Ordered porous Mn3O4@N-doped carbon/graphene hybrids derived from metal–organic frameworks for supercapacitor electrodes
Source abstract
Abstract
An ordered porous Mn3O4@N-doped carbon/graphene (MCG) composite has been synthesized through a facile carbonization of Mn-based metal–organic frameworks (Mn-MOFs) using the poly(styrene-co-AA) spheres as the template. Because of the periodic arrangement of metal nodes and organic ligands in the Mn-MOFs, the Mn3O4 nanoparticles with an average diameter of 7 nm are uniformly distributed and the carbon is formed in situ in the MCG composite. The MCG exhibits a specific surface area of 326 m2 g−1 with a total pore volume of 1.02 cm3 g−1, which is much higher than that of the Mn3O4-based composites reported to date. In addition, the MCG displays excellent electrochemical performances in an aqueous 1 M Na2SO4 electrolyte with a maximum specific capacitance of 456 F g−1 at 1 A g−1 and 246 F g−1 at 20 A g−1. The MCG also owns a good cycling stability with 98.1 % of the initial capacitance remaining after 2000 cycles at 5 A g−1.
Source: openaire · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Supercapacitor Materials and Fabrication · Conducting polymers and applications · Advanced battery technologies research
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (53)
Show source-provided references
1. Wei W, Cui X, Chen W, Ivey DG (2011) Manganese oxide-based materials as electrochemical supercapacitor electrodes. Chem Soc Rev 40:1697. doi: 10.1039/c0cs00127a10.1039/c0cs00127a ↗
2. Wang Y, Xia Y (2013) Recent progress in supercapacitors: from materials design to system construction. Adv Mater 25:5336. doi: 10.1002/adma.20130193210.1002/adma.201301932 ↗
3. Zhang C, Hatzell KB, Boota M et al (2014) Highly porous carbon spheres for electrochemical capacitors and capacitive flowable suspension electrodes. Carbon 77:155. doi: 10.1016/j.carbon.2014.05.01710.1016/j.carbon.2014.05.017 ↗
4. Mai Y, Zhang F, Feng X (2014) Polymer-directed synthesis of metal oxide-containing nanomaterials for electrochemical energy storage. Nanoscale 6:106. doi: 10.1039/c3nr04791a10.1039/c3nr04791a ↗
5. Wu Y, Liu S, Wang H, Wang X, Zhang X, Jin G (2013) A novel solvothermal synthesis of Mn3O4/graphene composites for supercapacitors. Electrochim Acta 90:210. doi: 10.1016/j.electacta.2012.11.12410.1016/j.electacta.2012.11.124 ↗
6. Zhao K, Liu S, Wu Y, Lv K, Yuan H, He Z (2015) Long cycling life supercapacitors electrode materials: ultrathin manganese dioxide nanoscrolls adhered to graphene by electrostatic self-assembly. Electrochim Acta 174:1234. doi: 10.1016/j.electacta.2015.06.13210.1016/j.electacta.2015.06.132 ↗
7. Zhu QL, Xu Q (2014) Metal-organic framework composites. Chem Soc Rev 43:5468. doi: 10.1039/c3cs60472a10.1039/c3cs60472a ↗
8. Sun J-K, Xu Q (2014) Functional materials derived from open framework templates/precursors: synthesis and applications. Energy Environ Sci 7:2071. doi: 10.1039/c4ee00517a10.1039/c4ee00517a ↗
9. Díaz R, Orcajo MG, Botas JA, Calleja G, Palma J (2012) Co8-MOF-5 as electrode for supercapacitors. Mater Lett 68:126. doi: 10.1016/j.matlet.2011.10.04610.1016/j.matlet.2011.10.046 ↗
10. Morozan A, Jaouen F (2012) Metal organic frameworks for electrochemical applications. Energy Environ Sci 5:9269. doi: 10.1039/c2ee22989g10.1039/c2ee22989g ↗
