journal article·2019-05

Hydrothermal self-assembly of α-Fe2O3 nanorings@graphene aerogel composites for enhanced Li storage performance

Tao Han, Yang Wei, Xiuzhi Jin, Hongfang Jiu, Lixin Zhang, Yu Sun, Jiao Tian, Ruirui Shang, Deliang Hang, Rong Zhao

Journal of Materials Science· Volume 54· Issue 9
Publisher page

Abstract

A three-dimensional (3D) graphene interconnected network coupled with uniformly dispersed α-Fe2O3 nanorings (α-Fe2O3@GA) was designed by a simple hydrothermal self-assembly strategy and was used as anode material for lithium-ion batteries (LIBs). The α-Fe2O3@GA composites delivered a reversible capacity of 1288 mA h g−1 over 100 cycles at 100 mA g−1 and excellent rate performance than those of pure α-Fe2O3, owing to the synergetic effect of hollow α-Fe2O3 nanorings and inherent 3D porous graphene aerogels. In virtue of their superior lithium storage performance, the α-Fe2O3@GA composites will be promising lithium-ion battery anode materials. Moreover, this study provides a versatile route to synthesis other 3D graphene aerogel-based transitional metal oxide materials for commercial applications in lithium-ion batteries.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Advancements in Battery Materials · Supercapacitor Materials and Fabrication · Layered Double Hydroxides Synthesis and Applications

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (54)

