journal article·2025-08

Enhancing dielectric characteristics of calcium copper titanate via lattice site modification

Amar Dev, Tupan Das, Piyali Biswas, Anant Shukla, P. Kour, S. K. Pradhan, Manoranjan Kar

Journal of Materials Science· Volume 60· Issue 30
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Abstract

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OpenAlex topics: Dielectric properties of ceramics · Ferroelectric and Piezoelectric Materials · Microwave Dielectric Ceramics Synthesis

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References (47)

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1. Li Q, Chen L, Gadinski MR, Zhang S, Zhang G, Li HU, Iagodkine E, Haque A, Chen LQ, Jackson TN, Wang Q (2015) Flexible high-temperature dielectric materials from polymer nanocomposites. Nature 523:576–57910.1038/nature14647 ↗
2. Ahmadipour M, Ain MF, Ahmad ZA (2016) A short review on copper calcium titanate (CCTO) electroceramic: synthesis, dielectric properties, film deposition, and sensing application. Nanomicro Lett 8:291–311
3. Das T, Rout SN, Dev A, Kar M, Appl. (2024) The MnAl-alloy nanoparticles incorporated PVDF-based piezoelectric nanogenerator as a self-powered real-time pedometer sensor. Phys Lett 125:163901
4. Chinnathambi M, Sakthisabarimoorthi A, Jose M, Robert R (2021) Study of the electrical and dielectric behaviour of selenium doped CCTO ceramics prepared by a facile sol-gel route. Mater Chem Phys 272:12497010.1016/j.matchemphys.2021.124970 ↗
5. Das T, Yadav MK, Dev A, Kar M (2024) Double perovskite-based wearable ternary nanocomposite piezoelectric nanogenerator for self-charging, human health monitoring and temperature sensor. Chem Eng J. 496:15392610.1016/j.cej.2024.153926 ↗
6. Zhang J, Deng T, Li P, Lv Y, Nan Y, Lei Z, Li Y, Li L (2024) Enhanced breakdown strength and dielectric loss of Ca1−3x/2Eux Cu3Ti4O12 ceramics prepared by polymer pyrolysis. J Mater Sci Mater Electron 35:24610.1007/s10854-024-12001-z ↗
7. Huang X, Jiang P (2015) Core–shell structured high‐k polymer nanocomposites for energy storage and dielectric applications. Adv Mater 27:546–55410.1002/adma.201401310 ↗
8. Adams TB, Sinclair DC, West AR, Sinclair DC, Anthony R (2002) Giant barrier layer capacitance effects in CaCu3Ti4O12 ceramic. West Adv Mater 14:1321–132310.1002/1521-4095(20020916)14:18<1321::AID-ADMA1321>3.0.CO;2-P ↗
9. Yanchevskii OZ, V’yunov OI, Belous AG, Kovalenko LL (2021) Dielectric properties of CaCu3Ti4O12 ceramics doped with aluminium and fluorine. J Alloys Compd. 874:15986110.1016/j.jallcom.2021.159861 ↗
10. Xiao M, Meng J, Li L (2019) Non-Ohmic behavior of copper-rich CCTO thin film prepared through magnetron sputtering method. J Mater Sci Mater Electron 30:9266–927210.1007/s10854-019-01255-7 ↗
11. Zhang J, Li Z, Liu Y, Zheng J, Lu W, Guo S, Lei Z, Lin L, Tian M (2020) Enhanced dielectric properties of CCTO ceramics doped by different halogen elements. J Mater Sci Mater Electron 31:8481–848810.1007/s10854-020-03383-x ↗
12. Thomas P, Ashokbabu A, Vaish R (2020) Structural, thermal and dielectric properties and thermal degradation kinetics of nylon 11/CaCu3Ti4O12 (CCTO) nanocomposites. J Therm Anal Calorim 141:1123–113510.1007/s10973-019-09105-8 ↗
13. Espinoza-González R, Hevia S, Adrian A (2018) Effects of strontium/lanthanum co-doping on the dielectric properties of CaCu3Ti4O12 prepared by reactive sintering. Ceram Int 44:15588–1559510.1016/j.ceramint.2018.05.223 ↗
