journal article·2015-08

Silane functionalization of graphene oxide and its use as a reinforcement in bismaleimide composites

Wei Li, Baoquan Zhou, Mingyu Wang, Zhonghui Li, Rong Ren

Journal of Materials Science· Volume 50· Issue 16
Publisher page

Abstract

Silane-functionalized graphene oxide (GO) nanosheets were synthesized by chemically grafting γ-methacryloxypropyltrimethoxysilane (MPTS) onto GO sheets. The resulting MPTS-functionalized GO (MPTS-GO) nanosheets were characterized by Fourier transform infrared spectroscopy, energy dispersive X-ray analysis, X-ray photoelectron spectra, X-ray diffraction, and Raman spectroscopy. Bismaleimide (BMI) composites filled with GO and MPTS-GO were prepared at different filler loading levels. The study showed that the exfoliation and dispersion of graphene sheets in BMI resin were significantly improved due to the surface functionalization effect. The tensile test indicated that the MPTS-GO/BMI nanocomposites showed higher tensile strength and modulus than the neat BMI resin and GO/BMI composites. Meanwhile, the impact strength of composites was also improved. The maximum increment of the tensile strength, tensile modulus, and impact strength of MPTS-GO/BMI nanocomposites were 22.17, 33.05, and 66.64 %, respectively. The fracture surface analysis revealed that the highly dispersed MPTS-GO nanosheets could trigger large-scale plastic deformation of resin matrix.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Graphene research and applications · Fiber-reinforced polymer composites · Mechanical Behavior of Composites

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (33)

