journal article·2021-05

Novel nanoscale Yb-MOF used as highly efficient electrode for simultaneous detection of heavy metal ions

Manh B. Nguyen, Dau Thi Ngoc Nga, Vu Thi Thu, Benoît Piro, Thuan Nguyen Pham Truong, Pham Thi Hai Yen, Giang H. Le, Le Quoc Hung, Tuan A. Vu, Vu Thi Thu Ha

Journal of Materials Science· Volume 56· Issue 13
Publisher page

Abstract

It is essential to develop new nanomaterials able to improve sensing performance of electrochemical sensors for determination of heavy metal pollutants. In this work, a novel nanoscale metal–organic-framework material (Yb-MOF) with Ytterbium (Yb) rare-earth metal core and benzenetricarboxylic (BTC) ligands was prepared in aqueous conditions using hydrothermal approach. The results have revealed highly porous structure of the as-synthesized material with specific active area up to 1166 m2 g−1. A sensing platform was then constructed by drop-casting Yb-MOF onto glassy carbon electrode for detection of two most commonly found heavy metal ion pollutants (Cd2+ and Pb2+) in water sources. The nanoporous structure of Yb-MOF is very profitable to the selective preconcentration of targeted metal ions. The detection limits were estimated to be 3.0 ppb, 1.6 ppb for Cd2+ and Pb2+ species, respectively. This work provides a new electrochemical sensing platform for fast and sensitive in-situ detection of water contaminants.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Electrochemical Analysis and Applications · Analytical Chemistry and Sensors · Metal-Organic Frameworks: Synthesis and Applications

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (39)

