journal article·2021-09Open access

A review on the direct electroplating of polymeric materials

Piotr Augustyn, Piotr Rytlewski, Krzysztof Moraczewski, Adam Mazurkiewicz

Journal of Materials Science· Volume 56· Issue 27

Abstract

Abstract This work is a review of the literature on the possibilities for electroplating of polymer materials. Methods of metalizing polymers and their composites were presented and discussed. Information from various publications on the electrical properties of polymers and polymer composites was collected and discussed. The most important results on the electroplating of conductive polymers and conductive composites were presented and compared. This work especially focuses on the electrical conductivity of polymer materials. The main focus was the efficiency of metal electrodeposition. Based on the analyzed publications, it was found that electrically deposited metal layers on conductive polymeric materials show discontinuity, considerable roughness, and different layer thickness depending on the distance from the contact electrode. The use of metal nanoparticles (AgNWs) or nickel nanoparticles (NiNPs) as a filler enables effective metallization of the polymer composite. Due to the high aspect ratio, it is possible to lower the percolation threshold with a low filler content in the polymer matrix. The presented review reveals many of the problems associated with the effectiveness of the electroplating methods. It indicates the need and direction for further research and development in the field of electroplating of polymer materials and modification of their electrical properties.
Source: crossref · Quality: baseline

Research context

OpenAlex topics: Conducting polymers and applications · Advanced Sensor and Energy Harvesting Materials · Polymer crystallization and properties

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (100+)

Show source-provided references
1. Żak T (2002) Poradnik Galwanotechnika 4th ed. WNT, Warszawa
2. Mehdizadeh M, Khorasanian M, Baghal S (2018) Direct electroplating of nickel on ABS plastic using polyaniline silver surface composite synthesized using different acids. J Coat Technol Res. https://doi.org/10.1007/s11998-018-0075-210.1007/s11998-018-0075-2 ↗
3. Guo RH, Jiang SQ, Yuen CWM, Ng MCF (2009) An alternative process for electroless copper plating on polyester fabric. J Mater Sci Mater Electron 20:33–3810.1007/s10854-008-9594-4 ↗
4. Li D, Goodwin K, Yang C (2008) Electroless copper deposition on aluminum–seeded ABS plastics. J Mater Sci 43:7121–7131. https://doi.org/10.1007/s10853-008-3031-110.1007/s10853-008-3031-1 ↗
5. Domenech SC Jr, Lima E, Drago V, De Lima JC, Borges Jr NG, Avila AOV, Soldi V (2003) Electroless plating of nickel–phosphorous on surface-modified poly(ethylene terephthalate) films. Appl Surf Sci 220:238–25010.1016/S0169-4332(03)00815-8 ↗
6. Celozzi S, Araneo R, Lovat G (2008) Electromagnetic shielding. Wiley Inc, Hoboken10.1002/9780470268483 ↗
7. Gryz K, Karpowicz J, Kurczewska A, Stefko A (2009) Ograniczenie ryzyka zawodowego przy źródłach pól elektromagnetycznych–przegląd wybranych materiałów barierowych. Bezpieczeństwo Pracy 3:22–26
8. Indulski IA (1987) Kryteria zdrowotne środowiska. Fale radiowe i mikrofale, PZWL, Warszawa
