Effect of MoO3, Nd2O3, and RuO2 on the crystallization of soda–lime aluminoborosilicate glasses
Source abstract
Abstract
The effect of adding Nd2O3, MoO3, and RuO2 separately or simultaneously on the crystallization of a soda-lime aluminoborosilicate glass during cooling from the melt or glass heating was studied by DTA, XRD (at room and high temperature), SEM, Raman, and optical absorption. Nd2O3 addition strongly reduces liquid-liquid phase separation and crystallization of calcium and sodium molybdates (CaMoO4 (powellite) and Na2MoO4) in Mo- rich compositions as long as Nd 3? ions remain solubilized in the glassy network. This suggests that (MoO4) 2- entities and Nd 3? ions are close to each other in the glass structure (Nd 3? ions would prevent the clustering of molybdate entities). The effect of MoO3 addition in Nd-rich compo- sitions is more complex since an increase of the solubility of Nd2O3 is observed, whereas the nucleation rate of an Nd-rich silicate apatite (Ca2Nd8(SiO4)6O2) in the bulk of the glass increases as soon as molybdates crystallized. The addition of RuO2 has a nucleating effect on apatite crys- tallization in the bulk but not on molybdates crystallization.
Source: openaire · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Glass properties and applications · Luminescence Properties of Advanced Materials · Nuclear materials and radiation effects
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (94)
Show source-provided references
1. Caurant D, Loiseau P, Majérus O, Aubin-Chevaldonnet V, Bardez I, Quintas A (2009) Glasses, glass–ceramics and ceramics for immobilization of highly radioactive nuclear wastes. Nova Science Publishers, New York
2. Gras JM, Do Quang R, Masson H, Lieven T, Ferry C, Poinssot C, Debes M, Delbecq JM (2007) Perspectives on the closed fuel cycle: implications for high-level waste matrices. J Nucl Mater 362:383–39410.1016/j.jnucmat.2007.01.210 ↗
3. Grambow B (2006) Nuclear waste glasses. How durable? Elements 2:357–36410.2113/gselements.2.6.357 ↗
4. Chauvin E, Ladirat C, Do Quang R (2009) French industrial vitrification plant: 30 years old and still innovating. Mater Res Soc Symp Proc 1193:249–25710.1557/PROC-1193-249 ↗
5. Peuget S, Cachia JN, Jegou C, Deschanels X, Roudil D, Broudic V, Delaye JM, Bart JM (2006) Irradiation stability of R7T7-type borosilicate glass. J Nucl Mater 354:1–1310.1016/j.jnucmat.2006.01.021 ↗
6. Donald IW (2010) Waste Immobilization in Glass and Ceramic Based Hosts. Radioactive, Toxic and Hazardous Wastes. Wiley, Chichester10.1002/9781444319354 ↗
7. Ojovan MI (2011) Handbook of advanced radioactive waste conditioning technologies. Woodhead Publishing Limited, Cambridge10.1533/9780857090959 ↗
8. Ojovan MI, Lee WE (2007) New developments in glassy nuclear wasteforms. Nova Science Publishers, New York
9. Ojovan MI, Lee WE (2011) Glassy wasteforms for nuclear waste immobilization. Metall Mater Trans A 42:837–85110.1007/s11661-010-0525-7 ↗
10. Brookes C, Harrison M, Riley A, Steele C (2010) The effect of increased waste loading on the durability of high level waste glass. Mater Res Symp Proc 1265:109–11410.1557/PROC-1265-AA03-05 ↗
11. Vienna JD (2010) Nuclear waste vitrification in the United States: recent developments and future options. Int J Appl Glass Sci 1:309–32110.1111/j.2041-1294.2010.00023.x ↗
