journal article·2023-06

Review on transition metals containing lithium borate glasses properties, applications and perspectives

Vimi Dua, S. K. Arya, K. Singh

Journal of Materials Science· Volume 58· Issue 21
Publisher page

Abstract

In this article, the transition metals effect on different properties of lithium borate glasses is reviewed. These glasses are useful for medical and energy storage, nonlinear optics and conversion devices. In the first part of this article, the basic properties of glasses are summarized, followed by variations in different lithium borate glass composition having various transition metal oxide and their effects on the characteristics of glass formed. In the last part, the conclusion and future perspectives are given and discussed the role of lithium oxide in glass compositions. The presence of higher valence levels of transition metals in glass decreases the overall conductivity of the glasses because of localized effects because of their higher charges and masses. On the other hand, mechanical properties are improved with transition metal oxides in the glass composition. Lower levels of lithium oxide in borate glass cause structural units to change from triangular to tetrahedral units without producing non-bridging oxygens in the glasses that enhance thermal and mechanical stability of the glasses. It could be related to the glass network connectivity and localized higher interaction among different charge carriers.
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Research context

OpenAlex topics: Glass properties and applications · Phase-change materials and chalcogenides · Luminescence Properties of Advanced Materials

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (100+)

Show source-provided references
1. Dong M, Zhou S, Xue X et al (2021) The potential use of boron containing resources for protection against nuclear radiation. Radiat Phys Chem 188:109601–109610. https://doi.org/10.1016/j.radphyschem.2021.10960110.1016/j.radphyschem.2021.109601 ↗
2. Punj S, Singh K (2019) Blue-green light emitting inherent luminescent glasses synthesized from agro-food wastes. J Mater Sci Mater Electron 30:3871–3881. https://doi.org/10.1007/s10854-019-00671-z10.1007/s10854-019-00671-z ↗
3. Calahoo C, Wondraczek L (2020) Ionic glasses: structure, properties and classification. J Non-Crystalline Solids X 8:100054. https://doi.org/10.1016/j.nocx.2020.10005410.1016/j.nocx.2020.100054 ↗
4. An Y, Han X, Liu Y et al (2022) Progress in solid polymer electrolytes for lithium-ion batteries and beyond. Small 18:2103617. https://doi.org/10.1002/SMLL.20210361710.1002/SMLL.202103617 ↗
5. Elias JA, Montes E, Torres-Castro A et al (2022) Mn, Cu and Cr nanoparticles in Li2B4O7 glass: radiation shielding and optical properties. Radiat Phys Chem 194:110037. https://doi.org/10.1016/j.radphyschem.202210.1016/j.radphyschem.2022 ↗
6. Al-Baradi AM, Alotaibi BM, Alharbi N et al (2022) Gamma radiation shielding and mechanical studies on highly dense lithium iron borosilicate glasses modified by zinc oxide. SILICON. 14:10391–10399. https://doi.org/10.1007/s12633-022-01801-910.1007/s12633-022-01801-9 ↗
7. Singh J (2003) Electronic processes in amorphous semiconductors. J Mater Sci Mater Electron 14:171–186. https://doi.org/10.1023/A:102231010897810.1023/A:1022310108978 ↗
