Improvement in ion transport in Na3PSe4–Na3SbSe4 by Sb substitution
Source abstract
Abstract
Exploration of advanced solid electrolytes is a highly relevant research topic for all-solid-state batteries and sensors. One of the effective ways to improve the ion transport is cation substitution. In this work, single-phase Na3P1−x Sb x Se4 polycrystalline compounds are synthesized via solid-state reaction method. The impact of Sb substitution on the chemical structure is revealed by X-ray powder diffraction and Raman spectroscopy. Sb substitution enlarges the unit cell and thus increases the ionic conductivity of Na3P1−x Sb x Se4. Na3SbSe4 as a fully substituted compound achieves the lowest activation energy value of 0.19 eV and the highest ionic conductivity value of 3.7 mS/cm, one of the best values among sulfide solid electrolytes. Together with a low grain-boundary resistance, a single Na+ transference number, and high thermal stability, Na3SbSe4 is a very promising solid electrolyte for all-solid-state sodium batteries.
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Research context
OpenAlex topics: Advancements in Battery Materials · Advanced Battery Materials and Technologies · Solid-state spectroscopy and crystallography
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References (48)
Show source-provided references
1. Larcher D, Tarascon JM (2015) Towards greener and more sustainable batteries for electrical energy storage. Nat Chem 7:19–2910.1038/nchem.2085 ↗
2. Kundu D, Talaie E, Duffort V, Nazar LF (2015) The emerging chemistry of sodium ion batteries for electrochemical energy storage. Angew Chem Int Ed 54:3431–344810.1002/anie.201410376 ↗
3. Wen Z, Hu Y, Wu X, Han J, Gu Z (2013) Main challenges for high performance NAS battery: materials and interfaces. Adv Funct Mater 23:1005–101810.1002/adfm.201200473 ↗
4. Pan H, Hu YS, Chen L (2013) Room-temperature stationary sodium-ion batteries for large-scale electric energy storage. Energy Environ Sci 6:2338–236010.1039/c3ee40847g ↗
5. Bachman JC, Muy S, Grimaud A, Chang HH, Pour N, Lux SF, Paschos O, Maglia F, Lupart S, Lamp P, Giordano L, Shao-Horn Y (2016) Inorganic solid-state electrolytes for lithium batteries: mechanisms and properties governing ion conduction. Chem Rev 116:140–16210.1021/acs.chemrev.5b00563 ↗
6. Kim JG, Son B, Mukherjee S, Schuppert N, Bates A, Kwon O, Choi MJ, Chung HY, Park S (2015) A review of lithium and non-lithium based solid state batteries. J Power Sources 282:299–32210.1016/j.jpowsour.2015.02.054 ↗
7. Kalhoff J, Eshetu GG, Bresser D, Passerini S (2015) Safer electrolytes for lithium-ion batteries: state of the art and perspectives. Chemsuschem 8:2154–217510.1002/cssc.201500284 ↗
8. Jung YS, Oh DY, Nam YJ, Park KH (2015) Issues and challenges for bulk-type all-solid-state rechargeable lithium batteries using sulfide solid electrolytes. Isr J Chem 55:472–48510.1002/ijch.201400112 ↗
9. Zhang L, Yang K, Dong J, Lu L (2015) Recent developments in thio-LISICON solid electrolytes. J Yanshan Univ 39:95–106
10. Yao X, Huang B, Yin J, Peng G, Huang Z, Gao C, Liu D, Xu X (2016) All-solid-state lithium batteries with inorganic solid electrolytes: review of fundamental science. Chin Phys B 25:01880210.1088/1674-1056/25/1/018802 ↗
11. Vignarooban K, Kushagra R, Elango A, Badami P, Mellander BE, Xu X, Tucker TG, Nam C, Kannan AM (2016) Current trends and future challenges of electrolytes for sodium-ion batteries. Int J Hydrog Energy 41:2829–284610.1016/j.ijhydene.2015.12.090 ↗
12. Sun C, Liu J, Gong Y, Wilkinson DP, Zhang J (2017) Recent advances in all-solid-state rechargeable lithium batteries. Nano Energy 33:363–38610.1016/j.nanoen.2017.01.028 ↗