9. Unnikrishnan D (2006) Potentiel de la technologie MID pour les composants passifs et des antennes, PhD Dissertation, Universite De Grenoble
10. Franke J (2014) Three-dimensional molded interconnect devices (3D-MID). Hanser, Monachium10.3139/9781569905524 ↗
11. Franke J (1995) Integrierte Entwicklung neuer Produkt- und Produktionstechnologien für räumliche spritzgegossene Schaltungsträger(3-D MID), Dissertation, Erlangen
12. Mai TT, Schultze JW, Staikov G (2004) Relation between surface preconditioning and metal deposition in direct galvanic metallization of insulating surfaces. J Solid State Electrochem 8:201–20810.1007/s10008-003-0426-4 ↗
13. Mai TT, Schultze JW, Staikov G, Munoz AG (2005) Mechanism of galvanic metallization of CoS—activated insulating polymer surfaces. Thin Solid Films 488:321–32810.1016/j.tsf.2005.04.069 ↗
14. Pan CT (2004) Selective electroless copper plating micro—coil assisted by 248 nm excimer laser. Microelectr Eng 71:242–25110.1016/j.mee.2003.12.003 ↗
15. Carraro C, Maboudian R, Magagnin L (2007) Metallization and nanostructuring of semiconductor surfaces by galvanic displacement processes. Surf Sci Rep 62:499–52510.1016/j.surfrep.2007.08.002 ↗
16. Hari KK, John S, Srinivasan KN, Praveen J, Ganesan M, Kavimani PM (2006) An overall aspect of electroless Ni–P deposition—A review article. Metal Mater Trans 37A:1917–1926
17. Hryniewicz T (2004) Technologia powierzchni i powłok. Wydawnictwo Politechniki Koszalińskiej, Koszalin
18. Kotnarowska D (2007) Powłoki ochronne. Wydawnictwo Politechniki Radomskiej, Radom
19. Charbonnier M, Romand M, Goepfert Y, Leonard D, Bouadi M (2006) Copper metallization of polymers by a palladium-free electroless process. Surf Coat Technol 200(18–19):5478–548610.1016/j.surfcoat.2005.07.061 ↗
20. Mallory GO (2002) Electroless plating: fundaments and applications. Noyes Publications/William Andrew Publications, New York
21. Touir R, Larhzil H, Ebntouhami M, Cherkaoui M, Chassaing E (2006) Electroless deposition of copper in acidic solutions using hypophospite reducing agent. J Appl Electrochem 36:69–7510.1007/s10800-005-9025-7 ↗
22. Burke LD, Bruton GM, Collins JA (1998) The redox properties of active sites and the importance of the latter in electrocatalysis at copper in base. Electrochim Acta 44:1467–147910.1016/S0013-4686(98)00270-9 ↗
23. Charbonnier M, Romand M (2003) Polymer pretreatments for enhanced adhesion of metals deposited by the electroless process. Inter J Adhesion Adhesives 23:277–28510.1016/S0143-7496(03)00045-9 ↗
24. Mattox DM (1998) Handbook of physical vapor deposition (PVD) Processing 2nd ed. Noyes Publication, Westwood
25. Malandrino G, Jones AC, Hitchman ML (2009) Chemical vapor deposition. precursors, processes and applications. Angew Chem 121(41):7614–7615. https://doi.org/10.1002/ange.20090357010.1002/ange.200903570 ↗
26. Sung Y, Chou YH, Hwu WH, Fan YC, Cheng JL, Ger MD (2009) Electroless copper deposition by non–isothermal deposition technology. Mat Chem Phys 113:303–30810.1016/j.matchemphys.2008.07.075 ↗
27. Lee C, Huang Y, Kuo L (2007) Catalytic effect of Pd nanoparticles on electroless copper deposition. J Solid State Electrochem 11:639–64610.1007/s10008-006-0216-x ↗
