journal article·2017-08Open access

Nanocomposites of graphene nanoplatelets in natural rubber: microstructure and mechanisms of reinforcement

Suhao Li, Zheling Li, Timothy L. Burnett, Thomas J. A. Slater, Teruo Hashimoto, Robert J. Young

Journal of Materials Science· Volume 52· Issue 16

Abstract

The microstructure and mechanisms of reinforcement have been investigated in nanocomposites consisting of graphene nanoplatelets (GNPs) in natural rubber (NR). Nanocomposites with four different loadings of three different sized GNPs were prepared and were bench-marked against nanocomposites loaded with N330 carbon black. The microstructure of the nanocomposites was characterised though a combination of scanning electron microscopy, polarised Raman spectroscopy and X-ray computed tomography (CT), where it was shown that the GNPs were well dispersed with a preferred orientation parallel to the surface of the nanocomposite sheets. The mechanical properties of the nanocomposites were evaluated using tensile testing and it was shown that, for a given loading, there was a three times greater increase in stiffness for the GNPs than for the carbon black. Stress transfer from the NR to the GNPs was evaluated from stress-induced Raman bands shifts indicating that the effective Young’s modulus of the GNPs in the NR was of the order of 100 MPa, similar to the value evaluated using the rule of mixtures from the stress-strain data.
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Research context

OpenAlex topics: Polymer Nanocomposites and Properties · Graphene research and applications · Polymer crystallization and properties

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References (48)