8. Dyre JC, Schroøder TB (2000) Universality of ac conduction in disordered solids. Rev Mod Phys 72:873–892. https://doi.org/10.1103/RevModPhys.72.87310.1103/RevModPhys.72.873 ↗
9. Greaves GN, Sen S (2007) Inorganic glasses, glass-forming liquids and amorphizing solids. Adv Phys 56:1–16610.1080/00018730601147426 ↗
10. Kovalenko MV, Manna L, Cabot A et al (2015) Prospects of nanoscience with nanocrystals. ACS Nano 9:1012–1057. https://doi.org/10.1021/nn506223h10.1021/nn506223h ↗
11. Rüssel C (1999) Introduction to glass science and technology. Zeitschrift für Phys Chemie 208:292–293. https://doi.org/10.1524/zpch.1999.208.part_1_2.29210.1524/zpch.1999.208.part_1_2.292 ↗
12. Singh K, Walia T (2021) Review on silicate and borosilicate-based glass sealants and their interaction with components of solid oxide fuel cell. Int J Energy Res 45:20559–2058210.1002/er.7161 ↗
13. Shaaban KS, Al-Baradi AM, Ali AM (2022) Investigation of BaO reinforced TiO2-p2O5-li2O glasses for optical and neutron shielding applications. RSC Adv 12:3036–3043. https://doi.org/10.1039/d2ra00171c10.1039/d2ra00171c ↗
14. Azizan SA, Hashim S, Razak NA et al (2014) Physical and optical properties of Dy3+: Li2O-K2O-B2O3glasses. J Mol Struct 1076:20–25. https://doi.org/10.1016/J.MOLSTRUC.2014.07.03210.1016/J.MOLSTRUC.2014.07.032 ↗
15. Gaafar MS, El-Batal FH, El-Gazery M, Mansour SA (2009) Effect of doping by different transition metals on the acoustical properties of alkali borate glasses. Acta Phys Pol A 115:671–678. https://doi.org/10.12693/APhysPolA.115.67110.12693/APhysPolA.115.671 ↗
16. Bahadur D, Lahl N, Singh K et al (2004) Influence of nucleating agents on the chemical interaction of MgO-Al2O3-SiO2-B2O3 glass sealants with components of SOFCs. J Electrochem Soc 151:A58–A562. https://doi.org/10.1149/1.164757010.1149/1.1647570 ↗
17. Punj S, Singh J, Singh K (2021) Ceramic biomaterials: properties, state of the art and future prospectives. Ceram Int 47:28059–2807410.1016/j.ceramint.2021.06.238 ↗
18. Danewalia SS, Singh K, Arya SK (2021) Influence of vanadium oxide on non-isothermal crystallization kinetics of zinc lithium borate glasses. J Non Cryst Solids 553:120471. https://doi.org/10.1016/J.JNONCRYSOL.2020.12047110.1016/J.JNONCRYSOL.2020.120471 ↗
19. Abdel-Wahab FA, Fayad AM, Abdel-Baki M, AbdelMaksoud H (2018) Role of non-bridging oxygen defect in the ionic conductivity and associated oxygen trap centers in lead-borate oxide glass: effect of structural substitution of PbO for Ag2O and Li2O modifiers. J Non Cryst Solids 500:84–91. https://doi.org/10.1016/j.jnoncrysol.2018.06.03310.1016/j.jnoncrysol.2018.06.033 ↗
20. Mozzi RL, Warren BE (1970) The structure of vitreous boron oxide. J Appl Crystallogr 3:251–257. https://doi.org/10.1107/S002188987000614310.1107/S0021889870006143 ↗
21. Karogh JM (1962) The crystal structure of lithium diborate, Li2O. 2B2O3. Acta Cryst 15:190–19310.1107/S0365110X6200050X ↗
22. Shaaban KS, Al-Baradi AM, Ali AM (2022) Gamma-ray shielding and mechanical characteristics of iron-doped lead phosphosilicate glasses. SILICON 14:8971–8979. https://doi.org/10.1007/s12633-022-01702-x10.1007/s12633-022-01702-x ↗
