Halloysite for clay–polymer nanocomposites: effects of nanofillers on the anti-corrosion, mechanical, microstructure, and flame-retardant properties—a review
Bibliographic record
Abstract
No abstract is available for this record. The assistant can identify its topic from the title, but cannot infer the study’s results.
Source: Not provided · Quality: missing
Research context
OpenAlex topics: Clay minerals and soil interactions · Polymer Nanocomposites and Properties · Layered Double Hydroxides Synthesis and Applications
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (100+)
Show source-provided references
1. Bastus NG, Comenge J, Puntes V (2011) Kinetically controlled seeded growth synthesis of citrate-stabilized gold nanoparticles of up to 200 nm: size focusing versus Ostwald ripening. Langmuir 27(17):11098–1110510.1021/la201938u ↗
2. Wu J, Ji G, Wu Q (2022) Preparation of epoxy/ZrO2 composite coating on the Q235 surface by electrostatic spraying and its corrosion resistance in 3.5% NaCl solution. RSC Adv 12(17):10625–1063310.1039/D2RA01220K ↗
3. Chandraraj SS, Xavier JR (2022) Electrochemical and mechanical investigation into the effects of polyacrylamide/TiO2 in polyurethane coatings on mild steel structures in chloride media. J Mater Sci 57(28):13362–1338410.1007/s10853-022-07483-3 ↗
4. Erpek CEY, Ozkoc G, Yilmazer U (2017) Comparison of natural halloysite with synthetic carbon nanotubes in poly (lactic acid) based composites. Polym Compos 38(11):2337–234610.1002/pc.23816 ↗
5. Xavier JR (2018) Investigation on the effect of nano-ceria on the epoxy coatings for corrosion protection of mild steel in natural seawater. Anticorros Methods Mater. https://doi.org/10.1108/ACMM-04-2017-178410.1108/ACMM-04-2017-1784 ↗
6. Shi G, Zhang MQ, Rong MZ, Wetzel B, Friedrich K (2003) Friction and wear of low nanometer Si3N4 filled epoxy composites. Wear 254(7–8):784–79610.1016/S0043-1648(03)00190-X ↗
7. Khodaei P, Shabani-Nooshabadi M, Behpour M (2019) Epoxy-based nanocomposite coating reinforced by a zeolite complex: its anticorrosion properties on mild steel in 3.5 wt.% NaCl media. Prog Org Coat 136:10525410.1016/j.porgcoat.2019.105254 ↗
8. Khoeini M, Bazgir S, Tamizifar M, Nemati A, Arzani K (2010) Preparation and morphological study of epoxy/silane modified nanoclay nanocomposites. Asian J Chem 22(1):797
9. Xavier JR (2021) Electrochemical and dynamic mechanical studies of newly synthesized polyurethane/SiO2-Al2O3 mixed oxide nanocomposite coated steel immersed in 3.5% NaCl solution. Surf Interfaces 22:10084810.1016/j.surfin.2020.100848 ↗
10. Hillier S, Brydson R, Delbos E, Fraser T, Gray N, Pendlowski H, Phillips I, Robertson J, Wilson I (2016) Correlations among the mineralogical and physical properties of halloysite nanotubes (HNTs). Clay Miner 51(3):325–35010.1180/claymin.2016.051.3.11 ↗
11. Bertuoli PT, Piazza D, Scienza LC, Zattera AJ (2014) Preparation and characterization of montmorillonite modified with 3-aminopropyltriethoxysilane. Appl Clay Sci 87:46–5110.1016/j.clay.2013.11.020 ↗
12. Mitra K (2010) Assessing optimal growth of desired species in epoxy polymerization under uncertainty. Chem Eng J 162(1):322–33010.1016/j.cej.2010.05.004 ↗