28. Mubarak A, Hamzah E, Toff MRM (2005) Review of physical vapour deposition (PVD) techniques for hard coating. J Mekanikal 20:42–51
29. Forster J, Gopalraja P, Gung TJ, Sundarrajan A, Fu X, Hammond N, Fu J, Kelkar U, Bhatnagar A (2005) A PVD based barrier technology for the 45 nm mode. Microelectr Eng 82:594–59910.1016/j.mee.2005.07.062 ↗
30. Grigorov GI, Grigorov KG, Sporken R, Caudano R (1996) Ion – induced densification of PVD films–a choice of the optimum density of ion bombardment. Appl Phys A 63:399–40110.1007/BF01567334 ↗
31. Burakowski T, Wierzchoń T (1995) Inżynieria powierzchni metali. WNT, Warszawa
32. Dobrzański LA (2009) Kształtowanie struktury i właściwości powierzchni materiałów inżynierskich i biomedycznych. International OCSCO World Press, Gliwice
33. Michalski AJ (2000) Fizykochemiczne podstawy otrzymywania powłok z fazy gazowej. Oficyna Wydawnicza Politechniki Warszawskiej, Warszawa
34. Doppelt P (1997) Copper CVD precursors and processes for advanced metallization. Microelectr Eng 37(38):89–9510.1016/S0167-9317(97)00097-X ↗
35. Devi A, Shivashankar SA (1998) Thermal chemical vapour deposition of copper films from copper ethylacetoacetate: microstructure and electrical resistivity. J Mater Sci Lett 17:367–369. https://doi.org/10.1023/A:100651871401110.1023/A:1006518714011 ↗
36. Norman JAT, Perez M, Schultz SE, Waechtler T (2008) New precursors for CVD copper metallization. Microelectr Eng 85:2159–216310.1016/j.mee.2008.05.036 ↗
37. Kada T, Ishikawa M, Machida H, Ogura A, Ohshita Y, Soai K (2005) Volatile CVD precursors for Ni film: cyclopentadienylallynickel. J Crystal Growth 275:e1115–e111910.1016/j.jcrysgro.2004.11.198 ↗
38. Minczewski J, Marczenko Z (2020) Chemia analityczna, PWN, Warszawa, vol. 1, 2
39. Jones L, Atkins P (2019) Chemia ogólna—cząsteczki, materia, reakcje. PWN, Warszawa
40. Nezakati T, Seifalian A, Tan A, Seifalian AM (2018) Conductive Polymers: opportunities and challenges in biomedical applications. Chem Rev 118(14):6766–6843. https://doi.org/10.1021/acs.chemrev.6b0027510.1021/acs.chemrev.6b00275 ↗
41. Kumar D, Sharma RC (1998) Advances in conductive polymers. Eur Polymer J 34(8):1053–106010.1016/S0014-3057(97)00204-8 ↗
42. Lam JWY, Tang BZ (2005) Functional polyacetylenes. Acc Chem Res 38:745–75410.1021/ar040012f ↗
43. Rosen BM, Wilson CJ, Wilson DA, Peterca M, Imam MR, Percec V (2009) Dendron-mediated self-assembly, disassembly, and self-organization of complex systems. Chem Rev 109:6275–654010.1021/cr900157q ↗
44. Yashima E, Maeda K, Iida H, Furusho Y, Nagai K (2009) Helical polymers: synthesis, structures, and functions. Chem Rev 109:6102–621110.1021/cr900162q ↗
45. Mao Y, Xu HP, Zhao H, Yuan WZ, Qin A, Yu Y, Faisal M, Xiao AZ, Sun JZ, Tang BZ (2011) Composites of quaternized poly(pyridylacetylene) and silver nanoparticles: nanocomposite preparation, conductivity, and photoinduced patterning. J Mater Chem 21:13627–1363310.1039/c1jm11459j ↗
46. Masuda T, Higashimura T (1984) Synthesis of high polymers from substituted acetylenes: exploitation of molybdenum- and Tungsten based catalysts. Acc Chem Res 17:51–5610.1021/ar00098a002 ↗
47. Akagi K (2009) Helical “polyacetylene: asymmetric polymerization in a chiral liquid-crystal field.” Chem Rev 109:5354–540110.1021/cr900198k ↗