11. Liu B, Shioyama H, Jiang H, Zhang X, Xu Q (2010) Metal–organic framework (MOF) as a template for syntheses of nanoporous carbons as electrode materials for supercapacitor. Carbon 48:456. doi: 10.1016/j.carbon.2009.09.06110.1016/j.carbon.2009.09.061 ↗
12. Zhang Q, Uchaker E, Candelaria SL, Cao G (2013) Nanomaterials for energy conversion and storage. Chem Soc Rev 42:3127. doi: 10.1039/C3CS00009E10.1039/C3CS00009E ↗
13. Amali AJ, Sun J-K, Xu Q (2014) From assembled metal-organic framework nanoparticles to hierarchically porous carbon for electrochemical energy storage. Chem Commun 50:1519. doi: 10.1039/C3CC48112C10.1039/C3CC48112C ↗
14. Chaikittisilp W, Hu M, Wang H et al (2012) Nanoporous carbons through direct carbonization of a zeolitic imidazolate framework for supercapacitor electrodes. Chem Commun 48:7259. doi: 10.1039/C2CC33433J10.1039/C2CC33433J ↗
15. Zhao Y, Liu M, Deng X et al (2015) Nitrogen-functionalized microporous carbon nanoparticles for high performance supercapacitor electrode. Electrochim Acta 153:448. doi: 10.1016/j.electacta.2014.11.17310.1016/j.electacta.2014.11.173 ↗
16. Zhong S, Zhan C, Cao D (2015) Zeolitic imidazolate framework-derived nitrogen-doped porous carbons as high performance supercapacitor electrode materials. Carbon 85:51. doi: 10.1016/j.carbon.2014.12.06410.1016/j.carbon.2014.12.064 ↗
17. Wu R, Wang DP, Han J et al (2015) A general approach towards multi-faceted hollow oxide composites using zeolitic imidazolate frameworks. Nanoscale 7:965. doi: 10.1039/c4nr05135a10.1039/c4nr05135a ↗
18. Jeon J-W, Sharma R, Meduri P et al (2014) In situ one-step synthesis of hierarchical nitrogen-doped porous carbon for high-performance supercapacitors. ACS Appl Mater Interfaces 6:7214. doi: 10.1021/am500339x10.1021/am500339x ↗
19. Torad NL, Salunkhe RR, Li Y et al (2014) Electric double-layer capacitors based on highly graphitized nanoporous carbons derived from ZIF-67. Chem Eur J 20:7895. doi: 10.1002/chem.20140008910.1002/chem.201400089 ↗
20. Sevilla M, Mokaya R (2014) Energy storage applications of activated carbons: supercapacitors and hydrogen storage. Energy Environ Sci 7:1250. doi: 10.1039/c3ee43525c10.1039/c3ee43525c ↗
21. Xi K, Cao S, Peng X, Ducati C, Kumar RV, Cheetham AK (2013) Carbon with hierarchical pores from carbonized metal-organic frameworks for lithium sulphur batteries. Chem Commun 49:2192. doi: 10.1039/c3cc38009b10.1039/c3cc38009b ↗
22. Yan X, Li X, Yan Z, Komarneni S (2014) Porous carbons prepared by direct carbonization of MOFs for supercapacitors. Appl Surface Sci 308:306. doi: 10.1016/j.apsusc.2014.04.16010.1016/j.apsusc.2014.04.160 ↗
23. Zhang Y-Z, Wang Y, Xie Y-L et al (2014) Porous hollow Co3O4 with rhombic dodecahedral structures for high-performance supercapacitors. Nanoscale 6:14354. doi: 10.1039/C4NR04782F10.1039/C4NR04782F ↗
24. Hou L, Lian L, Zhang L, Pang G, Yuan C, Zhang X (2015) Self-sacrifice template fabrication of hierarchical mesoporous bi-component-active ZnO/ZnFe2O4 sub-microcubes as superior anode towards high-performance lithium-ion battery. Adv Funct Mater 25:238. doi: 10.1002/adfm.20140282710.1002/adfm.201402827 ↗
25. Banerjee PC, Lobo DE, Middag R, Ng WK, Shaibani ME, Majumder M (2015) electrochemical capacitance of Ni-doped metal organic framework and reduced graphene oxide composites: more than the sum of its parts. ACS Appl Mater Interfaces 7:3655. doi: 10.1021/am508119c10.1021/am508119c ↗
