journal article·2021-11

One-step sonochemical synthesis of NiMn-LDH for supercapacitors and overall water splitting

Mutawara Mahmood Baig, Iftikhar Hussain Gul, Rabia Ahmad, Sherjeel Mahmood Baig, Muhammad Zarrar Khan, Naseem Iqbal

Journal of Materials Science· Volume 56· Issue 33
Publisher page

Abstract

Transition metals are attracting numerous interests for their substantial applications in supercapacitors and as non-noble metal electrocatalyst for overall water splitting. Herein, the NiMn layer double hydroxide (NiMn-LDH) is developed using the sonochemical route at different reaction times, which act as a multifunctional electrode for supercapacitors and overall water splitting. The capacitance of layer double hydroxide (LDH) synthesized at 4 h (NiMn-LDH-4 h) of reaction time was found to be 527 F g−1 at 1 A g−1, with 91.2% capacitance retention after 5,000 cycles at 2 A g−1 in 6 M KOH. For hydrogen and oxygen evolution reactions, the NiMn-LDH-4 h electrode exhibits a standard of 10 mA cm−2 at an overpotential of 120 mV and 296 mV, respectively, in 1 M KOH. Moreover, fabricated NiMn-LDH-4 h||NiMn-LDH-4 h electrolyzer for overall water splitting benchmarks 10 mA cm−2 at 1.6 V. The superior electrochemical properties of the NiMn-LDH electrodes might be attributed to quick diffusion paths and enhanced redox reaction of NiMn-LDH nanosheets because of the high surface area.
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Research context

OpenAlex topics: Supercapacitor Materials and Fabrication · Advanced battery technologies research · Electrocatalysts for Energy Conversion

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