23. Biswas D, Das AS, Mondal R et al (2020) Structural properties and electrical conductivity mechanisms of semiconducting quaternary nanocomposites: effect of two transition metal oxides. J Phys Chem Solids 144:109505. https://doi.org/10.1016/j.jpcs.2020.10950510.1016/j.jpcs.2020.109505 ↗
24. Arya SK, Chhina MK, Choudhary R et al (2022) Growth of different nanocrystalline phases in ZnO–Li2O–B2O3–TiO2–V2O5 glass and their effect on photoluminescence and photocatalytic activity. Ceram Int 48:20619–20626. https://doi.org/10.1016/j.ceramint.2022.04.03010.1016/j.ceramint.2022.04.030 ↗
25. Bajaj A, Khanna A, Chen B et al (2009) Structural investigation of bismuth borate glasses and crystalline phases. J Non Cryst Solids 355:45–53. https://doi.org/10.1016/J.JNONCRYSOL.2008.09.03310.1016/J.JNONCRYSOL.2008.09.033 ↗
26. Sørensen SS, Østergaard MB, Stepniewska M et al (2020) Metal-organic framework glasses possess higher thermal conductivity than their crystalline counterparts. ACS Appl Mater Interfaces 12:18893–18903. https://doi.org/10.1021/acsami.0c0231010.1021/acsami.0c02310 ↗
27. Onodera Y, Kohara S, Salmon PS et al (2020) Structure and properties of densified silica glass: characterizing the order within disorder. NPG Asia Mater 12:1–16. https://doi.org/10.1038/s41427-020-00262-z10.1038/s41427-020-00262-z ↗
28. Lass EA, Zhu A, Shiflet GJ, Joseph Poon S (2010) A short-range ordering description of amorphous metal alloys using the central atoms model. Acta Mater 58:5460–5470. https://doi.org/10.1016/j.actamat.2010.06.02210.1016/j.actamat.2010.06.022 ↗
29. Karki A, Feller S, Lim HP et al (1987) The density of sodium-borate glasses related to atomic arrangements. J Non Cryst Solids 92:11–19. https://doi.org/10.1016/S0022-3093(87)80355-110.1016/S0022-3093(87)80355-1 ↗
30. Feller SA, Dell WJ, Bray PJ (1982) 10B NMR studies of lithium borate glasses. J Non Cryst Solids 51:21–30. https://doi.org/10.1016/0022-3093(82)90186-710.1016/0022-3093(82)90186-7 ↗
31. Shaaban KS, Al-Baradi AM, Wahab EAA (2022) The impact of Y2O3 on physical and optical characteristics, polarizability, optical basicity, and dispersion parameters of B2O3–SiO2–Bi2O3–TiO2 glasses. SILICON 14:5057–5065. https://doi.org/10.1007/s12633-021-01309-810.1007/s12633-021-01309-8 ↗
32. Abdel Wahab EA, Shaaban KS (2021) Structural and optical features of aluminum lead borate glass doped with Fe2O3. Appl Phys A Mater Sci Process 127:1–12. https://doi.org/10.1007/s00339-021-05062-y10.1007/s00339-021-05062-y ↗
33. El-Maaref AA, Alotaibi BM, Alharbi N et al (2022) Effect of Fe2O3 as an aggregate replacement on mechanical, and gamma/ neutron radiation shielding properties of phosphoaluminate glasses. J Inorg Organomet Polym Mater 32:3117–3127. https://doi.org/10.1007/s10904-022-02345-610.1007/s10904-022-02345-6 ↗
34. Weirauch DAJ (2005) The surface tension of glass-forming melts. Prop Glas Melts. https://doi.org/10.1201/9781420027310.ch610.1201/9781420027310.ch6 ↗
35. Kodama M, Matsushita T, Kojima S (1995) Velocity of sound and elastic properties of Li2O-B2O3 glasses. Jpn J Appl Phys 34:2570–2576. https://doi.org/10.1143/JJAP.34.257010.1143/JJAP.34.2570 ↗