48. Liu J, Lam JWY, Tang BZ (2009) Acetylenic polymers: syntheses, structures, and functions. Chem Rev 109:5799–586710.1021/cr900149d ↗
49. Saechtling H (2008) Tworzywa sztuczne–poradnik, WNT, Warszawa
50. MacDiarmid AG, Heeger AJ (1980) Organic metals and semiconductors: The chemistry of polyacetylene, (CH)x, and its derivatives. Synth Met 1(2):101–118. https://doi.org/10.1016/0379-6779(80)90002-810.1016/0379-6779(80)90002-8 ↗
51. Schopf G, Kossmehl G (1997) Polythiophenes-electrically conductive polymers. Adv Polym Sci. https://doi.org/10.1007/BFb011161910.1007/BFb0111619 ↗
52. Gondek E, Sanetra J, Armatys P, Nizioł J, Chaczaturian K, Danel A (2004) Nowe pirazolochinoliny i ich zastosowanie w organicznych diodach elektroluminescencyjnych z poli(n-winylokarbazolem) w charakterze matrycy. Polimery 49:163–17010.14314/polimery.2004.163 ↗
53. Leclerc M, Faid K (1997) Electrical and optical properties of processable polythiophene derivatives: structure-property relationships. Adv Mater 9:1087–109410.1002/adma.19970091404 ↗
54. Li X-G, Huang M-R, Duan W, Yang YL (2002) Novel multifunctional polymers from aromatic diamines by oxidative polymerizations. Chem Rev 102:2925–303010.1021/cr010423z ↗
55. Guimard NK, Gomez N, Schmidt CE (2007) Conducting polymers in biomedical engineering. Prog Polym Sci 32:876–92110.1016/j.progpolymsci.2007.05.012 ↗
56. Fonner JM, Schmidt CE, Ren PA (2010) Combined molecular dynamics and experimental study of doped polypyrrole. Polymer 51:4985–499310.1016/j.polymer.2010.08.024 ↗
57. Chaturvedi V, Tanaka S, Kaeriyama K (1992) Preparation of poly(p-phenylene)via processable precursors. J Chem Soc Chem Commun 22:1658. https://doi.org/10.1039/c3992000165810.1039/c39920001658 ↗
58. Gibas E (2016) Polimery I dodatki przewodzące. Przetwórstwo Tworzyw 6:519–529
59. Kumar D, Sharma RC (1998) Advances in conductive polymers. Polym J 34(8):1053–1060
60. Rasmussen SC (2017) The early history of polyaniline: discovery and origins. Substantia 1(2):99–109. https://doi.org/10.13128/substantia-3010.13128/substantia-30 ↗
61. Kargirwar SR, Thakare SR, Choudhary MD, Kondawar SB, Dhakate SR (2011) “Morphology and electrical conductivity of self-doping polyanilines synthesized via selfassembly”, process. Adv Mater Lett 2:397–40110.5185/amlett.2011.4245 ↗
62. Tiwari A, Kumar R, Prabaharan M, Pandey RR, Kumari P, Chaturvedi A, Mishra AK (2010) Nanofibrous polyaniline thin film prepared by plasma-induced polymerization technique for detection of NO2 gas. Polym Adv Technol 21:615–62010.1002/pat.1470 ↗
63. Long Y, Chen Z, Wang N, Li J, Wan M (2004) Electronic transport in PANI-CSA/ PANI-DBSA polyblends. Phys B 344:82–8710.1016/j.physb.2003.09.245 ↗
64. Lee IS, Lee JY, Sung JH, Choi HJ (2005) Synthesis and electrorheological characteristics of polyaniline-titanium dioxide hybrid suspension. Synth Met 152:173–17610.1016/j.synthmet.2005.07.211 ↗
65. Lövenich W (2014) PEDOT-properties and applications. Polym Sci Ser C 56(1):135–14310.1134/S1811238214010068 ↗
66. Worfolk BJ, Andrews SC, Park S, Reinspach J, Liu N, Toney MF, Bao Z (2015) Ultrahigh electrical conductivity in solution-sheared polymeric transparent films. PNAS 112(46):14138–14143. https://doi.org/10.1073/pnas.150995811210.1073/pnas.1509958112 ↗
