Sustainable metal oxides and their composites for lithium-ion batteries and multifunctional applications
Source abstract
Abstract
Abstract The sustainability of the world's complex systems and economy relies on an efficient energy supply, with electrochemical energy storage playing a pivotal role in meeting the growing energy demands. However, the electrochemical performance of the existing batteries remains grossly, inadequate to meet the energy demands of modern devices. This is largely due to the persistent challenges with electrode materials. Hence, this review explores the versatility of transition metal oxides and their composites as promising materials for sustainable lithium-ion battery operations. By focusing on innovative composite architectures, this review highlights the potential of conducting polymer/transition metal oxide composites to enhance the electrochemical performance of lithium-ion batteries through improved electrical conductivity, mechanical flexibility, and cycling stability. Moreover, the review investigates the two-dimensional nanomaterials/metal oxide composites, emphasizing their role in optimizing lithium-ion diffusion and its reaction kinetics. Additionally, multimetallic oxide composites are presented, showcasing their synergistic properties that contribute to high capacity and structural stability. The findings underscore the adaptability of transition metal oxides and their composites in advancing the next-generation lithium-ion batteries, sodium-ion batteries, zinc-ion batteries, supercapacitor technologies, sensors, and electrocatalyst.
Source: crossref · Quality: baseline
Research context
OpenAlex topics: Advancements in Battery Materials · Advanced Battery Materials and Technologies · Extraction and Separation Processes
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (100+)
Show source-provided references
1. Hannan MA, Hoque MM, Hussain A, Yusof Y, Ker PJ (2018) State-of-the-art and energy management system of lithium-ion batteries in electric vehicle applications: Issues and recommendations. IEEE Access 6:19362–1937810.1109/ACCESS.2018.2817655 ↗
2. Masias A, Marcicki J, Paxton WA (2021) Opportunities and challenges of lithium ion batteries in automotive applications. ACS Energy Lett 6(2):621–63010.1021/acsenergylett.0c02584 ↗
3. Liu J, Xiao J, Yang J, Wang W, Shao Y, Liu P, Whittingham MS (2023) The TWh challenge: next generation batteries for energy storage and electric vehicles. Next Energy 1(1):10001510.1016/j.nxener.2023.100015 ↗
4. Wen J, Zhao D, Zhang C (2020) An overview of electricity powered vehicles: lithium-ion battery energy storage density and energy conversion efficiency. Renew Energy 162:1629–164810.1016/j.renene.2020.09.055 ↗
5. Jia R, Yu L, Zeng H, Wang C, Li H, Xu B (2024) Metal-organic framework cobalt gallate derived high-voltage carbon coated lithium cobalt oxide cathode and porous carbon supported cobalt oxide anode materials for superior lithium-ion storage. Sustain Mater Technol 40:e00978
6. Cheng H, Shapter JG, Li Y, Gao G (2021) Recent progress of advanced anode materials of lithium-ion batteries. J Energy Chem 57:451–46810.1016/j.jechem.2020.08.056 ↗
