Bimetallic Fe/Co-MOFs for tetracycline elimination
Source abstract
Abstract
Fe/Co metal–organic frameworks (Fe/Co-MOFs) were synthesized by a solvothermal method using terephthalic acid (BDC) and N,N-dimethylformamide (DMF), and the removal of tetracycline (TC) was accomplished with high efficiency. We explored the influence of Co content on the characteristics of the bimetallic MOFs. The structures of the Fe/Co-MOFs were characterized by X-ray diffraction, scanning electron microscopy, Fourier transform infrared spectroscopy (FTIR), and nitrogen physisorption analysis. The results showed that Co2+ was well loaded in the Fe-MOFs. Due to the different coordination behaviors of Co2+ and Fe3+ with BDC, the Fe/Co-MOFs formed a new 3D structure with a spike ball-like morphology. The morphology changed dramatically, leading to a large specific surface area, and the activity of the Lewis acid sites was greatly enhanced. Through FTIR and XPS analysis before and after adsorption, the adsorption process was mainly affected by coordination action. The largest TC adsorption capacity was observed when the Fe/Co ratio was equal to 1:3, and the saturated adsorption capacity was 139.8 mg g−1.
Source: openaire · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Metal-Organic Frameworks: Synthesis and Applications · Adsorption and biosorption for pollutant removal · Advanced Photocatalysis Techniques
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (41)
Show source-provided references
1. Zhu K, Shen Y, Hou J, Gao J, He D, Huang J, He H, Lei L et al (2021) One-step synthesis of nitrogen and sulfur co-doped mesoporous graphite-like carbon nanosheets as a bifunctional material for tetracycline removal via adsorption and catalytic degradation processes: Performance and mechanism. Chem Eng J 412:128521. https://doi.org/10.1016/j.cej.2021.12852110.1016/j.cej.2021.128521 ↗
2. Ens W, Senner F, Gygax B, Schlotterbeck G (2014) Development, validation, and application of a novel LC-MS/MS trace analysis method for the simultaneous quantification of seven iodinated X-ray contrast media and three artificial sweeteners in surface, ground, and drinking water. Anal Bioanal Chem 406(12):2789–2798. https://doi.org/10.1007/s00216-014-7712-010.1007/s00216-014-7712-0 ↗
3. Wang H, Wu Y, Feng M, Tu W, Xiao T, Xiong T, Ang H, Yuan X et al (2018) Visible-light-driven removal of tetracycline antibiotics and reclamation of hydrogen energy from natural water matrices and wastewater by polymeric carbon nitride foam. Water Res 144:215–225. https://doi.org/10.1016/j.watres.2018.07.02510.1016/j.watres.2018.07.025 ↗
4. Deblonde T, Cossu-Leguille C, Hartemann P (2011) Emerging pollutants in wastewater: a review of the literature. Int J Hyg Envir Heal 214(6):442–448. https://doi.org/10.1016/j.ijheh.2011.08.00210.1016/j.ijheh.2011.08.002 ↗
5. Valcarcel Y, Gonzalez Alonso S, Rodriguez-Gil JL, Gil A, Catala M (2011) Detection of pharmaceutically active compounds in the rivers and tap water of the Madrid Region (Spain) and potential ecotoxicological risk. Chemosphere 84(10):1336–1348. https://doi.org/10.1016/j.chemosphere.2011.05.01410.1016/j.chemosphere.2011.05.014 ↗
6. Kemper N (2008) Veterinary antibiotics in the aquatic and terrestrial environment. Ecol Indic 8(1):1–13. https://doi.org/10.1016/j.ecolind.2007.06.00210.1016/j.ecolind.2007.06.002 ↗