26. Peng L, Zhang J, Xue Z, Han B, Li J, Yang G (2013) Large-pore mesoporous Mn3O4 crystals derived from metal-organic frameworks. Chem Commun 49:11695. doi: 10.1039/C3CC46853D10.1039/C3CC46853D ↗
27. Bai Z, Zhang Y, Zhang Y, Guo C, Tang B, Sun D (2015) MOFs-derived porous Mn2O3 as high-performance anode material for Li-ion battery. J Mater Chem A 3:5266. doi: 10.1039/C4TA06292B10.1039/C4TA06292B ↗
28. Khan IA, Badshah A, Nadeem MA, Haider N, Nadeem MA (2014) A copper based metal-organic framework as single source for the synthesis of electrode materials for high-performance supercapacitors and glucose sensing applications. Int J Hydrogen Energy 39:19609. doi: 10.1016/j.ijhydene.2014.09.10610.1016/j.ijhydene.2014.09.106 ↗
29. Ma TY, Dai S, Jaroniec M, Qiao SZ (2014) Metal-organic framework derived hybrid Co3O4-carbon porous nanowire arrays as reversible oxygen evolution electrodes. J Am Chem Soc 136:13925. doi: 10.1021/ja508255310.1021/ja5082553 ↗
30. Xia W, Zou R, An L, Xia D, Guo S (2015) A metal-organic framework route to in situ encapsulation of Co@Co3O4@C core@bishell nanoparticles into a highly ordered porous carbon matrix for oxygen reduction. Energy Environ Sci 8:568. doi: 10.1039/C4EE02281E10.1039/C4EE02281E ↗
31. Liu L, Guo H, Liu J et al (2014) Self-assembled hierarchical yolk-shell structured NiO@C from metal-organic frameworks with outstanding performance for lithium storage. Chem Commun 50:9485. doi: 10.1039/C4CC03807J10.1039/C4CC03807J ↗
32. Meng W, Chen W, Zhao L et al (2014) Porous Fe3O4/carbon composite electrode material prepared from metal-organic framework template and effect of temperature on its capacitance. Nano Energy 8:133. doi: 10.1016/j.nanoen.2014.06.00710.1016/j.nanoen.2014.06.007 ↗
33. Yeager M, Du W, Si R, Su D, Marinković N, Teng X (2012) Highly efficient K0.15MnO2 birnessite nanosheets for stable pseudocapacitive cathodes. J Phys Chem C 116:20173. doi: 10.1021/jp304809r10.1021/jp304809r ↗
34. Tsumura T, Tsumori K, Shimizu G, Toyoda M (2012) Electrochemical properties of spinel-type manganese oxide/porous carbon nanocomposite powders in 1 M KOH aqueous solution. J Phys Chem Solids 73:237. doi: 10.1016/j.jpcs.2011.10.03610.1016/j.jpcs.2011.10.036 ↗
35. Wang K, Shi X, Lu A et al (2015) High nitrogen-doped carbon/Mn3O4 hybrids synthesized from nitrogen-rich coordination polymer particles as supercapacitor electrodes. Dalton Trans 44:151. doi: 10.1039/c4dt02456g10.1039/c4dt02456g ↗
36. Lee HJ, Choi S, Oh M (2014) Well-dispersed hollow porous carbon spheres synthesized by direct pyrolysis of core-shell type metal-organic frameworks and their sorption properties. Chem Commun 50:4492. doi: 10.1039/c4cc00943f10.1039/c4cc00943f ↗
37. H-x Zhong J, Wang Y-w Zhang et al (2014) ZIF-8 derived graphene-based nitrogen-doped porous carbon sheets as highly efficient and durable oxygen reduction electrocatalysts. Angew Chem Int Ed 53:14235. doi: 10.1002/anie.20140899010.1002/anie.201408990 ↗
38. Marcano DC, Kosynkin DV, Berlin JM et al (2010) Improved synthesis of graphene oxide. ACS Nano 4:4806. doi: 10.1021/nn100636810.1021/nn1006368 ↗
39. Li L-J, Li Y (2004) Hydrothermal synthesis and crystal structure of a novel 2-D coordination polymer [Mn2(pdc)2(H2O)3]n2nH2O (pdc = pyridine-2,3-dicarboxylate). J Mol Struct 694:199. doi: 10.1016/j.molstruc.2004.03.02910.1016/j.molstruc.2004.03.029 ↗