13. Rehbock C, Merk V, Gamrad L, Streubel R, Barcikowski S (2013) Size control of laser-fabricated surfactant-free gold nanoparticles with highly diluted electrolytes and their subsequent bioconjugation. Phys Chem Chem Phys 15(9):3057–306710.1039/C2CP42641B ↗
14. Olivier MG, Fedel M, Sciamanna V, Vandermiers C, Motte C, Poelman M, Deflorian F (2011) Study of the effect of nanoclay incorporation on the rheological properties and corrosion protection by a silane layer. Prog Org Coat 72(1–2):15–2010.1016/j.porgcoat.2010.11.022 ↗
15. Xavier JR (2022) Novel multilayer structural epoxy composite coating containing graphene oxide and silanized chromium carbide for the protection of steel structures. J Coat Technol Res. https://doi.org/10.1007/s11998-022-00643-910.1007/s11998-022-00643-9 ↗
16. Kumar SS, Kakooei S, Ismail MC, Haris M (2020) Synthesis and characterization of metal ion end capped nanocontainer loaded with duo green corrosion inhibitors. J Market Res 9(4):8350–8354
17. Joo Y, Sim JH, Jeon Y, Lee SU, Sohn D (2013) Opening and blocking the inner-pores of halloysite. Chem Commun 49(40):4519–452110.1039/c3cc40465j ↗
18. Nazari MH, Zhang Y, Mahmoodi A, Xu G, Yu J, Wu J, Shi X (2022) Nanocomposite organic coatings for corrosion protection of metals: a review of recent advances. Prog Org Coat 162:10657310.1016/j.porgcoat.2021.106573 ↗
19. Deng S, Zhang J, Ye L, Wu J (2008) Toughening epoxies with halloysite nanotubes. Polymer 49(23):5119–512710.1016/j.polymer.2008.09.027 ↗
20. Beryl JR, Xavier JR (2021) Influence of silane functionalized nanoclay on the barrier, mechanical and hydrophobic properties by clay nanocomposite films in an aggressive chloride medium. Colloids Surf A 630:12762510.1016/j.colsurfa.2021.127625 ↗
21. Xavier JR, Vinodhini SP, Beryl JR (2021) Effect of silane-functionalized RuO2 nanoparticles on the anticorrosive and mechanical properties of poly (methyl methacrylate) coatings. Metall Mater Trans A 52(9):3896–390910.1007/s11661-021-06351-0 ↗
22. Ji WG, Hu JM, Liu L, Zhang JQ, Cao CN (2008) Enhancement of corrosion performance of epoxy coatings by chemical modification with GPTMS silane monomer. J Adhes Sci Technol 22(1):77–9210.1163/156856108X292287 ↗
23. Xavier JR, Beryl JR, Vinodhini SP (2021) Novel multifunctional nanocomposites for superior barrier, hydrophobic and mechanical properties of Mg alloy in marine environment. Surf Coat Technol 421:12747510.1016/j.surfcoat.2021.127475 ↗
24. Rooj S, Das A, Thakur V, Mahaling RN, Bhowmick AK, Heinrich G (2010) Preparation and properties of natural nanocomposites based on natural rubber and naturally occurring halloysite nanotubes. Mater Des 31(4):2151–215610.1016/j.matdes.2009.11.009 ↗
25. Krishnaiah P, Ratnam CT, Manickam S (2017) Development of silane grafted halloysite nanotube reinforced polylactide nanocomposites for the enhancement of mechanical, thermal and dynamic-mechanical properties. Appl Clay Sci 135:583–59510.1016/j.clay.2016.10.046 ↗
26. Xavier JR (2020) Investigation on the anticorrosion, adhesion and mechanical performance of epoxy nanocomposite coatings containing epoxy-silane treated nano-MoO3 on mild steel. J Adhes Sci Technol 34(2):115–13410.1080/01694243.2019.1661658 ↗
27. Tully J, Yendluri R, Lvov Y (2016) Halloysite clay nanotubes for enzyme immobilization. Biomacromol 17(2):615–62110.1021/acs.biomac.5b01542 ↗