14. Lunkenheimer P, Bobnar V, Pronin AV, Ritus AI, Volkov AA, Loidl A (2002) Origin of apparent colossal dielectric constants. Phys Rev B 66:05210510.1103/PhysRevB.66.052105 ↗
15. Kobayashi W, Terasaki I (2005) CaCu3Ti4O12/CaTiO3 composite dielectrics: Ba/Pb-free dielectric ceramics with high dielectric constants. Appl Phys Lett 87:03290210.1063/1.1997278 ↗
16. Subramanian MA, Li D, Duan N, Reisner BA, Sleight AW (2000) High dielectric constant in ACu3Ti4O12 and ACu3Ti3FeO12 phases. J Solid State Chem 151:323–32510.1006/jssc.2000.8703 ↗
17. Raval PY, Makadiya AR, Pansara PR, Sharma PU, Vasoya NH, Bhalodia JA, Kumar S, Dolia SN, Modi KB (2018) Effect of thermal history on structural, microstructural properties and J–E characteristics of CaCu3Ti4O12 polycrystalline ceramic. Mater Chem Phys 212:343–35010.1016/j.matchemphys.2018.03.041 ↗
18. Yang L, Wang H, Zhang F, Yang Y, Qu S, Leng D, Ma X (2023) Synthetic technologies, property enhancements and versatile applications of calcium copper titanate: a review. Nano Energy. 114:10860910.1016/j.nanoen.2023.108609 ↗
19. Rauf S, Hanif MB, Tayyab Z, Veis M, Yousaf Shah MAK, Mushtaq N, Medvedev D, Tian Y, Xia C, Motola M, Zhu B (2025) Alternative strategy for development of dielectric calcium copper titanate-based electrolytes for low-temperature solid oxide fuel cells. Nanomicro Lett. 17:1–23
20. Macchesney JB, Gallagher PK, Dimarcello FV (1963) Stabilized barium titanate ceramics for capacitor dielectrics. J Am Ceram Soc 46:197–20210.1111/j.1151-2916.1963.tb19771.x ↗
21. Feliksik K, Kozielski L, Szafraniak-Wiza I, Goryczka T, Adamczyk-Habrajska M (2019) Dielectric and impedance studies of (Ba, Ca) TiO3 ceramics obtained from mechanically synthesized powders. Mater 12:403610.3390/ma12244036 ↗
22. Lee J-W, Koh J-H (2015) Grain size effects on the dielectric properties of CaCu3Ti4O12 ceramics for supercapacitor applications. Ceram Int 41:10442–1044710.1016/j.ceramint.2015.04.109 ↗
23. West AR, Adams TB, Morrison FD, Sinclair DC (2004) Novel high capacitance materials:-BaTiO3: La and CaCu3Ti4O12. J Eur Ceram Soc 24:1439–144810.1016/S0955-2219(03)00510-7 ↗
24. Das T, Biswas P, Dev A, Mallick J, Kar M (2024) Multi-functional piezoelectric nanogenerator based on relaxor ferroelectric materials (BSTO) and conductive fillers (MWCNTs) for self-powered memristor and optoelectronic devices. Chem Eng J 479:14790010.1016/j.cej.2023.147900 ↗
25. Dhugga LK, Baskey HB, Gaur KK, Singh DP (2023) Absorption dominant electromagnetic interference shielding in the novel polypyrrole-CaCu3Ti4O12-CoFe2O4 nanocomposites. Compos Technol 240:11006710.1016/j.compscitech.2023.110067 ↗
26. Dhavala L, Bhimireddi R, Muthukumar SV, Kollipara VS, Varma KBR (2008) RSC. 41:035401
27. Kumar L, Kumar P, Narayan A, Kar M (2013) Rietveld analysis of XRD patterns of different sizes of nanocrystalline cobalt ferrite. Int Nano Lett 3:1–1210.1186/2228-5326-3-8 ↗
28. Jani KK, Barad DV, Raval PY, Nehra M, Vasoya NH, Jakhar N, Modi KB, Kumar S, Lim DK, Singhal RK (2021) Ca2+-substitution effect on the electronic structure of CaCu3Ti4O12 studied by electron spectroscopy for chemical analysis. Ceram Int 47:5542–554810.1016/j.ceramint.2020.10.138 ↗
29. Kolev N, Bontchev RP, Jacobson AJ, Popov VN, Hadjiev VG, Litvinchuk AP, Iliev MN (2002) Raman spectroscopy of CaCu3Ti4O12. Phys Rev B 66:13210210.1103/PhysRevB.66.132102 ↗
30. Robins LH, Kaiser DL, Rotter LD, Schenck PK, Stauf GT, Rytz D (1994) Investigation of the structure of barium titanate thin films by Raman spectroscopy. J Appl Phys 76:7487–749810.1063/1.357978 ↗
