Ni supported on YSZ: XAS and XPS characterization and catalytic activity for CO2 methanation
Source abstract
Abstract
Ni supported on yttrium-stabilized zirconium oxide catalysts have been prepared by electroless plating method. Structure, electronic and chemical state of Ni as a function of Ni content (1, 7 and 12 wt%) have been characterized combining X-ray diffraction, X-ray absorption spectroscopy, X-ray photoelectron spectroscopy, temperature-programmed reduction (H2-TPR) and BET. The catalytic activity for the CO2 methanation was studied in the 250–500 °C temperature range, finding the highest CO2 conversion and CH4 selectivity for the catalyst with the largest Ni loading. A dependence of activity and CH4 selectivity on Ni crystallites size was highlighted.
Source: openaire · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Catalytic Processes in Materials Science · Catalysts for Methane Reforming · CO2 Reduction Techniques and Catalysts
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References (35)
Show source-provided references
1. Reiter G, Lindorfer J (2015) Evaluating CO2 sources for power-to-gas applications: a case study for Austria. J CO2 Util 10:40–4910.1016/j.jcou.2015.03.003 ↗
2. Schiebahn S, Grube T, Robinius M, Tietze V, Kumar B, Stolten D (2015) Power to gas: technological overview, systems analysis and economic assessment for a case study in Germany. Int J Hydrogen Energy 40:4285–429410.1016/j.ijhydene.2015.01.123 ↗
3. Gahleitner G (2013) Hydrogen from renewable electricity: an international review of power-to-gas pilot plants for stationary applications. Int J Hydrogen Energy 38:2039–206110.1016/j.ijhydene.2012.12.010 ↗
4. Rönsch S, Schneider J, Matthischke S, Schlüter M, Götz M, Lefebvre J, Prabhakaran P, Bajohr S (2016) Review on methanation—from fundamentals to current projects. Fuel 166:276–29610.1016/j.fuel.2015.10.111 ↗
5. Meylan FD, Moreau V, Erkman S (2016) Material constraints related to storage of future European renewable electricity surpluses with CO2 methanation. Energy Policy 94:366–37610.1016/j.enpol.2016.04.012 ↗
6. Aziz MAA, Jalil AA, Triwahyono S, Ahmad A (2015) CO2 methanation over heterogeneous catalysts: recent progress and future prospects. Green Chem 17:2647–266310.1039/C5GC00119F ↗
7. Aziz MAA, Jalil AA, Triwahyono S, Mukti RR, Taufiq-Yap YH, Sazegar MR (2014) Highly active Ni-promoted mesostructured silica nanoparticles for CO2 methanation. Appl Catal B 147:359–36810.1016/j.apcatb.2013.09.015 ↗
8. Westermann A, Azambre B, Bacariza MC, Graça I, Ribeiro MF, Lopes JM, Henriques C (2015) Insight into CO2 methanation mechanism over NiUSY zeolites: an operando IR study. Appl Catal B 174–175:120–12510.1016/j.apcatb.2015.02.026 ↗
9. Takano H, Kirihata Y, Izumiya K, Kumagai N, Habazaki H, Hashimoto K (2016) Highly active Ni/Y-doped ZrO2 catalysts for CO2 methanation. Appl Surf Sci 388:653–66310.1016/j.apsusc.2015.11.187 ↗
10. da Silva DCD, Letichevsky S, Borges LEP, Appel LG (2012) The Ni/ZrO2 catalyst and the methanation of CO and CO2. Int J Hydrogen Energy 37:8923–892810.1016/j.ijhydene.2012.03.020 ↗
11. Tada S, Shimizu T, Kameyama H, Haneda T, Kikuchi R (2012) Ni/CeO2 catalysts with high CO2 methanation activity and high CH4 selectivity at low temperatures. Int J Hydrogen Energy 37:5527–553110.1016/j.ijhydene.2011.12.122 ↗
12. Kwak JH, Kovarik L, Szanyi J (2013) CO2 reduction on supported Ru/Al2O3 catalysts: cluster size dependence of product selectivity. ACS Catal 3:2449–245510.1021/cs400381f ↗
13. Kwak JH, Kovarik L, Szanyi J (2013) Heterogeneous catalysis on atomically dispersed supported metals: CO2 reduction on multifunctional Pd catalysts. ACS Catal 3:2094–210010.1021/cs4001392 ↗
14. Ocampo F, Louis B, Kiwi-Minsker L, Roger A-C (2011) Effect of Ce/Zr composition and noble metal promotion on nickel based CexZr1−xO2 catalysts for carbon dioxide methanation. Appl Catal A 392:36–4410.1016/j.apcata.2010.10.025 ↗
15. Mutz B, Carvalho HWP, Mangold S, Kleist W, Grunwaldt J-D (2015) Methanation of CO2: structural response of a Ni-based catalyst under fluctuating reaction conditions unraveled by operando spectroscopy. J Catal 327:48–5310.1016/j.jcat.2015.04.006 ↗
16. He S, Li C, Chen H, Su D, Zhang B, Cao X, Wang B, Wei M, Evans DG, Duan X (2013) A surface defect-promoted Ni nanocatalyst with simultaneously enhanced activity and stability. Chem Mater 25:1040–104610.1021/cm303517z ↗
