journal article·2018-12Open access

Synthesis of tin oxide-coated gold nanostars and evaluation of their surface-enhanced Raman scattering activities

Aylin Elci, Ozge Demirtas, Ibrahim Murat Ozturk, Alpan Bek, Emren Nalbant Esenturk

Journal of Materials Science· Volume 53· Issue 24

Abstract

Tin oxide-coated gold nanostar hybrid nanostructures are prepared by first synthesizing gold nanostars (ca. 400 nm), then introducing Na2SnO3 precursor followed by its hydrolysis and formation of a tin oxide layer on nanoparticle surface. The synthesized hybrid structures have been characterized by combination of UV–Vis spectroscopy, transmission electron microscope (TEM), energy-dispersive X-ray studies, scanning electron microscope (SEM), X-Ray diffraction (XRD) and Fourier transform infrared (FTIR) spectroscopy. The TEM and SEM analyses showed that gold nanostars have a coating with an approximate thickness of 15 nm. The tin (IV) oxide coating on the gold nanostars was identified by XRD and XPS analyses and confirmed by FTIR spectroscopy. Surface-enhanced Raman scattering (SERS) spectroscopy was performed on tin oxide-coated and uncoated gold nanostars with crystal violet as a probe molecule. The SERS studies revealed field enhancement properties of Au nanostars, thus their strong SERS activity remained after tin oxide coating.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Gold and Silver Nanoparticles Synthesis and Applications · Nanocluster Synthesis and Applications · Copper-based nanomaterials and applications

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (53)