7. Dhason MVA, Bhattacharya I, Mansour M, Lazer SJ, Banik T, Soyoye B (2025) Conductive polymers in si anodes for lithium-ion batteries: advancements, challenges and future aspects. Mater Today Energy, p 10189710.1016/j.mtener.2025.101897 ↗
8. Hailu AG, Ramar A, Wang F-M, Yeh N-H, Tiong P-W, Hsu C-C, Chang Y-J, Chen M-M, Chen T-W, Wang C-C (2022) The development of super electrically conductive Si material with polymer brush acid and emeraldine base and its auto-switch design for high-safety and high-performance lithium-ion battery. Electrochim Acta 429:14082910.1016/j.electacta.2022.140829 ↗
9. Ponnusamy K, Kandhasamy K, Gopi P, Sivasankar P (2024) Transition metal oxide-based nanomaterials for lithium-ion battery applications: synthesis, properties, and prospects. Nanostruct Mater Energy Storage 1:371–42310.1002/9783527838851.ch11 ↗
10. Folorunso O, Hamam Y, Sadiku R, Ray SS, Adekoya GJ (2021) Investigation of graphene loaded polypyrrole for lithium-ion battery. Mater Today: Proc 38:635–638
11. Folorunso O, Hamam Y, Sadiku R, Ray SS, Adekoya GJ (2021) Synthesis methods of borophene, graphene-loaded polypyrrole nanocomposites and their benefits for energy storage applications: a brief overview. FlatChem 26:10021110.1016/j.flatc.2020.100211 ↗
12. Aslam J, Wang Y (2023) Metal oxide wrapped by reduced graphene oxide nanocomposites as anode materials for lithium-ion batteries. Nanomaterials 13(2):29610.3390/nano13020296 ↗
13. Su Y, Li S, Wu D, Zhang F, Liang H, Gao P, Cheng C, Feng X (2012) Two-dimensional carbon-coated graphene/metal oxide hybrids for enhanced lithium storage. ACS Nano 6(9):8349–835610.1021/nn303091t ↗
14. Zhang Z, Zhao J, Zhou J, Zhao Y, Tang X, Zhuo S (2017) Interfacial engineering of metal oxide/graphene nanoscrolls with remarkable performance for lithium ion batteries. Energy Storage Mater 8:35–4110.1016/j.ensm.2017.03.003 ↗
15. Wu Z-S, Zhou G, Yin L-C, Ren W, Li F, Cheng H-M (2012) Graphene/metal oxide composite electrode materials for energy storage. Nano Energy 1(1):107–13110.1016/j.nanoen.2011.11.001 ↗
16. Pazhamalai P, Krishnan V, Mohamed Saleem MS, Kim S-J, Seo H-W (2024) Investigating composite electrode materials of metal oxides for advanced energy storage applications. Nano Convergence 11(1):3010.1186/s40580-024-00437-2 ↗
17. Hussain SZ, Ihrar M, Hussain SB, Oh WC, Ullah K (2020) A review on graphene based transition metal oxide composites and its application towards supercapacitor electrodes. SN Appl Sci 2:1–2310.1007/s42452-020-2515-8 ↗
18. Wu Y, Zhan L, Huang K, Wang H, Yu H, Wang S, Peng F, Lai C (2016) Iron based dual-metal oxides on graphene for lithium-ion batteries anode: effects of composition and morphology. J Alloy Compd 684:47–5410.1016/j.jallcom.2016.05.151 ↗
19. Folorunso O, Kumar N, Hamam Y, Sadiku R, Ray SS (2022) Facile solvent/drying fabrication of PVA/PPy/rGO: a novel nanocomposite for energy storage applications. Results Mater 15:10029510.1016/j.rinma.2022.100295 ↗