67. Yfantis DK, Kakos SI, Lamprakopoulos S, Depountis S, Yfantis CD (2006) Copper electrodeposition on insulators (plastics) using highly conductive polypyrrole films. International conference on environment, ecosystems, and development, Venice, Italy, (pp 20–22)
68. Hepel M, Chen Y-M, Stephenso R (1996) Effect of the composition of polypyrrole substrate on the electrodeposition of copper and nickel. J Electrochem Soc 143(2):498. https://doi.org/10.1149/1.183647110.1149/1.1836471 ↗
69. Danks TN, Slade RCT, Varcoe JR (2002) Comparison of PVDF- and FEP-based radiation-grafted alkaline anion-exchange membranes for use in low temperature portable DMFCs. J Mater Chem 12(12):3371–337310.1039/b208627a ↗
70. Zouaoui A, Stéphan O, Carrier M, Moutet JC (1999) Electrodeposition of copper into functionalized polypyrrole films. J Electroanal Chem 474(2):113–122. https://doi.org/10.1016/s0022-0728(99)00310-110.1016/s0022-0728(99)00310-1 ↗
71. Bard AJ, Faulkner LR (2001) Electrochemical methods: fundamentals and applications. John Wiley & Sons, Hoboken
72. Nichols RJ, Schröer D, Meyer H (1995) An in situ scanning probe microscopy study of copper electrodeposition on conductive polypyrrole. Electrochim Acta 40(10):1479–1485. https://doi.org/10.1016/0013-4686(95)00051-f10.1016/0013-4686(95)00051-f ↗
73. De Leeuw DM, Kraakman PA, Bongaerts PFG, Mutsaers CMJ, Klaassen DBM (1994) Electroplating of conductive polymers for the metallization of insulators. Synth Met 66(3):263–273. https://doi.org/10.1016/0379-6779(94)90076-010.1016/0379-6779(94)90076-0 ↗
74. Kuciel S, Liber-Kneć A Kompozyty polimerowe na osnowie termoplastów. http://tworzywa.com.pl/Wiadomo%C5%9Bci/Kompozyty-polimerowe-na-osnowie-termoplast%C3%B3w-20974.html. Accessed 18 Mar 2020
75. Myalski J, Wieczorek J (2009) Właściwości kompozytów polimerowych zawierających cząstki srebra. Kompozyty 9(2):175–180
76. Hansne A, Hinrichsen EL (1992) Some remarks on percolation. Phys Scr 44:55–6110.1088/0031-8949/1992/T44/008 ↗
77. McLachlan DS (1988) Measurement and analysis of a model dual-conductivity medium using a generalised effective-medium theory. J Phys C Solid State Phys 21(8):1521–1532. https://doi.org/10.1088/0022-3719/21/8/02510.1088/0022-3719/21/8/025 ↗
78. Newnham RE, Skinner DP, Cross LE (1978) Connectivity and piezoelectric-pyroelectric composites. Mater Res Bull 13(5):525–536. https://doi.org/10.1016/0025-5408(78)90161-710.1016/0025-5408(78)90161-7 ↗
79. Pal R (2007) On the Electrical Conductivity of Particulate Composites. J Compos Materials. https://doi.org/10.1177/002199830707648910.1177/0021998307076489 ↗
80. Król IA, Redlich G, Obersztyn E, Fortuniak K, Maklewska E, Olejnik M, Bartczak A (2010) Surowce o właściwościach elektroprzewodzących w wyrobach wysokospecjalistycznych. Techniczne Wyroby Włókiennicze 18:12
81. Renishaw (2020) Proszki metali do wytwarzania przyrostowego. https://www.renishaw.pl/pl/proszki-metali-do-wytwarzania-przyrostowego--31457. Accessed 1 July 2020
82. Mayer P, Kaczmar JW (2008) Właściwości i zastosowania włókien węglowych I szklanych. Tworzywa Sztuczne i Chemia 6:52–56