7. Wang J, Lei S, Liang L (2020) Preparation of porous activated carbon from semi-coke by high temperature activation with KOH for the high-efficiency adsorption of aqueous tetracycline. Appl Surf Sci 530:147187. https://doi.org/10.1016/j.apsusc.2020.14718710.1016/j.apsusc.2020.147187 ↗
8. Chen J, Yu X, Li C, Tang X, Sun Y (2020) Removal of tetracycline via the synergistic effect of biochar adsorption and enhanced activation of persulfate. Chem Eng J 382:122916. https://doi.org/10.1016/j.cej.2019.12291610.1016/j.cej.2019.122916 ↗
9. Li M, Liu Y, Yang C, Liu S, Tan X, He Y, Liu N, Zhou L et al (2020) Effects of heteroaggregation with metal oxides and clays on tetracycline adsorption by graphene oxide. Sci Total Environ 719:137283. https://doi.org/10.1016/j.scitotenv.2020.13728310.1016/j.scitotenv.2020.137283 ↗
10. Liu M, Zhao Z, Yu W (2020) Citric acid modified wood membranes for efficient adsorption of tetracycline: Effect of alkali pretreatment concentration and adsorption mechanism. Chem Eng J 393:124748. https://doi.org/10.1016/j.cej.2020.12474810.1016/j.cej.2020.124748 ↗
11. Palacio DA, Leiton LM, Urbano BF, Rivas BL (2020) Tetracycline removal by polyelectrolyte copolymers in conjunction with ultrafiltration membranes through liquid-phase polymer-based retention. Environ Res 182:109014. https://doi.org/10.1016/j.envres.2019.10901410.1016/j.envres.2019.109014 ↗
12. Zhou J, Ma F, Guo H (2020) Adsorption behavior of tetracycline from aqueous solution on ferroferric oxide nanoparticles assisted powdered activated carbon. Chem Eng J 384:123290. https://doi.org/10.1016/j.cej.2019.12329010.1016/j.cej.2019.123290 ↗
13. Zhao Q, Zhang L, Wang X, Jia X, Xu P, Zhao M, Dai R (2019) Simultaneous efficient adsorption and photocatalytic degradation of methylene blue over iron(III)-based metal-organic frameworks: a comparative study. Transit Metal Chem 44(8):789–797. https://doi.org/10.1007/s11243-019-00349-910.1007/s11243-019-00349-9 ↗
14. Wang Z, Lai C, Qin L, Fu Y, He J, Huang D, Li B, Zhang M et al (2020) ZIF-8-modified MnFe2O4 with high crystallinity and superior photo-Fenton catalytic activity by Zn-O-Fe structure for TC degradation. Chem Eng J 392:124851. https://doi.org/10.1016/j.cej.2020.12485110.1016/j.cej.2020.124851 ↗
15. Jin J, Yang Z, Xiong W, Zhou Y, Xu R, Zhang Y, Cao J, Li X et al (2019) Cu and Co nanoparticles co-doped MIL-101 as a novel adsorbent for efficient removal of tetracycline from aqueous solutions. Sci Total Environ 650:408–418. https://doi.org/10.1016/j.scitotenv.2018.08.43410.1016/j.scitotenv.2018.08.434 ↗
16. Martins AC, Pezoti O, Cazetta AL, Bedin KC, Yamazaki DAS, Bandoch GFG, Asefa T, Visentainer JV et al (2015) Removal of tetracycline by NaOH-activated carbon produced from macadamia nut shells: Kinetic and equilibrium studies. Chem Eng J 260:291–299. https://doi.org/10.1016/j.cej.2014.09.01710.1016/j.cej.2014.09.017 ↗
17. Liu P, Liu W, Jiang H, Chen J, Li W, Yu H (2012) Modification of bio-char derived from fast pyrolysis of biomass and its application in removal of tetracycline from aqueous solution. Bioresource Technol 121:235–240. https://doi.org/10.1016/j.biortech.2012.06.08510.1016/j.biortech.2012.06.085 ↗