36. Reddy CN, Chakradhar RPS (2007) Elastic properties and spectroscopic studies of fast ion conducting Li2O-ZnO-B2O3 glass system. Mater Res Bull 42:1337–1347. https://doi.org/10.1016/j.materresbull.2006.10.00110.1016/j.materresbull.2006.10.001 ↗
37. Raghvan V (2008) Mater. Sci. Eng. 5th ed
38. Sigaev VN, Golubev NV, Stefanovich SY et al (2008) Second-order optical non-linearity initiated in Li2O-Nb2O5-SiO2 and Li2O-ZnO-Nb2O5-SiO2 glasses by formation of polar and centrosymmetric nanostructures. J Non Cryst Solids 354:873–881. https://doi.org/10.1016/j.jnoncrysol.2007.08.03310.1016/j.jnoncrysol.2007.08.033 ↗
39. Shaaban SKH, Arowaili ZA et al (2022) Mechanical and thermodynamic characteristics of 22SiO2-22SiO2-23Bi2O3-37B2O3-13TiO2 -(5–x)LiF-xBaO glasses. SILICON 14:6457–646510.1007/s12633-021-01441-5 ↗
40. Liang X, Li S, Yang G et al (2022) High lithium-ion conductivity in all-solid-state lithium batteries by Sb doping LLZO. Appl Phys A Mater Sci Process 128:1–12. https://doi.org/10.1007/s00339-021-05128-x10.1007/s00339-021-05128-x ↗
41. Alrowaili ZA, Ali AM, Al-Baradi AM et al (2022) A significant role of MoO3 on the optical, thermal, and radiation shielding characteristics of B2O3–P2O5–Li2O glasses. Opt Quantum Electron 54:1–19. https://doi.org/10.1007/s11082-021-03447-010.1007/s11082-021-03447-0 ↗
42. Ali AM, Alrowaili ZA, Al-Baradi AM et al (2022) A study of thermal, and optical properties of 22SiO2-23Bi2O3-37B2O3-13TiO2-(5–x) LiF-xBaO glasses. SILICON 14:6447–6455. https://doi.org/10.1007/s12633-021-01440-610.1007/s12633-021-01440-6 ↗
43. Šesták J (1985) Some thermodynamic aspects of the glassy state. Thermochim Acta 95:459–471. https://doi.org/10.1016/0040-6031(85)85312-010.1016/0040-6031(85)85312-0 ↗
44. Sakka S, Mackenzie JD (1971) Relation between apparent glass transition temperature and liquids temperature for inorganic glasses. J Non Cryst Solids 6:145–162. https://doi.org/10.1016/0022-3093(71)90053-610.1016/0022-3093(71)90053-6 ↗
45. Dua V, Singh K (2022) Crystallization kinetics study of magnesium vanadate glasses using non-isothermal method. J Non Cryst Solids 595:121820. https://doi.org/10.1016/J.JNONCRYSOL.2022.12182010.1016/J.JNONCRYSOL.2022.121820 ↗
46. Hrubý A (1973) Glass-forming tendency in the GeSx system. Czechoslov J Phys 23:1263–1272. https://doi.org/10.1007/BF0159120910.1007/BF01591209 ↗
47. Kissinger HE (1957) Reaction kinetics in differential thermal analysis. Anal Chem 29:1702–1706. https://doi.org/10.1021/ac60131a04510.1021/ac60131a045 ↗
48. Lösche A, Mott NF, Davis EA (1972) Electron Process Non Cryst Mater 7:K55–K56. https://doi.org/10.1002/crat.1972007042010.1002/crat.19720070420 ↗
49. Chomka W, Samatowicz D, Gzowski O, Murawski L (1981) Internal friction and electrical conductivity of phosphate glass with two TM oxides. J Non Cryst Solids 45:145–14810.1016/0022-3093(81)90100-9 ↗
50. Sayer M, Lynch GF (1973) Impurity effects in tungsten phosphate glasses. II. Electrical and optical properties. J Phys CSolid State Phys Iopsci Iop Org 6:3674–369010.1088/0022-3719/6/24/026 ↗
51. Singh K, Rokade S (1984) Electrical conductivity of a new solid electrolyte glass material Li2OLiNbO3B2O3. J Power Sour 13:151–158. https://doi.org/10.1016/0378-7753(84)87085-810.1016/0378-7753(84)87085-8 ↗
52. Harani R, Hogarth CA (1986) Electrical conduction in copper phosphate glasses containing nickel or cobalt. J Mater Sci 21:3509–3512. https://doi.org/10.1007/BF0055379310.1007/BF00553793 ↗