12. Crum JV, Turo L, Riley B, Tang M, Kossoy A (2012) Multi-phase glass–ceramics as a waste form for combined fission products: alkalis, alkaline earths, lanthanides, and transition metals. J Am Ceram Soc 95:1297–130310.1111/j.1551-2916.2012.05089.x ↗
13. Dussossoy JL, Schuller S, Advocat T (2007) The formulation of new high level waste glasses with an increased waste loading charges. In: Extended abstracts of the international congress on glass (CD-ROM), Strasbourg
14. Guillaumont R (2004) Éléments chimiques à considérer dans l’aval du cycle nucléaire. C R Chim 7:1129–113410.1016/j.crci.2003.09.014 ↗
15. Bardez I, Caurant D, Dussossoy JL, Loiseau P, Gervais C, Ribot F, Neuville DR, Baffier N, Fillet C (2006) Development and characterization of rare earth-rich glassy matrices envisaged for the immobilization of concentrated nuclear waste solutions. Nucl Sci Eng 153:272–28410.13182/NSE06-A2613 ↗
16. Bardez I, Caurant D, Loiseau P, Dussossoy JL, Gervais C, Ribot F, Neuville DR, Baffier N (2005) Structural characterization of rare earth rich glasses for nuclear waste immobilization. Phys Chem Glasses 46:320–329
17. Pinet O, Dussossoy JL, David C, Fillet C (2008) Glass matrices for immobilizing nuclear waste containing molybdenum and phosphorus. J Nucl Mater 377:307–31210.1016/j.jnucmat.2007.11.013 ↗
18. Dunnett BF, Gribble NR, Short R, Turner E, Steele CJ, Riley AD (2012) Vitrification of high molybdenum waste. Glass Technol Eur J Glass Sci Technol A 53:166–171
19. Dunnett BF, Gribble NR, Riley AD, Steele CJ (2009) Initial investigation into the vitrification of high molybdenum solids in borosilicate glass. Mater Res Soc Symp Proc 1193:291–29710.1557/PROC-1193-291 ↗
20. Short RJ, Turner E, Dunnett BF, Riley A (2008) Devitrified and phase separated material found in simulated high level nuclear waste glasses containing Ca and Zn additions. Mater Res Soc Symp Proc 1107:261–26710.1557/PROC-1107-261 ↗
21. Boucetta H, Podor R, Stievano L, Ravaux J, Carrier X, Casale S, Gossé S, Monteiro A, Schuller S (2012) Mechanism of RuO2 crystallization in borosilicate glass: an original in situ ESEM approach. Inorg Chem 51:3478–348910.1021/ic202156y ↗
22. Akai T, Nishii J, Yamashita M, Yamanaka H (1997) Chemical behavior of platinum-group metals in oxide glasses. J Non-Cryst Solids 222:304–30910.1016/S0022-3093(97)90128-9 ↗
23. Demin AV, Fedorova MI, Matyunin YI (1996) Localization of platinum-group elements and technetium and the solidification of high-level liquid wastes. Atom Energy 80:178–18110.1007/BF02414804 ↗
24. Caurant D, Majérus O, Fadel E, Lenoir M, Gervais C, Pinet O (2007) Effect of molybdenum on the structure and on the crystallization of SiO2–B2O3–Na2O–CaO glasses. J Am Ceram Soc 90:774–78310.1111/j.1551-2916.2006.01467.x ↗
25. Majérus O, Caurant D, Quintas A, Dussossoy J-L, Bardez I, Loiseau P (2011) Effect of boron oxide addition on the Nd3+ cations environment in a Nd-rich soda–lime aluminoborosilicate glass. J Non-Cryst Solids 357:2744–275110.1016/j.jnoncrysol.2011.02.018 ↗
26. Rose PB, Woodward DI, Ojovan MI, Hyatt NC, Lee WE (2011) Crystallisation of a simulated borosilicate high-level waste glass produced on a full-scale vitrification line. J Non-Cryst Solids 357:2989–300110.1016/j.jnoncrysol.2011.04.003 ↗