31. Hilczer B, Kulek J, Polomska M, Glinchuk MD, Rangulya AV, Pietraszko A (2005) Dielectric and pyroelectric response of BaTiO3-PVDF nanocomposites. Ferroelctr 316:31–4110.1080/00150190590963101 ↗
32. Almeida AFL, Fechine PBA, Graça MPF, Valente MA, Sombra ASB (2009) Structural and electrical study of CaCu3Ti4O12 (CCTO) obtained in a new ceramic procedure. J Mater Sci: Mater Electron 20:163–170
33. Cortés JA, Cotrim G, Orrego S, Simões AZ, Ramírez MA (2018) Dielectric and non-ohmic properties of Ca2Cu2Ti4-xSnxO12 (0.0≤ x≤ 4.0) multiphasic ceramic composites. J Alloys Compd 735:140–14910.1016/j.jallcom.2017.11.089 ↗
34. Jesurani S, Kanagesan S, Kalaivani T, Ashok K (2012) Dielectric properties of Erbium doped CaCu3Ti4O12 prepared by sol–gel self combustion method. J Mater Sci Mater Electron 23:692–69610.1007/s10854-011-0473-z ↗
35. Kashyap R, Mishra RK, Thakur OP, Tandon RP (2012) Structural, dielectric properties and electrical conduction behaviour of Dy substituted CaCu3Ti4O12 ceramics. Ceram Int 38:6807–681310.1016/j.ceramint.2012.05.078 ↗
36. Fang T-T, Shiau H-K (2004) Mechanism for developing the boundary barrier layers of CaCu3Ti4O12. J. Am. Ceram. Soc. 87:2072–207910.1111/j.1151-2916.2004.tb06362.x ↗
37. Wang H, Yang Y, Yang L (2023) Optimization of dielectric loss in calcium copper titanate based on different doping modification strategies. Ceram Int 49:38399–3841910.1016/j.ceramint.2023.09.186 ↗
38. Biswas P, Das T, Dev A, Shukla A, Datta S, Singh RK, Kar M (2024) Structural and enhanced dielectric properties of Al-modified lanthanum strontium manganites. Ceram Int 50:30514–3053210.1016/j.ceramint.2024.05.349 ↗
39. Rani S, Shekhar M, Dev A, Prasad S, Kar M, Kumar P (2024) Temperature dependent dielectric relaxation and current conduction mechanism in Ba and Ti co-doped bismuth ferrite ceramic. J Sol-Gel Sci Technol 110:443–46110.1007/s10971-024-06373-1 ↗
40. Rahman MA, Hossain AKMA (2014) Electrical transport properties of Mn–Ni–Zn ferrite using complex impedance spectroscopy. Phys Scr 89:02580310.1088/0031-8949/89/02/025803 ↗
41. Baricka BK, Choudhary RNP, Pradhan DK (2013) Dielectric and impedance spectroscopy of zirconium modified (Na0. 5Bi0. 5) TiO3 ceramics. Ceram Int 39:5695–570410.1016/j.ceramint.2012.12.087 ↗
42. Parida K, ChoudharyMater RNP (2017) Structural, electrical, optical and magneto-electric characteristics of chemically synthesized CaCu3Ti4O12 dielectric ceramics. Res Express 4:07630210.1088/2053-1591/aa76cd ↗
43. Paswan SK, Pradhan LK, Kumar P, Kumari S, Kar M, Kumar L (2022) Electrical transport properties of nanocrystalline and bulk nickel ferrite using complex impedance spectroscopy: a comparative study. Phys Scr 97:09581210.1088/1402-4896/ac87dc ↗
44. Zulqarnain M, Ali SS, Hira U, Feng JF, Khan MI, Rizwan M, Javed K, Farid G, Hassan MS (2022) Superparamagnetic contributions, optical band gap tuning and dominant interfacial resistive mechanisms in ferrites nanostructures. J Alloys Compd 894:16243110.1016/j.jallcom.2021.162431 ↗
45. Sharma S, Shamim K, Ranjan A, Rai R, Kumari P, Sinha S (2015) Impedance and modulus spectroscopy characterization of lead free barium titanate ferroelectric ceramics. Ceram Int 41:7713–772210.1016/j.ceramint.2015.02.102 ↗
46. Xu C, Zhao X, Ren L, Sun J, Yang L, Guo J, Liao R (2019) Enhanced electrical properties of CaCu3Ti4O12 ceramics by spark plasma sintering: role of Zn and Al co-doping. J Alloys Compd 792:1079–108710.1016/j.jallcom.2019.04.131 ↗
47. Amaral F, Valente MA, Costa LC, Non-Cryst J (2010) Dielectric properties of CaCu3Ti4O12 (CCTO) doped with GeO2. Solids 356:822–827