journal article·2018-03Open access

Conditions for the occurrence of acicular ferrite transformation in HSLA steels

H. Zhao, B. P. Wynne, E. J. Palmiere

Journal of Materials Science· Volume 53· Issue 5

Abstract

For the class of steels collectively known as high strength low alloy (HSLA), an acicular ferrite (AF) microstructure produces an excellent combination of strength and toughness. The conditions for the occurrence of the AF transformation are, however, still unclear, especially the effects of austenite deformation and continuous cooling. In this research, a commercial HSLA steel was used and subjected to deformation via plane strain compression with strains ranging from 0 to 0.5 and continuous cooling at rates between 5 and 50 °C s−1. Based on the results obtained from optical microscopy, scanning electron microscopy and electron backscattering diffraction mapping, the introduction of intragranular nucleation sites and the suppression of bainitic ferrite (BF) laths lengthening were identified as the two key requirements for the occurrence of AF transformation. Austenite deformation is critical to meet these two conditions as it introduces a high density of dislocations that act as intragranular nucleation sites and deformation substructures, which suppress the lengthening of BF laths through the mechanism of mechanical stabilisation of austenite. However, the suppression effect of austenite deformation is only observed under relatively slow cooling rates or high transformation temperatures, i.e., conditions where the driving force for advancing the transformation interface is not sufficient to overcome the austenite deformation substructures.
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Research context

OpenAlex topics: Microstructure and Mechanical Properties of Steels · Magnetic Properties and Applications · Hydrogen embrittlement and corrosion behaviors in metals

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References (77)

