Evaluation of synthesized polyaniline nanofibres as corrosion protection film coating on copper substrate by electrophoretic deposition
Source abstract
Abstract
Abstract In this current paper, we report the use of inexpensive, simple electrophoretic deposition (EPD) technique in developing polyaniline (PANI) aqueous colloidal suspension coating on copper (Cu) substrate. Polyaniline nanoparticle films were deposited electrophoretically on the surface of copper sheet electrode. A colloidal suspension with high stability was produced by a liquid polyaniline in the presence of formic acid and acetonitrile as electrolyte for the EPD process. The suspension of the PANI was characterized by measuring the zeta potential of the suspension using zeta-sizer analyser. The PANI coating was used as barrier for corrosion protection of the Cu sheet. Operating parameters such as operating time, applied voltage, and the concentration were used with deposition at the cathode. Characterization such as XRD, SEM, FT-IR, and UV–Vis was carried out, and the corrosion protection offered by the PANI on the Cu surface was examined using potentiodynamic (Tafel) polarization in 3.5% NaCl solution at room temperature. As a result, the optimum parameters for obtaining a homogenous coating on the Cu sheet were attained at the voltage of 15 V and deposition time of 180 s with 50 mg/mL PANI concentration. The attained results indicated inhibition efficiency for PANI deposit of 92.92% indicating protection against corrosion.
Source: crossref · Quality: baseline
Research context
OpenAlex topics: Conducting polymers and applications · Electrophoretic Deposition in Materials Science · Advanced Sensor and Energy Harvesting Materials
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (66)
Show source-provided references
1. Sauvant-Moynot V, Gonzalez S, Kittel J (2008) Self-healing coatings: an alternative route for anticorrosion protection. Prog Org Coat 63(3):307–315. https://doi.org/10.1016/j.porgcoat.2008.03.00410.1016/j.porgcoat.2008.03.004 ↗
2. Su F, Yao K (2014) Facile fabrication of superhydrophobic surface with excellent mechanical abrasion and corrosion resistance on copper substrate by a novel method. ACS Appl Mater Interfaces 6(11):8762–8770. https://doi.org/10.1021/am501539b10.1021/am501539b ↗
3. Zhao Y, Xing C, Zhang Z, Yu L (2017) Superhydrophobic polyaniline/polystyrene micro/nanostructures as anticorrosion coatings. React Funct Polym 119(February):95–104. https://doi.org/10.1016/j.reactfunctpolym.2017.08.00510.1016/j.reactfunctpolym.2017.08.005 ↗
4. Zaghloul MMY, Zaghloul MMY (2017) Influence of flame retardant magnesium hydroxide on the mechanical properties of high density polyethylene composites. J Reinf Plast Compos 36(24):1802–1816. https://doi.org/10.1177/073168441772714310.1177/0731684417727143 ↗
5. Zaghloul MMYM (2018) Mechanical properties of linear low-density polyethylene fire-retarded with melamine polyphosphate. J Appl Polym Sci 135:46770. https://doi.org/10.1002/app.4677010.1002/app.46770 ↗
6. Zaghloul MMYM et al (2021) Wear Behaviour of polymeric materials reinforced with man-made fibres: a comprehensive review about fibre volume fraction influence on wear performance. J Reinf Plast Compos 215–241. https://doi.org/10.1177/0731684421105173310.1177/07316844211051733 ↗
7. Caldona EB, de Leon ACC, Pajarito BB, Advincula RC (2017) Novel anti-corrosion coatings from rubber-modified polybenzoxazine-based polyaniline composites. Appl Surf Sci 422:162–171. https://doi.org/10.1016/j.apsusc.2017.05.08310.1016/j.apsusc.2017.05.083 ↗
