journal article·2021-02

Hydrogen production from ammonia borane hydrolysis catalyzed by non-noble metal-based materials: a review

Chenyang Wang, Jianling Zhao, Xihua Du, Shuo Sun, Xiaofei Yu, Xinghua Zhang, Zunming Lu, Lanlan Li, Xiaojing Yang

Journal of Materials Science· Volume 56· Issue 4
Publisher page

Abstract

As a promising chemical hydrogen storage material, ammonia borane (AB, NH3BH3) has been receiving significant attention for its hydrogen release property. Researches on the development of effective catalysts for AB hydrolysis under mild conditions have been of potential application interest. In the last few years, some non-noble metal-based materials have been developed for dehydrogenation of AB via hydrolysis, due to their low cost, high activity, and high durability. Therefore, the summary and analysis of the rapidly developing non-noble metal catalyst systems without noble metals can better grasp the current development status to guide subsequent design and research. In this review, the latest advances in non-noble metal-based catalysts are summarized, which can be divided into the following categories: pure metal-based materials, metal-based compounds (borides, phosphides, and oxides), and metal/metal compound heterogeneous structures. Investigations into the composition, structure, and activity enhancement of the catalyst are further highlighted. Besides, hydrolysis mechanisms, catalyst persistence, and AB regeneration are also discussed.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Hydrogen Storage and Materials · Ammonia Synthesis and Nitrogen Reduction · MXene and MAX Phase Materials

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (100+)

Show source-provided references
1. Manoharan Y, Hosseini SE, Butler B, Alzhahrani H, Senior BTF, Ashuri T, Krohn J (2019) Hydrogen fuel cell vehicles; current status and future prospect. Appl Sci 9(11):229610.3390/app9112296 ↗
2. Midilli A, Ay M, Dincer I, Rosen MA (2005) On hydrogen and hydrogen energy strategies. Renew Sustain Energy Rev 9(3):255–27110.1016/j.rser.2004.05.003 ↗
3. Geng S, Yang W, Yu YS (2019) Building MoS2/S-doped g-C3N4 layered heterojunction electrocatalysts for efficient hydrogen evolution reaction. J Catal 375:441–44710.1016/j.jcat.2019.06.026 ↗
4. Hosseini SE, Wahid MA (2016) Hydrogen production from renewable and sustainable energy resources: Promising green energy carrier for clean development. Renew Sustain Energy Rev 57:850–86610.1016/j.rser.2015.12.112 ↗
5. Møller KT, Jensen TR, Akiba E, Li HW (2017) Hydrogen-A sustainable energy carrier. Prog Nat Sci Mater Int 27(1):34–4010.1016/j.pnsc.2016.12.014 ↗
6. He T, Pachfule P, Wu H, Xu Q, Chen P (2016) Hydrog carriers Nat Rev Mater 1(12):1606710.1038/natrevmats.2016.67 ↗
7. Yu X, Tang Z, Sun D, Ouyang L, Zhu M (2017) Recent advances and remaining challenges of nanostructured materials for hydrogen storage applications. Prog Mater Sci 88:1–4810.1016/j.pmatsci.2017.03.001 ↗
8. Bonaccorso F, Colombo L, Yu G, Stoller M, Tozzini V, Ferrari AC, Ruoff RS, Pellegrini V (2015) 2D materials Graphene related two-dimensional crystals and hybrid systems for energy conversion and storage. Science 347(6217):124650110.1126/science.1246501 ↗