Show source-provided references
1. Murphy CJ, Sau TK, Gole AM et al (2005) Anisotropic metal nanoparticles: synthesis, assembly, and optical applications. J Phys Chem B 109:13857–13870. https://doi.org/10.1021/jp051684610.1021/jp0516846 ↗
2. Gong C, Dias MRS, Wessler GC et al (2017) Near-field optical properties of fully alloyed noble metal nanoparticles. Adv Opt Mater 5:1600568. https://doi.org/10.1002/adom.20160056810.1002/adom.201600568 ↗
3. Hartland GV (2011) Optical studies of dynamics in noble metal nanostructures. Chem Rev 111:3858–3887. https://doi.org/10.1021/cr100254710.1021/cr1002547 ↗
4. Eustis S, El-Sayed MA (2006) Why gold nanoparticles are more precious than pretty gold: noble metal surface plasmon resonance and its enhancement of the radiative and nonradiative properties of nanocrystals of different shapes. Chem Soc Rev 35:209–217. https://doi.org/10.1039/B514191E10.1039/B514191E ↗
5. Choi KW, Kim DY, Ye SJ, Park OO (2014) Shape- and size-controlled synthesis of noble metal nanoparticles. Adv Mater Res 3:199–216. https://doi.org/10.12989/amr.2014.3.4.19910.12989/amr.2014.3.4.199 ↗
6. Ghosh SK, Pal T (2007) Interparticle coupling effect on the surface plasmon resonance of gold nanoparticles: from theory to applications. Chem Rev 107:4797–4862. https://doi.org/10.1021/cr068028210.1021/cr0680282 ↗
7. Nalbant Esenturk E, Hight Walker AR (2009) Surface-enhanced Raman scattering spectroscopy via gold nanostars. J Raman Spectrosc 40:86–91. https://doi.org/10.1002/jrs.208410.1002/jrs.2084 ↗
8. Senthil Kumar P, Pastoriza-Santos I, Rodríguez-González B et al (2008) High-yield synthesis and optical response of gold nanostars. Nanotechnology 19:015606. https://doi.org/10.1088/0957-4484/19/01/01560610.1088/0957-4484/19/01/015606 ↗
9. Nehl CL, Liao H, Hafner JH (2006) Optical properties of star-shaped gold nanoparticles. Nano Lett 6:683–688. https://doi.org/10.1021/nl052409y10.1021/nl052409y ↗
10. Kneipp K, Wang Y, Kneipp H et al (1997) Single molecule detection using surface-enhanced Raman scattering (SERS). Phys Rev Lett 78:1667–1670. https://doi.org/10.1103/PhysRevLett.78.166710.1103/PhysRevLett.78.1667 ↗
11. Kozanoglu D, Apaydin DH, Cirpan A, Esenturk EN (2013) Power conversion efficiency enhancement of organic solar cells by addition of gold nanostars, nanorods, and nanospheres. Org Electron 14:1720–1727. https://doi.org/10.1016/j.orgel.2013.04.00810.1016/j.orgel.2013.04.008 ↗
12. Zhou N, Polavarapu L, Wang Q, Xu Q-H (2015) Mesoporous SnO2-coated metal nanoparticles with enhanced catalytic efficiency. ACS Appl Mater Interfaces 7:4844–4850. https://doi.org/10.1021/am508803c10.1021/am508803c ↗
13. Park J, Huang J, Wang W et al (2012) Heat transport between Au nanorods, surrounding liquids, and solid supports. J Phys Chem C 116:26335–26341. https://doi.org/10.1021/jp308130d10.1021/jp308130d ↗
14. Zhao T, Jiang X-F, Gao N et al (2013) Solvent-dependent two-photon photoluminescence and excitation dynamics of gold nanorods. J Phys Chem B 117:15576–15583. https://doi.org/10.1021/jp405929w10.1021/jp405929w ↗
15. Jiang C, Guan Z, Rachel Lim SY et al (2011) Two-photon ratiometric sensing of Hg2+ by using cysteine functionalized Ag nanoparticles. Nanoscale 3:3316. https://doi.org/10.1039/c1nr10396b10.1039/c1nr10396b ↗
16. Nam J, Won N, Jin H et al (2009) pH-induced aggregation of gold nanoparticles for photothermal cancer therapy. J Am Chem Soc 131:13639–13645. https://doi.org/10.1021/ja902062j10.1021/ja902062j ↗
17. Evcimen NI, Coskun S, Kozanoglu D et al (2015) Growth of branched gold nanoparticles on solid surfaces and their use as surface-enhanced Raman scattering substrates. RSC Adv 5:101656–101663. https://doi.org/10.1039/C5RA18570J10.1039/C5RA18570J ↗
18. Lee SH, Rusakova I, Hoffman DM et al (2013) Monodisperse SnO2-coated gold nanoparticles are markedly more stable than analogous SiO2-coated gold nanoparticles. ACS Appl Mater Interfaces 5:2479–2484. https://doi.org/10.1021/am302740z10.1021/am302740z ↗