53. Physics RS-J of PDA (1984) undefined (1984) Effect of Fe ions on electrical conductivity and ESR in tellurium-vanadate glasses. Iopsci Iop Org 17:57–60
54. Bhogi A, Srinivas B, Papolu P et al (2022) Effect of Mn2+ ions on spectroscopic and electrical properties of lithium strontium borate glasses. Mater Chem Phys 291:126698. https://doi.org/10.1016/j.matchemphys.2022.12669810.1016/j.matchemphys.2022.126698 ↗
55. Seth VP, Yadav A, Gupta SK (1988) Electrical conductivity and ESR of lithium borate glasses containing mixed transition metal oxides. J Mater Sci 23:3495–3500. https://doi.org/10.1007/BF0054048510.1007/BF00540485 ↗
56. Jozwiak P, Garbarczyk JE (2005) Mixed electronic-ionic conductivity in the glasses of the Li2O-V2O5-P2O5 system. Solid State Ionics. 2163–216610.1016/j.ssi.2004.06.028 ↗
57. Bässler H (1993) Charge transport in disordered organic photoconductors a monte carlo simulation study. Phys status solidi 175:15–5610.1002/pssb.2221750102 ↗
58. Jha PK, Pandey OP, Singh K (2015) Crystallization and glass transition kinetics of Na2s-P2s5-based super-ionic glasses. Part Sci Technol 33:166–171. https://doi.org/10.1080/02726351.2014.94766110.1080/02726351.2014.947661 ↗
59. Vinatier P, Ménétrier M, Levasseur A (1999) Aggregation of the doping salt in B2S3-Li2S-LiI glasses, effect on the dynamical properties. Solid State Ionics 116:35–45. https://doi.org/10.1016/s0167-2738(98)00215-x10.1016/s0167-2738(98)00215-x ↗
60. Namikawa H (1975) Characterization of the diffusion process in oxide glasses based on the correlation between electric conduction and dielectric relaxation. J Non Cryst Solids 18:173–195. https://doi.org/10.1016/0022-3093(75)90019-810.1016/0022-3093(75)90019-8 ↗
61. Strom U, Hendrickson JR, Wagner RJ, Taylor PC (1974) Disorder-induced far infrared absorption in amorphous materials. Solid State Commun 15:1871–1875. https://doi.org/10.1016/0038-1098(74)90106-910.1016/0038-1098(74)90106-9 ↗
62. Arya SK, Danewalia SS, Singh K (2016) Frequency independent low-: K lithium borate nanocrystalline glass ceramic and glasses for microelectronic applications. J Mater Chem C 4:3328–3336. https://doi.org/10.1039/c5tc03364k10.1039/c5tc03364k ↗
63. Yamane M, Asahara Y (2000) Glasses for photonics10.1017/CBO9780511541308 ↗
64. Urbach F (1953) The long-wavelength edge of photographic sensitivity and of the electronic absorption of solids [8]. Phys Rev 92:132410.1103/PhysRev.92.1324 ↗
65. Algarni SA, El-Maaref AA, Alotaibi BM et al (2022) Physical, optical, and radiation shielding features of yttrium lithium borate glasses. J Inorg Organomet Polym Mater 32:2873–2881. https://doi.org/10.1007/s10904-022-02321-010.1007/s10904-022-02321-0 ↗
66. Bhogi A, Srinivas B, Padmavathi P et al (2022) Absorption spectrum fitting method (ASF), DASF method and structural studies of Li2O–SrO–B2O3–MnO quaternary glass system. Opt Mater (Amst) 133:112911. https://doi.org/10.1016/j.optmat.2022.11291110.1016/j.optmat.2022.112911 ↗
67. Gedam RS, Ramteke DD (2012) Electrical and optical properties of lithium borate glasses doped with Nd2O3. J Rare Earths 30:785–789. https://doi.org/10.1016/S1002-0721(12)60130-610.1016/S1002-0721(12)60130-6 ↗