9. Ren J, Musyoka NM, Langmi HW, Mathe M, Liao S (2017) Current research trends and perspectives on materials-based hydrogen storage solutions: A critical review. Int J Hydrog Energy 42(1):289–31110.1016/j.ijhydene.2016.11.195 ↗
10. Li L, Huang Y, An C, Wang Y (2019) Lightweight hydrides nanocomposites for hydrogen storage: Challenges, progress and prospects. Sci China Mater 62(11):1597–162510.1007/s40843-019-9556-1 ↗
11. Kumar R, Karkamkar A, Bowden M, Autrey T (2019) Solid-state hydrogen rich boron-nitrogen compounds for energy storage. Chem Soc Rev 48(21):5350–538010.1039/C9CS00442D ↗
12. Roy B, Hajari A, Kumar V, Manna J, Sharma P (2018) Kinetic model analysis and mechanistic correlation of ammonia borane thermolysis under dynamic heating conditions. Int J Hydrog Energy 43(22):10386–1039510.1016/j.ijhydene.2018.04.124 ↗
13. Sanyal U, Demirci UB, Jagirdar BR, Miele P (2011) Hydrolysis of ammonia borane as a hydrogen source: fundamental issues and potential solutions towards implementation. Chemsuschem 4(12):1731–173910.1002/cssc.201100318 ↗
14. Zhang H, Huang M, Wen J, Li Y, Li A, Zhang L, Ali AM, Li Y (2019) Sub-3 nm Rh nanoclusters confined within a metal-organic framework for enhanced hydrogen generation. Chem Commun (Camb) 55(32):4699–470210.1039/C9CC00003H ↗
15. Yao K, Zhao C, Wang N, Li T, Lu W, Wang J (2020) An aqueous synthesis of porous PtPd nanoparticles with reversed bimetallic structures for highly efficient hydrogen generation from ammonia borane hydrolysis. Nanoscale 12(2):638–64710.1039/C9NR07144J ↗
16. Ma H, Na C (2015) Isokinetic temperature and size-controlled activation of ruthenium-catalyzed ammonia borane hydrolysis. ACS Catal 5(3):1726–173510.1021/cs5019524 ↗
17. Zhang L, Wang Y, Li J, Ren X, Lv H, Su X, Hu Y, Xu D, Liu B (2018) Ultrasmall Ru nanoclusters on nitrogen-enriched hierarchically porous carbon support as remarkably active catalysts for hydrolysis of ammonia borane. ChemCatChem 10(21):4910–491610.1002/cctc.201801192 ↗
18. Liu B, Xu Y, Zhang S, Lv X, Ling Y, Zhou Z, Liu J (2019) FeCo alloy encapsulated within carbon nanotube as efficient and stable catalyst for ammonia borane hydrolysis. Mater Lett 239:124–12710.1016/j.matlet.2018.12.078 ↗
19. Wang C, Tuninetti J, Wang Z, Zhang C, Ciganda R, Salmon L, Moya S, Ruiz J, Astruc D (2017) Hydrolysis of ammonia-borane over ni/zif-8 nanocatalyst: high efficiency, mechanism, and controlled hydrogen release. J Am Chem Soc 139(33):11610–1161510.1021/jacs.7b06859 ↗
20. Yüksel Alpaydın C, Gülbay SK, Ozgur Colpan C (2020) A review on the catalysts used for hydrogen production from ammonia borane. Int J Hydrog Energy 45(5):3414–343410.1016/j.ijhydene.2019.02.181 ↗
21. WangFuYangMartinez MoroRamirezMoyaSalmonRuizAstruc QFSMMSLJD (2018) Dramatic synergy in copt nanocatalysts stabilized by “click” dendrimers for evolution of hydrogen from hydrolysis of ammonia borane. ACS Catal 9(2):1110–1119
22. Zhang J, Dong Y, Liu Q, Zhou M, Mi G, Du X (2019) Hierarchically alloyed Pd–Cu microarchitecture with tunable shapes: morphological engineering, and catalysis for hydrogen evolution reaction of ammonia borane. Int J Hydrog Energy 44(57):30226–3023610.1016/j.ijhydene.2019.09.213 ↗
