journal article·2020-11

High current density electrodeposition of NiFe/Nickel Foam as a bifunctional electrocatalyst for overall water splitting in alkaline electrolyte

Jiqiong Lian, Yihui Wu, Jingjing Sun

Journal of Materials Science· Volume 55· Issue 31
Publisher page

Abstract

Developing highly efficient and inexpensive bifunctional electrocatalysts is a grand challenge in water splitting process. In this article, NiFe electrocatalysts on nickel foam are prepared by electrodeposition method using high current density. The optimized NiFe electrocatalyst presented excellent electrocatalytic activities in 1.0 M KOH medium with low overpotentials of 100 mV for hydrogen evolution reaction and 230 mV for oxygen evolution reaction to achieve 10 mA·cm−2, respectively. Moreover, the optimized NiFe electrocatalyst as bifunctional electrocatalyst toward overall water splitting only needs a small cell voltage of 1.57 V to obtain 10 mA·cm−2. The extremely electrocatalytic performance of NiFe electrocatalyst is attributed to the fast charge transfer kinetics, large electrochemical surface area, and the conductive nickel foam.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Electrocatalysts for Energy Conversion · Advanced battery technologies research · Advanced Photocatalysis Techniques

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (39)

Show source-provided references
1. Yongwen T, Min L, Pan L et al (2019) Three-dimensional nanoporous Co9S4P4 pentlandite as a bifunctional electrocatalyst for overall neutral water splitting. ACS Appl Mater Interfaces 11:3880–388810.1021/acsami.8b17961 ↗
2. Chao H, Biao Z, Yang L et al (2020) A hybrid Co NPs@CNT nanocomposite as highly efficient electrocatalyst for oxygen evolution reaction. Appl Surf Sci 507:14515510.1016/j.apsusc.2019.145155 ↗
3. Aiping W, Ying X, Hui M et al (2018) Integrating the active OER and HER components as the heterostructures for the efficient overall water splitting. Nano Energy 44:353–36310.1016/j.nanoen.2017.11.045 ↗
4. Xiaoping G, Yanan Z, Yujia T et al (2019) Graphyne doped with transition-metal single atoms as effective bifunctional electrocatalysts for water splitting. Appl Surf Sci 492:8–1510.1016/j.apsusc.2019.06.050 ↗
5. Rong S, Jiaxin W, Zhi W et al (2019) Unique NiFe-NiCoO2 Hollow polyhedron as bifunctional electrocatalysts for water splitting. J Energy Chem 33:74–8010.1016/j.jechem.2018.08.016 ↗
6. Lu X, Futao Z, Jiahui C et al (2018) Amorphous NiFe nanotube arrays bifunctional electrocatalysts for efficient electrochemical overall water splitting. ACS Appl Energy Mater 1:1210–121710.1021/acsaem.7b00313 ↗
7. Shaofang F, Junhua S, Chengzhou Z et al (2018) Ultrafine and highly disordered Ni2Fe1 nanofoams enabled highly efficient oxygen evolution reaction in alkaline electrolyte. Nano Energy 44:319–32610.1016/j.nanoen.2017.12.010 ↗
8. Qingyun L, Hao W, Xina W et al (2017) Bifunctional Ni1−xFex layered double hydroxides/Ni foam electrodes for high-efficient overall water splitting: A study on compositional tuning and valence state evolution. Int J Hydrogen Energy 42:5560–556810.1016/j.ijhydene.2016.06.056 ↗
9. Guanqun H, Xiao S, Shanshan L et al (2017) Electrodeposited MoSx films assisted by liquid crystal template with ultrahigh electrocatalytic activity for hydrogen evolution reaction. Int J Hydrogen Energy 42:5132–513810.1016/j.ijhydene.2017.01.009 ↗