28. Parhizkar N, Ramezanzadeh B, Shahrabi T (2018) Corrosion protection and adhesion properties of the epoxy coating applied on the steel substrate pre-treated by a sol-gel based silane coating filled with amino and isocyanate silane functionalized graphene oxide nanosheets. Appl Surf Sci 439:45–5910.1016/j.apsusc.2017.12.240 ↗
29. Xavier JR (2020) Effect of surface modified WO3 nanoparticle on the epoxy coatings for the adhesive and anticorrosion properties of mild steel. J Appl Polym Sci 137(5):4832310.1002/app.48323 ↗
30. Xavier JR (2022) Novel multilayer structural epoxy nanocomposite coating for enhanced adhesion and protection properties of steel. Polym Plast Technol Mater. https://doi.org/10.1080/25740881.2022.207116010.1080/25740881.2022.2071160 ↗
31. Henriques RR, Soares BG (2021) Sepiolite modified with phosphonium ionic liquids as anticorrosive pigment for epoxy coatings. Appl Clay Sci 200:10589010.1016/j.clay.2020.105890 ↗
32. Shchukin DG, Lamaka SV, Yasakau KA, Zheludkevich ML, Ferreira MGS, Mohwald H (2008) Active anticorrosion coatings with halloysite nanocontainers. J Phys Chem C 112(4):958–96410.1021/jp076188r ↗
33. Raj XJ, Nishimura T (2016) Evaluation of the corrosion protection performance of epoxy-coated high manganese steel by SECM and EIS techniques. J Fail Anal Prev 16(3):417–42610.1007/s11668-016-0102-5 ↗
34. Fakhrullina GI, Akhatova FS, Lvov YM, Fakhrullin RF (2015) Toxicity of halloysite clay nanotubes in vivo: a caenorhabditis elegans study. Environ Sci Nano 2(1):54–5910.1039/C4EN00135D ↗
35. Ha SR, Rhee KY, Park SJ, Lee JH (2010) Temperature effects on the fracture behavior and tensile properties of silane-treated clay/epoxy nanocomposites. Compos B Eng 41(8):602–60710.1016/j.compositesb.2010.09.015 ↗
36. Boomadevi Janaki G, Xavier JR (2020) Evaluation of mechanical properties and corrosion protection performance of surface modified nano-alumina encapsulated epoxy coated mild steel. J Bio Tribo Corros 6(1):1–1110.1007/s40735-019-0316-7 ↗
37. Piscitelli F, Scamardella AM, Romeo V, Lavorgna M, Barra G, Amendola E (2012) Epoxy composites based on amino-silylated MMT: the role of interfaces and clay morphology. J Appl Polym Sci 124(1):616–62810.1002/app.35015 ↗
38. Xavier JR (2019) Investigation into the effect of Cr2O3 nanoparticles on the protective properties of epoxy coatings on carbon steel in 35% NaCl solution by scanning electrochemical microscopy. Prot Met Phys Chem Surf 55(1):80–8810.1134/S2070205119010167 ↗
39. Vennerberg D, Rueger Z, Kessler MR (2014) Effect of silane structure on the properties of silanized multiwalled carbon nanotube-epoxy nanocomposites. Polymer 55(7):1854–186510.1016/j.polymer.2014.02.018 ↗
40. Hojiyev R, Ulcay Y, Çelik MS (2017) Development of a clay-polymer compatibility approach for nanocomposite applications. Appl Clay Sci 146:548–55610.1016/j.clay.2017.07.007 ↗
41. Xavier JR (2020) Galvanic corrosion of copper/titanium in aircraft structures using a cyclic wet/dry corrosion test in marine environment by EIS and SECM techniques. SN Appl Sci 2(8):1–1010.1007/s42452-020-3145-x ↗
42. Kang H, Liu X, Zhang S, Li J (2017) Functionalization of halloysite nanotubes (HNTs) via mussel-inspired surface modification and silane grafting for HNTs/soy protein isolate nanocomposite film preparation. RSC Adv 7(39):24140–2414810.1039/C7RA02987J ↗
