Efficient removal of Pb(II) by Ti3C2Tx powder modified with a silane coupling agent
Source abstract
Abstract
As a layered material, Ti3C2Tx powders possess high ion-exchange capability and relative stable physical properties, but there are some drawbacks associated with Ti3C2Tx powders such as weak adsorption ability in dealing with the organic pollutions and heavy metal ions. A simple method is employed to regulate Ti3C2Tx powders with the silane coupling agent KH570, which is proved to be an efficient way for adsorption to Pb(II). In this work, Ti3C2Tx powders with the modification of KH570 (Ti3C2Tx-KH570) possesses high specific surface area, thermostability and high ion-exchange capability. From the experiment of adsorption, when the concentration of Ti3C2Tx-KH570 powders in the solution is about 3.2 g L−1, the removal rate is about 99.99%. In addition, the adsorption capacity of Ti3C2Tx-KH570 powders to Pb2+ is approximately 147.29 mg g−1 at the temperature of 30 °C, while the adsorption capability of Ti3C2Tx powders to Pb2+ is 48.28 mg g−1. A higher concentration of silane clogs, the available space making it inaccessible for lead adsorption, which indicates that the internal MXene hydroxyl groups are in the majority responsible for Pb2+ adsorption. The Pb2+ adsorption depends on the availability of MXene hydroxyl groups and KH570 carbonyl group of methacryloxypropyl chain. The result indicates that KH570 is a new direction for the surface modification of Ti3C2Tx powders.
Source: openaire · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: MXene and MAX Phase Materials · Aluminum Alloys Composites Properties
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (45)
Show source-provided references
1. Luo SL, Xu XL, Zhou GY, Liu CB, Tang YH, Liu YT (2014) Amino siloxane oligomer-linked graphene oxide as an efficient adsorbent for removal of Pb(II) from wastewater. J Hazard Mater 274:145–15510.1016/j.jhazmat.2014.03.062 ↗
2. Zheng J, Chen KH, Yan X, Chen SJ, Hu GC, Peng XW, Yuan JG, Mai BX, Yang ZY (2013) Heavy metals in food, house dust, and water from an e-waste recycling area in South China and the potential risk to human health. Ecotoxicol Environ Saf 96:205–21210.1016/j.ecoenv.2013.06.017 ↗
3. Li ZL, Xiao D, Ge YY, Koehler S (2015) Surface-functionalized porous lignin for fast and efficient lead removal from aqueous solution. ACS Appl Mater Interfaces 7:15000–1500910.1021/acsami.5b03994 ↗
4. Hertz-Picciotto I (2000) The evidence that lead increases the risk for spontaneous abortion. Am J Ind Med 38:300–30910.1002/1097-0274(200009)38:3<300::AID-AJIM9>3.0.CO;2-C ↗
5. Restrepo HG, Sicard D, Torres MM (2000) DNA damage and repair in cells of lead exposure people. Am J Ind Med 38:330–33410.1002/1097-0274(200009)38:3<330::AID-AJIM13>3.0.CO;2-Z ↗
6. Ahmaruzzaman M, Gupta VK (2011) Rice husk and its ash as low-cost adsorbents in water and wastewater treatment. Ind Eng Chem Res 50:13589–1361310.1021/ie201477c ↗
7. Gang W, Chang Q, Zhang MY (2013) Removal of Cr(VI) from aqueous solution by flocculant with the capacity of reduction and chelation. J Hazard Mater 248–249:115–121
8. Mathew A, Parambadath S, Kim SY, Ha HM, Ha CS (2016) Diffusion mediated selective adsorption of Zn2+ from artificial seawater by MCM-41. Micropor Mesopor Mat 229:124–13310.1016/j.micromeso.2016.04.028 ↗
9. Tan Y, Chen M, Hao Y (2012) High efficient removal of Pb(II) by amino-functionalized Fe3O4 magnetic nano-particles. Chem Eng J 191:104–11110.1016/j.cej.2012.02.075 ↗
10. Zhao G, Li J, Ren X, Chen C, Wang X (2011) Few-layered graphene oxide nanosheets as superior sorbents for heavy metal ion pollution management. Environ Sci Technol 45:10454–1046210.1021/es203439v ↗
11. Liu C, Jia FF, Wang QM, Yang BQ, Song SX (2017) Two-dimensional molybdenum disulfide as adsorbent for high-efficient Pb(II) removal from water. App Mater Today 9:220–22810.1016/j.apmt.2017.07.009 ↗
12. Zhang JF, Xie XD, Liang C, Zhu WH, Meng XG (2019) Characteristics and mechanism of Pb(II) adsorption/desorption on GO/r-GO under sulfide-reducing conditions. J Ind Eng Chem 73:233–24010.1016/j.jiec.2019.01.029 ↗
13. Xiong C, Wang SX, Sun WT, Li Y (2019) Selective adsorption of Pb(II) from aqueous solution using nanosilica functionalized with diethanolamine: equilibrium, kinetic and thermodynamic. Microchem J 146:270–27810.1016/j.microc.2019.01.005 ↗
14. Hope MA, Forse AC, Griffith KJ, Lukatskaya MR, Ghidiu M, Gogotsi Y, Grey CP (2016) NMR reveals the surface functionalisation of Ti3C2 MXene. Phys Chem Chem Phys 18:5099–510210.1039/C6CP00330C ↗