19. Zhou N, Ye C, Polavarapu L, Xu Q-H (2015) Controlled preparation of Au/Ag/SnO2 core–shell nanoparticles using a photochemical method and applications in LSPR based sensing. Nanoscale 7:9025–9032. https://doi.org/10.1039/C5NR01579K10.1039/C5NR01579K ↗
20. Janković V, Yang(Michael) Y, You J et al (2013) Active layer-incorporated, spectrally tuned Au/SiO2 core/shell nanorod-based light trapping for organic photovoltaics. ACS Nano 7:3815–3822. https://doi.org/10.1021/nn400246q10.1021/nn400246q ↗
21. Wang Y, Li L, Wang C, Wang T (2016) Facile approach to synthesize uniform Au@mesoporous SnO2 yolk–shell nanoparticles and their excellent catalytic activity in 4-nitrophenol reduction. J Nanopart Res 18:2. https://doi.org/10.1007/s11051-015-3307-810.1007/s11051-015-3307-8 ↗
22. Seh ZW, Liu S, Zhang S-Y et al (2011) Synthesis and multiple reuse of eccentric Au@TiO2 nanostructures as catalysts. Chem Commun 47:6689. https://doi.org/10.1039/c1cc11729g10.1039/c1cc11729g ↗
23. You L, Mao Y, Ge J (2012) Synthesis of stable SiO2 @Au-nanoring colloids as recyclable catalysts: galvanic replacement taking place on the surface. J Phys Chem C 116:10753–10759. https://doi.org/10.1021/jp211918510.1021/jp2119185 ↗
24. Song H-M, Chon B-S, Jeon S-H et al (2015) Synthesis of Au@SnO2 core–shell nanoparticles with controllable shell thickness and their CO sensing properties. Mater Chem Phys 166:87–94. https://doi.org/10.1016/j.matchemphys.2015.09.03110.1016/j.matchemphys.2015.09.031 ↗
25. Prakash J, Kumar V, Kroon RE et al (2016) Optical and surface enhanced Raman scattering properties of Au nanoparticles embedded in and located on a carbonaceous matrix. Phys Chem Chem Phys 18:2468–2480. https://doi.org/10.1039/C5CP06134B10.1039/C5CP06134B ↗
26. Taub N, Krichevski O, Markovich G (2003) Growth of gold nanorods on surfaces. J Phys Chem B 107:11579–11582. https://doi.org/10.1021/jp036144s10.1021/jp036144s ↗
27. Fang C, Jia H, Chang S et al (2014) (Gold core)/(titania shell) nanostructures for plasmon-enhanced photon harvesting and generation of reactive oxygen species. Energy Environ Sci 7:3431–3438. https://doi.org/10.1039/C4EE01787K10.1039/C4EE01787K ↗
28. Shen Q, Jiang J, Liu S et al (2014) Facile synthesis of Au–SnO2 hybrid nanospheres with enhanced photoelectrochemical biosensing performance. Nanoscale 6:6315–6321. https://doi.org/10.1039/C4NR00520A10.1039/C4NR00520A ↗
29. Lee SH, Hoffman DM, Jacobson AJ, Lee TR (2013) Transparent, homogeneous tin oxide (SnO2) thin films containing SnO2-coated gold nanoparticles. Chem Mater 25:4697–4702. https://doi.org/10.1021/cm402098n10.1021/cm402098n ↗
30. Sun Y, Yang X, Zhao H, Wang R (2017) Non-symmetric hybrids of noble metal-semiconductor: interplay of nanoparticles and nanostructures in formation dynamics and plasmonic applications. Prog Nat Sci Mater Int 27:157–168. https://doi.org/10.1016/j.pnsc.2017.03.00610.1016/j.pnsc.2017.03.006 ↗
31. Yu Y-T, Dutta P (2011) Synthesis of Au/SnO2 core–shell structure nanoparticles by a microwave-assisted method and their optical properties. J Solid State Chem 184:312–316. https://doi.org/10.1016/j.jssc.2010.11.00910.1016/j.jssc.2010.11.009 ↗
32. Tripathy SK, Mishra A, Jha SK et al (2013) Synthesis of thermally stable monodispersed Au@SnO2 core–shell structure nanoparticles by a sonochemical technique for detection and degradation of acetaldehyde. Anal Methods 5:1456. https://doi.org/10.1039/c3ay26549h10.1039/c3ay26549h ↗
33. Zhan Q, Qian J, Li X, He S (2010) A study of mesoporous silica-encapsulated gold nanorods as enhanced light scattering probes for cancer cell imaging. Nanotechnology 21:055704. https://doi.org/10.1088/0957-4484/21/5/05570410.1088/0957-4484/21/5/055704 ↗
34. Atta S, Tsoulos TV, Fabris L (2016) Shaping gold nanostar electric fields for surface-enhanced Raman spectroscopy enhancement via silica coating and selective etching. J Phys Chem C 120:20749–20758. https://doi.org/10.1021/acs.jpcc.6b0194910.1021/acs.jpcc.6b01949 ↗
35. Al-Ogaidi I, Gou H, Al-kazaz AKA et al (2014) A gold@silica core–shell nanoparticle-based surface-enhanced Raman scattering biosensor for label-free glucose detection. Anal Chim Acta 811:76–80. https://doi.org/10.1016/j.aca.2013.12.00910.1016/j.aca.2013.12.009 ↗
