Selective synthesis of brookite, anatase and rutile nanoparticles: thermolysis of TiCl4 in aqueous nitric acid
Source abstract
Abstract
The three polymorphs of titania (anatase, rutile and brookite) have been obtained as nanoparticles selectively and with well definite morphologies (platelets of brookite, rods of rutile) by thermohydrolysis of TiCl4 in concentrated aqueous nitric acid. The selectivity of the synthesis depends strongly on the acidity of the medium. The presence of concentrated nitrate ions seems to be the determining factor for the formation of brookite and its stabilization against recrystallization.
Source: openaire · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: TiO2 Photocatalysis and Solar Cells · Advanced Photocatalysis Techniques · Chemical Synthesis and Characterization
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (42)
Show source-provided references
1. Ohzuku T, Hirai T (1982) Electrochim Acta 27:126310.1016/0013-4686(82)80146-1 ↗
2. Fuyuki T, Kobayashi T, Matsunami H (1988) J Electrochem Soc 135:24810.1149/1.2095566 ↗
3. Kavan L, Kratochvilova K, Grätzel M (1995) J Electroanal Chem 394:9310.1016/0022-0728(95)03976-N ↗
4. Braun JH, Baidins A, Marganski RE (1992) Prog Org Coat 20:10510.1016/0033-0655(92)80001-D ↗
5. Fujishima A, Honda K (1972) Nature 238:3710.1038/238037a0 ↗
6. Voltz HG, Kämpf G, Fitzky G (1973) Prog Org Coat 2:233
7. Serpone N, Pelizzeti E (1989) In: Photocatalysis: Fundamentals and applications. Wiley, London, UK
8. O’regan B, Moser J, Andersen M, Grätzel M (1990) J Phys Chem 94:872010.1021/j100387a017 ↗
9. O’regan B, Grätzel M (1991) Nature 353:73710.1038/353737a0 ↗
10. Van De Krol R, Goossens A, Schoonman J (1997) J Electrochem Soc 144:172310.1149/1.1837668 ↗
11. Koelsch M, Cassaignon S, Ta Thanh Minh C, Guillemoles J-F, Jolivet J-P (2004) Thin Solid Films 451–452:8610.1016/j.tsf.2003.11.150 ↗
12. Koelsch M, Cassaignon S, Guillemoles J-F, Jolivet J-P (2002) Thin Solid Films 403–404:31210.1016/S0040-6090(01)01509-7 ↗
13. Cassaignon S, Koelsch M, Guillemoles J-F, Jolivet J-P (2004) In: Hoffman W, Bal JL Ossenbrink H, Palz W, Helm P (eds) Proceedings of the 19th Eur. Photovoltaic Solar Energy Conf. 2004, (Paris, France), p 305
14. Moritz T, Reiss J, Diesner K, Su D, Chemseddine A (1997) J Phys Chem B 101:805210.1021/jp9705131 ↗
15. Ichinose H, Terasaki M, Katsuki H (1996) J Ceram Soc Jpn 104:71510.2109/jcersj.104.715 ↗
16. Yamamoto S, Nishikura H, Terao Y (1988) Crystalline titania sol and its manufacture. Patent JP 1988/63017221
17. Matijevic E, Budnick M, Meites L (1977) J Colloid Interface Sci 61:30210.1016/0021-9797(77)90393-9 ↗
18. Koelsch M, Cassaignon S, Jolivet J-P (2004) In: Kelder EM, Leite ER, Tarascon J-M, Chiang Y-M (eds) Proceedings of the Mater. Res. Soc. Symp. Proc. 822, Warrendale, PA10.1557/PROC-822-S3.8 ↗
19. Pottier A, Cassaignon S, Chaneac C, Tronc E, Jolivet J-P (2003) J Mater Chem 13:87710.1039/b211271j ↗
20. Iwasaki M, Hara M, Ito S (1998) J Mater Sci Lett 17:176910.1023/A:1006660209934 ↗
21. Allan WB and Bousquet LG (1939) Titanium dioxide. Patent US 1939/2182420
22. Chemseddine A, Moritz T (1999) Eur J Inorg Chem 1999:23510.1002/(SICI)1099-0682(19990202)1999:2<235::AID-EJIC235>3.0.CO;2-N ↗
23. Bischoff BL, Anderson MA (1995) Chem Mater 7:177210.1021/cm00058a004 ↗
24. Seo D, Lee J, Kim H (2001) J Cryst Growth 233:29810.1016/S0022-0248(01)01494-4 ↗
25. Li Y, Fan Y, Chen Y (2002) J Mater Chem 12:138710.1039/b200018k ↗
26. Yin H, Wada Y, Kitamura T, Kambe S, Murasawa S, Mori H, Sakata T, Yanagida S (2001) J Mater Chem 11:169410.1039/b008974p ↗
27. Cheng H, Ma J, Zhao Z, Qi L (1995) Chem Mater 7:66310.1021/cm00052a010 ↗
28. Aruna ST, Tirosh S, Zaban A (2000) J Mater Chem 10:238810.1039/b001718n ↗
29. Keesmann I (1966) Z Anorg Allg Chem 346:3010.1002/zaac.19663460105 ↗
30. Mistuhashi T, Watanabe M (1978) Mineral J 9:23610.2465/minerj.9.236 ↗
31. Nagase T, Ebina T, Iwasaki T, Hayashi H, Onodera Y, Chatterjee M (1999) Chem Lett 28:91110.1246/cl.1999.911 ↗
32. Zheng Y, Shi E, Cui S, Li W, Hu X (2000) J Am Ceram Soc 83:263410.1111/j.1151-2916.2000.tb01605.x ↗
33. Kominami H, Kohno M, Kera Y (2000) J Mater Chem 10:115110.1039/a908528i ↗
34. Pottier A, Chaneac C, Tronc E, Mazerolles L, Jolivet J-P (2001) J Mater Chem 11:111610.1039/b100435m ↗
35. Bekkerman LI, Dobrovol’skii IP, Ivakin AA, (1976) Russ J Inorg Chem 21:418
36. Lee JH, Yang YS (2006) J Mater Sci 41:55710.1007/s10853-005-2152-z ↗
37. Charlot G (1961) In: Les méthodes de la chimie analytique, Masson & Cie, Paris, France
38. Weissler A (1945) Ind Eng Chem Anal Ed 17:69510.1021/i560147a007 ↗
39. Langford JI, Wilson AJC (1978) J Appl Crystallogr 11:10210.1107/S0021889878012844 ↗
40. Nabivanets BI (1962) Russ J Inorg Chem 7:412
41. Golub AM, Tishchenko AF, Kokot IF, Kalinichenko AM (1971) Ukr Khim. Zh. (Russ. Ed.) 34:533
42. Jolivet J-P (2000) In: Metal oxide chemistry and synthesis: from solution to solid state. Wiley, Chichester, UK