23. Yang X, Cheng F, Liang J, Tao Z, Chen J (2011) Carbon-supported Ni1-x@Pt-x (x=0.32, 0.43, 0.60, 0.67, and 0.80) core-shell nanoparticles as catalysts for hydrogen generation from hydrolysis of ammonia borane. Int J Hydrog Energy 36(3):1984–199010.1016/j.ijhydene.2010.11.069 ↗
24. Yang X, Cheng F, Tao Z, Chen J (2011) Hydrolytic dehydrogenation of ammonia borane catalyzed by carbon supported Co core-Pt shell nanoparticles. J Power Sour 196(5):2785–278910.1016/j.jpowsour.2010.09.079 ↗
25. Yang X, Cheng F, Liang J, Tao Z, Chen J (2009) PtxNi1-x nanoparticles as catalysts for hydrogen generation from hydrolysis of ammonia borane. Int J Hydrog Energy 34(21):8785–879110.1016/j.ijhydene.2009.08.075 ↗
26. Ren X, Lv H, Yang S, Wang Y, Li J, Wei R, Xu D, Liu B (2019) promoting effect of heterostructured nio/ni on pt nanocatalysts toward catalytic hydrolysis of ammonia borane. J Phys Chem Lett 10(23):7374–738210.1021/acs.jpclett.9b03080 ↗
27. Kang K, Gu X, Guo L, Liu P, Sheng X, Wu Y, Cheng J, Su H (2015) Efficient catalytic hydrolytic dehydrogenation of ammonia borane over surfactant-free bimetallic nanoparticles immobilized on amine-functionalized carbon nanotubes. Int J Hydrog Energy 40(36):12315–1232410.1016/j.ijhydene.2015.07.081 ↗
28. Guo L, Gu X, Kang K, Wu Y, Cheng J, Liu P, Wang T, Su H (2015) Porous nitrogen-doped carbon-immobilized bimetallic nanoparticles as highly efficient catalysts for hydrogen generation from hydrolysis of ammonia borane. J Mater Chem A 3(45):22807–2281510.1039/C5TA05487G ↗
29. Liu M, Zhou L, Luo X, Wan C, Xu L (2020) Recent advances in noble metal catalysts for hydrogen production from ammonia borane. Catalysts 10(7):78810.3390/catal10070788 ↗
30. Xu Q, Chandra M (2006) Catalytic activities of non-noble metals for hydrogen generation from aqueous ammonia-borane at room temperature. J Power Sources 163(1):364–37010.1016/j.jpowsour.2006.09.043 ↗
31. Chandra M, Xu Q (2006) A high-performance hydrogen generation system: Transition metal-catalyzed dissociation and hydrolysis of ammonia-borane. J Power Sour 156(2):190–19410.1016/j.jpowsour.2005.05.043 ↗
32. Nozaki A, Tanihara Y, Kuwahara Y, Ohmichi T, Mori K, Nagase T, Yasuda HY, Yamashita H (2016) Skeletal Ni catalysts prepared from amorphous Ni-Zr alloys: enhanced catalytic performance for hydrogen generation from ammonia borane. ChemPhysChem 17(3):412–41710.1002/cphc.201500964 ↗
33. Nozaki A, Kittima S, Tanihara Y, Kuwahara Y, Ohmichi T, Kamegawa T, Mori K, Yamashita H (2016) Efficient hydrogen generation from ammonia borane on skeletal Cu catalysts prepared from Cu-Ti amorphous alloys. J Jpn Inst Met Mater 80(6):365–36910.2320/jinstmet.J2016002 ↗
34. Fang Y, Xiao Z, Li J, Lollar C, Liu L, Lian X, Yuan S, Banerjee S, Zhang P, Zhou HC (2018) Formation of a highly reactive cobalt nanocluster crystal within a highly negatively charged porous coordination cage. Angew Chem Int Ed 57(19):5283–528710.1002/anie.201712372 ↗
35. Zhao X, Ke D, Han S, Li Y, Zhang H, Cai Y (2019a) Reduced graphene oxide sheets supported waxberry-like co catalysts for improved hydrolytic dehydrogenation of ammonia borane. ChemistrySelect 4(9):2513–251810.1002/slct.201804017 ↗
36. Guo K, Li H, Yu Z (2018) Size-Dependent catalytic activity of monodispersed nickel nanoparticles for the hydrolytic dehydrogenation of ammonia borane. ACS Appl Mater Interfaces 10(1):517–52510.1021/acsami.7b14166 ↗