20. Folorunso O, Olukanmi P, Thokozani S (2023) Conductive polymers’ electronic structure modification for multifunctional applications. Mater Today Commun, p 10630810.1016/j.mtcomm.2023.106308 ↗
21. Yang Z-Z, Zhou Z-L, Li C-W, Ma P-K, Wang C, Wang H-Y (2021) ZnCo2O4 nanorods coated with annealed polypyrrole/poly (vinyl alcohol) composites as anode materials for lithium-ion batteries. ACS Appl Nano Mater 4(5):4496–450310.1021/acsanm.0c02447 ↗
22. Wang Y, Li B, Zhang B, Tian S, Yang X, Ye H, Xia Z, Zheng G (2020) Application of MOFs-derived mixed metal oxides in energy storage. J Electroanal Chem 878:11457610.1016/j.jelechem.2020.114576 ↗
23. Riyanto E, Kristiantoro T, Martides E, Prawara B, Mulyadi D (2023) Lithium-ion battery performance improvement using two-dimensional materials. Mater Today: Proc 87:164–171
24. Folorunso O, Hamam Y, Sadiku R, Ray SS, Adekoya GJ (2021) Theoretical analysis of borophene for lithium ion electrode. Mater Today: Proc 38:485–489
25. Folorunso O, Onibonoje MO, Hamam Y, Sadiku R, Ray SS (2022) Fabrication and model characterization of the electrical conductivity of PVA/PPy/rGO nanocomposite. Molecules 27(12):369610.3390/molecules27123696 ↗
26. Khan K, Tareen AK, Aslam M, Wang R, Zhang Y, Mahmood A, Ouyang Z, Zhang H, Guo Z (2020) Recent developments in emerging two-dimensional materials and their applications. J Mater Chem C 8(2):387–44010.1039/C9TC04187G ↗
27. Kim T, Song W, Son D-Y, Ono LK, Qi Y (2019) Lithium-ion batteries: outlook on present, future, and hybridized technologies. J Mater Chem A 7(7):2942–296410.1039/C8TA10513H ↗
28. Zhu X, Zhu Y, Murali S, Stoller MD, Ruoff RS (2011) Nanostructured reduced graphene oxide/Fe2O3 composite as a high-performance anode material for lithium ion batteries. ACS Nano 5(4):3333–333810.1021/nn200493r ↗
29. Folorunso O, Sadiku R, Hamam Y (2024) Heteroatom-doped carbon allotropes in battery applications. In: Heteroatom-doped carbon allotropes: progress in synthesis, characterization, and applications. ACS Publications, pp 105–12510.1021/bk-2024-1491.ch004 ↗
30. Li X, Zhang Y, Zhong Q, Li T, Li H, Huang J (2014) Surface decoration with MnO2 nanoplatelets on graphene/TiO2 (B) hybrids for rechargeable lithium-ion batteries. Appl Surf Sci 313:877–88210.1016/j.apsusc.2014.06.096 ↗
31. Li T, Lan Y, Yang W, Wang J, Wang C, Yao S, Wang Y (2024) High capacity and excellent cyclic performances of Mn2O3/Mn3O4/C materials as li-ion battery anode. J Mater Sci: Mater Electron 35(1):9
32. Fang S, Bresser D, Passerini S (2022) Transition metal oxide anodes for electrochemical energy storage in lithium‐and sodium‐ion batteries. Transition metal oxides for electrochemical energy storage, pp 55–9910.1002/9783527817252.ch4 ↗
33. Reddy M, Yu C, Jiahuan F, Loh KP, Chowdari B (2013) Li-cycling properties of molten salt method prepared nano/submicrometer and micrometer-sized CuO for lithium batteries. ACS Appl Mater Interfaces 5(10):4361–436610.1021/am400579q ↗
34. Wu H-Y, Hon M-H, Kuan C-Y, Leu C (2015) Synthesis of TiO2 (B)/SnO2 composite materials as an anode for lithium-ion batteries. Ceram Int 41(8):9527–953310.1016/j.ceramint.2015.04.011 ↗