Show source-provided references
1. Donnet JB, Voet A (1976) Carbon black: physics, chemistry and elastomer reinforcement. Marcel Dekker, New York
2. Edwards DC (1990) Polymer-filler interactions in rubber reinforcement. J Mater Sci 25:4175–4185. doi: 10.1007/bf0058107010.1007/bf00581070 ↗
3. Boonstra BB (1979) Role of particulate fillers in elastomer reinforcement: a review. Polymer 20:691–704. doi: 10.1016/0032-3861(79)90243-X10.1016/0032-3861(79)90243-X ↗
4. Koerner H, Price G, Pearce NA, Alexander M, Vaia RA (2004) Remotely actuated polymer nanocomposites–stress-recovery of carbon-nanotube-filled thermoplastic elastomers. Nat Mater 3:115–120. doi: 10.1038/nmat105910.1038/nmat1059 ↗
5. Leblanc JL (2002) Rubber–filler interactions and rheological properties in filled compounds. Prog Polym Sci 27:627–687. doi: 10.1016/S0079-6700(01)00040-510.1016/S0079-6700(01)00040-5 ↗
6. Frogley MD, Ravich D, Wagner HD (2003) Mechanical properties of carbon nanoparticle-reinforced elastomers. Compos Sci Technol 63:1647–1654. doi: 10.1016/S0266-3538(03)00066-610.1016/S0266-3538(03)00066-6 ↗
7. Donnet JB (2003) Nano and microcomposites of polymers elastomers and their reinforcement. Compos Sci Technol 63:1085–1088. doi: 10.1016/S0266-3538(03)00028-910.1016/S0266-3538(03)00028-9 ↗
8. Joly S, Garnaud G, Ollitrault R, Bokobza L, Mark JE (2002) Organically modified layered silicates as reinforcing fillers for natural rubber. Chem Mater 14:4202–4208. doi: 10.1021/cm020093e10.1021/cm020093e ↗
9. Ponnamma D, Sadasivuni KK, Grohens Y, Guo Q, Thomas S (2014) Carbon nanotube based elastomer composites—an approach towards multifunctional materials. J Mater Chem C 2:8446–8485. doi: 10.1039/c4tc01037j10.1039/c4tc01037j ↗
10. Sherif A, Izzuddin Z, Qingshi M, Nobuyuki K, Andrew M, Hsu-Chiang K, Peter M, Jun M, Liqun Z (2013) Melt compounding with graphene to develop functional, high-performance elastomers. Nanotechnology 24:165601. doi: 10.1088/0957-4484/24/16/16560110.1088/0957-4484/24/16/165601 ↗
11. Basu D, Das A, Stöckelhuber KW, Wagenknecht U, Heinrich G (2014) Advances in layered double hydroxide (LDH)-based elastomer composites. Prog Polym Sci 39:594–626. doi: 10.1016/j.progpolymsci.2013.07.01110.1016/j.progpolymsci.2013.07.011 ↗
12. Novoselov KS, Geim AK, Morozov S, Jiang D, Zhang Y, Dubonos S, Grigorieva I, Firsov A (2004) Electric field effect in atomically thin carbon films. Science 306:666–669. doi: 10.1126/science.110289610.1126/science.1102896 ↗
13. Novoselov KS, Geim AK, Morozov SV, Jiang D, Katsnelson MI, Grigorieva IV, Dubonos SV, Firsov AA (2005) Two-dimensional gas of massless Dirac fermions in graphene. Nature 438:197–200. doi: 10.1038/nature0423310.1038/nature04233 ↗
14. Geim AK, Novoselov KS (2007) The rise of graphene. Nat Mater 6:183–191. doi: 10.1126/science.110289610.1126/science.1102896 ↗
15. Lee C, Wei X, Kysar JW, Hone J (2008) Measurement of the elastic properties and intrinsic strength of monolayer graphene. Science 321:385–388. doi: 10.1126/science.115799610.1126/science.1157996 ↗
16. Young RJ, Kinloch IA (2013) Graphene and graphene-based nanocomposites. Nanosci-Spec Per Rep 1:145–179. doi: 10.1039/9781849734844-0014510.1039/9781849734844-00145 ↗
17. Young RJ, Kinloch IA, Gong L, Novoselov KS (2012) The mechanics of graphene nanocomposites: a review. Compos Sci Technol 72:1459–1476. doi: 10.1016/j.compscitech.2012.05.00510.1016/j.compscitech.2012.05.005 ↗
18. Young RJ (2016) Graphene and graphene-based nanocomposites. Cism Courses Lect 563:75–98. doi: 10.1007/978-3-7091-1887-0_410.1007/978-3-7091-1887-0_4 ↗
19. Young RJ, Liu MF (2016) The microstructure of a graphene-reinforced tennis racquet. J Mater Sci 51:3861–3867. doi: 10.1007/s10853-015-9705-610.1007/s10853-015-9705-6 ↗