37. Wei W, Wang Z, Xu J, Zong L, Zhao K, Wang H, Li H, Yu R (2017) Cobalt hollow nanospheres: controlled synthesis, modification and highly catalytic performance for hydrolysis of ammonia borane. Sci Bull 62(5):326–33110.1016/j.scib.2017.01.012 ↗
38. Li Z, He T, Liu L, Chen W, Zhang M, Wu G, Chen P (2017) Covalent triazine framework supported non-noble metal nanoparticles with superior activity for catalytic hydrolysis of ammonia borane: from mechanistic study to catalyst design. Chem Sci 8(1):781–78810.1039/C6SC02456D ↗
39. Zhang J, Chen C, Yan W, Duan F, Zhang B, Gao Z, Qin Y (2016) Ni nanoparticles supported on CNTs with excellent activity produced by atomic layer deposition for hydrogen generation from the hydrolysis of ammonia borane. Catal Sci Technol 6(7):2112–211910.1039/C5CY01497B ↗
40. Zhang X-L, Zhang D-X, Chang G-G, Ma X-C, Wu J, Wang Y, Yu H-Z, Tian G, Chen J, Yang X-Y (2019) Bimetallic (Zn/Co) MOFs-derived highly dispersed metallic Co/HPC for completely hydrolytic dehydrogenation of Ammonia-Borane. Ind Eng Chem Res 58(17):7209–721610.1021/acs.iecr.9b00897 ↗
41. Zhang F, Ma C, Zhang Y, Li H, Fu D, Du X, Zhang X-M (2018) N-doped mesoporous carbon embedded Co nanoparticles for highly efficient and stable H-2 generation from hydrolysis of ammonia borane. J Power Sour 399:89–9710.1016/j.jpowsour.2018.07.069 ↗
42. Li M, Hu J, Lu H (2016) A stable and efficient 3D cobalt-graphene composite catalyst for the hydrolysis of ammonia borane. Catal Sci Technol 6(19):7186–719210.1039/C6CY01253A ↗
43. Wen M, Cui Y, Kuwahara Y, Mori K, Yamashita H (2016) Non-noble-metal nanoparticle supported on metal-organic framework as an efficient and durable catalyst for promoting h-2 production from ammonia borane under visible light irradiation. ACS Appl Mater Inter 8(33):21278–2128410.1021/acsami.6b04169 ↗
44. Song J, Gu X, Cheng J, Fan N, Zhang H, Su H (2018) Remarkably boosting catalytic H-2 evolution from ammonia borane through the visible-light-driven synergistic electron effect of non-plasmonic noble-metal-free nanoparticles and photoactive metal-organic frameworks. Appl Catal 225:424–43210.1016/j.apcatb.2017.12.024 ↗
45. Liu P, Gu X, Kang K, Zhang H, Cheng J, Su H (2017) Highly efficient catalytic hydrogen evolution from ammonia borane using the synergistic effect of crystallinity and size of noble-metal-free nanoparticles supported by porous metal organic frameworks. ACS Appl Mater Inter 9(12):10759–1076710.1021/acsami.7b01161 ↗
46. Liu H, Liu X, Yang W, Shen M, Geng S, Yu C, Shen B, Yu Y (2019) Photocatalytic dehydrogenation of formic acid promoted by a superior PdAg@g-C3N4 Mott-Schottky heterojunction. J Mater Chem A 7(5):2022–202610.1039/C8TA11172C ↗
47. Wang C, Sun D, Yu X, Zhang X, Lu Z, Wang X, Zhao J, Li L, Yang X (2018) Cu/Ni nanoparticles supported on TiO2(B) nanotubes as hydrogen generation photocatalysts via hydrolysis of ammonia borane. Inorg Chem Front 5(8):2038–204410.1039/C8QI00492G ↗
48. Wang C, Yu X, Zhang X, Lu Z, Wang X, Han X, Zhao J, Li L, Yang X (2020) Enhanced hydrogen production from ammonia borane over CuNi alloy nanoparticles supported on TiO2(B)/anatase mixed-phase nanofibers with high specific surface area. J Alloys Compd 815:15243110.1016/j.jallcom.2019.152431 ↗