35. Evmenenko G, Fister TT, Buchholz DB, Li Q, Chen K-S, Wu J, Dravid VP, Hersam MC, Fenter P, Bedzyk MJ (2016) Morphological evolution of multilayer Ni/NiO thin film electrodes during lithiation. ACS Appl Mater Interfaces 8(31):19979–1998610.1021/acsami.6b05040 ↗
36. Fernando JF, Zhang C, Firestein KL, Nerkar JY, Golberg DV (2019) ZnO quantum dots anchored in multilayered and flexible amorphous carbon sheets for high performance and stable lithium ion batteries. J Mater Chem A 7(14):8460–847110.1039/C8TA12511B ↗
37. Yan B, Li X, Fu X, Zhang L, Bai Z, Yang X (2020) An elaborate insight of lithiation behavior of V2O5 anode. Nano Energy 78:10523310.1016/j.nanoen.2020.105233 ↗
38. Tang J, Ni S, Chen Q, Yang X, Zhang L (2017) Optimized fabrication of NiCr2O4 and its electrochemical performance in half-cell and full-cell lithium ion batteries. J Alloy Compd 698:121–12710.1016/j.jallcom.2016.12.193 ↗
39. Wang B, Ruan T, Chen Y, Jin F, Peng L, Zhou Y, Wang D, Dou S (2020) Graphene-based composites for electrochemical energy storage. Energy Storage Mater 24:22–5110.1016/j.ensm.2019.08.004 ↗
40. Wei G, Zhou J, Xie M (2020) Fe3O4/graphene aerogel as high-performance flexible anode for sodium-ion battery. J Phys: Conf Ser 1637(1):01207910.1088/1742-6596/1637/1/012079 ↗
41. Khan BM, Oh WC, Nuengmatch P, Ullah K (2023) Role of graphene-based nanocomposites as anode material for Lithium-ion batteries. Mater Sci Eng, B 287:11614110.1016/j.mseb.2022.116141 ↗
42. Zhang Y, Liu W, Zhu Y, Zhang Y, Zhang R, Li K, Liu G (2021) Facile self-assembly solvothermal preparation of CuO/Cu2O/coal-based reduced graphene oxide nanosheet composites as an anode for high-performance lithium-ion batteries. Energy Fuels 35(10):8961–896910.1021/acs.energyfuels.1c00473 ↗
43. Rai AK, Anh LT, Gim J, Mathew V, Kang J, Paul BJ, Singh NK, Song J, Kim J (2013) Facile approach to synthesize CuO/reduced graphene oxide nanocomposite as anode materials for lithium-ion battery. J Power Sources 244:435–44110.1016/j.jpowsour.2012.11.112 ↗
44. Folorunso O, Sadiku R, Hamam Y, Ray SS (2022) An investigation of copper oxide-loaded reduced graphene oxide nanocomposite for energy storage applications. Appl Phys A 128(1):5410.1007/s00339-021-05205-1 ↗
45. Ranjbar-Azad M, Behpour M (2021) Facile in situ co-precipitation synthesis of CuO–NiO/rGO nanocomposite for lithium-ion battery anodes. J Mater Sci: Mater Electron 32(13):18043–18056
46. Xu Y-T, Guo Y, Song L-X, Zhang K, Yuen MM, Xu J-B, Fu X-Z, Sun R, Wong C-P (2015) Co-reduction self-assembly of reduced graphene oxide nanosheets coated Cu2O sub-microspheres core-shell composites as lithium ion battery anode materials. Electrochim Acta 176:434–44110.1016/j.electacta.2015.06.093 ↗
47. Zhang X, Hu Y, Zhu D, Xie A, Shen Y (2016) A novel porous CuO nanorod/rGO composite as a high stability anode material for lithium-ion batteries. Ceram Int 42(1):1833–183910.1016/j.ceramint.2015.09.147 ↗
48. Majumdar D, Baugh N, Bhattacharya SK (2017) Ultrasound assisted formation of reduced graphene oxide-copper (II) oxide nanocomposite for energy storage applications. Colloids Surf A 512:158–17010.1016/j.colsurfa.2016.10.010 ↗