83. Olszewski PK, Tarnawski I, Falkiewicz–Dulik M (2017) Synteza i właściwości elektroprzewodzące materiałów na bazie silikonu do zastosowań w przemyśle obuwniczym. Technologia i Jakość Wyrobów 62:4–16
84. McCunney RJ, Muranko HJ, Long CM, Hamade AK, Valberg PA, Morfeld P (2012) Carbon Black. In: Bingham E, Cohrssen B, Powell CH (eds) Patty’s Toxicology. Wiley, Hoboken. https://doi.org/10.1002/0471435139.tox111.pub210.1002/0471435139.tox111.pub2 ↗
85. Singh M, Vander Wal R (2018) Nanostructure quantification of carbon blacks. C 5(1):2. https://doi.org/10.3390/c501000210.3390/c5010002 ↗
86. Wang M-J, Gray CA, Reznek SR, Mahmud K, Kutsovsky Y (2003) Carbon black. Encycl Polym Sci Technol. https://doi.org/10.1002/0471440264.pst47710.1002/0471440264.pst477 ↗
87. Spahr ME, Gilardi R, Bonacchi D (2017) Carbon black for electrically conductive polymer applications. Polym Polym Compos. https://doi.org/10.1007/978-3-319-28117-9_3210.1007/978-3-319-28117-9_32 ↗
88. Rozpłoch F, Patyk J, Stankowski J (2007) Graphenes bonding forces in graphite. Acta Physica Polonica 112(3):557–56210.12693/APhysPolA.112.557 ↗
89. Geim AK, Kim P (2008) Carbon wonderland. Sci Am 298(4):90–97. https://doi.org/10.1038/scientificamerican0408-9010.1038/scientificamerican0408-90 ↗
90. Geim AK (2009) Graphene: status and prospects. Science 324(5934):1530–1534. https://doi.org/10.1126/science.115887710.1126/science.1158877 ↗
91. Novoselov KS, Jiang D, Schedin F, Booth TJ, Khotkevich VV, Morozov SV, Geim AK (2005) Two-dimensional atomic crystals. PNAS 102(30):10451–10453. https://doi.org/10.1073/pnas.050284810210.1073/pnas.0502848102 ↗
92. Pereira VM, Castro-Neto AH, Peres NMR (2009) Tight-binding approach to uniaxial strain in graphene. Phys Rev B. https://doi.org/10.1103/physrevb.80.04540110.1103/physrevb.80.045401 ↗
93. Lee C, Wei X, Kysar JW, Hone J (2008) Measurement of the elastic properties and intrinsic strength of monolayer graphene. Science 321(5887):385–388. https://doi.org/10.1126/science.115799610.1126/science.1157996 ↗
94. Liao L, Lin YC, Bao M, Cheng R, Bai J, Liu Y, Duan X (2010) High-speed graphene transistors with a self-aligned nanowire gate. Nature 467(7313):305–308. https://doi.org/10.1038/nature0940510.1038/nature09405 ↗
95. Moser J, Barreiro A, Bachtold A (2007) Current-induced cleaning of graphene. Appl Phys Lett 91(16):163513. https://doi.org/10.1063/1.278967310.1063/1.2789673 ↗
96. Hebda M, Łopata A (2012) Grafen–Materiał Przyszłości. Mechanika, 109(8-M):45–53
97. Huczko A (2004) Nanorurki Węglowe: Czarne diamenty XXI wieku. Bel Studio, Warszawa
98. Aqel A, El-Nour KMM, Ammar RAA, Al-Warthan A (2012) Carbon nanotubes, science, and technology part (I) structure, synthesis and characterization. Arab J Chem 5(1):1–23. https://doi.org/10.1016/j.arabjc.2010.08.02210.1016/j.arabjc.2010.08.022 ↗
99. Thostenson ET, Ren Z, Chou TW (2001) Advances in the science and technology of carbon nanotubes and their composites: a review. Compos Sci Technol 61(13):1899–1912. https://doi.org/10.1016/s0266-3538(01)00094-x10.1016/s0266-3538(01)00094-x ↗
100. Dobrzańska-Danikiewicz AD, Łukowiec D, Cichocki D, Wolany W (2020) Nanokompozyty złożone z nanorurek węglowych pokrytych nanokryształami metali szlachetnych. http://www.openaccesslibrary.com/vol22015/1.pdf. Accesed 15 Aug 2020