Phase transformation kinetics during continuous heating of a β-quenched Ti–10V–2Fe–3Al alloy
Source abstract
Abstract
The effect of heating rate on the phase transformation kinetics of a Ti–10V–2Fe–3Al metastable b titanium alloy quenched from the b field is investigated by fast in situ high energy synchrotron X-ray diffraction and differential scanning calorimetry. The initial microstructure is formed by a00 martensite and fine xath particles distributed in the retained b-phase matrix. The phase transformation sequence varies with the heating rate as revealed by analysis of the continuous evolution of crystallographic relationships between phases. At low temperatures an athermal reversion of a00 martensite into b takes place. This reversion occurs to a larger extent with increasing heating rate. On the other hand, diffusion–driven precipitation and growth of the x phase is observed for lower heating rates accompanying the reverse martensitic transformation. Furthermore, the results show that the stable a phase can form through three different paths: (a) from the x phase, (b) from a00 martensite, and (c) from the b phase.
Source: openaire · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Titanium Alloys Microstructure and Properties · Intermetallics and Advanced Alloy Properties · Additive Manufacturing Materials and Processes
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (61)
Show source-provided references
1. Banerjee D, Williams JC (2013) Perspectives on titanium science and technology. Acta Mater 61:844–87910.1016/j.actamat.2012.10.043 ↗
2. Boyer RR, Briggs RD (2005) The use of titanium alloys in the aerospace industry. J Mater Eng Perform 14:681–68510.1361/105994905X75448 ↗
3. Maeshima T, Nishida M (2004) Shape memory and mechanical properties of biomedical Ti–Sc–Mo alloys. Mater Trans 45:1101–110510.2320/matertrans.45.1101 ↗
4. Duerig TW, Williams JC (1984) Microstructure and properties of beta titanium alloys. In: Boyer RR, Rosenberg HW (eds) Beta titanium alloys in the 1980’s. The Metallurgical Society of AIME, Atlanta, pp 16–69
5. Miyazaki S, Sachdeva RL (2009) Shape memory effect and superelasticity in Ti–Ni alloys. In: Yoneyama T, Miyazaki S (eds) Shape memory alloys for biomedical applications. Woodhead, Cambridge, pp 3–1810.1533/9781845695248.1.3 ↗
6. Duerig TW, Albrecht J, Richter D, Fischer P (1982) Formation and reversion of stress induced martensite in Ti–10V–2Fe–3Al. Acta Metall 30:2161–217210.1016/0001-6160(82)90137-7 ↗
7. Ohmori Y, Ogo T, Nakai K, Kobayashi S (2001) Effects of ω-phase precipitation on β → α, α″ transformations in a metastable β titanium alloy. Mater Sci Eng A 312:182–18810.1016/S0921-5093(00)01891-8 ↗
8. Ivasishin OM, Markovsky PE, Semiatin SL, Ward CH (2005) Aging of coarse- and fine-grained β titanium alloys. Mater Sci Eng A 405:296–30510.1016/j.msea.2005.06.027 ↗
9. Nag S, Banerjee R, Srinivasan R, Hwang JY, Harper M, Fraser HL (2009) ω-Assisted nucleation and growth of α precipitates in the Ti–5Al–5Mo–5V–3Cr–0.5Fe β titanium alloy. Acta Mater 57:2136–214710.1016/j.actamat.2009.01.007 ↗
10. Bein S, Béchet J (1996) Phase transformation kinetics and mechanisms in titanium alloys Ti-6.2.4.6, β-CEZ and Ti-10.2.3. J Phys IV 6:99–108
11. Malinov S, Sha W, Markovsky P (2003) Experimental study and computer modeling of the β → α+β phase transformation in β21s alloy at isothermal conditions. J Alloys Compd 348:110–11810.1016/S0925-8388(02)00804-6 ↗