49. Wu S, Fu G, Lv W, Wei J, Chen W, Yi H, Gu M, Bai X, Zhu L, Tan C (2018) A single-step hydrothermal route to 3D hierarchical Cu2O/CuO/rGO nanosheets as high-performance anode of lithium-ion batteries. Small 14(5):170266710.1002/smll.201702667 ↗
50. Muhammad N, Yasin G, Li A, Chen Y, Saleem HM, Liu R, Li D, Sun Y, Zheng S, Chen X (2020) Volumetric buffering of manganese dioxide nanotubes by employing ‘as is’ graphene oxide: an approach towards stable metal oxide anode material in lithium-ion batteries. J Alloy Compd 842:15580310.1016/j.jallcom.2020.155803 ↗
51. Lv K, Zhang Y, Zhang D, Ren W, Sun L (2017) Mn3O4 nanoparticles embedded in 3D reduced graphene oxide network as anode for high-performance lithium ion batteries. J Mater Sci: Mater Electron 28:14919–14927
52. Feng Y, Zhang Y, Song X, Wei Y, Battaglia VS (2017) Facile hydrothermal fabrication of ZnO–graphene hybrid anode materials with excellent lithium storage properties. Sustain Energy Fuels 1(4):767–77910.1039/C7SE00102A ↗
53. Varghese SP, Babu B, Prasannachandran R, Antony R, Shaijumon M (2019) Enhanced electrochemical properties of Mn3O4/graphene nanocomposite as efficient anode material for lithium ion batteries. J Alloy Compd 780:588–59610.1016/j.jallcom.2018.11.394 ↗
54. Lee S-W, Lee C-W, Yoon S-B, Kim M-S, Jeong JH, Nam K-W, Roh KC, Kim K-B (2016) Superior electrochemical properties of manganese dioxide/reduced graphene oxide nanocomposites as anode materials for high-performance lithium ion batteries. J Power Sources 312:207–21510.1016/j.jpowsour.2016.02.049 ↗
55. Chowdury MSK, Park YJ., Park SB, Park Y-I (2024) Two-dimensional nanostructured pristine graphene and heteroatom-doped graphene-based materials for energy conversion and storage devices. Sustain Mater Technol, p e0112410.1016/j.susmat.2024.e01124 ↗
56. Sui Z-Y, Wang C, Shu K, Yang Q-S, Ge Y, Wallace GG, Han B-H (2015) Manganese dioxide-anchored three-dimensional nitrogen-doped graphene hybrid aerogels as excellent anode materials for lithium ion batteries. J Mater Chem A 3(19):10403–1041210.1039/C5TA01508A ↗
57. Ma Z, Zhao T (2016) Reduced graphene oxide anchored with MnO2 nanorods as anode for high rate and long cycle Lithium ion batteries. Electrochim Acta 201:165–17110.1016/j.electacta.2016.03.200 ↗
58. Li S, Yu L-L, Shi Y-T, Fan J, Li R-B, Fan G-D, Xu W-L, Zhao J-T (2019) Greatly enhanced faradic capacities of 3D porous Mn3O4/G composites as lithium-ion anodes and supercapacitors by C–O–Mn bonding. ACS Appl Mater Interfaces 11(10):10178–1018810.1021/acsami.8b21063 ↗
59. Park JH, Choi WY, Lee S, Kim T-S, Lee JW (2020) Graphene intercalated free-standing carbon paper coated with MnO2 for anode materials of lithium ion batteries. Electrochim Acta 348:13631010.1016/j.electacta.2020.136310 ↗
60. Zhou Z, Chaoying D, Wenchao P, Yang L, Fengbao Z, Fan X (2021) One-step fabrication of two-dimensional hierarchical Mn2O3@ graphene composite as high-performance anode materials for lithium ion batteries. J Mater Sci Technol 80:13–1910.1016/j.jmst.2020.12.006 ↗
