journal article·2016-05

Inherently flame-retardant flexible bio-based polyurethane sealant with phosphorus and nitrogen-containing polyurethane prepolymer

Haiyang Ding, Chenglong Xia, Jifu Wang, Chunpeng Wang, Fuxiang Chu

Journal of Materials Science· Volume 51· Issue 10
Publisher page

Abstract

A novel phosphorus and nitrogen-containing flame-retardant polyurethane prepolymer (FRPUP) was successfully synthesized and characterized by FTIR, 1H NMR, and 31P NMR. The flame-retardant polyurethane sealants (FRPUS) were prepared by curing FRPUP with castor oil. The flame-retardant properties of samples were investigated by the limiting oxygen index and cone calorimeter testing (CCT). The results showed that FRPUP can improve the flame retardancy of polyurethane sealants (PUS). The thermal decomposition behavior of the PUS was investigated by thermogravimetric analysis. Moreover, the thermal degradation mechanisms of FRPUS were investigated by thermogravimetric analysis/infrared spectrometry, FTIR, and X-ray photoelectron spectroscopy. The results indicated that the good flame retardancy of FRPUS can be attributed to the synergistic effect of phosphorus and nitrogen in FRPUP.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Flame retardant materials and properties · Polymer composites and self-healing · Silicone and Siloxane Chemistry

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

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