10. Majid A, Bryan HRS, Wanfeng Y et al (2018) Dynamic hydrogen bubble templated NiCu phosphide electrodes for pH-insensitive hydrogen evolution reactions. ACS sustainable Chem Eng 6:2866–287110.1021/acssuschemeng.7b02492 ↗
11. Qu NS, Zhu D, Chan KC et al (2003) Pulse electrodeposition of nanocrystalline nickel using ultra narrow pulse width and high peak current density. Surf Coat Tech 168:123–12810.1016/S0257-8972(03)00014-8 ↗
12. Changwei S, Wei Y, Junming G et al (2012) Modulated morphology of Fe foils electrodeposited at a high current density by adding cations. Vacuum 86:2095–210110.1016/j.vacuum.2012.05.032 ↗
13. Bo Y, Fei Q, Xinqiang W et al (2017) Nanocrystalline Co0.85Se as a highly efficient non-noble-metal electrocatalyst for hydrogen evolution reaction. Electrochim Acta 247:468–47410.1016/j.electacta.2017.07.007 ↗
14. Leifan Z, Lijun L, Guimei H et al (2020) Hydrogen evolution over N-doped CoS2 nanosheets enhanced by superaerophobicity and electronic modulation. Appl Surf Sci 504:14449010.1016/j.apsusc.2019.144490 ↗
15. Xiaoli X, Yuyao J, Maowen X et al (2018) MnO2-CoP3 nanowires array: An efficient electrocatalyst for alkaline oxygen evolution reaction with enhanced activity. Electrochem Commun 86:161–16510.1016/j.elecom.2017.12.008 ↗
16. Toghraei A, Shahrabi T, Gh BD et al (2020) Electrodeposition of self-supported Ni–Mo–P film on Ni foam as an affordable and high-performance electrocatalyst toward hydrogen evolution reaction. Electrochim Acta 335:13564310.1016/j.electacta.2020.135643 ↗
17. Kai W, Jiangshui L, Xuan Z et al (2020) In-situ formation of Ni (oxy)hydroxide on Ni foam as an efficient electrocatalyst for oxygen evolution reaction. Int J Hydrogen Energy 45:8490–849610.1016/j.ijhydene.2020.01.043 ↗
18. Muhammad AZGS, Sambath B, Abdul J et al (2019) NiCoFe oxide amorphous nanoheterostructres for oxygen evolution reaction. Int J Hydrogen Energy 44:22991–2300110.1016/j.ijhydene.2019.07.018 ↗
19. Yihui W, Ying G, Hanwei H et al (2019) Electrodeposition of self-supported Ni–Fe–Sn film on Ni foam: an efficient electrocatalyst for oxygen evolution reaction. Electrochim Acta 301:39–4610.1016/j.electacta.2019.01.151 ↗
20. Xianyan H, Xiaoyan Z, Xiaofang Z et al (2018) Simple solvothermal synthesis of uniform Pt66Ni34 nanoflowers as advanced electrocatalyst to significantly boost the catalytic activity and durability of hydrogen evolution reaction. Electrochim Acta 271:397–40510.1016/j.electacta.2018.03.169 ↗
21. Wenjiao D, Yuqian S, Meng L et al (2019) Noble-metal-free electrocatalyst based on a mixed CoNi metal-organic framework for oxygen evolution reaction. J Alloys Compd 792:69–7610.1016/j.jallcom.2019.03.399 ↗
22. Xiaodong Y, Lihong T, Kexue L et al (2016) FeNi3/NiFeOx nanohybrids as highly efficient bifunctional electrocatalysts for overall water splitting. Adv Mater Interfaces 3:160036810.1002/admi.201600368 ↗
23. Wushuai D, Li L, Yimeng L et al (2020) A novel Ni–S–Mn electrode with hierarchical morphology fabricated by gradient electrodeposition for hydrogen evolution reaction. Appl Surf Sci 514:14594410.1016/j.apsusc.2020.145944 ↗
24. Min Z, Yongde Y, Qing Y et al (2019) In situ growth of Ni0.85Se on graphene as a robust electrocatalyst for hydrogen evolution reaction. Int J Hydrogen Energy 45:10486–10493