61. Wang G, Chen Y, Konstantinov K, Yao J, Ahn J-H, Liu H, Dou S (2002) Nanosize cobalt oxides as anode materials for lithium-ion batteries. J Alloy Compd 340(1–2):L5–L1010.1016/S0925-8388(02)00005-1 ↗
62. Mei J, Liao T, Ayoko GA, Bell J, Sun Z (2019) Cobalt oxide-based nanoarchitectures for electrochemical energy applications. Prog Mater Sci 103:596–67710.1016/j.pmatsci.2019.03.001 ↗
63. Kesavan T, Boopathi S, Kundu M, Maduraiveeran G, Sasidharan M (2018) Morphology-dependent electrochemical performance of spinel-cobalt oxide nanomaterials towards lithium-ion batteries. Electrochim Acta 283:1668–167810.1016/j.electacta.2018.07.084 ↗
64. Mussa Y, Ahmed F, Abuhimd H, Arsalan M, Alsharaeh E (2019) Enhanced Electrochemical performance at high temperature of Cobalt Oxide/Reduced Graphene Oxide Nanocomposites and its application in lithium-ion batteries. Sci Rep 9(1):4410.1038/s41598-018-37032-5 ↗
65. Avvaru VS, Fernandez IJ, Feng W, Hinder SJ, Rodríguez MC, Etacheri V (2021) Extremely pseudocapacitive interface engineered CoO@ 3D-NRGO hybrid anodes for high energy/power density and ultralong life lithium-ion batteries. Carbon 171:869–88110.1016/j.carbon.2020.09.058 ↗
66. Younes G, Sina A, Motahareh H, Sadrnezhaad SK, Abolghasem D (2025) Synthesis and characterization of nitrogen-doped graphene cryogel (NGC)/Co3O4 nanocomposites as high-capacity anode materials for Li-ion batteries. J Appl Electrochem, pp 1–1610.1007/s10800-025-02285-2 ↗
67. Sagar GL, Brijesh K, Mukesh P, Amudha A, Bhat KS, Nagaraja H (2024) Enhanced electrochemical performance of low-content graphene oxide in porous Co3O4 microsheets for dual applications of lithium-ion battery anode and lithium-ion capacitor. J Electron Mater 53(3):1517–152910.1007/s11664-023-10903-y ↗
68. Wang S-G, Xie Y, Hou Y-L, Zeng R, Qin T, Guan H-B, Zhao D-L (2022) Graphene aerogel encapsulated Co3O4 open-ended microcage anode with enhanced performance for lithium-ion batteries. Appl Surf Sci 605:15475910.1016/j.apsusc.2022.154759 ↗
69. Zhu J, Tu W, Pan H, Zhang H, Liu B, Cheng Y, Deng Z, Zhang H (2020) Self-templating synthesis of hollow Co3O4 nanoparticles embedded in N, S-dual-doped reduced graphene oxide for lithium ion batteries. ACS Nano 14(5):5780–578710.1021/acsnano.0c00712 ↗
70. Dou Y, Xu J, Ruan B, Liu Q, Pan Y, Sun Z, Dou SX (2016) Atomic layer-by-layer Co3O4/graphene composite for high performance lithium-ion batteries. Adv Energy Mater 6(8):150183510.1002/aenm.201501835 ↗
71. Zhu T, Wang Y, Li Y, Cai R, Zhang J, Yu C, Wu J, Cui J, Zhang Y, Ajayan PM (2020) CoO quantum dots anchored on reduced graphene oxide aerogels for lithium-ion storage. ACS Appl Nano Mater 3(10):10369–1037910.1021/acsanm.0c02290 ↗
72. Zhu G, Yang Q, Yang Z, Che R (2023) Graphene oxide-wrapped porous hollow Co3O4 microspheres with enhanced lithium storage performance. Langmuir 39(8):3094–310110.1021/acs.langmuir.2c03187 ↗
73. Tu C, Peng A, Zhang Z, Qi X, Zhang D, Wang M, Huang Y, Yang Z (2021) Surface-seeding secondary growth for CoO@ Co9S8 PN heterojunction hollow nanocube encapsulated into graphene as superior anode toward lithium ion storage. Chem Eng J 425:13064810.1016/j.cej.2021.130648 ↗