Show source-provided references
1. Smith Y, Coldren A, Cryderman R (1972) Manganese–molybdenum–niobium acicular ferrite steels with high strength and toughness. In: Toward improved ductility and toughness. Climax Molybdenum Company (Japan) Ltd, Kyoto, pp 119–142
2. Pontremoli M, Bufalini P, Aprile A, Jannone C (1984) Development of grade API X80 pipeline steel plates produced by controlled rolling. Metals Technol 11(1):504–51410.1179/030716984803275197 ↗
3. Cryderman R, Coldren A, Bell J, Grozier J (1969) Controlled-cooled structural steels modified with columbium, molybdenum and boron. ASM Trans Q 62(3):561–574
4. Zhao H, Palmiere EJ (2017) Effect of austenite deformation on the microstructure evolution and grain refinement under accelerated cooling conditions. Metall Mater Trans A 48(7):3389–339910.1007/s11661-017-3987-z ↗
5. Bhadeshia HKDH (1992) Bainite in steels. Inst. of Metals, London
6. Lan L, Chang Z, Kong X, Qiu C, Zhao D (2017) Phase transformation, microstructure, and mechanical properties of X100 pipeline steels based on TMCP and HTP concepts. J Mater Sci 52(3):1661–1678. https://doi.org/10.1007/s10853-016-0459-610.1007/s10853-016-0459-6 ↗
7. Zhao M, Tang B, Shan Y, Yang K (2003) Role of microstructure on sulfide stress cracking of oil and gas pipeline steels. Metall Mater Trans A 34(5):1089–109610.1007/s11661-003-0128-7 ↗
8. Zhong Y, Xiao F, Zhang J, Shan Y, Wang W, Yang K (2006) In situ TEM study of the effect of M/A films at grain boundaries on crack propagation in an ultra-fine acicular ferrite pipeline steel. Acta Mater 54(2):435–44310.1016/j.actamat.2005.09.015 ↗
9. Chiou C, Yang J, Huang C (2001) The effect of prior compressive deformation of austenite on toughness property in an ultra-low carbon bainitic steel. Mater Chem Phys 69(1):113–12410.1016/S0254-0584(00)00379-5 ↗
10. Janzen TS, Horner WN (1998) Alliance pipeline—a design shift in long distance gas transmission. In: Proceedings of the international pipeline conference. ASME, New York10.1115/IPC1998-2010 ↗
11. Grimpe F, Meimeth S, Heckmann C, Liessem A, Gehrke A (2005) Development, production and application of heavy plates in grades up to X120. In: 1st international conference “Super-High Strength Steels”, Rome, Italy, pp 2–4
12. Kim YM, Lee H, Kim NJ (2008) Transformation behavior and microstructural characteristics of acicular ferrite in linepipe steels. Mater Sci Eng A 478(1):361–37010.1016/j.msea.2007.06.035 ↗
13. Bai D, Yue S, Maccagno T, Jonas J (1998) Effect of deformation and cooling rate on the microstructures of low carbon Nb–B steels. ISIJ Int 38(4):371–37910.2355/isijinternational.38.371 ↗
14. Lee JL, Hon MH, Cheng GH (1987) The intermediate transformation of Mn–Mo–Nb steel during continuous cooling. J Mater Sci 22(8):2767–2777. https://doi.org/10.1007/BF0108646910.1007/BF01086469 ↗
15. Xiao F, Liao B, Shan YY, Qiao GY, Zhong Y, Zhang C, Yang K (2006) Challenge of mechanical properties of an acicular ferrite pipeline steel. Mater Sci Eng A 431(1):41–5210.1016/j.msea.2006.05.029 ↗
16. Xiao F, Liao B, Ren D, Shan Y, Yang K (2005) Acicular ferritic microstructure of a low-carbon Mn–Mo–Nb microalloyed pipeline steel. Mater Charact 54(4–5):305–31410.1016/j.matchar.2004.12.011 ↗
17. Zhao MC, Yang K, Xiao FR, Shan YY (2003) Continuous cooling transformation of undeformed and deformed low carbon pipeline steels. Mater Sci Eng A 355(1):126–13610.1016/S0921-5093(03)00074-1 ↗
18. Zolotarevskii NY, Zisman A, Panpurin S, Titovets YF, Golosienko S, Khlusova E (2014) Effect of the grain size and deformation substructure of austenite on the crystal geometry of bainite and martensite in low-carbon steels. Met Sci Heat Treat 55(9–10):550–55810.1007/s11041-014-9668-2 ↗
19. Kawata H, Sakamoto K, Moritani T, Morito S, Furuhara T, Maki T (2006) Crystallography of ausformed upper bainite structure in Fe–9Ni–C alloys. Mater Sci Eng A 438:140–14410.1016/j.msea.2006.02.175 ↗
20. Malet L, Barnett M, Jacques P, Godet S (2009) Variant selection during the γ-to-αb phase transformation in hot-rolled bainitic TRIP-aided steels. Scripta Mater 61(5):520–52310.1016/j.scriptamat.2009.05.015 ↗
21. Shewmon PG (1969) Transformations in metals. McGraw-Hill, New York
22. Hulka K, Gray J (2001) High temperature processing of line pipe steels. In: Proceedings of the international symposium niobium, pp 587–612
23. Stalheim DG (2005) The use of high temperature processing (HTP) steel for high strength oil and gas transmission pipeline applications. Iron Steel 40(11):699–704
24. Sun L, Thomas M, Wynne B, Palmiere E, Mingard K, Roebuck B (2010) Mapping microstructure inhomogeneity using electron backscatter diffraction in 316L stainless steel subjected to hot plane strain compression tests. Mater Sci Technol 26(12):1477–148610.1179/026708310X12688283410280 ↗