49. Wang Y, Bao S, Liu Y, Yang W, Yu Y, Feng M, Li K (2020) Efficient photocatalytic reduction of Cr(VI) in aqueous solution over CoS2/g-C3N4-rGO nanocomposites under visible light. Appl Surf Sci 510:14549510.1016/j.apsusc.2020.145495 ↗
50. Zhang H, Gu X, Song J, Fan N, Su H (2017) Non-Noble metal nanoparticles supported by postmodified porous organic semiconductors: highly efficient catalysts for visible-light-driven on-demand H-2 evolution from ammonia borane. ACS Appl Mater Inter 9(38):32767–3277410.1021/acsami.7b10280 ↗
51. Song J, Gu X, Cao Y, Zhang H (2019) Porous oxygen vacancy-rich V2O5 nanosheets as superior semiconducting supports of nonprecious metal nanoparticles for efficient on-demand H2 evolution from ammonia borane under visible light irradiation. J Mater Chem A 7(17):10543–1055110.1039/C9TA01674K ↗
52. Zhang H, Gu X, Song J (2020) Co, Ni-based nanoparticles supported on graphitic carbon nitride nanosheets as catalysts for hydrogen generation from the hydrolysis of ammonia borane under broad-spectrum light irradiation. Int J Hydrog Energy 45(41):21273–2128610.1016/j.ijhydene.2020.05.178 ↗
53. Yan J-M, Zhang X-B, Han S, Shioyama H, Xu Q (2009) Magnetically recyclable Fe-Ni alloy catalyzed dehydrogenation of ammonia borane in aqueous solution under ambient atmosphere. J Power Sour 194(1):478–48110.1016/j.jpowsour.2009.04.023 ↗
54. Yang K, Yao QL, Lu ZH, Kang ZB, Chen XS (2017) Facile synthesis of cumo nanoparticles as highly active and cost-effective catalysts for the hydrolysis of ammonia borane. Acta Phys-Chim Sin 33(5):993–100010.3866/PKU.WHXB201702087 ↗
55. Yang K, Yao Q, Huang W, Chen X, Lu Z-H (2017) Enhanced catalytic activity of NiM (M=Cr, Mo, W) nanoparticles for hydrogen evolution from ammonia borane and hydrazine borane. Int J Hydrog Energy 42(10):6840–685010.1016/j.ijhydene.2016.12.029 ↗
56. Furukawa S, Nishimura G, Takayama T, Komatsu T (2019) Highly Active Ni- and Co-Based Bimetallic Catalysts for Hydrogen Production From Ammonia-Borane. Front Chem 7:13810.3389/fchem.2019.00138 ↗
57. Zhang J, Li H, Zhang H, Zhu Y, Mi G (2016) Porously hierarchical Cu@Ni cubic-cage microstructure: Very active and durable catalyst for hydrolytically liberating H-2 gas from ammonia borane. Renew Energy 99:1038–104510.1016/j.renene.2016.07.066 ↗
58. Wang C, Li L, Yu X, Lu Z, Zhang X, Wang X, Yang X, Zhao J (2020) Regulation of d-Band Electrons to Enhance the Activity of Co-Based Non-Noble Bimetal Catalysts for Hydrolysis of Ammonia Borane. ACS Sustainable Chem Eng 8(22):8256–826610.1021/acssuschemeng.0c01475 ↗
59. Wang C, Wang H, Wang Z, Li X, Chi Y, Wang M, Gao D, Zhao Z (2018) Mo remarkably enhances catalytic activity of Cu@MoCo core-shell nanoparticles for hydrolytic dehydrogenation of ammonia borane. Int J Hydrog Energy 43(15):7347–735510.1016/j.ijhydene.2018.02.172 ↗
60. Sang W, Wang C, Zhang X, Yu X, Yu C, Zhao J, Wang X, Yang X, Li L (2017) Dendritic Co0.52Cu0.48 and Ni0.19Cu0.81 alloys as hydrogen generation catalysts via hydrolysis of ammonia borane. Int J Hydrog Energy 42(52):30691–3070310.1016/j.ijhydene.2017.10.130 ↗
61. Li S-J, Wang H-L, Yan J-M, Jiang Q (2017) Oleylamine-stabilized Cu0.9Ni0.1 nanoparticles as efficient catalyst for ammonia borane dehydrogenation. Int J Hydrog Energy 42(40):25251–2525710.1016/j.ijhydene.2017.08.120 ↗