13. Tatsumisago M, Nagao M, Hayashi A (2013) Recent development of sulfide solid electrolytes and interfacial modification for all-solid-state rechargeable lithium batteries. J Asian Ceram Soc 1:17–2510.1016/j.jascer.2013.03.005 ↗
14. Takada K (2013) Progress and prospective of solid-state lithium batteries. Acta Mater 61:759–77010.1016/j.actamat.2012.10.034 ↗
15. Hayashi A, Sakuda A, Tatsumisago M (2016) Development of sulfide solid electrolytes and interface formation processes for bulk-type all-solid-state Li and Na batteries. Front Energy Res 4:2510.3389/fenrg.2016.00025 ↗
16. Lin Z, Liang C (2015) Lithium–sulfur batteries: from liquid to solid cells. J Mater Chem A 3:936–95810.1039/C4TA04727C ↗
17. Slater MD, Kim D, Lee E, Johnson CS (2013) Sodium-ion batteries. Adv Funct Mater 23:947–95810.1002/adfm.201200691 ↗
18. Palomares V, Casas-Cabanas M, Castillo-Martínez E, Han MH, Rojo T (2013) Update on Na-based battery materials: a growing research path. Energy Environ Sci 6:2312–233710.1039/c3ee41031e ↗
19. Hayashi A, Noi K, Sakuda A, Tatsumisago M (2012) Superionic glass-ceramic electrolytes for room-temperature rechargeable sodium batteries. Nat Commun 3:85610.1038/ncomms1843 ↗
20. Hayashi A, Noi K, Tanibata N, Nagao M, Tatsumisago M (2014) High sodium ion conductivity of glass–ceramic electrolytes with cubic Na3PS4. J Power Sources 258:420–42310.1016/j.jpowsour.2014.02.054 ↗
21. Tanibata N, Noi K, Hayashi A, Tatsumisago M (2014) Preparation and characterization of highly sodium ion conducting Na3PS4–Na4SiS4 solid electrolytes. RSC Adv 4:17120–1712310.1039/C4RA00996G ↗
22. Berbano SS, Seo I, Bischoff CM, Schuller KE, Martin SW (2012) Formation and structure of Na2S + P2S5 amorphous materials prepared by melt-quenching and mechanical milling. J Noncryst Solids 358:93–9810.1016/j.jnoncrysol.2011.08.030 ↗
23. Jha PK, Pandey OP, Singh K (2014) Crystallization and glass transition kinetics of Na2S–P2S5-based super-ionic glasses. Part Sci Technol 33:166–171
24. Noi K, Hayashi A, Tatsumisago M (2014) Structure and properties of the Na2S–P2S5 glasses and glass–ceramics prepared by mechanical milling. J Power Sources 269:260–26510.1016/j.jpowsour.2014.06.158 ↗
25. Tanibata N, Noi K, Hayashi A, Kitamura N, Idemoto Y, Tatsumisago M (2014) X-ray crystal structure analysis of sodium-ion conductivity in 94 Na3PS4·6 Na4SiS4 glass-ceramic electrolytes. Chem Electro Chem 1:1130–1132
26. Hibi Y, Tanibata N, Hayashi A, Tatsumisago M (2015) Preparation of sodium ion conducting Na3PS4–NaI glasses by a mechanochemical technique. Solid State Ion 270:6–910.1016/j.ssi.2014.11.024 ↗
27. Zhu Z, Chu IH, Deng Z, Ong SP (2015) Role of Na+ interstitials and dopants in enhancing the Na+ conductivity of the cubic Na3PS4 superionic conductor. Chem Mater 27:8318–832510.1021/acs.chemmater.5b03656 ↗
28. Chu IH, Kompella CS, Nguyen H, Zhu Z, Hy S, Deng Z, Meng YS, Ong SP (2016) Room-temperature all-solid-state rechargeable sodium-ion batteries with a Cl-doped Na3PS4 superionic conductor. Sci Rep 6:3373310.1038/srep33733 ↗
29. Klerk NJJ, Wagemaker M (2016) Diffusion mechanism of the sodium-ion solid electrolyte Na3PS4 and potential improvements of halogen doping. Chem Mater 28:3122–313010.1021/acs.chemmater.6b00698 ↗
30. Yu C, Ganapathy S, Klerk NJJ, Eck ERH, Wagemaker M (2016) Na-ion dynamics in tetragonal and cubic Na3PS4, a Na-ion conductor for solid state Na-ion batteries. J Mater Chem A 4:15095–1510510.1039/C6TA05896E ↗
