journal article·2015-04

Preparation and characterization of ethylene-vinyl acetate/halloysite nanotube nanocomposites

Hossein Cheraghi Bidsorkhi, Hossein Adelnia, Raheleh Heidar Pour, Mohammad Soheilmoghaddam

Journal of Materials Science· Volume 50· Issue 8
Publisher page

Abstract

Ethylene-vinyl acetate (EVA) nanocomposites based on halloysite nanotubes (HNT) were prepared by solution casting method. The thermal, mechanical, water uptake, as well as oxygen permeability properties of the nanocomposites were examined. X-ray diffraction (XRD) and field emission scanning electron microscopy showed that HNTs were dispersed well into the EVA matrix. XRD data also suggested that HNT frustrates chain ordering and reduced total crystallinity percentage. The thermal and mechanical properties of the nanocomposites were improved with HNT loading, up to 3 wt%. Both ductility and toughness were enhanced by incorporation of up to 3 wt% of HNT, implicitly confirming that HNT has been dispersed in EVA homogeneously. The addition of HNT also enhanced the water resistance and oxygen permeability of the prepared nanocomposites.
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Research context

OpenAlex topics: Clay minerals and soil interactions · Polymer Nanocomposites and Properties · Layered Double Hydroxides Synthesis and Applications

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (59)