12. Bruneseaux F, Geandier G, Gautier E, Appolaire B, Dehmas M, Boulet P (2007) In situ characterization of the transformation sequences of Ti17 alloy by high energy X-ray diffraction: Influence of the thermal path. In: Niinomi M, Akiyama S, Hagiwara M, Ikeda M, Maruyama K (eds) Ti-2007 science and technology. The Japan Institute of Metals, Sendai, pp 563–566
13. Contrepois Q, Carton M, Lecomte-Beckers J (2011) Characterization of the β phase decomposition in Ti–5Al–5Mo–5V–3Cr at slow heating rates. Open J Met 1:1–1110.4236/ojmetal.2011.11001 ↗
14. Carton M, Jacques P, Clément N, Lecomte-Beckers J (2007) Study of transformations and microstructural modifications in Ti-LCB and Ti-555 alloys using differential scanning calorimetry. In: Niinomi M, Akiyama S, Hagiwara M, Ikeda M, Maruyama K (eds) Ti-2007 science and technology. The Japan Institute of Metals, Sendai, pp 491–494
15. Liss KD, Bartels A, Schreyer A, Clemens H (2003) High-energy X-rays: a tool for advanced bulk investigations in materials science and physics. Texture Microstruct 35:219–25210.1080/07303300310001634952 ↗
16. Aeby-Gautier E, Bruneseaux F, Teixeira J, Appolaire B, Geandier G, Denis S (2007) Microstructural formation in Ti alloys: in-situ characterization of phase transformation kinetics. JOM 59:54–5810.1007/s11837-007-0011-x ↗
17. Jones NG, Dashwood RJ, Jackson M, Dye D (2009) β phase decomposition in Ti–5Al–5Mo–5V–3Cr. Acta Mater 57:3830–383910.1016/j.actamat.2009.04.031 ↗
18. Wollmann M, Kiese J, Wagner L (2011) Properties and applications of titanium alloys in transport. In: Zhou L, Chang H, Lu Y, Xu D (eds) Ti-2011. Science Press Beijing, Beijing, pp 837–844
19. Eylon D, Vassel A, Combres Y, Boyer RR, Bania PJ, Schutz RW (1994) Issues in the development of beta titanium alloys. JOM 46:14–1510.1007/BF03220741 ↗
20. Boyer R, Welsch G, Collings EW (1994) Material properties handbook: titanium alloys, 4th edn. ASM International, Ohio
21. Lin W, Dalmazzone D, Fürst W, Delahaye A, Fournaison L, Clain P (2013) Acurate DSC measurement of the phase transition temperature in the TBPB–water system. J Chem Thermodyn 61:132–13710.1016/j.jct.2013.02.005 ↗
22. Pompe G, Schulze U, Hu J, Pionteck J, Höhne GWH (1999) Separation of glass transition and melting polyethylene/poly(butyl-methacrylate-co-methyl-methacrylate) interpenetrating polymer networks in TMDSC and DSC curves. Thermochim Acta 337:179–18610.1016/S0040-6031(99)00164-1 ↗
23. ID15 - High Energy Scattering Beamline, ESRF (1999). http://www.esrf.eu/UsersAndScience/Experiments/StructMaterials/ID15 . Accessed 09 July 2014
24. P07 - The High Energy Materials Science Beamline, DESY (2010). http://photon-science.desy.de/facilities/petra_iii/beamlines/p07_high_energy_materials_science/index_eng.html . Accessed 09 July 2014
25. Staron P, Fischer T, Lippmann T, Stark A, Daneshpour S, Schnubel D, Uhlmann E, Gerstenberger R, Camin B, Reimers W, Eidenberger E, Clemens H, Huber N, Schreyer A (2011) In situ experiments with synchrotron high-energy X-rays and neutrons. Adv Eng Mater 13:658–66310.1002/adem.201000297 ↗
26. Hammersley A, Svensson SO, Thompson A (1994) Calibration and correction of spatial distortions in 2D detector systems. Nucl Instrum Methods Phys Res A 346:312–32110.1016/0168-9002(94)90720-X ↗