62. Bulut A, Yurderi M, Ertas IE, Celebi M, Kaya M, Zahmakiran M (2016) Carbon dispersed copper-cobalt alloy nanoparticles: a cost-effective heterogeneous catalyst with exceptional performance in the hydrolytic dehydrogenation of ammonia-borane. Appl Catal B 180:121–12910.1016/j.apcatb.2015.06.021 ↗
63. Sun D, Hao Y, Wang C, Zhang X, Yu X, Yang X, Li L, Lu Z, Shang W (2020) TiO2-CdS supported CuNi nanoparticles as a highly efficient catalyst for hydrolysis of ammonia borane under visible-light irradiation. Int J Hydrog Energy 45(7):4390–440210.1016/j.ijhydene.2019.11.212 ↗
64. Yang X, Li Q, Li L, Lin J, Yang X, Yu C, Liu Z, Fang Y, Huang Y, Tang C (2019) CuCo binary metal nanoparticles supported on boron nitride nanofibers as highly efficient catalysts for hydrogen generation from hydrolysis of ammonia borane. J Power Sour 431:135–14310.1016/j.jpowsour.2019.05.038 ↗
65. Zacho SL, Mielby J, Kegnaes S (2018) Hydrolytic dehydrogenation of ammonia borane over ZIF-67 derived Co nanoparticle catalysts. Catal Sci Technol 8(18):4741–474610.1039/C8CY01500G ↗
66. Wang H, Zhao Y, Cheng F, Tao Z, Chen J (2016) Cobalt nanoparticles embedded in porous N-doped carbon as long-life catalysts for hydrolysis of ammonia borane. Catal Sci Technol 6(10):3443–344810.1039/C5CY01756D ↗
67. Lee M-H, Deka JR, Cheng C-J, Lu N-F, Saikia D, Yang Y-C, Kao H-M (2019) Synthesis of highly dispersed ultra-small cobalt nanoparticles within the cage-type mesopores of 3D cubic mesoporous silica via double agent reduction method for catalytic hydrogen generation. Appl Surf Sci 470:764–77210.1016/j.apsusc.2018.11.171 ↗
68. Gao M, Yu Y, Yang W, Li J, Xu S, Feng M, Li H (2019) Ni nanoparticles supported on graphitic carbon nitride as visible light catalysts for hydrolytic dehydrogenation of ammonia borane. Nanoscale 11(8):3506–351310.1039/C8NR09005J ↗
69. Wu Y, Wu X, Liu Q, Huang C, Qiu X (2017) Magnetically recyclable Ni@h-BN composites for efficient hydrolysis of ammonia borane. Int J Hydrogen Energy 42(25):16003–1601110.1016/j.ijhydene.2017.05.081 ↗
70. Yang XJ, Li LL, Sang WL, Zhao JL, Wang XX, Yu C, Zhang XH, Tang CC (2017) Boron nitride supported Ni nanoparticles as catalysts for hydrogen generation from hydrolysis of ammonia borane. J Alloys Compd 693:642–64910.1016/j.jallcom.2016.09.204 ↗
71. Qiu X, Wu X, Wu Y, Liu Q, Huang C (2016) The release of hydrogen from ammonia borane over copper/hexagonal boron nitride composites. RSC Adv 6(108):106211–10621710.1039/C6RA24000C ↗
72. Al-Enizil AM, Brooks RM, Ahmad MM, Ei-Halwany MM, El-Newehy MH, Yousef A (2018) In-situ synthesis of amorphous co nanoparticles supported onto TiO2 nanofibers as a catalyst for hydrogen generation from the hydrolysis of ammonia borane. J Nanosci Nanotechnol 18(7):4714–471910.1166/jnn.2018.15300 ↗
73. Zhu J, Ma L, Feng J, Geng T, Wei W, Xie J (2018) Facile synthesis of Cu nanoparticles on different morphology ZrO2 supports for catalytic hydrogen generation from ammonia borane. J Mater Sci Mater Electron 29(17):14971–1498010.1007/s10854-018-9635-6 ↗
74. Liu T, Wang Q-T, Sun Y-H, Zhao M (2019) Facile synthesis of monodispersed co nanoparticles on titanium carbides for hydrolysis of ammonia borane at mild temperature. J Nanosci Nanotechnol 19(11):7392–739710.1166/jnn.2019.16722 ↗