25. Hongjiao H, Junnan S, Deshuang Y et al (2020) Few-layer FePS3 decorated with thin MoS2 nanosheets for efficient hydrogen evolution reaction in alkaline and acidic media. Appl Surf Sci 525:14662310.1016/j.apsusc.2020.146623 ↗
26. Junfeng Q, Min Y, Sa H et al (2020) Copper and cobalt co-doped Ni3S2 grown on nickel foam for highly efficient oxygen evolution reaction. Appl Surf Sci 502:14417210.1016/j.apsusc.2019.144172 ↗
27. Yu J, Xuehui G, Changqing T et al (2019) Co2Ni alloy/N-doped CNTs composite as efficient hydrogen evolution reaction catalyst in alkaline medium. J Alloys Compd 791:779–78510.1016/j.jallcom.2019.03.392 ↗
28. Zexing W, Min S, Zijin Z et al (2019) Porous two-dimensional layerd molybdenum compounds coupled with N-doped carbon based electrocatalysts for hydrogen evolution reaction. Appl Surf Sci 465:724–72910.1016/j.apsusc.2018.09.194 ↗
29. Zhengcui W, Zexian Z, Jiansong H et al (2018) Fe-doped NiO mesoporous nanosheets array for highly efficient overall water splitting. J Catal 358:243–25210.1016/j.jcat.2017.12.020 ↗
30. Jie X, Jing L, Jiawei S et al (2018) In situ engineering of double-phase interface in Mo/Mo2C heteronanosheets for boosted hydrogen evolution reaction. ACS Energy Lett 3:341–34810.1021/acsenergylett.7b01180 ↗
31. Caiyun H, Xianggui K, Meihong J et al (2018) Metal Ni-decorated Fe3O4 nanoparticles: A new and efficient electrocatalyst for oxygen evolution reaction. Mater Lett 222:138–14110.1016/j.matlet.2018.03.142 ↗
32. Luo G, Xin YEC, Yonghua D et al (2018) Enhanced catalysis of the electrochemical oxygen evolution reaction by iron(III) ions adsorbed on amorphous cobalt oxide. ACS Catal 8:807–81410.1021/acscatal.7b03509 ↗
33. Jiqiong L, Yihui W, Houan Z et al (2018) One-step synthesis of amorphous Ni–Fe–P alloy as bifunctional electrocatalyst for overall water splitting in alkaline medium. Int J Hydrogen Energy 43:12929–1293810.1016/j.ijhydene.2018.05.107 ↗
34. Gao MY, Zeng JR, Zhang QB et al (2018) Scalable one-step electrochemical deposition of nanoporous amorphous S-doped NiFe2O4/Ni3Fe composite films as highly efficient electrocatalysts for oxygen evolution with ultrahigh stability. J Mater Chem A 6:1551–156010.1039/C7TA08474A ↗
35. Jiahao Y, Gongzhen C, Wei L (2017) Ternary nickel-iron sulfide microflowers as a robust electrocatalyst for bifunctional water splitting. J Mater Chem A 5:15838–1584410.1039/C7TA04438K ↗
36. Yunmei D, Huiqi Q, Yanru L et al (2019) Bimetallic CoFeP hollow microspheres as highly efficient bifunctional electrocatalysts for overall water splitting in alkaline media. Appl Surf Sci 465:816–82310.1016/j.apsusc.2018.09.231 ↗
37. Huafeng F, Jun H, Guangliang C et al (2019) Hollow Ni-V-Mo chalcogenide nanopetals as bifunctional electrocatalyst for overall water splitting. ACS Sustain Chem Eng 7:1622–163210.1021/acssuschemeng.8b05378 ↗
38. Meijing S, Yu H, Mengmeng Z et al (2018) Controllable synthesis of Co2P nanorods as high-efficiency bifunctional electrocatalyst for overall water splitting. J Power Sources 402:345–35210.1016/j.jpowsour.2018.09.042 ↗
39. Song W, Jiabo H, Guodong L et al (2017) Nano-netlike carbon fibers decorated with highly dispersed CoSe2 nanoparticles as efficient hydrogen evolution electrocatalysts. J Alloys Compd 702:611–66110.1016/j.jallcom.2017.01.290 ↗