74. Lin J, Raji ARO, Nan K, Peng Z, Yan Z, Samuel EL, Natelson D, Tour JM (2014) Iron oxide nanoparticle and graphene nanoribbon composite as an anode material for high-performance li-ion batteries. Adv Funct Mater 24(14):2044–204810.1002/adfm.201303023 ↗
75. Li J, Yan L (2022) Synthesis of Fe2O3/rGO based composites as anode material for lithium ion batteries using sewage sludge as source of iron (III) oxide. Int J Electrochem Sci 17(11):22117310.20964/2022.11.81 ↗
76. Peng J, Hu N, Jin A, Li M, Xu ZJ, Yu L (2024) Synthesis of mesoporous layered iron oxide/rGO composites for stable sodium-and lithium-ion batteries. Next Materials 3:10015010.1016/j.nxmate.2024.100150 ↗
77. Petnikota S, Marka SK, Banerjee A, Reddy M, Srikanth V, Chowdari B (2015) Graphenothermal reduction synthesis of ‘exfoliated graphene oxide/iron (II) oxide’composite for anode application in lithium ion batteries. J Power Sources 293:253–26310.1016/j.jpowsour.2015.05.075 ↗
78. Kang Y, Yu X, Kota M, Park HS (2017) Carbon nanotubes branched on three-dimensional, nitrogen-incorporated reduced graphene oxide/iron oxide hybrid architectures for lithium ion battery anode. J Alloy Compd 726:88–9410.1016/j.jallcom.2017.07.264 ↗
79. Jia X, Ge Y, Shao L, Wang C, Wallace GG (2019) Tunable conducting polymers: toward sustainable and versatile batteries. ACS Sustain Chem Eng 7(17):14321–1434010.1021/acssuschemeng.9b02315 ↗
80. Tajik S, Beitollahi H, Nejad FG, Shoaie IS, Khalilzadeh MA, Asl MS, Van Le Q, Zhang K, Jang HW, Shokouhimehr M (2020) Recent developments in conducting polymers: applications for electrochemistry. RSC Adv 10(62):37834–3785610.1039/D0RA06160C ↗
81. Chen Y, Chen X, Zhang Y (2021) A comprehensive review on metal-oxide nanocomposites for high-performance lithium-ion battery anodes. Energy Fuels 35(8):6420–644210.1021/acs.energyfuels.1c00315 ↗
82. Kalladi AJ, Arun K, Ramesan M (2024) Eco-friendly synthesis, characterization, and properties of copper oxide nanoparticles in cashew gum/polypyrrole blend for energy storage applications. Int J Biol Macromol 277:13447310.1016/j.ijbiomac.2024.134473 ↗
83. Yin Z, Fan W, Ding Y, Li J, Guan L, Zheng Q (2015) Shell structure control of PPy-modified CuO composite nanoleaves for lithium batteries with improved cyclic performance. ACS Sustain Chem Eng 3(3):507–51710.1021/sc500755d ↗
84. Yin Z, Ding Y, Zheng Q, Guan L (2012) CuO/polypyrrole core–shell nanocomposites as anode materials for lithium-ion batteries. Electrochem Commun 20:40–4310.1016/j.elecom.2012.04.005 ↗
85. Wang Y, Cao L, Li J, Kou L, Huang J, Feng Y, Chen S (2020) Cu/Cu2O@ Ppy nanowires as a long-life and high-capacity anode for lithium ion battery. Chem Eng J 391:12359710.1016/j.cej.2019.123597 ↗
86. Parveen N, Ansari SA, Ansari MZ, Ansari MO (2022) Manganese oxide as an effective electrode material for energy storage: a review. Environ Chem Lett 20(1):283–30910.1007/s10311-021-01316-6 ↗
87. Soulamidis G, Kourmousi M, Mitsopoulou CA, Stouraiti C (2024) Electrochemical behavior of natural manganese oxides: transforming mining waste into energy storage materials. Minerals 14(5):45510.3390/min14050455 ↗