68. Gedam RS, Deshpande VK (2006) An anomalous enhancement in the electrical conductivity of Li2O: B2O3: Al2O3 glasses. Solid State Ionics 177:2589–2592. https://doi.org/10.1016/j.ssi.2006.03.05610.1016/j.ssi.2006.03.056 ↗
69. Venkat Reddy P, Laxmi Kanth C, Prashanth Kumar V et al (2005) Optical and thermoluminescence properties of R2O-RF-B2O3 glass systems doped with MnO. J Non Cryst Solids 351:3752–3759. https://doi.org/10.1016/j.jnoncrysol.2005.08.03910.1016/j.jnoncrysol.2005.08.039 ↗
70. Lahl N, Singh K, Singheiser L et al (2000) Crystallisation kinetics in AO-Al2O3-SiO2-B2O3 glasses (A = Ba, Ca, Mg). J Mater Sci 35:3089–3096. https://doi.org/10.1023/A:100485141827410.1023/A:1004851418274 ↗
71. Singh S, Singh K (2014) Effect of in-situ reduction of Fe3+ on physical, structural and optical properties of calcium sodium silicate glasses and glass ceramics. J Non Cryst Solids 386:100–104. https://doi.org/10.1016/j.jnoncrysol.2013.11.04310.1016/j.jnoncrysol.2013.11.043 ↗
72. Arya SK, Danewalia SS, Arora M, Singh K (2016) Effect of variable oxidation states of vanadium on the structural, optical, and dielectric properties of B2O3-Li2O-ZnO-V2O5 glasses. J Phys Chem B 120:12168–12176. https://doi.org/10.1021/acs.jpcb.6b0828510.1021/acs.jpcb.6b08285 ↗
73. Umar SA, Halimah MK, Ibrahim GG et al (2021) Oxide ion/electronic polarizability, optical basicity and linear dielectric susceptibility of TeO2–B2O3–SiO2 glasses. Ceram Int 47:21668–21678. https://doi.org/10.1016/j.ceramint.2021.04.18010.1016/j.ceramint.2021.04.180 ↗
74. Kurkjian C, CR K, GE P (1974) An EPR study of Ti3+-Ti4+ in TiO2-SiO2 glasses15:12–17
75. Chakradhar RPS, Yasoda B, Rao JL, Gopal NO (2006) Mixed alkali effect in Li2O-Na2O-B2O3 glasses containing CuO-an EPR and optical study. J Non Cryst Solids 352:3864–3871. https://doi.org/10.1016/J.JNONCRYSOL.2006.06.03310.1016/J.JNONCRYSOL.2006.06.033 ↗
76. Labanowska M (2001) EPR monitoring of redox processes in transition metal oxide catalysts. ChemPhysChem 2:712–73110.1002/1439-7641(20011217)2:12<712::AID-CPHC712>3.0.CO;2-H ↗
77. Dalal S, Khasa S, Dahiya MS et al (2015) Optical and thermal investigations on vanadyl doped zinc lithium borate glasses. J Asian Ceram Soc 3:234–239. https://doi.org/10.1016/j.jascer.2015.03.00410.1016/j.jascer.2015.03.004 ↗
78. Piguet JL, Shelby JE (1985) Preparation and properties of silver borate glasses. J Am Ceram Soc 68:450–455. https://doi.org/10.1111/J.1151-2916.1985.TB10173.X10.1111/J.1151-2916.1985.TB10173.X ↗
79. Pal I, Agarwal A, Sanghi S, Aggarwal MP (2012) Structure and optical absorption of Sm3+ and Nd3+ ions in cadmium bismuth borate glasses with large radiative transition probabilities. Opt Mater (Amst) 34:1171–1180. https://doi.org/10.1016/j.optmat.2012.01.02310.1016/j.optmat.2012.01.023 ↗
80. Gedam RS, Ramteke DD (2013) Influence of CeO2 addition on the electrical and optical properties of lithium borate glasses. J Phys Chem Solids 74:1399–1402. https://doi.org/10.1016/j.jpcs.2013.04.02210.1016/j.jpcs.2013.04.022 ↗
81. Babu P, Jayasankar CK (2001) Spectroscopy of Pr3+ ions in lithium borate and lithium fluoroborate glasses. Phys B Condens Matter 301:326–340. https://doi.org/10.1016/S0921-4526(01)00239-310.1016/S0921-4526(01)00239-3 ↗