8. Donescu D et al (2017) Synthesis and magnetic properties of inverted core-shell polyaniline-ferrite composite. Appl Surf Sci 414:8–17. https://doi.org/10.1016/j.apsusc.2017.04.06110.1016/j.apsusc.2017.04.061 ↗
9. Zaghloul MMY, Zaghloul MYM, Zaghloul MMY (2017) Experimental and modeling analysis of mechanical-electrical behaviors of polypropylene composites filled with graphite and MWCNT fillers. Polym Testing 63:467–474. https://doi.org/10.1016/j.polymertesting.2017.09.00910.1016/j.polymertesting.2017.09.009 ↗
10. Jafari Y, Ghoreishi SM, Shabani Nooshabadi M (2017) Electrosynthesis, characterization and corrosion inhibition study of dbsa-doped polyaniline coating on 310 stainless steel. Iran J Chem Chem Eng 36(5):23–32
11. Nagashima A et al (1993) Electronic structure of monolayer graphite on some transition metal carbide surfaces. Surf Sci 287–288(PART 2):609–613. https://doi.org/10.1016/0039-6028(93)91037-P10.1016/0039-6028(93)91037-P ↗
12. Nanoelectronics G et al (2007) Berg+04Jpcb. 1–5. https://doi.org/10.1021/jp040650f.10.1021/jp040650f ↗
13. Wu Z-S et al (2009) Field emission of single-layer graphene films prepared by electrophoretic deposition. Adv Mater 21(17):1756–1760. https://doi.org/10.1002/adma.20080256010.1002/adma.200802560 ↗
14. Zhu G, Pan L, Lu T, Xu T, Sun Z (2011) Electrophoretic deposition of reduced graphene-carbon nanotubes composite films as counter electrodes of dye-sensitized solar cells. J Mater Chem 21(38):14869–14875. https://doi.org/10.1039/c1jm12433a10.1039/c1jm12433a ↗
15. Eda G, Emrah Unalan H, Rupesinghe N, Amaratunga GAJ, Chhowalla M (2008) Field emission from graphene based composite thin films. Appl Phys Lett 93(23):1–4. https://doi.org/10.1063/1.302833910.1063/1.3028339 ↗
16. Nethravathi C, Rajamathi M (2008) Chemically modified graphene sheets produced by the solvothermal reduction of colloidal dispersions of graphite oxide. Carbon N Y 46(14):1994–1998. https://doi.org/10.1016/j.carbon.2008.08.01310.1016/j.carbon.2008.08.013 ↗
17. Zaghloul MYM, Zaghloul MMY, Zaghloul MMY (2021) Developments in polyester composite materials—an in-depth review on natural fibres and nano fillers. Compos Struct 278:114698. https://doi.org/10.1016/j.compstruct.2021.11469810.1016/j.compstruct.2021.114698 ↗
18. Park JH, Kim JS, Park JM (2013) Electrophoretic deposition of nano-ceramics for the photo-generated cathodic corrosion protection of steel substrates. Surf Coat Technol 236:172–181. https://doi.org/10.1016/j.surfcoat.2013.09.04410.1016/j.surfcoat.2013.09.044 ↗
19. Zaghloul MMY, Mohamed YS, El-Gamal H (2018) Fatigue and tensile behaviors of fiber-reinforced thermosetting composites embedded with nanoparticles. J Compos Mater 53(6):709–718. https://doi.org/10.1177/002199831879009310.1177/0021998318790093 ↗
20. Mohamed YS, El-Gamal H, Zaghloul MMYM (2018) Microhardness behavior of fiber reinforced thermosetting composites embedded with cellulose nanocrystals. Alexandria Eng J 57(4):4113–4119. https://doi.org/10.1016/j.aej.2018.10.01210.1016/j.aej.2018.10.012 ↗
21. Zaghloul MMY (2018) Effect of nano particles on the mechanical properties of thermosetting polymeric materials reinforced with glass fibers, M. Sc thesis, Faculty of Engineering, Alexandria University, Egypt
22. Aly KI, Mahdy A, Hegazy MA, Al-Muaikel NS, Kuo S-W, Gamal Mohamed M (2020) Corrosion resistance of mild steel coated with phthalimide-functionalized polybenzoxazines. Coatings 10:1114. https://doi.org/10.3390/coatings1011111410.3390/coatings10111114 ↗
23. Mohamed MG, Kuo SW, Mahdy A, Ghayd IM, Aly KI (2020) Bisbenzylidene cyclopentanone and cyclohexanone-functionalized polybenzoxazine nanocomposites: synthesis, characterization, and use for corrosion protection on mild steel. Mater Today Commun 25:101418. https://doi.org/10.1016/j.mtcomm.2020.10141810.1016/j.mtcomm.2020.101418 ↗