88. Dawadi S, Gupta A, Khatri M, Budhathoki B, Lamichhane G, Parajuli N (2020) Manganese dioxide nanoparticles: synthesis, application and challenges. Bull Mater Sci 43:1–1010.1007/s12034-020-02247-8 ↗
89. Zhao C, Yan J, Tian X, Xue X, Zhao Y (2023) Progress in thermal energy storage technologies for achieving carbon neutrality. Carbon Neutrality 2(1):1010.1007/s43979-023-00050-y ↗
90. Zhao Y, Zhu Y, Zhang X (2020) Challenges and perspectives for manganese-based oxides for advanced aqueous zinc-ion batteries. InfoMat 2(2):237–26010.1002/inf2.12042 ↗
91. Abdah MAAM, Mokhtar M, Khoon LT, Sopian K, Dzulkurnain NA, Ahmad A, Sulaiman Y, Bella F, Su’ait MS (2021) Synthesis and electrochemical characterizations of poly (3, 4-ethylenedioxythiophene/manganese oxide coated on porous carbon nanofibers as a potential anode for lithium-ion batteries. Energy Reports 7:8677–868710.1016/j.egyr.2021.10.110 ↗
92. Li Y, Ye D, Liu W, Shi B, Guo R, Pei H, Xie J (2017) A three-dimensional core-shell nanostructured composite of polypyrrole wrapped MnO2/reduced graphene oxide/carbon nanotube for high performance lithium ion batteries. J Colloid Interface Sci 493:241–24810.1016/j.jcis.2017.01.008 ↗
93. Wang C, Liu H, Jiang M, Wang Y, Liu R, Luo Z, Liu X, Xu W, Xiong C, Fang D (2017) Ammonium vanadate@ polypyrrole@ manganese dioxide nanowire arrays with enhanced reversible lithium storage. Appl Surf Sci 416:402–41010.1016/j.apsusc.2017.04.069 ↗
94. Zeng D, Zheng B, Peng S, Kang J, Tang Q, Wang W, Sun L, Liu L (2024) Construction of flexible multilayer PPy/MnO/C composites with ultrafast reaction kinetics for lithium-ion batteries. J Alloys Compd, p 17649110.1016/j.jallcom.2024.176491 ↗
95. Mu K, Tao Y, Peng Z, Hu G, Du K, Cao Y (2019) Surface architecture modification of high capacity Li1. 2Ni0. 2Mn0. 6O2 with synergistic conductive polymers LiPPA and PPy for lithium ion batteries. Appl Surf Sci 495:14350310.1016/j.apsusc.2019.07.245 ↗
96. Feng Y, Liu H, Lu Q, Liu Y, Li J, He X, Liu X, Mikhailova D (2022) Designing hierarchical MnO/polypyrrole heterostructures to couple polysulfides adsorption and electrocatalysis in lithium-sulfur batteries. J Power Sources 520:23088510.1016/j.jpowsour.2021.230885 ↗
97. Chavan UD, Prajith P, Kandasubramanian B (2022) Polypyrrole based cathode material for battery application. Chem Eng J Adv 12:10041610.1016/j.ceja.2022.100416 ↗
98. Yan M, Zhang Y, Li Y, Huo Y, Yu Y, Wang C, Jin J, Chen L, Hasan T, Wang B (2016) Manganese dioxide nanosheet functionalized sulfur@ PEDOT core–shell nanospheres for advanced lithium–sulfur batteries. J Mater Chem A 4(24):9403–941210.1039/C6TA03211G ↗
99. Krishnan SG, Arulraj A, Khalid M, Reddy M, Jose R (2021) Energy storage in metal cobaltite electrodes: opportunities & challenges in magnesium cobalt oxide. Renew Sustain Energy Rev 141:11079810.1016/j.rser.2021.110798 ↗
100. Izwan MI, Krishnan SG, Jose R (2020) Thin chemisorbed polyaniline film on cobalt oxide as an electrode for hybrid energy storage devices. ChemistrySelect 5(26):7973–798310.1002/slct.202001879 ↗