Show source-provided references
1. Riman D, Jirovsky D, Hrbac J, Prodromidis M (2014) Green and facile electrode modification by spark discharge: bismuth oxide-screen printed electrodes for the screening of ultra-trace Cd(II) and Pb(II). Electrochem Commun 50:20–2310.1016/j.elecom.2014.11.003 ↗
2. Giao NQ, Dang VH, Yen PTH, Phong PH, Ha VTT, Duy PK, Chung H (2019) Au nanodendrite incorporated graphite pencil lead as a sensitive and simple electrochemical sensor for simultaneous detection of Pb(II), Cu(II) and Hg(II). J Appl Electrochem 49(8):839–84610.1007/s10800-019-01326-x ↗
3. Lee S, Bong S, Ha J, Kwak M, Park S-K, Piao Y (2015) Electrochemical deposition of bismuth on activated graphene-nafion composite for anodic stripping voltammetric determination of trace heavy metals. Sens Actuat B 215:62–6910.1016/j.snb.2015.03.032 ↗
4. Zhao G, Liu G (2019) Synthesis of a three-dimensional (BiO)2CO3@single-walled carbon nanotube nanocomposite and its application for ultrasensitive detection of trace Pb(II) and Cd(II) by incorporating Nafion. Sens Actuat B 288:71–7910.1016/j.snb.2019.02.106 ↗
5. Yu L, Zhang Q, Yang B, Xu Q, Xu Q, Hu X (2018) Electrochemical sensor construction based on Nafion/calcium lignosulphonate functionalized porous graphene nanocomposite and its application for simultaneous detection of trace Pb2+ and Cd2+. Sens Actuat B 259:540–55110.1016/j.snb.2017.12.103 ↗
6. Wang Y, Wu Y, Xie J, Hu X (2013) Metal–organic framework modified carbon paste electrode for lead sensor. Sens Actuat B 177:1161–116610.1016/j.snb.2012.12.048 ↗
7. Guo H, Zheng Z, Zhang Y, Lin H, Xu Q (2017) Highly selective detection of Pb2+ by a nanoscale Ni-based metal–organic framework fabricated through one-pot hydrothermal reaction. Sens Actuat B 248:430–43610.1016/j.snb.2017.03.147 ↗
8. Li Y, Xia T, Zhang J, Cui Y, Li B, Yang Y, Qian G (2019) A manganese-based metal-organic framework electrochemical sensor for highly sensitive cadmium ions detection. J Solid State Chem 275:38–4210.1016/j.jssc.2019.03.051 ↗
9. Sanati S, Abazari R, Morsali A, Kirillov AM, Junk PC, Wang J (2019) An asymmetric supercapacitor based in a non-calcined 3D pillared cobalt (II) metal-organic framework with long cylic stability. Inorg Chem 58:16100–1611110.1021/acs.inorgchem.9b02658 ↗
10. Sanati S, Abazari R, Morsali A (2020) Enhanced electrochemical oxygen and hydrogen evolution using an NU-1000@NiMn-LDHS composite electrode in alkaline electrolyte. Chem Commun 56:6652–665510.1039/D0CC01146K ↗
11. Abazari R, Morsali A, Dubai DP (2020) An advanced composite with ultrafast photocatalytic performance for the degradation of antibiotics by natural sunlight without oxidizing the source over TMU-5@Ni-Ti LDH: mechanistic insight and toxicity assessment. Inorg Chem Front 7:2287–230410.1039/D0QI00050G ↗
12. Roushani M, Valipour A, Saedi Z (2016) Electroanalytical sensing of Cd2+ based on metal–organic framework modified carbon paste electrode. Sens Actuat B 233:419–42510.1016/j.snb.2016.04.106 ↗
13. Wang Y, Wang L, Huang W, Zhang T, Hu X, Perman JA, Ma S (2017) A metal–organic framework and conducting polymer based electrochemical sensor for high performance cadmium ion detection. J Mater Chem A 5(18):8385–839310.1039/C7TA01066D ↗
14. Wang X, Qi Y, Shen Y, Yuan Y, Zhang L, Zhang C, Sun Y (2020) A ratiometric electrochemical sensor for simultaneous detection of multiple heavy metal ions based on ferrocene-functionalized metal-organic framework. Sens Actuat B 310:12775610.1016/j.snb.2020.127756 ↗
15. Ye W, Li Y, Wang J, Li B, Cui Y, Yang Y, Qian G (2020) Electrochemical detection of trace heavy metal ions using a Ln-MOF modified glass carbon electrode. J Solid State Chem 281:12103210.1016/j.jssc.2019.121032 ↗
16. Jiang H-L, Tsumori N, Xu Q (2010) A series of (6,6)-connected porous lanthanide−organic framework enantiomers with high thermostability and exposed metal sites: scalable syntheses, structures, and sorption properties. Inorg Chem 49(21):10001–1000610.1021/ic101294s ↗
17. Jamali A, Tehrani AA, Shemirani F, Morsali A (2016) Lanthanide metal–organic frameworks as selective microporous materials for adsorption of heavy metal ions. Dalton Trans 45(22):9193–920010.1039/C6DT00782A ↗
18. Burnett DL, Oozeerally R, Pertiwi R, Chamberlain TW, Cherkasov N, Clarkson GJ, Krisnandi YK, Degirmenci V, Walton RI (2019) A hydrothermally stable ytterbium metal-organic framework as a bifunctional solid-acid catalyst for glucose conversion. Chem Commun 55:11446–1144910.1039/C9CC05364F ↗
19. Gustafsson M, Bartoszewicz A, Martín-Matute B, Sun J, Grins J, Zhao T, Li Z, Zhu G, Zou X (2010) A family of highly stable lanthanide metal−organic frameworks: structural evolution and catalytic activity. Chem Mater 22(11):3316–332210.1021/cm100503q ↗