27. Abramoff MD, Magalhães PJ, Ram SJ (2004) Image processing with imageJ. Biophoton Int 11:36–41
28. Lutterotti L, Matthies S, Wenk HR, Schultz AJ, Richardson J (1997) Combined texture and structure analysis of deformed limestone from time-of-flight neutron diffraction spectra. J Appl Phys 81:594–60010.1063/1.364220 ↗
29. Cai MH, Lee CY, Kang S, Lee YK (2011) Fine-grained structure fabricated by strain-induced martensite and its reverse transformations in a metastable β titanium alloy. Scripta Mater 64:1098–110110.1016/j.scriptamat.2011.02.030 ↗
30. Banerjee S, Mukhopadhyay P (2007) Phase transformations: examples from titanium and zirconium alloys, 1st edn. Elsevier, Oxford
31. Willams JC, Fontaine D, Paton NE (1973) The ω-phase as an example of an unusual shear transformation. Metall Trans 4:2701–270810.1007/BF02644570 ↗
32. Sass SL (1972) The structure and decomposition of Zr and Ti B.C.C. solid solutions. J Less Common Met 28:157–17310.1016/0022-5088(72)90177-4 ↗
33. Li SJ, Cui TC, Hao YL, Yang R (2008) Fatigue properties of a metastable β-type titanium alloy with reversible phase transformation. Acta Biomater 4:305–31710.1016/j.actbio.2007.09.009 ↗
34. Dutta J, Ananthakrishna G, Banerjee S (2012) On the athermal nature of the β to ω transformation. Acta Mater 60:556–56410.1016/j.actamat.2011.10.005 ↗
35. Mantani Y, Takemoto Y, Hida M, Sakakibara A, Tajima M (2004) Phase transformation of a α″ martensite structure by aging in Ti-8 mass%Mo alloy. Mater Trans 45:1629–163410.2320/matertrans.45.1629 ↗
36. Popov AA, Illarionov AG, Grib SV, Elkina AO (2011) Formation conditions of omega phase in the titanium alloys after quenching. In: Zhou L, Chang H, Lu Y, Xu D (eds) Ti-2011. Science Press Beijing, Beijing, pp 694–697
37. Bönisch M, Calin M, Waitz T, Panigrahi A, Zehetbauer M, Gebert A, Skrotzki W, Eckert J (2013) Thermal stability and phase transformations of martensitic Ti–Nb alloys. Sci Technol Adv Mater 14:1–910.1088/1468-6996/14/5/055004 ↗
38. Liss KD, Stark A, Bartels A, Clemens H, Buslaps T, Phelan D, Yeoh LA (2008) Directional atomic rearrangements during transformations between the α- and γ-phases in titanium aluminides. Adv Eng Mater 10:389–39210.1002/adem.200700322 ↗
39. Ramsteiner IB, Shchyglo O, Mezger M, Udyansky A, Bugaev V, Schöder S, Reichert H, Dosch H (2008) Omega-like diffuse X-ray scattering in Ti–V caused by static lattice distortions. Acta Mater 56:1298–130510.1016/j.actamat.2007.11.015 ↗
40. Settefrati A, Dehmas M, Geandier G, Denand B, Aeby-Gautier E, Appolaire B, Khelifati G, Delfosse J (2011) Precipitation sequences in beta metastable phase of Ti-5553 alloy during ageing. In: Zhou L, Chang H, Lu Y, Xu D (eds) Ti-2011. Science Press Beijing, Beijing, pp 468–472
41. Basak CB, Neogy S, Srivastava D, Dey GK, Banerjee S (2011) Disordered bcc γ-phase to δ-phase transformation in Zr-rich U-Zr alloy. Philos Mag 91:3290–330610.1080/14786435.2011.577756 ↗
42. Banerjee D, Muraleedharan K, Strudel JL (1998) Substructure in titanium alloy martensite. Philos Mag A 77:299–32310.1080/01418619808223754 ↗
43. Obbard EG, Hao YL, Talling RJ, Li SJ, Zhang YW, Dye D, Yang R (2011) The effect of oxygen on α″ martensite and superelasticity in Ti–24Nb–4Zr–8Sn. Acta Mater 59:112–12510.1016/j.actamat.2010.09.015 ↗