75. Chen M, Xiong R, Cui X, Wang Q, Liu X (2019) SiO2-encompassed Co@N-doped porous carbon assemblies as recyclable catalysts for efficient hydrolysis of ammonia borane. Langmuir 35(3):671–67710.1021/acs.langmuir.8b03921 ↗
76. Li YT, Ullah S, Han Z, Zheng XC, Zheng GP (2020) Hierarchical porous CuNi-based bimetal-organic frameworks as efficient catalysts for ammonia borane hydrolysis. Catal Commun 143:10605710.1016/j.catcom.2020.106057 ↗
77. Chen MJ, Zhang DX, Li D, Ke SC, Ma XC, Chang GG, Chen J, Yang XY (2020) All-around coating of CoNi nanoalloy using a hierarchically porous carbon derived from bimetallic MOFs for highly efficient hydrolytic dehydrogenation of ammonia-borane. New J Chem 44(7):3021–302710.1039/C9NJ05484G ↗
78. Cui C, Liu Y, Mehdi S, Wen H, Zhou B, Li J, Li B (2020) Enhancing effect of Fe-doping on the activity of nano Ni catalyst towards hydrogen evolution from NH3BH3. Appl Catal B. https://doi.org/10.1016/j.apcatb.2020.11861210.1016/j.apcatb.2020.118612 ↗
79. Zhao X, Ke D, Han S, Li Y, Zhang H, Cai Y (2019b) Surfactant PVA-stabilized Co-Mo nanocatalyst supported by graphene oxide sheets toward the hydrolytic dehydrogenation of ammonia borane. NANO 14(11):195013710.1142/S1793292019501376 ↗
80. Brooks RM, Maafa IM, Al-Enizi AM, El-Halwany MM, Ubaidullah M, Yousef A (2019) Electrospun bimetallic nicr nanoparticles@carbon nanofibers as an efficient catalyst for hydrogen generation from ammonia borane. Nanomaterials 9(8):108210.3390/nano9081082 ↗
81. Xu M, Huai X, Zhang H (2018) Highly dispersed CuCo nanoparticles supported on reduced graphene oxide as high-activity catalysts for hydrogen evolution from ammonia borane hydrolysis. J Nanopart Res 20(12):32910.1007/s11051-018-4429-6 ↗
82. Du X, Tai Y, Liu H, Zhang J (2018) One-step synthesis of reduced graphene oxide supported CoW nanoparticles as efficient catalysts for hydrogen generation from NH3BH3. React Kinet Mech Catal 125(1):171–18110.1007/s11144-018-1392-2 ↗
83. Wang Q, Zhang F, Du F, Liu T (2017) A cost effective cobalt nickel nanoparticles catalyst with exceptional performance for hydrolysis of ammonia-borane. J Nanosci Nanotechnol 17(12):9333–933810.1166/jnn.2017.14331 ↗
84. Wang Q, Zhang Z, Liu J, Liu R, Liu T (2018) Bimetallic non-noble CoNi nanoparticles monodispersed on multiwall carbon nanotubes: highly efficient hydrolysis of ammonia borane. Mater Chem Phys 204:58–6110.1016/j.matchemphys.2017.10.036 ↗
85. Song F-Z, Zhu Q-L, Yang X-C, Xu Q (2016) Monodispersed CuCo nanoparticles supported on diamine-functionalized graphene as a non-noble metal catalyst for hydrolytic dehydrogenation of ammonia borane. Chemnanomat 2(10):942–94510.1002/cnma.201600198 ↗
86. Yao Q, Lu Z-H, Huang W, Chen X, Zhu J (2016) High Pt-like activity of the Ni-Mo/graphene catalyst for hydrogen evolution from hydrolysis of ammonia borane. J Mater Chem A 4(22):8579–858310.1039/C6TA02004F ↗
87. Zhao B, Liu J, Zhou L, Long D, Feng K, Sun X, Zhong J (2016) Probing the electronic structure of M-graphene oxide (M=Ni Co, NiCo) catalysts for hydrolytic dehydrogenation of ammonia borane. Appl Surf Sci 362:79–8510.1016/j.apsusc.2015.11.205 ↗