24. Kiran NU, Dey S, Singh BP, Besra L (2017) Graphene coating on copper by electrophoretic deposition for corrosion prevention. Coatings 7(12):214. https://doi.org/10.3390/coatings712021410.3390/coatings7120214 ↗
25. Stejskal J (2017) Conducting polymer hydrogels, vol 71. Elsevier, p 2
26. Li G, Martinez C, Semancik S (2005) Controlled electrophoretic patterning of polyaniline from a colloidal suspension. J Am Chem Soc 127(13):4903–4909. https://doi.org/10.1021/ja044176310.1021/ja0441763 ↗
27. Gomes EC, Oliveira MAS (2012) Chemical polymerization of aniline in hydrochloric acid (HCl) and formic acid (HCOOH) media. Differences between the two synthesized polyanilines. Am J Polym Sci 2(2):5–13. https://doi.org/10.5923/j.ajps.20120202.0210.5923/j.ajps.20120202.02 ↗
28. Krishnani KK et al (2013) Hexavalent chromium removal mechanism using conducting polymers. J Hazard Mater 252–253:99–106. https://doi.org/10.1016/j.jhazmat.2013.01.07910.1016/j.jhazmat.2013.01.079 ↗
29. Hares E, Hammad AS (2019) Electrophoretic deposition of graphene oxide nanosheets on copper pipe for electrophoretic deposition of graphene oxide nanosheets on copper. Arab J Sci Eng 44(6):5559–5569. https://doi.org/10.1007/s13369-019-03872-010.1007/s13369-019-03872-0 ↗
30. Amrollahi P, Krasinski JS, Vaidyanathan R, Tayebi L, Vashaee D (2016) Electrophoretic deposition (EPD): fundamentals and applications from nano- to microscale structures. Handbook of nanoelectrochemistry. Springer International Publishing, Cham, pp 561–59110.1007/978-3-319-15266-0_7 ↗
31. Boccaccini AR (2004) The use of electrophoretic deposition for the fabrication of ceramic matrix composites. Mater Sci Forum 455:221–224. https://doi.org/10.4028/www.scientific.net/msf.455-456.22110.4028/www.scientific.net/msf.455-456.221 ↗
32. Wu T-M, Lin Y-W, Liao C-S (2004) Preparation and characterization of polyaniline/multi-walled carbon nanotube composites. Corbon 43(4):734–740. https://doi.org/10.1016/j.carbon.2004.10.04310.1016/j.carbon.2004.10.043 ↗
33. Hamid ZA, Gomaa MH, Rehim SSA, Hamid MA, Ibrahim A (2019) Synthesis and Characterization of nanostructured polyaniline thin films with superhydrophobic properties. Coatings 9(11):748. https://doi.org/10.3390/COATINGS911074810.3390/COATINGS9110748 ↗
34. Reka Devi M, Saranya A, Pandiarajan J, Dharmaraja J, Prithivikumaran N, Jeyakumaran N (2019) Fabrication, spectral characterization, XRD and SEM studies on some organic acids doped polyaniline thin films on glass substrate. J King Saud Univ Sci 31(4):1290–1296. https://doi.org/10.1016/j.jksus.2018.02.00810.1016/j.jksus.2018.02.008 ↗
35. Chakraborty P, Kothari A, Nagarajan R (2018) Highly ordered polyaniline as an efficient dye remover. Adsorpt Sci Technol 36(1–2):429–440. https://doi.org/10.1177/026361741770014610.1177/0263617417700146 ↗
36. Elnaggar EM, Kabel KI, Farag AA, Al-Gamal AG (2017) Comparative study on doping of polyaniline with graphene and multi-walled carbon nanotubes. J Nanostructure Chem 7(1):75–83. https://doi.org/10.1007/S40097-017-0217-610.1007/S40097-017-0217-6 ↗
37. Ali Y, Kumar V, Sonkawade RG, Shirsat MD, Dhaliwal AS (2013) Two-step electrochemical synthesis of Au nanoparticles decorated polyaniline nanofiber. Vacuum 93:79–83. https://doi.org/10.1016/J.VACUUM.2013.01.00710.1016/J.VACUUM.2013.01.007 ↗
38. Shaikh AA, Waikar MR, Sonkawade RG (2019) Effect of different concentrations of KMnO4 precursor on supercapacitive properties of MnO thin films. J Electron Mater 48(12):8116–8128. https://doi.org/10.1007/S11664-019-07648-Y10.1007/S11664-019-07648-Y ↗