43. Yeh JM, Liou SJ, Lai CY, Wu PC, Tsai TY (2001) Enhancement of corrosion protection effect in polyaniline via the formation of polyaniline−clay nanocomposite materials. Chem Mater 13(3):1131–113610.1021/cm000938r ↗
44. Sugama T (2006) Polyphenylenesulfied/montomorillonite clay nanocomposite coatings: their efficacy in protecting steel against corrosion. Mater Lett 60(21–22):2700–270610.1016/j.matlet.2006.01.111 ↗
45. Chang KC, Chen ST, Lin HF, Lin CY, Huang HH, Yeh JM, Yu YH (2008) Effect of clay on the corrosion protection efficiency of PMMA/Na+-MMT clay nanocomposite coatings evaluated by electrochemical measurements. Eur Polymer J 44(1):13–2310.1016/j.eurpolymj.2007.10.011 ↗
46. Dai CF, Li PR, Yeh JM (2008) Comparative studies for the effect of intercalating agent on the physical properties of epoxy resin-clay based nanocomposite materials. Eur Polymer J 44(8):2439–244710.1016/j.eurpolymj.2008.06.015 ↗
47. Shi X, Nguyen TA, Suo Z, Liu Y, Avci R (2009) Effect of nanoparticles on the anticorrosion and mechanical properties of epoxy coating. Surf Coat Technol 204(3):237–24510.1016/j.surfcoat.2009.06.048 ↗
48. Prashantha K, Lacrampe MF, Krawczak P (2011) Processing and characterization of halloysite nanotubes filled polypropylene nanocomposites based on a masterbatch route: effect of halloysites treatment on structural and mechanical properties. Express Polym Lett 5(4):295–30710.3144/expresspolymlett.2011.30 ↗
49. Huttunen-Saarivirta E, Vaganov GV, Yudin VE, Vuorinen J (2013) Characterization and corrosion protection properties of epoxy powder coatings containing nanoclays. Prog Org Coat 76(4):757–76710.1016/j.porgcoat.2013.01.005 ↗
50. Xavier JR (2022) Superior surface protection, mechanical and hydrophobic properties of silanized tungsten carbide nanoparticles encapsulated epoxy nanocomposite coated steel structures in marine environment. SILICON. https://doi.org/10.1007/s12633-022-01842-010.1007/s12633-022-01842-0 ↗
51. Kumar V, Kumar M, Pugazhenthi G (2014) Effect of nanoclay content on the structural, thermal properties and thermal degradation kinetics of PMMA/organoclay nanocomposites. Int J Nano Biomater 5(1):27–4410.1504/IJNBM.2014.061809 ↗
52. Xavier JR (2020) Experimental investigation of the hybrid epoxy-silane coating for enhanced protection against the corrosion of aluminum alloy AA7075 frame in solar cells. Macromol Res 28(5):501–50910.1007/s13233-020-8065-5 ↗
53. Thakur S, Pani B, Singh M, Singh AK (2022) Organosilanes/Silicon-based nanocomposites as corrosion inhibitors. Functionalized nanomaterials for corrosion mitigation: synthesis, characterization, and applications. American Chemical Society, Washington, pp 271–290
54. Kartsonakis IA, Balaskas AC, Koumoulos EP, Charitidis CA, Kordas GC (2012) Incorporation of ceramic nanocontainers into epoxy coatings for the corrosion protection of hot dip galvanized steel. Corros Sci 57:30–4110.1016/j.corsci.2011.12.037 ↗
55. Xavier JR (2021) Superior corrosion protection performance of polypdopamine-intercalated CeO2/polyurethane nanocomposite coatings on steel in 3.5% NaCl solution. J Appl Electrochem 51(6):959–97510.1007/s10800-021-01547-z ↗
56. Xavier JR (2021) High protection performance of vanadium pentoxide-embedded polyfuran/epoxy coatings on mild steel. Polym Bull 78(10):5713–573910.1007/s00289-020-03400-3 ↗