27. Magnin M, Schuller S, Caurant D, Majérus O, de Ligny D, Mercier C (2009) Effect of compositional changes on the structure and crystallization tendency of a borosilicate glass containing MoO3. Ceram Trans 207:59–6810.1002/9780470538371.ch7 ↗
28. Schuller S, Pinet O, Penelon B (2011) Liquid–liquid phase separation process in borosilicate liquids enriched in molybdenum and phosphorus oxides. J Am Ceram Soc 94:447–45410.1111/j.1551-2916.2010.04131.x ↗
29. Cousi C, Bart F, Phalippou J (2004) Phase separation and crystallisation induced by adding molybdenum and phosphorus to a soda–lime–silica glass. Eur J Glass Sci Technol A 45:65–67
30. Caurant D, Majérus O, Fadel E, Quintas A, Gervais C, Charpentier T, Neuville DR (2010) Structural investigations of borosilicate glasses containing MoO3 by MAS NMR and Raman spectroscopies. J Nucl Mater 396:94–10110.1016/j.jnucmat.2009.10.059 ↗
31. Greer BJ, Kroeker S (2012) Characterisation of heterogeneous molybdate and chromate phase assemblages in model nuclear waste glasses by multinuclear magnetic resonance spectroscopy. Phys Chem Chem Phys 14:7375–738310.1039/c2cp40764g ↗
32. Kroeker S, Higman C, Michaelis VK, Svenda NB, Schuller S (2010) Precipitation of mixed-alkali molybdates during HLW vitrification. Mater Res Soc Symp Proc 1265:95–10110.1557/PROC-1265-AA03-03 ↗
33. Magnin M, Schuller S, Mercier C, Trebosc J, Caurant D, Majerus O, Angeli F, Charpentier T (2011) Modification of molybdenum structural environment in borosilicate glasses with increasing content of boron and calcium oxide by 95Mo MAS NMR. J Am Ceram Soc 94:4274–428210.1111/j.1551-2916.2011.04919.x ↗
34. Brinkman K, Fox K, Marra J, Reppert J, Crum J, Tang M (2013) Single phase melt processed powellite (Ba, Ca)MoO4 for the immobilization of Mo-rich nuclear waste. J Alloys Compd 551:136–414210.1016/j.jallcom.2012.09.049 ↗
35. Taurines T, Boizot B (2012) Microstructure of powellite-rich glass–ceramics: a model system for high level waste immobilization. J Am Ceram Soc 95:1105–111110.1111/j.1551-2916.2011.05015.x ↗
36. Mendoza C, Panczer G, de Ligny D, Bardez-Giboire I, Schuller S, Peuget S (2010) CaMoO4 in a molybdenum rich borosilicate glass–ceramic: a spectroscopic study. Ceram Trans 217:43–5510.1002/9780470909874.ch6 ↗
37. Ojovan MI, Juoi JM, Lee WE (2008) Application of glass composite materials for nuclear waste immobilization. J Pak Mater Soc 2:72–76
38. Ojovan MI, Juoi JM, Boccaccini AR, Lee WE (2008) Glass composite materials for nuclear and hazardous waste immobilization. Mater Res Soc Symp Proc 1107:245–25210.1557/PROC-1107-245 ↗
39. Kossoy A, Schulze R, Tang M, Safarik DJ, McCabe RJ (2013) Nd-Mo-borosilicate glass–ceramic: synthesis, characterization and response to ionizing radiation. J Nucl Mater 437:216–22110.1016/j.jnucmat.2013.02.038 ↗
40. Quintas A, Charpentier T, Majérus O, Caurant D, Dussossoy JL (2007) NMR study of a rare-earth rich aluminoborosilicate glass with varying CaO/Na2O ratio. Appl Magn Reson 32:613–63410.1007/s00723-007-0041-0 ↗
41. Quintas A, Majérus O, Caurant D, Dussossoy JL, Vermaut P (2007) Crystallization of a rare-earth rich aluminoborosilicate glass with varying CaO/Na2O ratio. J Am Ceram Soc 90:712–71910.1111/j.1551-2916.2006.01455.x ↗