18. Hao R, Xiao X, Zuo X, Nan J, Zhang W (2012) Efficient adsorption and visible-light photocatalytic degradation of tetracycline hydrochloride using mesoporous BiOI microspheres. J Hazard Mater 209–210:137–145. https://doi.org/10.1016/j.jhazmat.2012.01.00610.1016/j.jhazmat.2012.01.006 ↗
19. Kirchon A, Feng L, Drake HF, Joseph EA, Zhou H (2018) From fundamentals to applications: a toolbox for robust and multifunctional MOF materials. Chem Soc Rev 47(23):8611–8638. https://doi.org/10.1039/c8cs00688a10.1039/c8cs00688a ↗
20. Yuan S, Feng L, Wang K, Pang J, Bosch M, Lollar C, Sun Y, Qin J et al (2018) Stable metal-organic frameworks design, synthesis, and applications. Adv Mater 30:1870277. https://doi.org/10.1002/adma.20187027710.1002/adma.201870277 ↗
21. Induvesa P, Ratanatawanate C, Wongrueng A, Punyapalakul P (2021) Adsorption of iodinated trihalomethanes onto thiol functionalized ZIF-8s: Active adsorption sites, adsorptive mechanisms, and dehalogenation by-products. Sci Total Environ 754:142376. https://doi.org/10.1016/j.scitotenv.2020.14237610.1016/j.scitotenv.2020.142376 ↗
22. Cai X, Lin J, Pang M (2016) Facile synthesis of highly uniform Fe-MIL-88B particles. Cryst Growth Des 16(7):3565–3568. https://doi.org/10.1021/acs.cgd.6b0031310.1021/acs.cgd.6b00313 ↗
23. Ma M, Betard A, Weber I, Al-Hokbany NS, Fischer RA, Metzler-Nolte N (2013) Iron-based metal-organic frameworks MIL-88B and NH2-MIL-88B: high quality microwave synthesis and solvent-induced lattice “breathing.” Cryst Growth Des 13(6):2286–2291. https://doi.org/10.1021/cg301738p10.1021/cg301738p ↗
24. Hou S, Wu Y, Feng L, Chen W, Wang Y, Morlay C, Li F (2018) Green synthesis and evaluation of an iron-based metal-organic framework MIL-88B for efficient decontamination of arsenate from water. Dalton T 47(7):2222–2231. https://doi.org/10.1039/c7dt03775a10.1039/c7dt03775a ↗
25. Thuan VT, Duyen TCN, Hanh TNL, Dai-Viet NV, Van-Dat D, Van-Phuc D, Hong-Tham TN, Trinh DN et al (2019) Amino-functionalized MIL-88B(Fe)-based porous carbon for enhanced adsorption toward ciprofloxacin pharmaceutical from aquatic solutions. Cr Chim 22(11–12):804–812. https://doi.org/10.1016/j.crci.2019.09.00310.1016/j.crci.2019.09.003 ↗
26. Zhao Q, Wang C, Wang H, Wang J (2021) An ultra-dispersive, nonprecious metal MOF-FeZn catalyst with good oxygen reduction activity and favorable stability in acid. J Mater Sci 56(14):8600–8612. https://doi.org/10.1007/s10853-021-05803-710.1007/s10853-021-05803-7 ↗
27. Issa R, Ibrahim FA, Al-Ghoul M, Hmadeh M (2021) Controlled growth and composition of multivariate metal-organic frameworks-199 via a reaction-diffusion process. Nano Res. 14(2):423–431. https://doi.org/10.1007/s12274-020-2870-110.1007/s12274-020-2870-1 ↗
28. Kim M, Cahill JF, Prather KA, Cohen SM (2011) Postsynthetic modification at orthogonal reactive sites on mixed, bifunctional metal-organic frameworks. Chem Commun 47(27):7629–7631. https://doi.org/10.1039/c1cc12101d10.1039/c1cc12101d ↗
29. Xin W, Xu L, Lu K, Shan D (2020) Boosting oxygen reduction catalysis with Fe-N@ZnO codoped highly graphitized carbon derived from N, N ’-carbonyldiimidazole-Induced bimetallic coordinated polymer. Appl Surf Sci 505:144605. https://doi.org/10.1016/j.apsusc.2019.14460510.1016/j.apsusc.2019.144605 ↗