40. Gao F, Qu J, Zhao Z, Zhou Q, Li B, Qiu J (2014) A green strategy for the synthesis of graphene supported Mn3O4 nanocomposites from graphitized coal and their supercapacitor application. Carbon 80:640. doi: 10.1016/j.carbon.2014.09.00810.1016/j.carbon.2014.09.008 ↗
41. Jeon JW, Sharma R, Meduri P et al (2014) In situ one-step synthesis of hierarchical nitrogen-doped porous carbon for high-performance supercapacitors. ACS Appl Mater Interfaces 6:7214. doi: 10.1021/am500339x10.1021/am500339x ↗
42. Lee JH, Sa YJ, Kim TK, Moon HR, Joo SH (2014) A transformative route to nanoporous manganese oxides of controlled oxidation states with identical textural properties. J Mater Chem A 2:10435. doi: 10.1039/C4TA01272K10.1039/C4TA01272K ↗
43. Subramani K, Jeyakumar D, Sathish M (2014) Manganese hexacyanoferrate derived Mn3O4 nanocubes-reduced graphene oxide nanocomposites and their charge storage characteristics in supercapacitors. Phys Chem Chem Phys 16:4952. doi: 10.1039/c3cp54788d10.1039/c3cp54788d ↗
44. Cao X, Zheng B, Rui X, Shi W, Yan Q, Zhang H (2014) Metal oxide-coated three-dimensional graphene prepared by the use of metal-organic frameworks as precursors. Angew Chem Int Ed 53:1404. doi: 10.1002/anie.20130801310.1002/anie.201308013 ↗
45. Yang F, Zhao M, Sun Q, Qiao Y (2015) A novel hydrothermal synthesis and characterisation of porous Mn3O4 for supercapacitors with high rate capability. RSC Adv 5:9843. doi: 10.1039/C4RA10175H10.1039/C4RA10175H ↗
46. Xiao Y, Cao Y, Gong Y et al (2014) Electrolyte and composition effects on the performances of asymmetric supercapacitors constructed with Mn3O4 nanoparticles-graphene nanocomposites. J Power Sources 246:926. doi: 10.1016/j.jpowsour.2013.07.11810.1016/j.jpowsour.2013.07.118 ↗
47. Jiangying Q, Feng G, Quan Z et al (2013) Highly atom-economic synthesis of graphene/Mn(3)O(4) hybrid composites for electrochemical supercapacitors. Nanoscale 5:2999. doi: 10.1039/c3nr33700f10.1039/c3nr33700f ↗
48. Dong R, Ye Q, Kuang L et al (2013) Enhanced supercapacitor performance of Mn3O4 nanocrystals by doping transition-metal ions. ACS Appl Mater Interfaces 5:9508. doi: 10.1021/am402257y10.1021/am402257y ↗
49. Gund GS, Dubal DP, Patil BH, Shinde SS, Lokhande CD (2013) Enhanced activity of chemically synthesized hybrid graphene oxide/Mn3O4 composite for high performance supercapacitors. Electrochim Acta 92:205. doi: 10.1016/j.electacta.2012.12.12010.1016/j.electacta.2012.12.120 ↗
50. Li M, Xu W, Wang W, Liu Y, Cui B, Guo X (2014) Facile synthesis of specific FeMnO3 hollow sphere/graphene composites and their superior electrochemical energy storage performances for supercapacitor. J Power Sources 248:465. doi: 10.1016/j.jpowsour.2013.09.07510.1016/j.jpowsour.2013.09.075 ↗
51. Yang F, Zhao M, Sun Q, Qiao Y (2015) A novel hydrothermal synthesis and characterisation of porous Mn3O4 for supercapacitors with high rate capability. RSC Adv 5:9843. doi: 10.1039/C4RA10175H10.1039/C4RA10175H ↗
52. Wang K, Ma X, Zhang Z, Zheng M, Geng Z, Wang Z (2013) Indirect transformation of coordination-polymer particles into magnetic carbon-coated Mn3O4 (Mn3O4@C) nanowires for supercapacitor electrodes with good cycling performance. Chem Eur J 19:7084. doi: 10.1002/chem.20130018810.1002/chem.201300188 ↗
53. Liu Y, Wang W, Wang Y, Ying Y, Sun L, Peng X (2014) Binder-free three-dimensional porous Mn3O4 nanorods/reduced graphene oxide paper-like electrodes for electrochemical energy storage. RSC Adv 4:16374. doi: 10.1039/c4ra01395f10.1039/c4ra01395f ↗