57. Sims RA, Harmer Bassell SL, Quinton JS (2018) The oscillatory adsorption of self assembled organosilane films on aluminium oxide surfaces. Surf Interface Anal 50(8):813–81810.1002/sia.6483 ↗
58. Giannelis EP, Krishnamoorti R, Manias E (1999) Polymer-silicate nanocomposites: model systems for confined polymers and polymer brushes. Polym Confin Environ. https://doi.org/10.1007/3-540-69711-X_310.1007/3-540-69711-X_3 ↗
59. Lecouvet B, Gutierrez JG, Sclavons M, Bailly C (2011) Structure–property relationships in polyamide 12/halloysite nanotube nanocomposites. Polym Degrad Stab 96(2):226–23510.1016/j.polymdegradstab.2010.11.006 ↗
60. Kausar A (2020) Flame retardant potential of clay nanoparticles. Clay nanoparticles. Elsevier, Amsterdam, pp 169–18410.1016/B978-0-12-816783-0.00007-4 ↗
61. Xavier JR, Beryl JR, Vinodhini SP, Janaki GB (2021) Enhanced protective and mechanical properties of Polypyrrole coatings modified by Silane/CoO nanocomposite on AZ91 Mg alloy in chloride media. J Bio Tribo Corros 7(2):1–1710.1007/s40735-021-00479-7 ↗
62. De Silva RT, Pasbakhsh P, Goh KL, Chai SP, Chen J (2014) Synthesis and characterisation of poly (lactic acid)/halloysite bionanocomposite films. J Compos Mater 48(30):3705–371710.1177/0021998313513046 ↗
63. Ismail H, Pasbakhsh P, Fauzi MA, Bakar AA (2008) Morphological, thermal and tensile properties of halloysite nanotubes filled ethylene propylene diene monomer (EPDM) nanocomposites. Polym Test 27(7):841–85010.1016/j.polymertesting.2008.06.007 ↗
64. Pal P, Kundu MK, Malas A, Das CK (2014) Compatibilizing effect of halloysite nanotubes in polar–nonpolar hybrid system. J Appl Polym Sci. https://doi.org/10.1002/app.3958710.1002/app.39587 ↗
65. Li Z, Exposito DF, Gonzalez AJ, Wang DY (2017) Natural halloysite nanotube based functionalized nanohybrid assembled via phosphorus-containing slow-release method: a highly efficient way to impart flame retardancy to polylactide. Eur Polymer J 93:458–47010.1016/j.eurpolymj.2017.06.021 ↗
66. Calvino MM, Cavallaro G, Lisuzzo L, Milioto S, Lazzara G (2022) Separation of halloysite/kaolinite mixtures in water controlled by sucrose addition: the influence of the attractive forces on the sedimentation behavior. Colloids Surf A 641:12853010.1016/j.colsurfa.2022.128530 ↗
67. Zhang J, Guo Z, Zhi X, Tang H (2013) Surface modification of ultrafine precipitated silica with 3-methacryloxypropyltrimethoxysilane in carbonization process. Colloids Surf A 418:174–17910.1016/j.colsurfa.2012.11.057 ↗
68. Wan C, Qiao X, Zhang Y, Zhang Y (2003) Effect of different clay treatment on morphology and mechanical properties of PVC-clay nanocomposites. Polym Test 22(4):453–46110.1016/S0142-9418(02)00126-5 ↗
69. Tang Y, Ye L, Deng S, Yang C, Yuan W (2012) Influences of processing methods and chemical treatments on fracture toughness of halloysite–epoxy composites. Mater Des 42:471–47710.1016/j.matdes.2012.06.036 ↗
70. Li JY, Huang C, Zhang Q (2004) Enhanced electromechanical properties in all-polymer percolative composites. Appl Phys Lett 84(16):3124–312610.1063/1.1702127 ↗
71. Liu M, Jia Z, Jia D, Zhou C (2014) Recent advance in research on halloysite nanotubes-polymer nanocomposite. Prog Polym Sci 39(8):1498–152510.1016/j.progpolymsci.2014.04.004 ↗
72. Yang Y, Chen Y, Leng F, Huang L, Wang Z, Tian W (2017) Recent advances on surface modification of halloysite nanotubes for multifunctional applications. Appl Sci 7(12):121510.3390/app7121215 ↗
