journal article·2003-04

Effect of silane-coupling agent on natural rubber filled with silica generated in situ

K. Murakami, S. Iio, Y. Ikeda, H. Ito, M. Tosaka, S. Kohjiya

Journal of Materials Science· Volume 38· Issue 7
Publisher page

Abstract

The effect of silane coupling agent was investigated for the novel in situ silica loading to the natural rubber (NR) matrix. The silica was generated in situ by the sol-gel reaction of tetraethoxysilane in the NR matrix before its crosslinking. γ-mercaptopropyltrimethoxysilane (γ-MPS) significantly prevented the delay of sulfur curing and increased the wettability of NR onto in situ silica, which resulted in the increase of reinforcement effect for the NR vulcanizate. γ-MPS decreased the interaction between the in situ silica particles followed by dispersing the in situ silica particles homogeneously and decreasing the hardness, compression set, hysteresis loss and storage modulus at the rubbery state of in situ silica-filled NR vulcanizate. The NR/in situ silica composite with γ-MPS is a promising material for a high performance rubber product.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Polymer Nanocomposites and Properties · Liquid Crystal Research Advancements · Silicone and Siloxane Chemistry

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (28)

Show source-provided references
1. G. Kraus, “Reinforcement of Elastomers” Ch. 2 and 13 (Interscience, New York, 1965).
2. F. R. Eirich, (ed), “Science and Technology of Rubber” (Academic Press, Orlando, 1978).
3. W. W. Barbin and M. B. Rodgers, in “Science and Technology of Rubber, “2nd Ed.” edited by J. E. Mark, B. Erman and F. R. Eirich (Academic Press, San Diego, 1994) Ch. 9.
4. B. Schwaiger and A. Blume, RubberWorld 222(1) (2000) 32.
5. C. J. Brinker and G. W. Scherer, “Sol-Gel Science” (Academic Press, New York, 1982).
6. J. E. Mark, in “Science of Ceramic Chemical Processing” Ch. 47, edited by L. L. Hench and R. D. Ulrich (John Wiley & Sons, New York, 1985).
7. S. Kohjiya and Y. Ikeda, in “New Functionality Materials” Vol. C, edited by T. Tsuruta, M. Doyama and M. SENO (Elsevier, Amsterdam, 1993) p. 443.
8. Y. Ikeda, A. S. Hashim and S. Kohjiya, Bull. Inst. Chem. Res. Kyoto Univ. 2(5/6) (1995) 406.
9. B. Erman and J. E. Mark, “Structures and Properties of Rubberlike Networks” (Oxford University Press, New York, 1997) p. 265.10.1093/oso/9780195082371.001.0001 ↗
10. S. Kohjiya and Y. Ikeda, Rubber Chem. Technol. 73 (2000) 534.10.5254/1.3547604 ↗
11. S. Sakka, “Zoru-geru Houno Kagaku” (Agune Shofusya, Tokyo, 1988).
12. J. E. Mark and S. J. Pan, Makromol. Chem., Rapid Commun. 3 (1982) 681.10.1002/marc.1982.030031006 ↗
13. C.-C. Sun and J. E. Mark, J. Polym. Sci.: Part B: Polym. Phys. 25 (1987) 1561.10.1002/polb.1987.090250718 ↗
14. S. Kohjiya, A. Yajima, J. R. Yoon and Y. Ikeda, Nippon Gomu Kyokaishi 67 (1994) 859.10.2324/gomu.67.859 ↗
15. A. S. Hashim, Y. Ikeda and S. Kohjiya, Polym. Int. 38 (1995) 111.10.1002/pi.1995.210380202 ↗
16. K. Yoshimi, M. Yamaguchi and K. Nishimura, Nippon Gomu Kyokaishi 69 (1996) 485.10.2324/gomu.69.485 ↗
17. Y. Ikeda, A. Tanaka and S. Kohjiya, J. Mater. Chem. 7 (1997) 445.
18. Idem., ibid. 7 (1997) 1497.
19. Y. Ikeda and S. Kohjiya, Polymer 38 (1997) 4417.10.1016/S0032-3861(96)01037-3 ↗
20. M. Sugiya, K. Terakawa, Y. Miyamoto, S. Tomono, S. Kohjiya and Y. Ikeda, Kautsch. Gummi Kunstst. 50 (1997) 538.
21. A. S. Hashim, B. Azahari, Y. Ikeda and S. Kohjiya, Rubber Chem. Technol. 71 (1998) 289.10.5254/1.3538485 ↗
22. H. Tanahashi, S. Osanai, M. Shigekuni, S. Iio, K. Murakami, Y. Ikeda and S. Kohjiya, ibid. 71 (1998) 38.10.5254/1.3538470 ↗
23. K. Murakami, S. Osanai, M. Shigekuni, S. Iio, H. Tanahashi, S. Kohjiya and Y. Ikeda, ibid. 72 (1999) 119.10.5254/1.3538781 ↗
24. S. Kohjiya, K. Murakami, S. Iio, T. Tanahahi and Y. Ikeda, ibid., 74 (2001) 16.10.5254/1.3547635 ↗
25. H. Nakauchi, T. Utsunomiya, K. Masuda, S. Inoue and K. Naito, Nippon Gomu Kyokaishi 60 (1987) 267.10.2324/gomu.60.267 ↗
26. P. J. Flory, “Principles of Polymer Chemistry” (Cornell Univ. Press, Ithaca, NY, 1953).
27. S. Wolff, Rubber Chem. Technol. 69 (1996) 325.10.5254/1.3538376 ↗
28. J.-B. Donnet, ibid. 71 (1998) 323.10.5254/1.3538488 ↗