42. Quintas A, Caurant D, Majérus O, Dussossoy JL, Charpentier T (2008) Effect of changing the rare earth cation type on the structure and crystallization behavior of an aluminoborosilicate glass. Phys Chem Glasses 49:192–197
43. Quintas A, Caurant D, Majérus O, Charpentier T, Dussossoy JL (2009) Effect of compositional variations on charge compensation of AlO4 and BO4 entities and on crystallization tendency of a rare-earth-rich aluminoborosilicate glass. Mater Res Bull 44:1895–189810.1016/j.materresbull.2009.05.009 ↗
44. Kidari A, Dussossoy JL, Brackx E, Caurant D, Magnin M, Bardez-Giboire I (2012) Lanthanum and neodymium solubility in simplified SiO2–B2O3–Na2O–Al2O3–CaO high level waste glass. J Am Ceram Soc 95:2537–254410.1111/j.1551-2916.2012.05273.x ↗
45. Kidari A, Magnin M, Caraballo R, Tribet M, Doreau F, Peuget S, Dussossoy JL, Bardez-Giboire I, Jegou C (2012) Solubility and partitioning of minor-actinides and lanthanides in alumino-borosilicate nuclear glass. Proc. Chem 7:554–55810.1016/j.proche.2012.10.084 ↗
46. Weber WJ (1983) Radiation-induced swelling and amorphization in Ca2Nd8(SiO4)6O2. Radiat Effects 77:295–30810.1080/00337578308228193 ↗
47. Wald JW, Weber WJ (1984) Effects of self-radiation damage one the leachability of actinide-host phases. Adv Ceram Nucl Waste Manag 8:71–75
48. Weber WJ (1993) Alpha-decay induced amorphization in complex silicate structures. J Am Ceram Soc 76:1729–173810.1111/j.1151-2916.1993.tb06641.x ↗
49. Weber WJ, Ewing RC, Catlow CRA, Diaz de La Rubia T, Hobbs LW, Kinoshita C, Matzke Hj, Motta AT, Nastasi MA, Salje EHK, Vance ER, Zinkle SJ (1998) Radiation effects in crystalline ceramics for the immobilization of high-level nuclear waste and plutonium. J Mater Res 13:1434–148410.1557/JMR.1998.0205 ↗
50. Swain MV (1980) A fracture mechanics description of the microcracking about NiS inclusions in glass. J Non-Cryst Solids 38–39:451–45610.1016/0022-3093(80)90460-3 ↗
51. Serbena FC, Zanotto ED (2012) Internal residual stresses in glass–ceramics: a review. J Non-Cryst Solids 358:975–98410.1016/j.jnoncrysol.2012.01.040 ↗
52. Orlhac X (1999) Etude de la stabilité thermique du verre nucléaire. Modélisation de son évolution à long terme. Ph.D. thesis of the University of Montpellier 2
53. Pacaud F, Fillet C, Jacquet-Francillon N (1992) Effect of platinoids on French LWR reference glass properties. Mater Res Soc Symp Proc 257:161–16710.1557/PROC-257-161 ↗
54. Mitamura H, Murakami T, Banba T (1985) Crystalline phases in a devitrified simulated high-level waste glass containing the elements of the platinum group. J Nucl Mater 136:104–11610.1016/0022-3115(85)90036-4 ↗
55. Pflieger R, Lefebvre L, Malki M, Allix M, Grandjean A (2009) Behaviour of ruthenium dioxide particles in borosilicate glasses and melts. J Nucl Mater 389:450–45710.1016/j.jnucmat.2009.02.034 ↗
56. Igarashi H, Kawamura K, Takahashi T (1992) Effect of noble metal elements on viscosity and electrical resistivity of simulated vitrified products for high-level liquid waste. Mater Res Soc Symp Proc 257:169–17610.1557/PROC-257-169 ↗
57. Kelm M, Oser B (1992) The platinum metals in HLLW: glass products. Mater Res Soc Symp Proc 257:177–18210.1557/PROC-257-177 ↗