Show source-provided references
1. González-Benito J, Castillo E, Caldito JF (2013) Coefficient of thermal expansion of TiO2 filled EVA based nanocomposites. A new insight about the influence of filler particle size in composites. Eur Polym J 49(7):1747–175210.1016/j.eurpolymj.2013.04.023 ↗
2. Dehsari HS et al (2014) Efficient preparation of ultralarge graphene oxide using a PEDOT: PSS/GO composite layer as hole transport layer in polymer-based optoelectronic devices. RSC Advances 4(98):55067–5507610.1039/C4RA09474C ↗
3. Spitalsky Z et al (2010) Carbon nanotube–polymer composites: chemistry, processing, mechanical and electrical properties. Prog Polym Sci 35(3):357–40110.1016/j.progpolymsci.2009.09.003 ↗
4. Giannelis EP (1996) Polymer layered silicate nanocomposites. Adv Mater 8(1):29–3510.1002/adma.19960080104 ↗
5. Alhuthali A, Low IM (2013) Water absorption, mechanical, and thermal properties of halloysite nanotube reinforced vinyl-ester nanocomposites. J Mater Sci 48(12):4260–4273. doi: 10.1007/s10853-013-7240-x10.1007/s10853-013-7240-x ↗
6. Hao A et al (2014) Mechanical, thermal, and flame-retardant performance of polyamide 11–halloysite nanotube nanocomposites. J Mater Sci. doi: 10.1007/s10853-014-8575-7
7. Liu M et al (2014) Recent advance in research on halloysite nanotubes-polymer nanocomposite. Prog Polym Sci 39(8):1498–152510.1016/j.progpolymsci.2014.04.004 ↗
8. Hashemifard SA, Ismail AF, Matsuura T (2011) Mixed matrix membrane incorporated with large pore size halloysite nanotubes (HNT) as filler for gas separation: experimental. J Colloid Interface Sci 359(2):359–37010.1016/j.jcis.2011.03.077 ↗
9. Pasbakhsh P et al (2010) EPDM/modified halloysite nanocomposites. Appl Clay Sci 48(3):405–41310.1016/j.clay.2010.01.015 ↗
10. Rooj S et al (2010) Preparation and properties of natural nanocomposites based on natural rubber and naturally occurring halloysite nanotubes. Mater Des 31(4):2151–215610.1016/j.matdes.2009.11.009 ↗
11. Carli LN, Crespo JS, Mauler RS (2011) PHBV nanocomposites based on organomodified montmorillonite and halloysite: the effect of clay type on the morphology and thermal and mechanical properties. Compos A Appl Sci Manuf 42(11):1601–160810.1016/j.compositesa.2011.07.007 ↗
12. Hedicke-Höchstötter K, Lim GT, Altstädt V (2009) Novel polyamide nanocomposites based on silicate nanotubes of the mineral halloysite. Comp Sci Technol 69(3–4):330–33410.1016/j.compscitech.2008.10.011 ↗
13. Jang D, Zhang W, Choi H (2014) Polypyrrole-wrapped halloysite nanocomposite and its rheological response under electric fields. J Mater Sci 49(20):7309–7316. doi: 10.1007/s10853-014-8443-510.1007/s10853-014-8443-5 ↗
14. Deng S et al (2008) Toughening epoxies with halloysite nanotubes. Polymer 49(23):5119–512710.1016/j.polymer.2008.09.027 ↗
15. Liu M et al (2008) Natural inorganic nanotubes reinforced epoxy resin nanocomposites. J Polym Res 15(3):205–21210.1007/s10965-007-9160-4 ↗
16. Ning N-Y et al (2007) Crystallization behavior and mechanical properties of polypropylene/halloysite composites. Polymer 48(25):7374–738410.1016/j.polymer.2007.10.005 ↗
17. Du M, Guo B, Jia D (2006) Thermal stability and flame retardant effects of halloysite nanotubes on poly (propylene). Eur Polym J 42(6):1362–136910.1016/j.eurpolymj.2005.12.006 ↗
18. Ismail H et al (2008) Morphological, thermal and tensile properties of halloysite nanotubes filled ethylene propylene diene monomer (EPDM) nanocomposites. Polym Testing 27(7):841–85010.1016/j.polymertesting.2008.06.007 ↗
19. Guo B et al (2009) Styrene-butadiene rubber/halloysite nanotubes nanocomposites modified by sorbic acid. Appl Surf Sci 255(16):7329–733610.1016/j.apsusc.2009.03.092 ↗
20. Guo B et al (2008) Styrene–butadiene rubber/halloysite nanotubes nanocomposites modified by methacrylic acid. Appl Surf Sci 255(5):2715–272210.1016/j.apsusc.2008.07.188 ↗
21. Du M et al (2008) Carboxylated butadiene–styrene rubber/halloysite nanotube nanocomposites: interfacial interaction and performance. Polymer 49(22):4871–487610.1016/j.polymer.2008.08.042 ↗
22. Soheilmoghaddam M et al (2013) Regenerated cellulose/halloysite nanotube nanocomposite films prepared with an ionic liquid. Mater Chem Phys 141(2–3):936–94310.1016/j.matchemphys.2013.06.029 ↗
23. Hanid NA et al (2014) Development of regenerated cellulose/halloysites nanocomposites via ionic liquids. Carbohydr Polym 99:91–9710.1016/j.carbpol.2013.07.080 ↗
24. De Silva RT et al (2014) Influence of the processing methods on the properties of poly(lactic acid)/halloysite nanocomposites. Polym Comps. doi: 10.1002/pc.2324410.1002/pc.23244 ↗
25. Schmitt H et al (2012) Preparation and properties of novel melt-blended halloysite nanotubes/wheat starch nanocomposites. Carbohydr Polym 89(3):920–92710.1016/j.carbpol.2012.04.037 ↗
26. Sengupta R et al (2011) A review on the mechanical and electrical properties of graphite and modified graphite reinforced polymer composites. Prog Polym Sci 36(5):638–67010.1016/j.progpolymsci.2010.11.003 ↗
27. Kim H, Abdala AA, Macosko CW (2010) Graphene/polymer nanocomposites. Macromolecules 43(16):6515–653010.1021/ma100572e ↗
28. Bidsorkhi HC et al (2014) Mechanical, thermal and flammability properties of ethylene-vinyl acetate (EVA)/sepiolite nanocomposites. Polym Testing 37:117–12210.1016/j.polymertesting.2014.05.007 ↗
29. Zanetti M et al (2001) Synthesis and thermal behaviour of layered silicate–EVA nanocomposites. Polymer 42(10):4501–450710.1016/S0032-3861(00)00775-8 ↗
30. Riva A et al (2002) Thermal degradation and rheological behaviour of EVA/montmorillonite nanocomposites. Polym Degrad Stab 77(2):299–30410.1016/S0141-3910(02)00065-4 ↗