20. Andrius L, Aldona B, Aivaras K (2018) On the synthesis and chracterization of lanthanide metal organic framework. Ceramics 1:54–6410.3390/ceramics1010006 ↗
21. Dau TNN, Vu VH, Cao TT, Nguyen VC, Ly CT, Tran DL, Pham TTN, Loc NT, Piro B, Vu TT (2019) In-situ electrochemically deposited Fe3O4 nanoparticles onto graphene nanosheets as amperometric amplifier for electrochemical biosensing applications. Sens Actuact B Chem 283:52–6010.1016/j.snb.2018.11.152 ↗
22. Sun Y, Ma M, Tang B, Li S, Jiang L, Sun X, Que M, Tao C, Wu Z (2019) Graphene modified Cu-BTC with high stability in water and controllable selective adsorption of various gases. J Alloys Compd 808:15172110.1016/j.jallcom.2019.151721 ↗
23. Torres N, Galicia J, Plasencia Y, Cano A, Echevarría F, Desdin-Garcia LF, Reguera E (2018) Implications of structural differences between Cu-BTC and Fe-BTC on their hydrogen storage capacity. Colloids Surf A 549:138–14610.1016/j.colsurfa.2018.04.016 ↗
24. Teterin YA, Teterin AYu (2002) Structure of X-ray photoelectron spectra of lanthanide compounds. Russ Chem Rev 71(5):347–38110.1070/RC2002v071n05ABEH000717 ↗
25. Xu X, Clarke C, Ma C, Casillas G, Das M, Guan M, Liu D, Wang L, Tadich A, Du Y, Ton-That C, Jin D (2017) Depth-profiling of Yb3+ sensitizer ions in NaYF4 upconversion nanoparticles. Nanoscale 9(23):7719–772610.1039/C7NR01456B ↗
26. Kumar KN, Vijayalakshmi L, Choi J (2019) Investigation of upconversion photoluminescence of Yb3+/Er3+:NaLaMgWO6 noncytotoxic double-perovskite nanophosphors. Inorg Chem 58(3):2001–201110.1021/acs.inorgchem.8b02990 ↗
27. Gong G, Song Y, Tan H, Xie S, Zhang C, Xu L, Xu J, Zheng J (2019) Design of core/active-shell NaYF4:Ln3+@NaYF4:Yb3+ nanophosphors with enhanced red-green-blue upconversion luminescence for anti-counterfeiting printing. Compos Part B-Eng 179:10750410.1016/j.compositesb.2019.107504 ↗
28. Ramasamy P, Chandra P, Rhee SW, Kim J (2013) Enhanced upconversion luminescence in NaGdF4:Yb, Er nanocrystals by Fe3+ doping and their application in bioimaging. Nanoscale 5(18):8711–871710.1039/c3nr01608k ↗
29. Wu F, Su H, Zhu X, Wang K, Zhang Z, Wong W-K (2016) Near-infrared emissive lanthanide hybridized carbon quantum dots for bioimaging applications. J Mater Chem B 4(38):6366–637210.1039/C6TB01646D ↗
30. Wang L, He J, Chen X, Lv Y (2020) A lanthanide MOF catalyst with an excellent thermal stability for the synthesis of polycarbonate diol. J Iran Chem Soc 17:2335–234310.1007/s13738-020-01929-8 ↗
31. Wu Y, Qiu L-G, Wang W, Li Z-Q, Xu T, Wu Z-Y, Jiang X (2009) Kinetics of oxidation of hydroquinone to p-benzoquinone catalyzed by microporous metal-organic frameworks M3(BTC)2 [M = copper(II), cobalt(II), or nickel(II); BTC = benzene-1,3,5-tricarboxylate] using molecular oxygen. Transit Met Chem 34(3):263–26810.1007/s11243-009-9188-x ↗
32. Oveisi AR, Khorramabadi-zad A, Daliran S (2016) Iron-based metal–organic framework, Fe(BTC): an effective dual-functional catalyst for oxidative cyclization of bisnaphthols and tandem synthesis of quinazolin-4(3H)-ones. RSC Adv 6(2):1136–114210.1039/C5RA19013D ↗
33. Pérez VG, Jiménez M, Blanco R, Sanchez-Sanchez M (2017) Semi-crystalline Fe-BTC MOF material as an efficient support for enzyme immobilization. Catal Today 304:119–126
34. Yadav RS, Kumar D, Singh AK, Rai E, Rai SB (2018) Effect of Bi3+ ion on upconversion-based induced optical heating and temperature sensing characteristics in the Er3+/Yb3+ co-doped La2O3 nano-phosphor. RSC Adv 8(60):34699–3471110.1039/C8RA07438K ↗
35. Naderi HR, Ganjali MR, Dezfuli AS, Norouzi P (2016) Sonochemical preparation of a ytterbium oxide/reduced graphene oxide nanocomposite for supercapacitors with enhanced capacitive performance. RSC Adv 6(56):51211–5122010.1039/C6RA02943D ↗
36. da Luz LL, Lucena Viana BF, da Silva GCO, Gatto CC, Fontes AM, Malta M, Weber IT, Rodrigues MO, Júnior SA (2014) Controlling the energy transfer in lanthanide–organic frameworks for the production of white-light emitting materials. CrystEngComm 16(30):6914–691810.1039/C4CE00538D ↗
37. Donohue MD, Aranovich GL (1998) Classification of Gibbs adsorption isotherms. Adv Colloid Interface Sci 76–77:137–15210.1016/S0001-8686(98)00044-X ↗
38. Dong S, Suo G, Li N, Chen Z, Peng L, Fu Y, Yang Q, Huang T (2016) A simple strategy to fabricate high sensitive 2,4-dichlorophenol electrochemical sensor based on metal organic framework Cu3(BTC)2. Sens Actuat B 222:972–97910.1016/j.snb.2015.09.035 ↗
39. Gumpu MB, Veerapandian M, Krishnan UM, Rayappan JB (2017) Simultaneous electrochemical detection of Cd(II), Pb(II), As(III) and Hg(II) ions using ruthenium(II)-textured graphene oxide nanocomposite. Talanta 162:574–58210.1016/j.talanta.2016.10.076 ↗