39. Butoi B, Groza A, Dinca P, Balan A, Barna V (2017) Morphological and structural analysis of polyaniline and poly(o-anisidine) layers generated in a dc glow discharge plasma by using an oblique angle electrode deposition configuration. Polymers 9(12):732. https://doi.org/10.3390/POLYM912073210.3390/POLYM9120732 ↗
40. Freitas TV, Sousa EA, Fuzari GC, Arlindo PS (2018) Different morphologies of polyaniline nanostructures synthesized by interfacial polymerization. Mater Lett 224:42–45. https://doi.org/10.1016/j.matlet.2018.04.06210.1016/j.matlet.2018.04.062 ↗
41. Mitra M et al (2015) Reduced graphene oxide-polyaniline composites - Synthesis, characterization and optimization for thermoelectric applications. RSC Adv 5(39):31039–31048. https://doi.org/10.1039/c5ra01794g10.1039/c5ra01794g ↗
42. Hassanien AS, Akl AA (2019) Effect of Se addition on optical and electrical properties of chalcogenide CdSSe thin films. Superlattices Microstruct 89(January):153–169. https://doi.org/10.1016/j.spmi.2015.10.04410.1016/j.spmi.2015.10.044 ↗
43. Liang S, Yi M, Shen Z, Liu L, Zhang X, Ma S (2014) One-step green synthesis of graphene nanomesh by fluid-based method. RSC Adv 4(31):16127. https://doi.org/10.1039/c4ra01250j10.1039/c4ra01250j ↗
44. Chen J, Wang H, Deng J, Xu C, Wang Y (2018) Low-crystalline tungsten trioxide anode with superior electrochemical performance for flexible solid-state asymmetry supercapacitor. J Mater Chem A 6(19):8986–8991. https://doi.org/10.1039/C8TA01323C10.1039/C8TA01323C ↗
45. Sawant SA, Waikar MR, Rasal AS, Chodankar GR (2021) Chemical synthesis and supercapacitive evaluation of polyaniline nanofibers (PANINFs). J Mater Sci Mater Electron 32(9):11865–11876. https://doi.org/10.1007/s10854-021-05816-710.1007/s10854-021-05816-7 ↗
46. Kowalczuk D, Pitucha M (2019) Application of FTIR method for the assessment of immobilization of active substances in the matrix of bio medical materials. Materials 12(18):2972. https://doi.org/10.3390/ma1218297210.3390/ma12182972 ↗
47. Ami D, Natalello A, Doglia SM (2012) Fourier transform infrared microspectroscopy of complex biological systems: from intact cells to whole organisms. In: Uversky V, Dunker A (eds) Intrinsically disordered protein analysis. Methods in molecular biology (Methods and protocols), vol 895. Humana Press, Totowa, NJ. https://doi.org/10.1007/978-1-61779-927-3_710.1007/978-1-61779-927-3_7 ↗
48. Ramírez-Hernández A, Aguilar-Flores C, Aparicio-Saguilán A (2019) Fingerprint analysis of ftir spectra of polymers containing vinyl acetate. DYNA 86(209):198–205. https://doi.org/10.15446/DYNA.V86N209.7751310.15446/DYNA.V86N209.77513 ↗
49. Radhakrishnan S, Rao CRK, Vijayan M (2011) Performance of conducting polyaniline-DBSA and polyaniline-DBSA/Fe3O4 composites as electrode materials for aqueous redox supercapacitors. J Appl Polym Sci 122(3):1510–1518. https://doi.org/10.1002/app.3423610.1002/app.34236 ↗
50. Bian C, Yu Y, Xue G (2007) Synthesis of conducting polyaniline/TiO2 composite nanofibres by one-step in situ polymerization method. J Appl Polym Sci 104(1):21–26. https://doi.org/10.1002/APP.2563610.1002/APP.25636 ↗
51. Babazadeh M, Zalloi F, Olad A (2014) Fabrication of conductive polyaniline nanocomposites based on silica nanoparticles via in-situ chemical oxidative polymerization technique. Synth React Inorg Metal-Org Nano-Met Chem 45(1):86–91. https://doi.org/10.1080/15533174.2013.81868710.1080/15533174.2013.818687 ↗
52. Mostafaei A, Zolriasatein A (2012) Synthesis and characterization of conducting polyaniline nanocomposites containing ZnO nanorods. Prog Nat Sci Mater Int 22(4):273–280. https://doi.org/10.1016/J.PNSC.2012.07.00210.1016/J.PNSC.2012.07.002 ↗
