothermal carbon spheres by advanced solid-state MAS 13C NMR investigations. J Phys Chem C 113:9644–965410.1021/jp901582x ↗
27. Fang C, Zhao E, Kim T, Wang J, Hableel G, Reardon PJT, Wang T, Knowles SJC (2017) Organosilica nanoparticles with an intrinsic secondary amine: an efficient and reusable adsorbent for dyes. ACS Appl Mater Interfaces 9:15566–1557610.1021/acsami.7b04181 ↗
28. Lee SM, Tiwari D (2012) Organo and inorgano-organo-modified clays in the remediation of aqueous solutions: an overview. Appl Clay Sci 59–60:84–10210.1016/j.clay.2012.02.006 ↗
29. Ghaedi M, Hajjati S, Mahmudi Z, Tyagi I, Agarwal S, Maity A, Gupta VK (2015) Modeling of competitive ultrasonic assisted removal of the dyes—methylene blue and safranin-O using Fe3O4 nanoparticles. Chem Eng J 268:28–3710.1016/j.cej.2014.12.090 ↗
30. Alvand M, Shemirani F (2017) A Fe3O4@SiO2@graphene quantum dot core-shell structured nanomaterial as a fluorescent probe and for magnetic removal of mercury(II) ion. Microchim Acta 184:1621–162910.1007/s00604-017-2134-2 ↗
31. Kang Z, Wang E, Mao B, Su Z, Chen L, Xu L (2005) Obtaining carbon nanotubes from grass. Nanotechnology 16:119210.1088/0957-4484/16/8/036 ↗
32. Tang L, Ji R, Li X, Bai G, Liu CP, Hao J, Lin J, Jiang H, Teng KS, Yang Z (2014) Deep ultraviolet to near-infrared emission and photoresponse in layered N-doped graphene quantum dots. ACS Nano 8:6312–632010.1021/nn501796r ↗
33. Zhu S, Zhang J, Tang S, Qiao C, Wang L, Wang H, Liu X, Li B, Li Y, Yu W (2012) Surface chemistry routes to modulate the photoluminescence of graphene quantum dots: from fluorescence mechanism to up-conversion bioimaging applications. Adv Funct Mater 22:4732–474010.1002/adfm.201201499 ↗
34. Lu J, Fu F, Ding Z, Na L, Bing T (2017) Removal mechanism of selenite by Fe3O4-precipitated mesoporous magnetic carbon microspheres. J Hazard Mater 330:93–10410.1016/j.jhazmat.2017.01.056 ↗
35. Goworek J, Kierys A, Gac W, Borówka A, Kusak R (2009) Thermal degradation of CTAB in as-synthesized MCM-41. J Therm Anal Calorim 96:375–38210.1007/s10973-008-9055-6 ↗
36. Zheng X, Dou J, Yuan J, Qin W, Hong X, Ding A (2017) Removal of Cs+ from water and soil by ammonium-pillared montmorillonite/Fe3O4 composite. J Environ Sci 56:12–2410.1016/j.jes.2016.08.019 ↗
37. Guo Y, Qian J, Iqbal A, Zhang L, Liu W, Qin W (2017) Pd nanoparticles immobilized on magnetic carbon dots@Fe3O4 nanocubes as a synergistic catalyst for hydrogen generation. Int J Hydrog Energy 42:15167–1517710.1016/j.ijhydene.2017.04.253 ↗
38. Sitthichai S, Pilapong C, Thongtem T, Thongtem S (2015) CMC-coated Fe3O4 nanoparticles as new MRI probes for hepatocellular carcinoma. Appl Surf Sci 356:972–97710.1016/j.apsusc.2015.08.140 ↗
39. Lim SF, Zheng YM, Zou SW, Chen JP (2008) Characterization of copper adsorption onto an alginate encapsulated magnetic sorbent by a combined FT-IR, XPS, and mathematical modeling study. Environ Sci Technol 42:2551–255610.1021/es7021889 ↗
40. Boruah PK, Sharma B, Karbhal I, Shelke MV, Das MR (2016) Ammonia-modified graphene sheets decorated with magnetic Fe3O4 nanoparticles for the photocatalytic and photo-Fenton degradation of phenolic compounds under sunlight irradiation. J Hazard Mater 325:90–10010.1016/j.jhazmat.2016.11.023 ↗
41. Zhao C, Jiao Y, Hu F, Yang Y (2018) Green synthesis of carbon dots from pork and application as nanosensors for uric acid detection. Spectr Acta Part A Molec Spectr 190:360–36710.1016/j.saa.2017.09.037 ↗
42. Jia X, Dai R, Sun Y, Song H, Wu X (2016) One-step hydrothermal synthesis of Fe3O4/g-C3N4 nanocomposites with improved photocatalytic activities. J Mater Sci Mater Electron 27:1–8. https://doi.org/10.1021/am403830710.1021/am4038307 ↗
43. Zhang H, Liang X, Yang C, Niu C, Wang J, Su X (2016) Nano γ-Fe2O3/bentonite magnetic composites: synthesis, characterization and application as adsorbents. J Alloys Compd 688:1019–102710.1016/j.jallcom.2016.07.036 ↗
44. Song HJ, You S, Jia XH, Yang J (2015) MoS2 nanosheets decorated with magnetic Fe3O4 nanoparticles and their ultrafast adsorption for wastewater treatment. Ceram Int 41:13896–1390210.1016/j.ceramint.2015.08.023 ↗
45. Silva MMF, Oliveira MM, Avelino MC, Fonseca MG, Almeida RKS, Filho ECS (2012) Adsorption of an industrial anionic dye by modified-KSF-montmorillonite: evaluation of the kinetic, thermodynamic and equilibrium data. Chem Eng J 203:259–26810.1016/j.cej.2012.07.009 ↗
46. He X, Male KB, Nesterenko PN, Brabazon D, Paull B, Luong JH (2013) Adsorption and desorption of methylene blue on porous carbon monoliths and nanocrystalline cellulose. Appl Mater Interface 5:8796–880410.1021/am403222u ↗
47. Mary EA, Saravanakumar MP (2018) Facile synthesis and characterisation of AlNs using protein rich solution extracted from sewage sludge and its application for ultrasonic assisted dye adsorption: isotherms, kinetics, mechanism and RSM design. J Environ Manag 206:21510.1016/j.jenvman.2017.10.032 ↗
48. Zhou CJ, Wu QL, Lei TZ, Negulescu JI (2014) Adsorption kinetic and equilibrium studies for methylene blue dye by partially hydrolyzed polyacrylamide/cellulose nanocrystal nanocomposite hydrogels. Chem Eng J 251:17–2410.1016/j.cej.2014.04.034 ↗
49. Ho YS, Mckay G (1998) Sorption of dye from aqueous solution by peat. Chem Eng J 70:115–12410.1016/S0923-0467(98)00076-1 ↗
50. Langmuir I (2015) The adsorption of gases on plane surfaces of glass, mica and platinum. J Chem Phys 40:1361–1403
51. Ho YS, Huang CT, Huang HW (2002) Equilibrium sorption isotherm for metal ions on tree fern. Process Biochem 37:1421–143010.1016/S0032-9592(02)00036-5 ↗