20. Boland CS, Khan U, Ryan G, Barwich S, Charifou R, Harvey A, Backes C, Li Z, Ferreira MS, Mobius ME, Young RJ, Coleman JN (2016) Sensitive electromechanical sensors using viscoelastic graphene-polymer nanocomposites. Science 354:1257–1260. doi: 10.1126/science.aag287910.1126/science.aag2879 ↗
21. Papageorgiou DG, Kinloch IA, Young RJ (2016) Hybrid multifunctional graphene/glass-fibre polypropylene composites. Compos Sci Technol 137:44–51. doi: 10.1016/j.compscitech.2016.10.01810.1016/j.compscitech.2016.10.018 ↗
22. Kim H, Miura Y, Macosko CW (2010) Graphene/polyurethane nanocomposites for improved gas barrier and electrical conductivity. Chem Mater 22:3441–3450. doi: 10.1021/cm100477v10.1021/cm100477v ↗
23. Araby S, Meng Q, Zhang L, Kang H, Majewski P, Tang Y, Ma J (2014) Electrically and thermally conductive elastomer/graphene nanocomposites by solution mixing. Polymer 55:201–210. doi: 10.1016/j.polymer.2013.11.03210.1016/j.polymer.2013.11.032 ↗
24. Sadasivuni K, Saiter A, Gautier N, Thomas S, Grohens Y (2013) Effect of molecular interactions on the performance of poly(isobutylene-co-isoprene)/graphene and clay nanocomposites. Colloid Polym Sci 291:1729–1740. doi: 10.1007/s00396-013-2908-y10.1007/s00396-013-2908-y ↗
25. Chen B, Ma N, Bai X, Zhang H, Zhang Y (2012) Effects of graphene oxide on surface energy, mechanical, damping and thermal properties of ethylene-propylene-diene rubber/petroleum resin blends. RSC Adv 2:4683–4689. doi: 10.1039/c2ra01212j10.1039/c2ra01212j ↗
26. Zhan Y, Lavorgna M, Buonocore G, Xia H (2012) Enhancing electrical conductivity of rubber composites by constructing interconnected network of self-assembled graphene with latex mixing. J Mater Chem 22:10464–10468. doi: 10.1039/C2JM31293J10.1039/C2JM31293J ↗
27. Zhan Y, Wu J, Xia H, Yan N, Fei G, Yuan G (2011) Dispersion and exfoliation of graphene in rubber by an ultrasonically-assisted latex mixing and in situ reduction process. Macromol Mater Eng 296:590–602. doi: 10.1002/mame.20100035810.1002/mame.201000358 ↗
28. Potts JR, Shankar O, Du L, Ruoff RS (2012) Processing–morphology–property relationships and composite theory analysis of reduced graphene oxide/natural rubber nanocomposites. Macromolecules 45:6045–6055. doi: 10.1021/ma300706k10.1021/ma300706k ↗
29. Scherillo G, Lavorgna M, Buonocore GG, Zhan YH, Xia HS, Mensitieri G, Ambrosio L (2014) Tailoring assembly of reduced graphene oxide nanosheets to control gas barrier properties of natural rubber nanocomposites. ACS Appl Mater Interfaces 6:2230–2234. doi: 10.1021/am405768m10.1021/am405768m ↗
30. Potts JR, Shankar O, Murali S, Du L, Ruoff RS (2013) Latex and two-roll mill processing of thermally-exfoliated graphite oxide/natural rubber nanocomposites. Compos Sci Technol 74:166–172. doi: 10.1016/j.compscitech.2012.11.00810.1016/j.compscitech.2012.11.008 ↗
31. Hernández M, Bernal MdM, Verdejo R, Ezquerra TA, López-Manchado MA (2012) Overall performance of natural rubber/graphene nanocomposites. Compos Sci Technol 73:40–46. doi: 10.1016/j.compscitech.2012.08.01210.1016/j.compscitech.2012.08.012 ↗
32. Das A, Kasaliwal GR, Jurk R, Boldt R, Fischer D, Stöckelhuber KW, Heinrich G (2012) Rubber composites based on graphene nanoplatelets, expanded graphite, carbon nanotubes and their combination: a comparative study. Compos Sci Technol 72:1961–1967. doi: 10.1016/j.compscitech.2012.09.00510.1016/j.compscitech.2012.09.005 ↗
33. Wu J, Xing W, Huang G, Li H, Tang M, Wu S, Liu Y (2013) Vulcanization kinetics of graphene/natural rubber nanocomposites. Polymer 54:3314–3323. doi: 10.1016/j.polymer.2013.04.04410.1016/j.polymer.2013.04.044 ↗