31. Wenzel S, Leichtweiss T, Weber DA, Sann J, Zeier WG, Janek J (2016) Interfacial reactivity benchmarking of the sodium ion conductors Na3PS4 and sodium beta-alumina for protected sodium metal anodes and sodium all-solid-state batteries. ACS Appl Mater Interfaces 8:28216–2822410.1021/acsami.6b10119 ↗
32. Bo SH, Wang Y, Ceder G (2016) Structural and Na-ion conduction characteristics of Na3PSxSe4−x. J Mater Chem A 4:9044–905310.1039/C6TA03027K ↗
33. Pompe C, Pfitzner A (2012) Na3SbSe3: synthesis, crystal structure determination, raman spectroscopy, and ionic conductivity. Z Anorg Allg Chem 638:2158–216210.1002/zaac.201200370 ↗
34. Kim SK, Mao A, Sen S, Kim S (2014) Fast Na-ion conduction in a chalcogenide glass–ceramic in the ternary system Na2Se–Ga2Se3–GeSe2. Chem Mater 26:5695–569910.1021/cm502542p ↗
35. Richards WD, Tsujimura T, Miara LJ, Wang Y, Kim JC, Ong SP, Uechi I, Suzuki N, Ceder G (2016) Design and synthesis of the superionic conductor Na10SnP2S12. Nat Commun 7:1100910.1038/ncomms11009 ↗
36. Kandagal VS, Bharadwaj MD, Waghmare UV (2015) Theoretical prediction of a highly conducting solid electrolyte for sodium batteries: Na10GeP2S12. J Mater Chem A 3:12992–1299910.1039/C5TA01616A ↗
37. Yu Z, Shang SL, Seo JH, Wang D, Luo X, Huang Q, Chen S, Lu J, Li X, Liu ZK, Wang D (2017) Exceptionally high ionic conductivity in Na3P0.62As0.38S4 with improved moisture stability for solid-state sodium-ion batteries. Adv Mater 29:160556110.1002/adma.201605561 ↗
38. Bo S-H, Wang Y, Kim JC, Richards WD, Ceder G (2016) Computational and experimental investigations of Na-ion conduction in cubic Na3PSe4. Chem Mater 28:25210.1021/acs.chemmater.5b04013 ↗
39. Tian Y, Shi T, Richards WD, Li J, Bo S-H (2017) Compatibility issues between electrodes and electrolytes in solid-state batteries. Energ Environ Sci 10:115010.1039/C7EE00534B ↗
40. Zhang L, Yang K, Mi J, Lu L, Zhao L, Wang L, Li Y, Zeng H (2015) Na3PSe4: a novel chalcogenide solid electrolyte with high ionic conductivity. Adv Energy Mater 5:150129410.1002/aenm.201501294 ↗
41. Zhang L, Zhang D, Yang K, Yan X, Wang L, Mi J, Xu B, Li Y (2016) Vacancy-contained tetragonal Na3SbS4 superionic conductor. Adv Sci 3:160008910.1002/advs.201600089 ↗
42. Trevey JE, Jung YS, Lee SH (2010) Preparation of Li2S–GeSe2–P2S5 electrolytes by a single step ball milling for all-solid-state lithium secondary batteries. J Power Sources 195:4984–498910.1016/j.jpowsour.2010.02.042 ↗
43. Kim J, Yoon Y, Eom M, Shin D (2012) Characterization of amorphous and crystalline Li2S–P2S5–P2Se5 solid electrolytes for all-solid-state lithium ion batteries. Solid State Ion 225:626–63010.1016/j.ssi.2012.05.013 ↗
44. Liu Z, Tang Y, Wang Y, Huang F (2014) High performance Li2S–P2S5 solid electrolyte induced by selenide. J Power Sources 260:264–26710.1016/j.jpowsour.2014.03.036 ↗
45. Yang K, Dong J, Zhang L, Li Y, Wang L, Stevenson J (2015) Dual doping: an effective method to enhance the electrochemical properties of Li10GeP2S12-based solid electrolytes. J Am Ceram Soc 98:3831–383510.1111/jace.13800 ↗
46. Rodriguez-Carvajal J (1992) Recent advances in magnetic structure determination by neutron powder diffraction. Phys B 192:55–6910.1016/0921-4526(93)90108-I ↗
47. Hayashi A, Muramatsu H, Ohtomo T, Hama S, Tatsumisago M (2014) Improved chemical stability and cyclability in Li2S–P2S5–P2O5–ZnO composite electrolytes for all-solid-state rechargeable lithium batteries. J Alloys Compd 591:247–25010.1016/j.jallcom.2013.12.191 ↗
48. Wan H, Peng G, Yao X, Yang J, Cui P, Xu X (2016) Cu2ZnSnS4/graphene nanocomposites for ultrafast, long life all-solid-state lithium batteries using lithium metal anode. Energy Storage Mater 4:59–6510.1016/j.ensm.2016.02.004 ↗