Show source-provided references
1. Liu D, Cao G (2010) Engineering nanostructured electrodes and fabrication of film electrodes for efficient lithium ion intercalation. Energy Environ Sci 3:1218–123710.1039/b922656g ↗
2. Yuan C, Wu HB, Xie Y, Lou XW (2014) Mixed transition-metal oxides: design, synthesis, and energy-related applications. Angew Chem Int Ed 53:1488–150410.1002/anie.201303971 ↗
3. Mei J, Zhang Y, Liao T, Sun Z, Dou SX (2017) Strategies for improving the lithium-storage performance of 2D nanomaterials. Natl Sci Rev 5:389–41610.1093/nsr/nwx077 ↗
4. Liu H, Hu K, Yan D et al (2018) Recent advances on black phosphorus for energy storage, catalysis, and sensor applications. Adv Mater 30:180029510.1002/adma.201800295 ↗
5. Li Z, Ma Z, Wang Y, Chen R, Wu Z, Wang S (2018) LDHs derived nanoparticle-stacked metal nitride as interlayer for long-life lithium sulfur batteries. Sci Bull 63:169–17510.1016/j.scib.2017.12.018 ↗
6. Dou S, Tao L, Wang R, El Hankari S, Chen R, Wang S (2018) Plasma-assisted synthesis and surface modification of electrode materials for renewable energy. Adv Mater 30:170585010.1002/adma.201705850 ↗
7. Mei J, Liao T, Kou L, Sun Z (2017) Two-dimensional metal oxide nanomaterials for next-generation rechargeable batteries. Adv Mater 29:170017610.1002/adma.201700176 ↗
8. Zhao Y, Li X, Yan B et al (2016) Recent developments and understanding of novel mixed transition-metal oxides as anodes in lithium ion batteries. Adv Energy Mater 6:150217510.1002/aenm.201502175 ↗
9. Zhang L, Wu HB, Lou XWD (2014) Iron-oxide-based advanced anode materials for lithium-ion batteries. Adv Energy Mater 4:130095810.1002/aenm.201300958 ↗
10. Zhang J, Huang T, Liu Z, Yu A (2013) Mesoporous Fe2O3 nanoparticles as high performance anode materials for lithium-ion batteries. Electrochem Commun 29:17–2010.1016/j.elecom.2013.01.002 ↗
11. Wei W, Wang Z, Liu Z et al (2013) Metal oxide hollow nanostructures: fabrication and Li storage performance. J Power Sources 238:376–38710.1016/j.jpowsour.2013.03.173 ↗
12. Xiong QQ, Tu JP, Ge X, Wang XL, Gu CD (2015) One-step synthesis of hematite nanospindles from choline chloride/urea deep eutectic solvent with highly powerful storage versus lithium. J Power Sources 274:1–710.1016/j.jpowsour.2014.10.020 ↗
13. Keppeler M, Shen N, Nageswaran S, Srinivasan M (2016) Synthesis of α-Fe2O3/carbon nanocomposites as high capacity electrodes for next generation lithium ion batteries: a review. J Mater Chem A 4:18223–1823910.1039/C6TA08456G ↗
14. Wang X, Zhang M, Liu E et al (2016) Three-dimensional core-shell Fe2O3@carbon/carbon cloth as binder-free anode for the high-performance lithium-ion batteries. Appl Surf Sci 390:350–35610.1016/j.apsusc.2016.08.112 ↗
15. Luo D, Lin F, Xiao W, Zhu W (2017) Synthesis and electrochemical performance of α-Fe2O3@carbon aerogel composite as an anode material for Li-ion batteries. Ceram Int 43:2051–205610.1016/j.ceramint.2016.10.178 ↗
16. Lv X, Zhu Y, Yang T et al (2016) Liquid–solid–solution assembly of morphology-controllable Fe2O3/graphene nanostructures as high-performance LIB anodes. Ceram Int 42:19006–1901110.1016/j.ceramint.2016.09.056 ↗
17. Gao L, Gu C, Ren H, Song X, Huang J (2018) Synthesis of tin(IV) oxide@reduced graphene oxide nanocomposites with superior electrochemical behaviors for lithium-ions batteries. Electrochim Acta 290:72–8110.1016/j.electacta.2018.09.059 ↗
18. Liu H, Zou Y, Tao L et al (2017) Sandwiched thin-film anode of chemically bonded black phosphorus/graphene hybrid for lithium-ion battery. Small 13:170075810.1002/smll.201700758 ↗
19. Lv W, Li Z, Deng Y, Yang Q-H, Kang F (2016) Graphene-based materials for electrochemical energy storage devices: opportunities and challenges. Energy Storage Mater 2:107–13810.1016/j.ensm.2015.10.002 ↗
20. Dong Y, Wu Z-S, Ren W, Cheng H-M, Bao X (2017) Graphene: a promising 2D material for electrochemical energy storage. Sci Bull 62:724–74010.1016/j.scib.2017.04.010 ↗
21. Zhao Y, Wang LP, Sougrati MT et al (2017) A review on design strategies for carbon based metal oxides and sulfides nanocomposites for high performance Li and Na ion battery anodes. Adv Energy Mater 7:160142410.1002/aenm.201601424 ↗
22. Liu H, Tao L, Zhang Y et al (2017) Bridging covalently functionalized black phosphorus on graphene for high-performance sodium-ion battery. ACS Appl Mater Interfaces 9:36849–3685610.1021/acsami.7b11599 ↗
23. Lan Y, Li X, Li G, Luo Y (2015) Sol–gel method to prepare graphene/Fe2O3 aerogel and its catalytic application for the thermal decomposition of ammonium perchlorate. J Nanopart Res 17:39510.1007/s11051-015-3200-5 ↗
24. Zhang X, Sui Z, Xu B et al (2011) Mechanically strong and highly conductive graphene aerogel and its use as electrodes for electrochemical power sources. J Mater Chem 21:6494–649710.1039/c1jm10239g ↗
25. Suo Y, Zhao Q-Q, Meng J-K et al (2016) Fabrication and electrochemical properties of 3D Fe3O4@graphene aerogel composites as lithium-ion battery anodes. Mater Lett 174:36–3910.1016/j.matlet.2016.03.080 ↗
26. Lin Y-M, Abel PR, Heller A, Mullins CB (2011) α-Fe2O3 nanorods as anode material for lithium ion batteries. J Phys Chem Lett 2:2885–289110.1021/jz201363j ↗
27. Wang Z, Luan D, Madhavi S, Li CM, Lou XW (2011) α-Fe2O3 nanotubes with superior lithium storage capability. Chem Commun 47:8061–806310.1039/c1cc12111a ↗
28. Gu C, Song X, Zhang S, Ryu SO, Huang J (2017) Synthesis of hierarchical α-Fe2O3 nanotubes for high-performance lithium-ion batteries. J Alloys Compd 714:6–1210.1016/j.jallcom.2017.04.216 ↗