82. Bates T, Mackenzie DJ (1962) Ligand field theory and absorption spectra of transition metal ion in glasses. Modern Asp Vitreous State B 2:19
83. Werner AJ (1978) Colour generation and control in glass, by C R Bamford. Elsevier Color Res Appl 3:156–156. https://doi.org/10.1002/col.508003031710.1002/col.5080030317 ↗
84. Saddeek YB, Shaaban ER, Moustafa ES, Moustafa HM (2008) Spectroscopic properties, electronic polarizability, and optical basicity of Bi2O3–Li2O–B2O3 glasses. Phys B Condens Matter 403:2399–2407. https://doi.org/10.1016/J.PHYSB.2007.12.02710.1016/J.PHYSB.2007.12.027 ↗
85. Saddeek YB, Aly KA, Bashier SA (2010) Optical study of lead borosilicate glasses. Phys B Condens Matter 405:2407–2412. https://doi.org/10.1016/j.physb.2010.02.05510.1016/j.physb.2010.02.055 ↗
86. Reddy CN, Anavekar RV (2008) Elastic properties and spectroscopic studies of Li2O-B2O3-V2O5 glasses. Mater Chem Phys 112:359–365. https://doi.org/10.1016/j.matchemphys.2008.05.06210.1016/j.matchemphys.2008.05.062 ↗
87. Vijayalakshmi M, Vasantharani P (2010) Characterisation of 50V2O5. (50-x)PbO. xTiO2 Glass system by spectroscopic and thermal analysis.
88. Tauc J, Grigorovici R, Vancu A (1966) Optical properties and electronic structure of amorphous germanium. Phys status solidi 15:627–637. https://doi.org/10.1002/PSSB.1966015022410.1002/PSSB.19660150224 ↗
89. Zachariasen WH (1932) The atomic arrangement in glass. J Am Chem Soc 54:3841–3851. https://doi.org/10.1021/ja01349a00610.1021/ja01349a006 ↗
90. Elliott SR (1985) Physics of amorphous materials
91. Meera BN, Ramakrishna J (1993) Raman spectral studies of borate glasses. J Non Cryst Solids 159:1–21. https://doi.org/10.1016/0022-3093(93)91277-A10.1016/0022-3093(93)91277-A ↗
92. Parsons JL (1960) Vibrational spectra of orthorhombic metaboric acid. J Chem Phys 33:1860–1866. https://doi.org/10.1063/1.173151910.1063/1.1731519 ↗
93. Galeener FL, Lucovsky G, Mikkelsen JC (1980) Vibrational spectra and the structure of pure vitreous B2O3. Phys Rev B 22:3983–3990. https://doi.org/10.1103/PhysRevB.22.398310.1103/PhysRevB.22.3983 ↗
94. Walrafen GE, Samanta SR, Krishnan PN (1980) Raman investigation of vitreous and molten boric oxide. J Chem Phys 72:113–120. https://doi.org/10.1063/1.43889410.1063/1.438894 ↗
95. Windisch CF Jr, Risen WM (1982) Vibrational spectra of oxygen- and boron-isotopically substituted B2O3 glasses. J Non-Cryst Solids 48:307–323. https://doi.org/10.1016/0022-3093(82)90168-510.1016/0022-3093(82)90168-5 ↗
96. Karoge MJ (1969) The structure of vitreous and liquid boron oxide. J Non Cryst Solids 1:269–28410.1016/0022-3093(69)90025-8 ↗
97. Bril TW (1976) Raman spectroscopy of crystalline and vitreous borates. Philips Res Rep Suppl
98. Irion MM, Couzi A, Levasseur Reau MJ et al (1980) J Solid State Chem 31:285–29410.1016/0022-4596(80)90090-0 ↗
99. Kamitsos E, Karakassides MA, Chryssikos GD (1987) A vibrational study of lithium borate glasses with high Li2O content. Phys Chem Pascal Francis Inist Fr 28:203–209
100. Kamitsos EI, Karakassides MA, Chryssikos GD (1987) Vibrational spectra of magnesium-sodium-borate glasses. 2. Raman and mid-infrared investigation of the network structure. J Phys Chem 91:1073–1079. https://doi.org/10.1021/j100289a01410.1021/j100289a014 ↗