53. Melad O, Alhendawi H, Fayyad M (2014) The Influence of organic solvents on the polymerization of polyaniline. Res Rev J Chem 3(4): 40–47. Available: http://www.rroij.com/open-access/the-influence-of-organic-solvents-on-the-polymerization-of-polyaniline-40-47.pdf. (Online)
54. Direksilp C, Sirivat A (2020) Synthesis and characterization of hollow-sphered poly(N-methyaniline) for enhanced electrical conductivity based on the anionic surfactant templates and doping. Polymers 12(5):1023. https://doi.org/10.3390/POLYM1205102310.3390/POLYM12051023 ↗
55. Beygisangchin M, Rashid SA, Shafie S, Sadrolhosseini AR, Lim HN (2021) Preparations, properties, and applications of polyaniline and polyaniline thin films—a review. Polymers (Basel) 13(12):2003. https://doi.org/10.3390/polym1312200310.3390/polym13122003 ↗
56. Lowry GV et al (2016) Environmental science nano guidance to improve the scientific value of zeta- potential measurements in nanoEHS. Environ Sci Nano 3:953–965. https://doi.org/10.1039/C6EN00136J10.1039/C6EN00136J ↗
57. Taqvi S, Bassioni G (2015) Understanding wettability through zeta potential measurements. J Chem 1:1–19
58. Ostolska I (2014) Application of the zeta potential measurements to explanation of colloidal Cr2O3 stability mechanism in the presence of the ionic polyamino acids. Colloid Polym Sci 292:20–31. https://doi.org/10.1007/s00396-014-3276-y10.1007/s00396-014-3276-y ↗
59. Çabuk M (2016) Colloidal behaviors of conducting polymer/chitosan composite particles. In: Rahman M, Asiri A (eds) Advances in colloid science, IntechOpen. https://doi.org/10.5772/6512510.5772/65125 ↗
60. Deshpande PP, Jadhav NG, Gelling VJ, Sazou D (2014) Conducting polymers for corrosion protection: a review. J Coat Technol Res 11(4):473–494. https://doi.org/10.1007/s11998-014-9586-710.1007/s11998-014-9586-7 ↗
61. He W et al (2013) Electrophoretic deposition of graphene oxide as a corrosion inhibitor for sintered NdFeB. Appl Surf Sci 279:416–423. https://doi.org/10.1016/j.apsusc.2013.04.13010.1016/j.apsusc.2013.04.130 ↗
62. Al-Amiery AA, Ahmed MHO, Abdullah TA, Gaaz TS, Kadhum AAH (2018) Electrochemical studies of novel corrosion inhibitor for mild steel in 1 M hydrochloric acid. Results Phys 9:978–981. https://doi.org/10.1016/j.rinp.2018.04.00410.1016/j.rinp.2018.04.004 ↗
63. Gallegos-Melgar A, Serna SA, Lázaro I, Gutiérrez-Castañeda E-J, Mercado-Lemus VH, Arcos-Gutierrez H, Hernández-Hernández M, Porcayo-Calderón J, Mayen J, Monroy MDA (2020) Potentiodynamic polarization performance of a novel composite coating system of Al2O3/chitosan-sodium alginate, applied on an aluminum AA6063 alloy for protection in a chloride ions environment. Coatings 10(1):45. https://doi.org/10.3390/coatings1001004510.3390/coatings10010045 ↗
64. Dhanabal T, Amirthaganesan G, Ravichandran J (2011) Pitting corrosion protection of low nickel stainless steel by electropolymerized conducting polymer coating in 0.5 M NaCl solution. Bull Mater Sci 34(3):563–569. https://doi.org/10.1007/s12034-011-0113-510.1007/s12034-011-0113-5 ↗
65. Chen F, Liu P (2011) Conducting polyaniline nanoparticles and their dispersion for waterborne corrosion protection coatings. ACS Appl Mater Interfaces 3(7):2694–2702. https://doi.org/10.1021/AM200488M10.1021/AM200488M ↗
66. Sarkar N, Sahoo G, Das R, Prusty G, Sahu D, Swain SK (2016) Anticorrosion performance of three-dimensional hierarchical PANI@BN nanohybrids. Ind Eng Chem Res 55(11):2921–2931. https://doi.org/10.1021/acs.iecr.5b0488710.1021/acs.iecr.5b04887 ↗