36. Silva CO, Petersen SB, Reis CP et al (2016) EGF functionalized polymer-coated gold nanoparticles promote EGF photostability and EGFR internalization for photothermal therapy. PLoS ONE 11:e0165419. https://doi.org/10.1371/journal.pone.016541910.1371/journal.pone.0165419 ↗
37. Kreyling WG, Abdelmonem AM, Ali Z et al (2015) In vivo integrity of polymer-coated gold nanoparticles. Nat Nanotechnol 10:619–623. https://doi.org/10.1038/nnano.2015.11110.1038/nnano.2015.111 ↗
38. Tripathy SK, Jo J-N, Kwang-Joong O et al (2010) Optical studies of Au@SnO2/poly-(vinyl) alcohol core-shell nanoparticle thin films. J Mater Sci Mater Electron 21:758–764. https://doi.org/10.1007/s10854-009-9989-x10.1007/s10854-009-9989-x ↗
39. Esenturk EN, Hight Walker AR (2013) Gold nanostar @ iron oxide core–shell nanostructures: synthesis, characterization, and demonstrated surface-enhanced Raman scattering properties. J Nanopart Res 15:1364. https://doi.org/10.1007/s11051-012-1364-910.1007/s11051-012-1364-9 ↗
40. Wang X, Fan H, Ren P, Li M (2014) Carbon coated SnO2: synthesis, characterization, and photocatalytic performance. RSC Adv 4:10284. https://doi.org/10.1039/c3ra45882b10.1039/c3ra45882b ↗
41. Luo H, Liang LY, Cao HT et al (2012) Structural, chemical, optical, and electrical evolution of SnOx films deposited by reactive rf magnetron sputtering. ACS Appl Mater Interfaces 4:5673–5677. https://doi.org/10.1021/am301601s10.1021/am301601s ↗
42. Liu D, Wang J, Zhang Y et al (2018) Preparation of core–shell structured Au@SiO2 nanocomposite catalyst with Au core size below 2 nm without high-temperature calcination procedure. J Mater Sci 53:8086–8097. https://doi.org/10.1007/s10853-018-2085-y10.1007/s10853-018-2085-y ↗
43. Wang D, Tejerina B, Lagzi I et al (2011) Bridging interactions and selective nanoparticle aggregation mediated by monovalent cations. ACS Nano 5:530–536. https://doi.org/10.1021/nn102525210.1021/nn1025252 ↗
44. Zhao K, Du G, Luo L et al (2015) Novel multi-layered SnO2 nanoarray: self-sustained hydrothermal synthesis, structure, morphology dependence and growth mechanism. CrystEngComm 17:2030–2040. https://doi.org/10.1039/C4CE02310B10.1039/C4CE02310B ↗
45. Dertli E, Coskun S, Esenturk EN (2013) Gold nanowires with high aspect ratio and morphological purity: synthesis, characterization, and evaluation of parameters. J Mater Res 28:250–260. https://doi.org/10.1557/jmr.2012.40710.1557/jmr.2012.407 ↗
46. Kurniawan F, Rahmi R (2017) Synthesis of SnO2 nanoparticles by high potential electrolysis. Bull Chem React Eng Catal 12:281. https://doi.org/10.9767/bcrec.12.2.773.281-28610.9767/bcrec.12.2.773.281-286 ↗
47. Persaud I, Grossman WEL (1993) Surface-enhanced Raman scattering of triphenylmethane dyes on colloidal silver. J Raman Spectrosc 24:107–112. https://doi.org/10.1002/jrs.125024020910.1002/jrs.1250240209 ↗
48. Hildebrandt P, Stockburger M (1984) Surface-enhanced resonance Raman spectroscopy of Rhodamine 6G adsorbed on colloidal silver. J Phys Chem 88:5935–5944. https://doi.org/10.1021/j150668a03810.1021/j150668a038 ↗
49. Hrelescu C, Sau TK, Rogach AL et al (2009) Single gold nanostars enhance Raman scattering. Appl Phys Lett 94:153113. https://doi.org/10.1063/1.311964210.1063/1.3119642 ↗
50. Mei Y, Lu Y, Polzer F et al (2007) Catalytic activity of palladium nanoparticles encapsulated in spherical polyelectrolyte brushes and core–shell microgels. Chem Mater 19:1062–1069. https://doi.org/10.1021/cm062554s10.1021/cm062554s ↗
51. Johnson PB, Christy RW (1972) Optical constants of the noble metals. Phys Rev B 6:4370–4379. https://doi.org/10.1103/PhysRevB.6.437010.1103/PhysRevB.6.4370 ↗
52. Sharma C, Rathore GS, Dubey V (2014) Determination of optical constants of SnO2 thin film for display application. Adv Phys Lett 1:38–42
53. Baco S, Chik A, Md. Yassin F (2012) Study on optical properties of tin oxide thin film at different annealing temperature. J Sci Technol 4:61–72