17. Campelo JM, Luna D, Luque R, Marinas JM, Romero AA (2009) Sustainable preparation of supported metal nanoparticles and their applications in catalysis. Chemsuschem 2:18–4510.1002/cssc.200800227 ↗
18. Behrens M (2015) Coprecipitation: an excellent tool for the synthesis of supported metal catalysts—from the understanding of the well known recipes to new materials. Catal Today 246:46–5410.1016/j.cattod.2014.07.050 ↗
19. Tao K, Zhou S, Zhang Q, Kong C, Ma Q, Tsubaki N, Chen L (2013) Sol–gel auto-combustion synthesis of Ni–CexZr1−xO2 catalysts for carbon dioxide reforming of methane. RSC Adv 3:2228510.1039/c3ra42522c ↗
20. Wu Z, Ge S, Zhang M, Li W, Tao K (2009) Synthesis of nickel nanoparticles supported on metal oxides using electroless plating: controlling the dispersion and size of nickel nanoparticles. J Colloid Interface Sci 330:359–36610.1016/j.jcis.2008.10.083 ↗
21. Wu Z, Chen J, Di Q, Zhang M (2012) Size-controlled synthesis of a supported Ni nanoparticle catalyst for selective hydrogenation of p-nitrophenol to p-aminophenol. Catal Commun 18:55–5910.1016/j.catcom.2011.11.015 ↗
22. Hwang BJ (1995) Reaction mechanism of electroless deposition: observations of morphology evolution during nucleation and growth via tapping mode AFM. J Electrochem Soc 142:374910.1149/1.2048408 ↗
23. Wang TC, Chen B, Rubner MF, Cohen RE (2001) Selective electroless nickel plating on polyelectrolyte multilayer platforms. Langmuir 17:6610–661510.1021/la010755z ↗
24. Meneghini C, Bardelli F, Mobilio S (2012) ESTRA-FitEXA: a software package for EXAFS data analysis. Nucl Instrum Methods Phys Res, Sect B 285:153–15710.1016/j.nimb.2012.05.027 ↗
25. Mobilio S, Boscherini F, Meneghini C (eds) (2015) Synchrotron radiation: basics, methods and applications. Springer, Berlin
26. Battocchio C, Fratoddi I, Fontana L, Bodo E, Porcaro F, Meneghini C, Pis I, Nappini S, Mobilio S, Russo MV, Polzonetti G (2014) Silver nanoparticles linked by a Pt-containing organometallic dithiol bridge: study of local structure and interface by XAFS and SR-XPS. Phys Chem Chem Phys 16:11719–1172810.1039/c4cp01264j ↗
27. Battocchio C, Fratoddi I, Fontana L, Bodo E, Porcaro F, Meneghini C, Pis I, Nappini S, Mobilio S, Russo MV, Polzonetti G (2014) Silver nanoparticles linked by a Pt-containing organometallic dithiol bridge: study of local structure and interface by XAFS and SR-XPS. Phys Chem Chem Phys 16:1171910.1039/c4cp01264j ↗
28. Bergeret G, Gallezot P (2008) Particle size and dispersion measurements. In: Ertl G, Knözinger H, Schüth F, Weitkamp J (eds) Handbook of heterogeneous catalysis. Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim, Germany
29. Rodriguez JA, Hanson JC, Frenkel AI, Kim JY, Pérez M (2002) Experimental and theoretical studies on the reaction of H2 with NiO: role of O vacancies and mechanism for oxide reduction. J Am Chem Soc 124:346–35410.1021/ja0121080 ↗
30. Wei Y-L, Lin Y-Y, Yang J-Q, Wang HP, Hsiung T-L (2007) Effect of plasma treatment on Ni molecular environment in a spent catalyst and a plating sludge. J Electron Spectrosc Relat Phenom 156–158:232–23510.1016/j.elspec.2006.12.026 ↗
31. Bellido JDA, Assaf EM (2009) Effect of the Y2O3–ZrO2 support composition on nickel catalyst evaluated in dry reforming of methane. Appl Catal A 352:179–18710.1016/j.apcata.2008.10.002 ↗
32. Mori H (2003) Investigation of the interaction between NiO and yttria-stabilized zirconia (YSZ) in the NiO/YSZ composite by temperature-programmed reduction technique. Appl Catal A 245:79–8510.1016/S0926-860X(02)00634-8 ↗
33. Aldana PAU, Ocampo F, Kobl K, Louis B, Thibault-Starzyk F, Daturi M, Bazin P, Thomas S, Roger AC (2013) Catalytic CO2 valorization into CH4 on Ni-based ceria-zirconia. Reaction mechanism by operando IR spectroscopy. Catal Today 215:201–20710.1016/j.cattod.2013.02.019 ↗
34. Wu HC, Chang YC, Wu JH, Lin JH, Lin IK, Chen CS (2015) Methanation of CO2 and reverse water gas shift reactions on Ni/SiO2 catalysts: the influence of particle size on selectivity and reaction pathway. Catal Sci Technol 5:4154–416310.1039/C5CY00667H ↗
35. Wang X, Shi H, Kwak JH, Szanyi J (2015) Mechanism of CO2 hydrogenation on Pd/Al2O3 catalysts: kinetics and transient DRIFTS-MS studies. ACS Catal 5:6337–634910.1021/acscatal.5b01464 ↗