34. Yang H, Liu P, Zhang T, Duan Y, Zhang J (2014) Fabrication of natural rubber nanocomposites with high graphene contents via vacuum-assisted self-assembly. RSC Adv 4:27687–27690. doi: 10.1039/c4ra02950j10.1039/c4ra02950j ↗
35. Ozbas B, O’Neill CD, Register RA, Aksay IA, Prud’homme RK, Adamson DH (2012) Multifunctional elastomer nanocomposites with functionalized graphene single sheets. J Polym Sci Part B Polym Phys 50:910–916. doi: 10.1002/polb.2308010.1002/polb.23080 ↗
36. Ozbas B, Toki S, Hsiao BS, Chu B, Register RA, Aksay IA, Prud’homme RK, Adamson DH (2012) Strain-induced crystallization and mechanical properties of functionalized graphene sheet-filled natural rubber. J Polym Sci Part B Polym Phys 50:718–723. doi: 10.1002/polb.2306010.1002/polb.23060 ↗
37. Xing W, Wu J, Huang G, Li H, Tang M, Fu X (2014) Enhanced mechanical properties of graphene/natural rubber nanocomposites at low content. Polym Int 63:1674–1681. doi: 10.1002/pi.468910.1002/pi.4689 ↗
38. Schopp S, Thomann R, Ratzsch KF, Kerling S, Altstadt V, Mulhaupt R (2014) Functionalized graphene and carbon materials as components of styrene-butadiene rubber nanocomposites prepared by aqueous dispersion blending. Macromol Mater Eng 299:319–329. doi: 10.1002/mame.20130012710.1002/mame.201300127 ↗
39. Boland CS, Khan U, Backes C, O’Neill A, McCauley J, Duane S, Shanker R, Liu Y, Jurewicz I, Dalton AB, Coleman JN (2014) Sensitive, high-strain, high-rate bodily motion sensors based on graphene-rubber composites. ACS Nano 8:8819–8830. doi: 10.1021/Nn503454h10.1021/Nn503454h ↗
40. Matos CF, Galembeck F, Zarbin AJ (2014) Multifunctional and environmentally friendly nanocomposites between natural rubber and graphene or graphene oxide. Carbon 78:469–479. doi: 10.1016/j.carbon.2014.07.02810.1016/j.carbon.2014.07.028 ↗
41. Papageorgiou DG, Kinloch IA, Young RJ (2015) Graphene/elastomer nanocomposites. Carbon 95:460–484. doi: 10.1016/j.carbon.2015.08.05510.1016/j.carbon.2015.08.055 ↗
42. Li ZL, Young RJ, Kinloch IA, Wilson NR, Marsden AJ, Raju APA (2015) Quantitative determination of the spatial orientation of graphene by polarized Raman spectroscopy. Carbon 88:215–224. doi: 10.1016/j.carbon.2015.02.07210.1016/j.carbon.2015.02.072 ↗
43. Li ZL, Young RJ, Wilson NR, Kinloch IA, Valles C, Li Z (2016) Effect of the orientation of graphene-based nanoplatelets upon the Young’s modulus of nanocomposites. Compos Sci Technol 123:125–133. doi: 10.1016/j.compscitech.2015.12.00510.1016/j.compscitech.2015.12.005 ↗
44. Maire E, Withers PJ (2014) Quantitative X-ray tomography. Int Mater Rev 59:1–43. doi: 10.1179/1743280413Y.000000002310.1179/1743280413Y.0000000023 ↗
45. Zhang X, Aliasghari S, Nemcova A, Burnett TL, Kubena I, Smid M, Thompson GE, Skeldon P, Withers PJ (2016) X-ray computed tomographic investigation of the porosity and morphology of plasma electrolytic oxidation coatings. ACS Appl Mater Interfaces 8:8801–8810. doi: 10.1021/acsami.6b0027410.1021/acsami.6b00274 ↗
46. Evans JE, Friedrich H, Bals S, Bradley RS, Dahmen T, De Backer A, de Jonge N, Elbaum M, Goris B, Houben L, Leary RK, Midgley PA, Slusallek P, Trampert P, Van Aert S, Van Tendeloo G, Withers PJ, Wolf SG (2016) Advanced tomography techniques for inorganic, organic, and biological materials. MRS Bull 41:516–524. doi: 10.1557/mrs.2016.13410.1557/mrs.2016.134 ↗
47. Young RJ, Lovell PA (2013) Introduction to polymers, 3rd edn. CRC Press, Boca Baton
48. Gong L, Kinloch IA, Young RJ, Riaz I, Jalil R, Novoselov KS (2010) Interfacial stress transfer in a graphene monolayer nanocomposite. Adv Mater 22:2694–2697. doi: 10.1002/adma.20090426410.1002/adma.200904264 ↗