Show source-provided references
1. Kuilla T, Bhadra S, Yao D et al (2010) Recent advances in graphene based polymer composites. Prog Polym Sci 35:1350–137510.1016/j.progpolymsci.2010.07.005 ↗
2. Balandin AA, Ghosh S, Bao WZ et al (2008) Superior thermal conductivity of single-layer graphene. Nano Lett 8:902–90710.1021/nl0731872 ↗
3. Wang X, Xing W, Zhang P et al (2012) Covalent functionalization of graphene with organosilane and its use as a reinforcement in epoxy composites. Compos Sci Technol 68:854–861
4. Tang LC, Wan YJ, Yan D et al (2013) The effect of graphene dispersion on the mechanical properties of graphene/epoxy composites. Carbon 60:16–2710.1016/j.carbon.2013.03.050 ↗
5. Yang H, Li F, Shan C et al (2009) Covalent functionalization of chemically converted sheets via silane and its reinforcement. J Mater Chem 19:4632–463810.1039/b901421g ↗
6. McAllister MJ, Li JL, Adamson DH et al (2007) Single sheet functionalized graphene by oxidation and thermal expansion of graphite. Chem Mater 19:4396–440410.1021/cm0630800 ↗
7. Bao C, Guo Y, Song L et al (2011) In situ preparation of functionalized graphene oxide/epoxy nanocomposites with effective reinforcements. J Mater Chem 21:13290–1329810.1039/c1jm11434d ↗
8. Cano M, Khan U, Sainsbury T et al (2013) Improving the mechanical properties of graphene oxide based materials by covalent attachment of polymer chains. Carbon 52:363–37110.1016/j.carbon.2012.09.046 ↗
9. Geim AK (2009) Graphene: status and prospects. Science 324:1530–153410.1126/science.1158877 ↗
10. Park S, Ruoff RS (2009) Chemical methods for the production of graphenes. Nat Nanotechnol 4:217–22410.1038/nnano.2009.58 ↗
11. Wan YJ, Gong LX, Tang LC et al (2014) Mechanical properties of epoxy composites filled with silane-functionalized graphene oxide. Compos Part A 64:79–8910.1016/j.compositesa.2014.04.023 ↗
12. Zheng Li, Wang R, Young RJ et al (2013) Control of the functionality of graphene oxide for its application in epoxy nanocomposites. Polymer 54:6437–644610.1016/j.polymer.2013.09.054 ↗
13. Stankovich S, Piner RD, Nguyen ST et al (2006) Synthesis and exfoliation of isocyanate-treated graphene oxide nanoplatelets. Carbon 44:3342–334710.1016/j.carbon.2006.06.004 ↗
14. Ma PC, Kim JK, Tang BZ (2006) Functionalization of carbon nanotubes using a silane coupling agent. Carbon 44:3232–323810.1016/j.carbon.2006.06.032 ↗
15. Lin R, Lu W, Lin C (2004) Cure reactions in the blend of cyanate ester with maleimide. Polymer 45:4423–443510.1016/j.polymer.2004.04.050 ↗
16. Wang CS, Leu TS (1999) Novel bismaleimide with naphthalene and aryl ether linkages. J Appl Polym Sci 73:833–83910.1002/(SICI)1097-4628(19990801)73:5<833::AID-APP24>3.0.CO;2-1 ↗
17. Li Y, Gu A, Liang G et al (2008) Microcapsule-modified bismaleimide (BMI) resins. Compos Sci Technol 68:2107–211310.1016/j.compscitech.2008.03.015 ↗
18. Lin Q, Zheng R, Tian P (2010) Preparation and characterization of BMI resin/graphite oxide nanocomposites. Polym Test 29:537–54310.1016/j.polymertesting.2010.01.007 ↗
19. Chaudhori M, Galvin T, King J (1985) Characterization of bismaleimide system, XU292. SAMPE J 21:17–21
20. Rozenberg BA, Dzhavadyan EA, Morgan R et al (2002) High-performance bismaleimide matrices: cure kinetics and mechanism. Polym Adv Technol 13:837–84410.1002/pat.230 ↗
21. Gu A, Liang G, Liang D et al (2007) Bismaleimide/carbon nanotube hybrids for potential aerospace application: I static and dynamic mechanical properties. Polym Adv Technol 18:835–84010.1002/pat.944 ↗
22. Liu M, Duan Y, Wang Y et al (2014) Diazonium functionalization of graphene nanosheets and impact response of aniline modified graphene/bismaleimide nanocomposites. Mater Des 53:466–47410.1016/j.matdes.2013.07.027 ↗
23. Zhou J, Yao Z, Zhen W et al (2014) Dielectric and thermal performances of the graphene/bismaleimide/2, 2-diallylbisphenol A composite. Mater Lett 124:155–15710.1016/j.matlet.2014.03.074 ↗
24. Hu X, Meng J (2005) Effect of organoclay on the curing reactions in bismaleimide/diallyl bisphenol A resin. J Polym Sci 43:994–100610.1002/pola.20521 ↗
25. Hummers WS, Offeman RE (1958) Preparation of Graphitic Oxide. J Am Chem Soc 80:133910.1021/ja01539a017 ↗
26. Wan YJ, Tang LC, Gong LX et al (2014) Grafting of epoxy chains onto graphene oxide for epoxy composites with improved mechanical and thermal properties. Carbon 69:467–48010.1016/j.carbon.2013.12.050 ↗
27. McAllister MJ, Li J-L, Adamson DH et al (2007) Single sheet functionalized graphene by oxidation and thermal expansion of graphite. Chem Mater 19:4396–440410.1021/cm0630800 ↗
28. Wu N, She XL, Yang DJ et al (2012) Synthesis of network reduced graphene oxide in polystyrene matrix by a two-step reduction method for superior conductivity of the composite. J Mater Chem 22:17254–1726110.1039/c2jm33114d ↗
29. Kudin KN, Ozbas B, Schniepp HC et al (2007) Raman spectra of graphite oxide and functionalized graphene sheets. Nano Lett 8:36–4110.1021/nl071822y ↗
30. Shojaee SA, Zandiatashbar A, Koratkar N et al (2013) Raman spectroscopic imaging of graphene dispersion in polymer composites. Carbon 62:510–52010.1016/j.carbon.2013.05.068 ↗
31. Rafiee MA, Rafiee J, Wang Z et al (2009) Enhanced mechanical properties of nanocomposites at low graphene content. ACS Nano 3:3884–389010.1021/nn9010472 ↗
32. Qi XY, Yan D, Jiang ZG et al (2011) Enhanced electrical conductivity in polystyrene nanocomposites at ultra-low graphene content. ACS Appl Mater Interfaces 3:3130–313310.1021/am200628c ↗
33. Wang Y, Shi ZX, Fang JH et al (2011) Graphene oxide/polybenzimidazole composites fabricated by a solvent-exchange method. Carbon 49:1199–120710.1016/j.carbon.2010.11.036 ↗