88. Liang Z, Xiao X, Yu X, Huang X, Jiang Y, Fan X, Chen L (2018) Non-noble trimetallic Cu-Ni-Co nanoparticles supported on metal-organic frameworks as highly efficient catalysts for hydrolysis of ammonia borane. J Alloys Compd 741:501–50810.1016/j.jallcom.2017.12.151 ↗
89. Zhang H, Gu X, Liu P, Song J, Cheng J, Su H (2017) Highly efficient visible-light-driven catalytic hydrogen evolution from ammonia borane using non-precious metal nanoparticles supported by graphitic carbon nitride. J Mater Chem A 5(5):2288–229610.1039/C6TA08987A ↗
90. Cheng S, Liu Y, Zhao Y, Zhao X, Lang Z, Tan H, Qiu T, Wang Y (2019) Superfine CoNi alloy embedded in Al2O3 nanosheets for efficient tandem catalytic reduction of nitroaromatic compounds by ammonia borane. Dalton Trans 48(47):17499–1750610.1039/C9DT03838H ↗
91. Guo K, Ding Y, Luo J, Gu M, Yu Z (2019) NiCu bimetallic nanoparticles on silica support for catalytic hydrolysis of ammonia borane: composition-dependent activity and support size effect. ACS Appl Energy Mater 2(8):5851–586110.1021/acsaem.9b00997 ↗
92. Liao J, Lv F, Feng Y, Zhong S, Wu X, Zhang X, Wang H, Li J, Li H (2019) Electromagnetic-field-assisted synthesis of Ni foam film-supported CoCu alloy microspheres composed of nanosheets: a high performance catalyst for the hydrolysis of ammonia borane. Catal Commun 122:16–1910.1016/j.catcom.2019.01.010 ↗
93. Liu Y, Zhang J, Guan H, Zhao Y, Yang J-H, Zhang B (2018) Preparation of bimetallic Cu-Co nanocatalysts on poly (diallyldimethylammonium chloride) functionalized halloysite nanotubes for hydrolytic dehydrogenation of ammonia borane. Appl Surf Sci 427:106–11310.1016/j.apsusc.2017.08.171 ↗
94. Fan D, Lv X, Feng J, Zhang S, Bai J, Lu R, Liu J (2017) Cobalt nickel nanoparticles encapsulated within hexagonal boron nitride as stable, catalytic dehydrogenation nanoreactor. Int J Hydrog Energy 42(16):11312–1132010.1016/j.ijhydene.2017.03.139 ↗
95. Brown HSH, Finholt A, Gilbreath J, Hoekstra H, Hyde E (1953) Sodium borohydride its hydrolysis and its use as a reducing agent and in the generation of hydrogen. J Am Chem Soc 75(1):215–21910.1021/ja01097a057 ↗
96. Wang X, Liao J, Li H, Wang H, Wang R (2016) Solid-state-reaction synthesis of cotton-like CoB alloy at room temperature as a catalyst for hydrogen generation. J Colloid Interface Sci 475:149–15310.1016/j.jcis.2016.04.033 ↗
97. Wang Y, Meng W, Wang D, Li G, Wu S, Cao Z, Zhang K, Wu C, Liu S (2017) Nanostructured thin-film Co-B catalysts for hydrogen generation from hydrolysis of ammonia borane. Int J Hydrog Energy 42(52):30718–3072610.1016/j.ijhydene.2017.10.131 ↗
98. Zou Y, Gao Y, Xiang C, Chu H, Qiu S, Yan E, Xu F, Tang C, Sun L (2016) Cobalt-nickel-boron supported over polypyrrole-derived activated carbon for hydrolysis of ammonia borane. Metals 6(7):15410.3390/met6070154 ↗
99. Li C, Wang D, Wang Y, Li G, Hu G, Wu S, Cao Z, Zhang K (2018) Enhanced catalytic activity of the nanostructured Co-W-B film catalysts for hydrogen evolution from the hydrolysis of ammonia borane. J Colloid Interface Sci 524:25–3110.1016/j.jcis.2018.03.085 ↗
100. Li C, Meng W, Hu G, Wang Y, Cao Z, Zhang K (2018) Preparation and characterization of nanostructured Co-Mo-B thin film catalysts for the hydrolysis of ammonia borane. Int J Hydrog Energy 43(37):17664–1767210.1016/j.ijhydene.2018.07.180 ↗