29. Zhu J, Ng KY, Deng D (2014) Hollow cocoon-like hematite mesoparticles of nanoparticle aggregates: structural evolution and superior performances in lithium ion batteries. ACS Appl Mater Interfaces 6:2996–300110.1021/am4055996 ↗
30. Zhang J-J, Chen Y-L, Sun Y-F, Huang T, Yu A-S (2013) Hierarchical hollow Fe2O3 micro-flowers composed of porous nanosheets as high performance anodes for lithium-ion batteries. RSC Adv 3:20639–2064610.1039/c3ra43061h ↗
31. Liu H, Wang G (2014) An investigation of the morphology effect in Fe2O3 anodes for lithium ion batteries. J Mater Chem A 2:9955–995910.1039/C4TA01544D ↗
32. Li L, Li Z, Fu W, Li F, Wang J, Wang W (2015) α-Fe2O3@C nanorings as anode materials for high performance lithium ion batteries. J Alloys Compd 647:105–10910.1016/j.jallcom.2015.05.204 ↗
33. Sun Y-H, Liu S, Zhou F-C, Nan J-M (2016) Electrochemical performance and structure evolution of core-shell nano-ring α-Fe2O3@carbon anodes for lithium-ion batteries. Appl Surf Sci 390:175–18410.1016/j.apsusc.2016.08.071 ↗
34. Wang J, Lin L, He D (2018) Self-assembly of Fe2O3 nanotubes on graphene as an anode material for lithium ion batteries. J Alloys Compd 750:871–87710.1016/j.jallcom.2018.04.079 ↗
35. Zhu X, Zhu Y, Murali S, Stoller M, Ruoff R (2011) Nanostructured reduced graphene oxide/Fe2O3 composite as a high-performance anode material for lithium ion batteries. ACS Nano 5:3333–333810.1021/nn200493r ↗
36. Tung VC, Allen MJ, Yang Y, Kaner RB (2008) High-throughput solution processing of large-scale graphene. Nat Nanotechnol 4:25–2910.1038/nnano.2008.329 ↗
37. Jia CJ, Sun LD, Luo F et al (2008) Large-scale synthesis of single-crystalline iron oxide magnetic nanorings. J Amer Chem Soc 130:16968–1697710.1021/ja805152t ↗
38. Xiao L, Wu D, Han S et al (2013) Self-assembled Fe2O3/graphene aerogel with high lithium storage performance. ACS Appl Mater Interfaces 5:3764–376910.1021/am400387t ↗
39. Yang X, Sun H, Zhang L, Zhao L, Lian J, Jiang Q (2016) High efficient photo-fenton catalyst of α-Fe2O3/MoS2 hierarchical nanoheterostructures: reutilization for supercapacitors. Sci Rep 6:3159110.1038/srep31591 ↗
40. Zheng C, Niu S, Lv W et al (2017) Propelling polysulfides transformation for high-rate and long-life lithium–sulfur batteries. Nano Energy 33:306–31210.1016/j.nanoen.2017.01.040 ↗
41. Jia X, Lian D, Shi B, Dai R, Li C, Wu X (2017) Facile synthesis of α-Fe2O3@graphene oxide nanocomposites for enhanced gas-sensing performance to ethanol. J Mater Sci: Mater El 28:12070–12079
42. Xie S, Zhang M, Liu P et al (2017) Advanced negative electrode of Fe2O3/graphene oxide paper for high energy supercapacitors. Mater Res Bull 96:413–41810.1016/j.materresbull.2017.04.002 ↗
43. Qi X, Zhang HB, Xu J et al (2017) Highly efficient high-pressure homogenization approach for scalable production of high-quality graphene sheets and sandwich-structured α-Fe2O3/graphene hybrids for high-performance lithium-ion batteries. ACS Appl Mater Interfaces 9:11025–1103410.1021/acsami.7b00808 ↗
44. Li L, Zhou G, Weng Z, Shan X-Y, Li F, Cheng H-M (2014) Monolithic Fe2O3/graphene hybrid for highly efficient lithium storage and arsenic removal. Carbon 67:500–50710.1016/j.carbon.2013.10.022 ↗
45. Zhao Y, Zhai X, Yan D et al (2017) Rational construction the composite of graphene and hierarchical structure assembled by Fe2O3 nanosheets for lithium storage. Electrochim Acta 243:18–2510.1016/j.electacta.2017.04.085 ↗
46. Zhao Y, Yan D, Ding C et al (2016) Fe2O3 nanocubes exposed (012) active facets combination with graphene rendering enhanced lithium storage capability. J Power Sources 327:658–66510.1016/j.jpowsour.2016.07.097 ↗
47. Liu L, Yang X, Lv C et al (2016) Seaweed-derived route to Fe2O3 hollow nanoparticles/N-doped graphene aerogels with high lithium ion storage performance. ACS Appl Mater Interfaces 8:7047–705310.1021/acsami.5b12427 ↗
48. Wang R, Xu C, Du M et al (2014) Solvothermal-induced self-assembly of Fe2O3/GS aerogels for high Li-storage and excellent stability. Small 10:2260–226910.1002/smll.201303371 ↗
49. Liu S, Sun Y-H, Zhou F-C, Nan J-M (2016) Improved electrochemical performance of α-Fe2O3 nanorods and nanotubes confined in carbon nanoshells. Appl Surf Sci 375:101–10910.1016/j.apsusc.2016.03.061 ↗
50. Ma J, He YS, Zhang W et al (2015) An experimental insight into the advantages of in situ solvothermal route to construct 3D graphene-based anode materials for lithium-ion batteries. Nano Energy 16:235–24610.1016/j.nanoen.2015.06.026 ↗
51. Cui X, Zhu Y, Li F et al (2016) Enhanced rate capability of a lithium ion battery anode based on liquid–solid–solution assembly of Fe2O3 on crumpled graphene. RSC Adv 6:9007–901210.1039/C5RA22408J ↗
52. Liu Y, He D, Wu H, Duan J, Zhang Y (2015) Hydrothermal self-assembly of manganese dioxide/manganese carbonate/reduced graphene oxide aerogel for asymmetric supercapacitors. Electrochim Acta 164:154–16210.1016/j.electacta.2015.01.223 ↗
53. Meng J-K, Fu L, Liu Y-S et al (2017) Gas-liquid interfacial assembly and electrochemical properties of 3D highly dispersed α-Fe2O3@graphene aerogel composites with a hierarchical structure for applications in anodes of lithium ion batteries. Electrochim Acta 224:40–4810.1016/j.electacta.2016.12.039 ↗
54. Jiang T, Bu F, Feng X, Shakir I, Hao G, Xu Y (2017) Porous Fe2O3 nanoframeworks encapsulated within three-dimensional graphene as high-performance flexible anode for lithium-ion battery. ACS Nano 11:5140–514710.1021/acsnano.7b02198 ↗