58. Lutze W, Gong W, Perez-Cardenas FC, Matlack KS, Pegg IL, Schill P (2007) Testing and modelling the behaviour of platinoids during vitrification of high level radioactive waste. Part 1. Glass Technol 48:263–275
59. Krause C, Luckscheiter B (1991) Properties and behavior of the platinum group metals in the glass resulting from the vitrification of simulated nuclear fuel reprocessing waste. J Mater Res 6:2535–254610.1557/JMR.1991.2535 ↗
60. Simonnet C, Grandjean A, Phalippou J (2005) Electrical behavior of platinum-group metals in glass-forming oxide melts. J Nucl Mater 336:243–35010.1016/j.jnucmat.2004.09.019 ↗
61. Pinet O, Mure S (2009) Redox behavior of platinum-group metals in nuclear glass. J Non-Cryst Solids 355:221–22710.1016/j.jnoncrysol.2008.11.002 ↗
62. Caurant D, Majérus O, Loiseau P, Bardez I, Baffier N, Dussossoy JL (2006) Crystallization of neodymium-rich phases in silicate glasses developed for nuclear waste immobilization. J Nucl Mater 354:143–16210.1016/j.jnucmat.2006.03.014 ↗
63. Chouard N, Caurant D, Majérus O, Dussossoy JL, Ledieu A, Peuget S, Baddour-Hadjean R, Pereira-Ramos JP (2011) Crystallization and structural study of a MoO3-rich aluminoborosilicate glass with increasing Nd2O3 content. J Non-Cryst Solids 357:2752–276210.1016/j.jnoncrysol.2011.02.015 ↗
64. Chouard N, Caurant D, Majérus O, Dussosoy JL, Ledieu A, Klimin S, Pytalev D (2010) Effect of molybdenum and ruthenium on the crystallization tendency of a new nuclear glass containing high rare-earth concentrations. Mater Res Soc Symp Proc 1265:115–120
65. Cobb WT, Hrma P (1991) Behavior of RuO2 in a glass melt. Ceram Trans 23:233–237
66. Sundaram SK, Perez JM (2000) Noble metals and spinel settling in high level waste glass melters. Report PNNL-13347
67. Hrma P (2010) Crystallization during processing of nuclear waste glass. J Non-Cryst Solids 356:3019–302510.1016/j.jnoncrysol.2010.03.039 ↗
68. Long DA (1977) Raman spectroscopy. McGraw-Hill, New-York, p 276
69. Toumi M, Smiri-Dogguy L, Bulou A (2002) Structure cristalline et spectres Raman polarises de Na1.5Sm8.5(SiO4)6FO. Ann Chim Sci Mater 27:17–2610.1016/S0151-9107(02)80028-9 ↗
70. Rodriguez-Reyna E, Fuentes AF, Maczka M, Hanuza J, Boulahya K, Amador U (2006) Structural, microstructural and vibrational characterization of apatite-type lanthanum silicates prepared by mechanical milling. J Solid State Chem 179:522–53110.1016/j.jssc.2005.11.008 ↗
71. Hardcastle FD, Wachs IE (1990) Determination of molybdenum–oxygen bond distances and bond orders by Raman spectroscopy. J Raman Spectrosc 21:683–69110.1002/jrs.1250211009 ↗
72. Sarantopoulou E, Raptis C, Ves S, Christofilos D, Kourouklis GA (2002) Temperature and pressure dependence of Raman-active phonons of CaMoO4: an anharmonicity study. J Phys: Condens Matter 14:8925–8938
73. Porto SPS, Scott JF (1967) Raman spectra of CaWO4, SrWO4, CaMoO4 and SrMoO4. Phys Rev 157:716–71910.1103/PhysRev.157.716 ↗
74. Christofilos D, Kourouklis GA, Ves S (1995) A high pressure Raman study of calcium molybdate. J Phys Chem Solids 56:1125–112910.1016/0022-3697(95)00034-8 ↗
75. Mahadevan Pillai VP, Prodeep T, Bushiri MJ (1997) Vibrational spectroscopic studies of FeClMoO4, Na2MoO4 and Na2MoO4 2H2O/D2O. Spectrochim Acta Part A 53:867–87610.1016/S1386-1425(96)01853-7 ↗
