A Record-Breaking Loading Capacity for Single-Molecule Magnet Mn12 Clusters Achieved in a Mesoporous Ln-MOF
Source abstract
Abstract
A chiral mesoporous lanthanide-based metal–organic framework (Ln-MOF) was synthesized. More importantly, its loading capacity for Mn12Ac reached 40.15 mol %, which is not only larger than that reported for porous materials to date thus far but also significantly larger than that observed on the surface of LB film. Investigations on the crystal structures and the nitrogen adsorption isotherms reveal that the well-matched porous size with that of SMMs in MOFs, the flexible porosity of the MOFs, and the interactions between MOFs and SMMs are key for enhancing the loading capacity for SMMs in the MOFs.
Source: openalex_inverted_index · Quality: baseline
Research context
OpenAlex topics: Magnetism in coordination complexes · Metal-Organic Frameworks: Synthesis and Applications · Lanthanide and Transition Metal Complexes
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
Collaborative Innovation Center of Chemistry for Energy Materials, State Key Laboratory of Physical Chemistry of Solid Surface and Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, China
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China
Funding
National Natural Science Foundation of China
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