25. Shibata K, Asakura K (1995) Transformation behavior and microstructures in ultra-low carbon steels. ISIJ Int 35(8):982–99110.2355/isijinternational.35.982 ↗
26. Cizek P, Wynne BP, Davies CHJ, Hodgson PD (2014) The effect of simulated thermomechanical processing on the transformation behavior and microstructure of a low-carbon Mo–Nb linepipe steel. Metall Mater Trans A 46(1):407–42510.1007/s11661-014-2601-x ↗
27. Shrestha SL, Breen AJ, Trimby P, Proust G, Ringer SP, Cairney JM (2014) An automated method of quantifying ferrite microstructures using electron backscatter diffraction (EBSD) data. Ultramicroscopy 137:40–4710.1016/j.ultramic.2013.11.003 ↗
28. Zhao H, Wynne B, Palmiere E (2017) A phase quantification method based on EBSD data for a continuously cooled microalloyed steel. Mater Charact 123:339–34810.1016/j.matchar.2016.11.024 ↗
29. Takayama N, Miyamoto G, Furuhara T (2012) Effects of transformation temperature on variant pairing of bainitic ferrite in low carbon steel. Acta Mater 60(5):2387–239610.1016/j.actamat.2011.12.018 ↗
30. Zhu K, Barbier D, Iung T (2013) Characterization and quantification methods of complex BCC matrix microstructures in advanced high strength steels. J Mater Sci 48(1):413–423. https://doi.org/10.1007/s10853-012-6756-910.1007/s10853-012-6756-9 ↗
31. Zhao H, Wynne B, Palmiere E (2017) Effect of austenite grain size on the bainitic ferrite morphology and grain refinement of a pipeline steel after continuous cooling. Mater Charact 123:128–13610.1016/j.matchar.2016.11.025 ↗
32. Smirnov M, Pyshmintsev IY, Boryakova A (2010) Classification of low-carbon pipe steel microstructures. Metallurgist 54(7):444–45410.1007/s11015-010-9321-2 ↗
33. Yakubtsov I, Boyd J (2001) Bainite transformation during continuous cooling of low carbon microalloyed steel. Mater Sci Technol 17(3):296–30110.1179/026708301773002491 ↗
34. Kitahara H, Ueji R, Tsuji N, Minamino Y (2006) Crystallographic features of lath martensite in low-carbon steel. Acta Mater 54(5):1279–128810.1016/j.actamat.2005.11.001 ↗
35. Wang W, Yan W, Zhu L, Hu P, Shan Y, Yang K (2009) Relation among rolling parameters, microstructures and mechanical properties in an acicular ferrite pipeline steel. Mater Des 30(9):3436–344310.1016/j.matdes.2009.03.026 ↗
36. Kim S, Kim Y, Lim Y, Kim NJ (2006) Relationship between yield ratio and the material constants of the Swift equation. Met Mater Int 12(2):131–13510.1007/BF03027468 ↗
37. Fang H, Wang J, Yang Z, Li C, Bo X, Zheng Y (1999) Bainite transformation. Science Press, Beijing
38. Araki T, Kozasu I, Tankechi H, Shibata K, Enomoto M, Tamehiro H (1992) Atlas for bainitic microstructures. ISIJ, Tokyo
39. Araki T, Shibata K, Enomoto M (1991) Reviewed concept on the microstructural identification and terminology of low carbon ferrous bainites. Mater Sci Forum 56:275–28010.4028/www.scientific.net/MSF.56-58.275 ↗
40. Collins L, Godden M, Boyd J (1983) Microstructures of linepipe steels. Can Metall Q 22(2):169–17910.1179/cmq.1983.22.2.169 ↗
41. DeVito CPaA (1979) High-strength microalloyed pipe steels resistant to hydrogen-induced failures. In: MiCon 78: optimization of processing, properties, and service performance through microstructural control 672:53
42. Shang C, Hu L, Yang S, Wang X, Zhao Y, He X (2005) Forming and controlling of the acicular ferrite in low carbon microalloyed steel. Acta Metall Sin 41(5):471–476
43. Zhao M, Hanamura T, Qiu H, Nagai K, Shan Y-Y, Yang K (2005) Difference in the role of non-quench aging on mechanical properties between acicular ferrite and ferrite-pearlite pipeline steels. ISIJ Intl 45(1):116–12010.2355/isijinternational.45.116 ↗
44. Tang Z, Stumpf W (2008) The role of molybdenum additions and prior deformation on acicular ferrite formation in microalloyed Nb–Ti low-carbon line-pipe steels. Mater Charact 59(6):717–72810.1016/j.matchar.2007.06.001 ↗
45. Kim YM, Shin SY, Lee H, Hwang B, Lee S, Kim NJ (2007) Effects of molybdenum and vanadium addition on tensile and charpy impact properties of API X70 linepipe steels. Metall Mater Trans A 38(8):1731–174210.1007/s11661-007-9197-3 ↗
46. Liu C, Shi L, Liu Y, Li C, Li H, Guo Q (2016) Acicular ferrite formation during isothermal holding in HSLA steel. J Mater Sci 51(7):3555–3563. https://doi.org/10.1007/s10853-015-9675-810.1007/s10853-015-9675-8 ↗
47. Olson G, Cohen M (1976) A general mechanism of martensitic nucleation: Part II. FCC → BCC and other martensitic transformations. Metall Mater Trans A 7(12):1905–191410.1007/BF02659823 ↗
48. Brooks JW, Loretto MH, Smallman RE (1979) Direct observations of martensite nuclei in stainless steel. Acta Metall 27(12):1839–184710.1016/0001-6160(79)90074-9 ↗
49. Olson GB, Cohen M (1972) A mechanism for the strain-induced nucleation of martensitic transformations. J Less Common Methods 28(1):107–11810.1016/0022-5088(72)90173-7 ↗