76. Pope SJA, West YD (1995) Use of the FT Raman spectrum of Na2MoO4 to study sample heating by the laser. Spectrochim Acta Part A 51:2011–201710.1016/0584-8539(95)01470-X ↗
77. Luz-Lima C, Saraiva GD, Filho Souza AG, Paraguassu W, Freire PTC, Mendes Filho J (2010) Raman spectroscopy study of Na2MoO4 2H2O and Na2MoO4 under hydrostatic pressure. J Raman Spectrosc 41:576–58110.1002/jrs.2468 ↗
78. Bramnik KG, Ehrenberg H (2004) Study of the Na2O–MoO3 system. Na6Mo11O36: a new oxide with anatase-related structure, and the crystal structures of Na2MoO4. Z Anorg Allg Chem 630:1336–134010.1002/zaac.200400119 ↗
79. Felsche J (1972) Rare earth silicates with the apatite structure. J Solid State Chem 5:266–27510.1016/0022-4596(72)90039-4 ↗
80. Zhao D, Li L, Davis LL, Weber WJ, Ewing RC (2001) Gadolinium borosilicate glass-bonded Gd-silicate apatite: a glass–ceramic nuclear waste form for actinides. Mater Res Soc Symp Proc 663:199–20610.1557/PROC-663-199 ↗
81. Chouard N (2011) PhD Thesis, University of Paris VI. http://pastel.archives-ouvertes.fr/pastel-00644194 . Accessed 12 Dec 2011
82. Magnin M, Schuller S, Caurant D, Majérus O, de Ligny D, Advocat T (2008) Phase separation and crystallization in soda–lime borosilicate glass enriched in MoO3. In: Proceedings of 3rd Atalante international conference: nuclear fuel cycles for a sustainable future, Montpellier. http://hal.archives-ouvertes.fr/hal-00994577 . Accessed 22 May 2014
83. Magnin M (2009) PhD Thesis, University of Paris VI
84. Cormier L, Majérus O, Neuville DR, Calas G (2006) Temperature-induced structural modifications between alkali borate glasses and melts. J Am Ceram Soc 89:13–1910.1111/j.1551-2916.2005.00657.x ↗
85. Calas G, Le Grand M, Galoisy L, Ghaleb D (2003) Structural role of molybdenum in nuclear glasses: an EXAFS study. J Nucl Mater 322:15–2010.1016/S0022-3115(03)00277-0 ↗
86. Trapp HLV, Stevels JM (1959) Physical properties of invert glasses. Glastech Ber 32:32–52
87. Lucas J (1989) Fluoride glasses. J Mater Sci 24:1–13. doi: 10.1007/bf0066092610.1007/BF00660926 ↗
88. Wang WH, Dong C, Shek CH (2004) Bulk metallic glasses. Mater Sci Eng R Rep 44:45–8910.1016/j.mser.2004.03.001 ↗
89. Mysen BO, Richet P (2005) Silicate glasses and melts. Elsevier, Amsterdam
90. Deschamps T, Ollier N, Vezin H, Gonnet C (2012) Clusters dissolution of Yb3+ in codoped SiO2–Al2O3–P2O5 glass fiber and its relevance to photodarkening. J Chem Phys 136:014503-1–014503-410.1063/1.3673792 ↗
91. Kashchieva E, Petrov I, Aleksandrov L, Iordanova R, Dimitriev Y (2012) Microstructure of multicomponent borosilicate glasses containing MoO3. Phys Chem Glasses: Eur J Glass Sci Technol B 53:264–270
92. Henry N, Deniard P, Jobic S, Brec R, Fillet C, Bart F, Grandjean A, Pinet O (2004) Heat treatments versus microstructure in a molybdenum-rich borosilicate. J Non-Cryst Solids 333:199–20510.1016/j.jnoncrysol.2003.09.055 ↗
93. Schleid T, Hartenbach I (2011) Sheelite-type sodium neodymium(III) ortho-oximolybdate(VI) NaNd[MoO4]2. Acta Cryst E 67:i7110.1107/S1600536811046976 ↗
94. de Ligny D, Panczer G, Caurant D, Neuville DR (2008) Contribution of neodymium luminescence to the crystal growth study of a silicate apatite in a glassy matrix. Opt Mater 30:1694–169810.1016/j.optmat.2007.07.008 ↗