30. Qiao H, Yang Y, Dai X, Zhao H, Yong J, Yu L, Luan X, Cui M et al (2019) Amorphous (Fe) Ni-MOF-derived hollow (bi) metal/oxide@N-graphene polyhedron as effectively bifunctional catalysts in overall alkaline water splitting. Electrochim Acta 318:430–439. https://doi.org/10.1016/j.electacta.2019.06.08410.1016/j.electacta.2019.06.084 ↗
31. Wang M, Yang L, Guo C, Liu X, He L, Song Y, Zhang Q, Qu X et al (2018) Bimetallic Fe/Ti-based metal-organic framework for persulfate-assisted visible light photocatalytic degradation of orange II. ChemistrySelect (Weinheim) 3(13):3664–3674. https://doi.org/10.1002/slct.20170313410.1002/slct.201703134 ↗
32. Li W, Fang W, Chen W, Dinh K, Ren H, Zhao L, Liu C, Yan Q (2020) Bimetal-MOF nanosheets as efficient bifunctional electrocatalysts for oxygen evolution and nitrogen reduction reaction. J Mater Chem a 8(7):3658–3666. https://doi.org/10.1039/c9ta13473e10.1039/c9ta13473e ↗
33. Kim S, Park CG, Huh BK, Lee SH, Min CH, Lee YY, Kim YK, Park KH et al (2018) Metal-organic frameworks, NH2-MIL-88(Fe), as carriers for ophthalmic delivery of brimonidine. Acta Biomater 79:344–353. https://doi.org/10.1016/j.actbio.2018.08.02310.1016/j.actbio.2018.08.023 ↗
34. Surble S, Serre C, Mellot-Draznieks C, Millange F, Ferey G (2006) A new isoreticular class of metal-organic-frameworks with the MIL-88 topology. Chem Commun 3:284–286. https://doi.org/10.1039/b512169h10.1039/b512169h ↗
35. Rosi NL, Kim J, Eddaoudi M, Chen BL, O’Keeffe M, Yaghi OM (2005) Rod packings and metal-organic frameworks constructed from rod-shaped secondary building units. J Am Chem Soc 127(5):1504–1518. https://doi.org/10.1021/ja045123o10.1021/ja045123o ↗
36. Yi X, He X, Yin F, Yang T, Chen B, Li G (2020) NH2-MIL-88B-Fe for electrocatalytic N-2 fixation to NH3 with high Faradaic efficiency under ambient conditions in neutral electrolyte. J Mater Sci 55(26):12041–12052. https://doi.org/10.1007/s10853-020-04777-210.1007/s10853-020-04777-2 ↗
37. Pandi K, Choi J (2021) Selective removal of anionic ions from aqueous environment using iron-based metal-organic frameworks and their mechanistic investigations. J Mol Liq 329:115367. https://doi.org/10.1016/j.molliq.2021.11536710.1016/j.molliq.2021.115367 ↗
38. Wei Y, Zhang M, Liao P, Lin R, Li T, Shao G, Zhang J, Chen X (2015) Coordination templated [2+2+2] cyclotrimerization in a porous coordination framework. Nat Commun 6:8348. https://doi.org/10.1038/ncomms9348.10.1038/ncomms9348 ↗
39. Zhang Z, Chen Y, Wang Z, Hu C, Ma D, Chen W, Ao T (2021) Effective and structure-controlled adsorption of tetracycline hydrochloride from aqueous solution by using Fe-based metal-organic frameworks. Appl Surf Sci 542:148662. https://doi.org/10.1016/j.apsusc.2020.14866210.1016/j.apsusc.2020.148662 ↗
40. Xia J, Gao Y, Yu G (2021) Tetracycline removal from aqueous solution using zirconium-based metal-organic frameworks (Zr-MOFs) with different pore size and topology: adsorption isotherm, kinetic and mechanism studies. J Colloid Interf Sci 590:495–505. https://doi.org/10.1016/j.jcis.2021.01.04610.1016/j.jcis.2021.01.046 ↗
41. Wan D, Wu L, Liu Y, Chen J, Zhao H, Xiao S (2019) Enhanced adsorption of aqueous tetracycline hydrochloride on renewable porous clay-carbon adsorbent derived from spent bleaching earth via pyrolysis. Langmuir 35(11):3925–3936. https://doi.org/10.1021/acs.langmuir.8b0417910.1021/acs.langmuir.8b04179 ↗