44. Banumathy S, Mandal RK, Singh AK (2009) Structure of orthorhombic martensitic phase in binary Ti–Nb alloys. J Appl Phys 106:093518.1–093518.610.1063/1.3255966 ↗
45. Brown ARG, Clark D, Eastabrook J, Jepson KS (1964) The titanium–niobium system. Nature 201:914–91510.1038/201914a0 ↗
46. Aurelio G, Fernández-Guillermet A, Cuello GJ, Campo J (2002) Metastable phases in the Ti–V system: part I. Neutron diffraction study and assessment of structural properties. Metall Mater Trans A 33:1307–131710.1007/s11661-002-0057-x ↗
47. Kim HY, Ikehara Y, Kim JI, Hosoda H, Miyazaki S (2006) Martensitic transformation, shape memory effect and superelasticity of Ti–Nb binary alloys. Acta Mater 54:2419–242910.1016/j.actamat.2006.01.019 ↗
48. Williams JC, Hickman BS, Marcus HL (1971) The effect of omega phase on the mechanical properties of titanium alloys. Metall Trans 2:1913–191910.1007/BF02913423 ↗
49. Šmilauerová J, Janeček M, Harcuba P, Stráský J (2013) Aging study of TIMETAL LCB titanium alloy. Proc. Met.. http://www.metal2014.com/files/proceedings/12/reports/1536.pdf . Accessed 09 July 2014
50. Hickman BS (1969) The formation of omega phase in titanium and zirconium alloys: a review. J Mater Sci 4:554–563. doi: 10.1007/BF0055021710.1007/BF00550217 ↗
51. Devaraj A, Nag S, Srinivasan R, Williams REA, Banerjee S, Banerjee R, Fraser HL (2012) Experimental evidence of concurrent compositional and structural instabilities leading to ω precipitation in titanium–molybdenum alloys. Acta Mater 60:596–60910.1016/j.actamat.2011.10.008 ↗
52. Akahama Y, Kawamura H, Bihan TL (2001) New δ (distorted-bcc) titanium to 220 GPa. Phys Rev Lett 87:275503.1–275503.410.1103/PhysRevLett.87.275503 ↗
53. Vohra YK, Spencer PT (2001) Novel gamma-phase of titanium metal at megabar pressures. Phys Rev Lett 86:3068–307110.1103/PhysRevLett.86.3068 ↗
54. Duerig TW, Middleton RM, Terlinde GT, Williams JC (1980) Stress assisted transformation in Ti–10V–2Fe–3Al. In: Kimura H, Izuma O (eds) Titanium ‘80 science and technology. Metallurgical Society of AIME, Kyoto, pp 1503–1508
55. Davis R, Flower HM, West DRF (1979) Martensitic transformations in Ti–Mo alloys. J Mater Sci 14:712–722. doi: 10.1007/BF0077273510.1007/BF00772735 ↗
56. Bagariatskii IA, Nosova GI, Tagunova TV (1958) Factors in the formation of metastable phases in titanium-base alloys. Sov Phys Dokl 3:1014–1018
57. Settefrati A, Aeby-Gautier E, Appolaire B, Dehmas M, Geandier G, Khelifati G (2013) Low temperature transformation in the β-metastable Ti-5553 alloy. Mater Sci Forum 738–739:97–10210.4028/www.scientific.net/MSF.738-739.97 ↗
58. Malinov S, Sha W, Guo Z, Tang CC, Long AE (2002) Synchrotron X-ray diffraction study of the phase transformations in titanium alloys. Mater Charact 48:279–29510.1016/S1044-5803(02)00286-3 ↗
59. Duerig TW, Terlinde GT, Williams JC (1980) Phase transformations and tensile properties of Ti–10V–2Fe–3Al. Metall Trans A 11:1987–199810.1007/BF02655118 ↗
60. Ohmori Y, Natsui H, Nakai K, Ohtsubo H (1998) Effects of ω phase formation on decomposition of α″/β duplex phase structure in a metastable β Ti alloy. Mater Trans JIM 39:40–4810.2320/matertrans1989.39.40 ↗
61. Tang B, Kou HC, Wang YH, Zhu ZS, Zhang FS, Li JS (2012) Kinetics of orthorhombic martensite decomposition in TC21 alloy under isothermal conditions. J Mater Sci 47:521–529. doi: 10.1007/s10853-011-5829-510.1007/s10853-011-5829-5 ↗