50. Suezawa M, Cook H (1980) On the nucleation of martensite. Acta Metall 28(4):423–43210.1016/0001-6160(80)90132-7 ↗
51. Yeddu HK, Lookman T, Saxena A (2013) Strain-induced martensitic transformation in stainless steels: a three-dimensional phase-field study. Acta Mater 61(18):6972–698210.1016/j.actamat.2013.08.011 ↗
52. Zhang W, Jin Y, Khachaturyan A (2007) Phase field microelasticity modeling of heterogeneous nucleation and growth in martensitic alloys. Acta Mater 55(2):565–57410.1016/j.actamat.2006.08.050 ↗
53. Magee CL (1970) The nucleation of martensite. In: Aaronson HI, Zackay VF (eds) Phase Transformations. ASM, Metals Park, pp 115–156
54. Christian J (1969) The mechanism of phase transformations in crystalline solids. Institute of Metals, London
55. Shigeta T, Takada A, Terasaki H, Y-i Komizo (2013) The effects of ausforming on variant selection of martensite in Cr–Mo steel. Q J Jpn Weld Soc 31(4):178–18210.2207/qjjws.31.178s ↗
56. Yamamoto S, Yokoyama H, Yamada K, Niikura M (1995) Effects of the austenite grain size and deformation in the unrecrystallized austenite region on bainite transformation behavior and microstructure. ISIJ Int 35(8):1020–102610.2355/isijinternational.35.1020 ↗
57. Yang J, Huang C, Chiou C (1995) The influence of plastic deformation and cooling rates on the microstructural constituents of an ultra-low carbon bainitic steel. ISIJ Intl 35(8):1013–101910.2355/isijinternational.35.1013 ↗
58. Fujiwara K, Okaguchi S, Ohtani H (1995) Effect of hot deformation on bainite structure in low carbon steels. ISIJ Int 35(8):1006–101210.2355/isijinternational.35.1006 ↗
59. Díaz-Fuentes M, Gutiérrez I (2003) Analysis of different acicular ferrite microstructures generated in a medium-carbon molybdenum steel. Mater Sci Eng A 363(1):316–324 https://doi.org/10.1007/s10853-016-0459-610.1007/s10853-016-0459-6 ↗
60. Tari V, Rollett A, Beladi H (2013) Back calculation of parent austenite orientation using a clustering approach. J Appl Crystallogr 46(1):210–21510.1107/S002188981204914X ↗
61. Furuhara T, Kawata H, Morito S, Miyamoto G, Maki T (2008) Variant selection in grain boundary nucleation of upper bainite. Metall Mater Trans A 39(5):1003–101310.1007/s11661-008-9510-9 ↗
62. Lambert-Perlade A, Gourgues AF, Pineau A (2004) Austenite to bainite phase transformation in the heat-affected zone of a high strength low alloy steel. Acta Mater 52(8):2337–234810.1016/j.actamat.2004.01.025 ↗
63. Shipway P, Bhadeshia H (1997) The mechanical stabilisation of Widmanstätten ferrite. Mater Sci Eng A 223(1):179–18510.1016/S0921-5093(96)10479-2 ↗
64. Larn RH, Yang JR (2000) The effect of compressive deformation of austenite on the bainitic ferrite transformation in Fe–Mn–Si–C steels. Mater Sci Eng A 278(1–2):278–29110.1016/S0921-5093(99)00597-3 ↗
65. Larn R, Yang J (1999) The effect of compressive deformation of austenite on the Widmanstätten ferrite transformation in Fe–Mn–Si–C steel. Mater Sci Eng A 264(1):139–15010.1016/S0921-5093(98)01085-5 ↗
66. Leslie WC, Miller RL (1964) The stabilization of austenite by closely spaced boundaries. ASM Trans Q 57(4):972–979
67. Machlin ES, Cohen M (1951) Burst phenomenon in the martensitic transformation. Trans AIME 191(9):746–754
68. Shipway P, Bhadeshia H (1995) Mechanical stabilisation of bainite. Mater Sci Technol 11(11):1116–112810.1179/mst.1995.11.11.1116 ↗
69. Singh S, Bhadeshia H (1996) Quantitative evidence for mechanical stabilization of bainite. Mater Sci Technol 12(7):610–61210.1179/mst.1996.12.7.610 ↗
70. Chatterjee S, Wang H-S, Yang J, Bhadeshia H (2006) Mechanical stabilisation of austenite. Mater Sci Technol 22(6):641–64410.1179/174328406X86128 ↗
71. Honeycombe RWK (1969) Plastic deformation of metals. Cambridge University Press, Cambridge
72. Bhadeshia H (1981) A rationalisation of shear transformations in steels. Acta Metall 29(6):1117–113010.1016/0001-6160(81)90063-8 ↗
73. Taylor A, Cizek P, Hodgson P (2012) Orientation dependence of the substructure characteristics in a Ni–30Fe austenitic model alloy deformed in hot plane strain compression. Acta Mater 60(4):1548–156910.1016/j.actamat.2011.11.048 ↗
74. Hughes D, Liu Q, Chrzan D, Hansen N (1997) Scaling of microstructural parameters: misorientations of deformation induced boundaries. Acta Mater 45(1):105–11210.1016/S1359-6454(96)00153-X ↗
75. Hughes D, Chrzan D, Liu Q, Hansen N (1998) Scaling of misorientation angle distributions. Phys Rev Lett 81(21):4664–466710.1103/PhysRevLett.81.4664 ↗
76. Miyamoto G, Iwata N, Takayama N, Furuhara T (2012) Variant selection of lath martensite and bainite transformation in low carbon steel by ausforming. J Alloys Compd 577(1):528–532
77. Babu S, Bhadeshia H (1991) Mechanism of the transition from bainite to acicular ferrite. Mater Trans Jpn Inst Met 32(8):679–688