73. Berahman R, Raiati M, Mazidi MM, Paran SMR (2016) Preparation and characterization of vulcanized silicone rubber/halloysite nanotube nanocomposites: effect of matrix hardness and HNT content. Mater Des 104:333–34510.1016/j.matdes.2016.04.099 ↗
74. Ferrari PC, Araujo FF, Pianaro SA (2017) Halloysite nanotubes-polymeric nanocomposites: characteristics, modifications and controlled drug delivery approaches. Ceramica 63:423–43110.1590/0366-69132017633682167 ↗
75. Zhao Y, Abdullayev E, Vasiliev A, Lvov Y (2013) Halloysite nanotubule clay for efficient water purification. J Colloid Interface Sci 406:121–12910.1016/j.jcis.2013.05.072 ↗
76. Yang K, Chi Q, Wang X, Jiang Y, Li F, Xue B (2019) The role of halloysite on crystallinity, ion conductivity, thermal and mechanical properties of poly (ethylene-oxide)/halloysite nanocomposites. J Polym Res 26(6):1–1110.1007/s10965-019-1803-8 ↗
77. Ramakrishnan T, Raja Karthikeyan K, Tamilselvan V, Sivakumar S, Gangodkar D, Radha HR, Narain Singh A, Asrat Waji Y (2022) Study of various epoxy-based surface coating techniques for anticorrosion properties. Adv Mater Sci Eng. https://doi.org/10.1155/2022/528591910.1155/2022/5285919 ↗
78. Kouser S, Sheik S, Prabhu A, Nagaraja GK, Prashantha K, D’souza JN, Navada MK, Manasa DJ (2021) Effects of reinforcement of sodium alginate functionalized halloysite clay nanotubes on thermo-mechanical properties and biocompatibility of poly (vinyl alcohol) nanocomposites. J Mech Behav Biomed Mater 118:10444110.1016/j.jmbbm.2021.104441 ↗
79. Nicolini KP, Fukamachi CRB, Wypych F, Mangrich AS (2009) Dehydrated halloysite intercalated mechanochemically with urea: thermal behavior and structural aspects. J Colloid Interface Sci 338(2):474–47910.1016/j.jcis.2009.06.058 ↗
80. Monem M, Ahmadi Z, Fakhri V, Goodarzi V (2022) Preparing and characterization of Poly (glycerol-sebacic acid-urethane) (PGSU) nanocomposites: clearing role of unmodified and modified clay nanoparticles. J Polym Res 29(1):1–1410.1007/s10965-021-02866-7 ↗
81. Vahabi H, Saeb MR, Formela K, Cuesta JML (2018) Flame retardant epoxy/halloysite nanotubes nanocomposite coatings: exploring low-concentration threshold for flammability compared to expandable graphite as superior fire retardant. Prog Org Coat 119:8–1410.1016/j.porgcoat.2018.02.005 ↗
82. Price R, Gaber BP, Lvov YR (2001) In-vitro release characteristics of tetracycline HCl, khellin and nicotinamide adenine dineculeotide from halloysite; a cylindrical mineral. J Microencapsul 18(6):713–72210.1080/02652040010019532 ↗
83. Vergaro V, Abdullayev E, Lvov YM, Zeitoun A, Cingolani R, Rinaldi R, Leporatti S (2010) Cytocompatibility and uptake of halloysite clay nanotubes. Biomacromol 11(3):820–82610.1021/bm9014446 ↗
84. Feng YC, Cheng YF (2016) Fabrication of Halloysite nanocontainers and their compatibility with epoxy coating for anti-corrosion performance. Corros Eng Sci Technol 51(7):489–49710.1080/1478422X.2016.1142161 ↗
85. Krishnaiah P, Manickam S, Ratnam CT, Raghu MS, Parashuram L, Prasanna Kumar S, Jeon BH (2021) Mechanical, thermal and dynamic-mechanical studies of functionalized halloysite nanotubes reinforced polypropylene composites. Polym Polym Compos 29(8):1212–122110.1177/0967391120965115 ↗