31. Tian Y et al (2004) Study on the structure and properties of EVA/clay nanocomposites. J Mater Sci 39(13):4301–4303. doi: 10.1023/B:JMSC.0000033412.92494.ee10.1023/B:JMSC.0000033412.92494.ee ↗
32. Morlat-Therias S et al (2007) Polymer/carbon nanotube nanocomposites: influence of carbon nanotubes on EVA photodegradation. Polym Degrad Stab 92(10):1873–188210.1016/j.polymdegradstab.2007.06.021 ↗
33. Kim S et al (2007) Polysulfone and functionalized carbon nanotube mixed matrix membranes for gas separation: theory and experiment. J Membr Sci 294(1–2):147–15810.1016/j.memsci.2007.02.028 ↗
34. Wang B, Huang H-X (2013) Effects of halloysite nanotube orientation on crystallization and thermal stability of polypropylene nanocomposites. Polym Degrad Stab 98(9):1601–160810.1016/j.polymdegradstab.2013.06.022 ↗
35. Marcilla A et al (2005) Pyrolysis of polymers in the presence of a commercial clay. Polym Degrad Stab 88(3):456–46010.1016/j.polymdegradstab.2004.11.017 ↗
36. Yuan P et al (2008) Functionalization of halloysite clay nanotubes by grafting with γ-aminopropyltriethoxysilane. J Phys Chem C 112(40):15742–1575110.1021/jp805657t ↗
37. Sadeghi M et al (2008) Gas permeation properties of ethylene vinyl acetate–silica nanocomposite membranes. J Membr Sci 322(2):423–42810.1016/j.memsci.2008.05.077 ↗
38. Soheilmoghaddam M, Wahit MU (2013) Development of regenerated cellulose/halloysite nanotube bionanocomposite films with ionic liquid. Int J Biol Macromol 58:133–13910.1016/j.ijbiomac.2013.03.066 ↗
39. Guo B et al (2009) Crystallization behavior of polyamide 6/halloysite nanotubes nanocomposites. Thermochim Acta 484(1):48–5610.1016/j.tca.2008.12.003 ↗
40. Urresti O et al (2011) Oxygen permeability through poly(ethylene-co-vinyl acetate)/clay nanocomposites prepared by microwave irradiation. J Membr Sci 373(1–2):173–17710.1016/j.memsci.2011.03.003 ↗
41. Hoang T et al (2013) Tensile, rheological properties, thermal stability, and morphology of ethylene vinyl acetate copolymer/silica nanocomposites using EVA-g-maleic anhydride. J Comp Mater. doi: 10.1177/002199831347631910.1177/0021998313476319 ↗
42. Bai Y et al (2007) Pervaporation characteristics of ethylene–vinyl acetate copolymer membranes with different composition for recovery of ethyl acetate from aqueous solution. J Membr Sci 305(1):152–15910.1016/j.memsci.2007.07.042 ↗
43. Devallencourt C et al (2002) Study of transport of small molecules through ethylene-co-vinyl acetate copolymers films. Part A: Water molecules. Polym Testing 21(3):253–26210.1016/S0142-9418(01)00078-2 ↗
44. Mishra S, Luyt A (2008) Effect of organic peroxides on the morphological, thermal and tensile properties of EVA-organoclay nanocomposites. express. Polym Lett 2:256–26410.3144/expresspolymlett.2008.31 ↗
45. Wilson R et al (2012) Clay intercalation and its influence on the morphology and transport properties of EVA/clay nanocomposites. J Phys Chem C 116(37):20002–2001410.1021/jp302177y ↗
46. Arsac A, Carrot C, Guillet J (1999) Rheological characterization of ethylene vinyl acetate copolymers. J Appl Polym Sci 74(11):2625–263010.1002/(SICI)1097-4628(19991209)74:11<2625::AID-APP9>3.0.CO;2-G ↗
47. Han D et al (2011) Cellulose/graphite oxide composite films with improved mechanical properties over a wide range of temperature. Carbohydr Polym 83(2):966–97210.1016/j.carbpol.2010.09.006 ↗
48. Soheilmoghaddam M et al (2014) Characterization of bio regenerated cellulose/sepiolite nanocomposite films prepared via ionic liquid. Polym Testing 33:121–13010.1016/j.polymertesting.2013.11.011 ↗
49. Soheilmoghaddam M et al (2014) Bionanocomposites of regenerated cellulose/zeolite prepared using environmentally benign ionic liquid solvent. Carbohydr Polym 106:326–33410.1016/j.carbpol.2014.02.085 ↗
50. Gavgani JN et al (2014) Intumescent flame retardant polyurethane/starch composites: Thermal, mechanical, and rheological properties. J Appl Polym Sci 131:41158. doi: 10.1002/app.4115810.1002/app.41158 ↗
51. He Y et al (2012) Modified natural halloysite/potato starch composite films. Carbohydr Polym 87(4):2706–271110.1016/j.carbpol.2011.11.057 ↗
52. Liu M et al (2012) Chitosan/halloysite nanotubes bionanocomposites: structure, mechanical properties and biocompatibility. Int J Biol Macromol 51(4):566–57510.1016/j.ijbiomac.2012.06.022 ↗
53. Liu M, Zhang Y, Zhou C (2013) Nanocomposites of halloysite and polylactide. Appl Clay Sci 75:52–5910.1016/j.clay.2013.02.019 ↗
54. Pramanik M et al (2003) EVA/clay nanocomposite by solution blending: effect of aluminosilicate layers on mechanical and thermal properties. Macromol Res 11(4):260–26610.1007/BF03218362 ↗
55. Khodkar F, Ebrahimi NG (2011) Effect of irradiation on mechanical and structural properties of ethylene vinyl acetate copolymers hollow fibers. J Appl Polym Sci 119(4):2085–209210.1002/app.32926 ↗
56. Gavgani J, Adelnia H, Gudarzi M (2014) Intumescent flame retardant polyurethane/reduced graphene oxide composites with improved mechanical, thermal, and barrier properties. J Mater Sci 49(1):243–254. doi: 10.1007/s10853-013-7698-610.1007/s10853-013-7698-6 ↗
57. Swain SK et al (2013) Cellulose nanobiocomposites with reinforcement of boron nitride: study of thermal, oxygen barrier and chemical resistant properties. Carbohydr Polym 95(2):728–73210.1016/j.carbpol.2013.02.080 ↗
58. Ghosal K, Freeman BD (1994) Gas separation using polymer membranes: an overview. Polym Adv Technol 5(11):673–69710.1002/pat.1994.220051102 ↗
59. Liu M et al (2012) Novel polymer nanocomposite hydrogel with natural clay nanotubes. Colloid Polym Sci 290(10):895–90510.1007/s00396-012-2588-z ↗