86. Liu C, Luo YF, Jia ZX, Zhong BC, Li SQ, Guo BC, Jia DM (2011) Enhancement of mechanical properties of poly (vinyl chloride) with polymethyl methacrylate-grafted halloysite nanotube. Express Polym Lett 5(7):591–60310.3144/expresspolymlett.2011.58 ↗
87. Luo W, Wang X, Meyers C, Wannenmacher N, Sirisaksoontorn W, Lerner MM, Ji X (2013) Efficient fabrication of nanoporous Si and Si/Ge enabled by a heat scavenger in magnesiothermic reactions. Sci Rep 3(1):1–7
88. Xavier JR, Vinodhini SP (2022) Effects of incorporating silanized nanoclay on the barrier, hydrophobic and mechanical properties of epoxy resin in chloride environment. Ind Eng Chem Res 61(20):6973–698610.1021/acs.iecr.2c00786 ↗
89. Xavier JR (2022) Investigation into the effects of silanized nanoclay on the barrier properties of epoxy resin in chloride environment. J Mol Struct 1264:13326410.1016/j.molstruc.2022.133264 ↗
90. Paran SMR, Naderi G, Ghoreishy MHR (2017) Microstructure and mechanical properties of thermoplastic elastomer nanocomposites based on PA6/NBR/HNT. Polym Compos 38:E451–E46110.1002/pc.23936 ↗
91. Sikora JW, Gajdos I, Puszka A (2019) Polyethylene-matrix composites with halloysite nanotubes with enhanced physical/thermal properties. Polymers 11(5):78710.3390/polym11050787 ↗
92. Du M, Guo B, Liu M, Jia D (2006) Preparation and characterization of polypropylene grafted halloysite and their compatibility effect to polypropylene/halloysite composite. Polym J 38(11):1198–120410.1295/polymj.PJ2006038 ↗
93. He Y, Kong W, Wang W, Liu T, Liu Y, Gong Q, Gao J (2012) Modified natural halloysite/potato starch composite films. Carbohyd Polym 87(4):2706–271110.1016/j.carbpol.2011.11.057 ↗
94. Handge UA, Hedicke-Hochstotter K, Altstadt V (2010) Composites of polyamide 6 and silicate nanotubes of the mineral halloysite: influence of molecular weight on thermal, mechanical and rheological properties. Polymer 51(12):2690–269910.1016/j.polymer.2010.04.041 ↗
95. Gaaz TS, Sulong AB, Ansari MNM, Kadhum AAH, Al-Amiery AA, Al-Furjan MSH (2017) Effect of halloysite nanotubes loading on thermo-mechanical and morphological properties of polyurethane nanocomposites. Mater Technol 32(7):430–44210.1080/10667857.2016.1265278 ↗
96. Yuan P, Southon PD, Liu Z, Green ME, Hook JM, Antill SJ, Kepert CJ (2008) Functionalization of halloysite clay nanotubes by grafting with γ-aminopropyltriethoxysilane. J Phys Chem C 112(40):15742–1575110.1021/jp805657t ↗
97. Wan C, Chen B (2012) Reinforcement and interphase of polymer/graphene oxide nanocomposites. J Mater Chem 22(8):3637–364610.1039/c2jm15062j ↗
98. Fan J, Yang J, Wang L, Li H, Tian J, Ye J, Zhao Y (2021) Enhanced mechanical properties of epoxy nanocomposites with mildly surface-functionalized graphene oxide by tuned amine species. Appl Surf Sci 558:14996410.1016/j.apsusc.2021.149964 ↗
99. Vinodhini SP, Xavier JR (2021) Evaluation of corrosion protection performance and mechanical properties of epoxy-triazole/graphene oxide nanocomposite coatings on mild steel. J Mater Sci 56:7094–7110. https://doi.org/10.1007/s10853-020-05636-w10.1007/s10853-020-05636-w ↗
100. Pour ZS, Ghaemy M (2016) Polymer grafted graphene oxide: for improved dispersion in epoxy resin and enhancement of mechanical properties of nanocomposite. Compos Sci Technol 136:145–15710.1016/j.compscitech.2016.10.014 ↗