15. Yang JH, Zhang SZ, Ji JL, Wei SH (2015) Adsorption activities of O, OH, F and Au on Two-dimensional Ti2C and Ti3C2 Surface. Acta Phys Chim Sin 31:369–37610.3866/PKU.WHXB201412121 ↗
16. Shahzad F, Alhabeb M, Hatter CB, Anasori B, Man Hong S, Koo CM, Gogotsi Y (2016) Electromagnetic interference shielding with 2D transition metal carbides (MXenes). Science 35:1137–114010.1126/science.aag2421 ↗
17. Peng QM, Guo JX, Zhang QR, Xiang JY, Liu BZ, Zhou AG, Liu RQ, Tian YJ (2014) Unique lead adsorption behavior of activated hydroxyl group in two-dimensional titanium carbide. J Am Chem Soc 136:4113–411610.1021/ja500506k ↗
18. Shahzad A, Rasool K, Miran W, Nawaz M, Jang J, Mahmoud KA, Lee DS (2017) Two-dimensional Ti3C2Tx MXene nanosheets for efficient copper removal from water. ACS Sustain Chem Eng 5:114841–11498810.1021/acssuschemeng.7b02695 ↗
19. Shahzad A, Rasool K, Miran W, Nawaz M, Jang J, Mahmoud KA, Lee DS (2018) Mercuric ion capturing by recoverable titanium carbide magnetic nanocomposite. J Hazard Mater 344:811–81810.1016/j.jhazmat.2017.11.026 ↗
20. Ren CE, Hatzell KB, Alhabeb M, Ling Z, Mahmoud KA, Gogotsi Y (2015) Charge- and size-selective ion sieving through Ti3C2Tx MXene membranes. J Phys Chem Lett 6:4026–403110.1021/acs.jpclett.5b01895 ↗
21. Zhao JQ, Yang YW, Yang CH, Tian YP, Han Y, Liu J, Yin XT, Que WX (2018) A hydrophobic surface enabled salt-blocking 2D Ti3C2 MXene membrane for efficient and stable solar desalination. J Mater Chem A 6:16196–1620410.1039/C8TA05569F ↗
22. Shahzad A, Rasool K, Nawaz M, Miran W, Jang J, Moztahida M, Mahmoud KA, Lee DS (2018) Heterostructural TiO2/Ti3C2Tx (MXene) for photocatalytic degradation of antiepileptic drug carbamazepine. Chem Eng J 349:748–75510.1016/j.cej.2018.05.148 ↗
23. Skubal LR, Meshkov NK, Rajh T (2002) Cadmium removal from water using thiolactic acid-modified titanium dioxide nanoparticles. J Photochem Photobiol A 148:393–39710.1016/S1010-6030(02)00069-2 ↗
24. Yan M, Zeng G, Li X, Zhao C, Yang G, Gong J, Tang L, Huang D (2017) Titanium dioxide nanotube arrays with silane coupling agent modification for heavy metal reduction and persistent organic pollutant degradation. N J Chem 41(11):4377–438910.1039/C6NJ03196J ↗
25. Zhao J, Milanova M, Warmoeskerkena MMCG, Dutschk V (2012) Surface modification of TiO2 nanoparticles with silane coupling agents. Colloids Surf A 413:273–27910.1016/j.colsurfa.2011.11.033 ↗
26. Tai Y, Qian J (2008) Study of surface modification of nano-SiO2 with macromolecular coupling agent (LMPB-g-MAH). Chem Eng J 141:354–36110.1016/j.cej.2008.03.012 ↗
27. Arkles B (1977) Tailoring surfaces with silanes. ChemTech 7:766–778
28. Naguib M, Kurtoglu M, Presser V, Lu J, Niu J, Heon M, Hultman L, Gogotsi Y, Barsoum MW (2011) Two-dimensional nanocrystals produced by exfoliation of Ti3AlC2. Adv Mater 23:4207–420710.1002/adma.201190147 ↗
29. Nagappan S, Ha HM, Park SS, Jo NJ, Ha CS (2017) One-pot synthesis of multi-functional magnetite–polysilsesquioxane hybrid nanoparticles for the selective Fe3+ and some heavy metal ions adsorption. RSC Adv 7:19106–1911610.1039/C7RA00159B ↗
30. Huang YX, Keller AA (2015) EDTA functionalized magnetic nanoparticles sorbent for cadmium and lead contaminated water treatment. Water Res 80:159–16810.1016/j.watres.2015.05.011 ↗
31. Zheng M, Guo RS, Liu ZC, Wang BY, Meng LC, Li FY, Li TT, Luo YN (2018) MoS2 intercalated p-Ti3C2 anode materials with sandwich-like three dimensional conductive networks for lithium-ion batteries. J Alloy Compo 735:1262–127010.1016/j.jallcom.2017.11.250 ↗
32. Mashtalir O, Naguib M, Mochalin VN, Dall’Agnese Y, Heon M, Barsoum MW, Gogotsi Y (2013) Intercalation and delamination of layered carbides and carbonitrides. Nat Commun 4:1716–172310.1038/ncomms2664 ↗
33. Luo J, Tao X, Zhang J, Xia Y, Huang H, Zhang L, Gan Y, Liang C, Zhang W (2016) Sn4+ ion decorated highly conductive Ti3C2 MXene: promising lithium-ion anodes with enhanced volumetric capacity and cyclic performance. ACS Nano 10:2491–249910.1021/acsnano.5b07333 ↗
34. Luo J, Zhang W, Yuan H, Jin C, Zhang L, Huang H, Liang C, Xia Y, Zhang J, Gan Y, Tao X (2017) Pillared structure design of MXene with ultra-large interlayer spacing for high performance lithium-ion capacitors. ACS Nano 11:2459–246910.1021/acsnano.6b07668 ↗
35. Epling WS, Hoflund GB, Weaver JF, Tsubota S, Haruta M (1996) Surface characterization study of Au/α-Fe2O3 and Au/Co3O4 low-temperature CO oxidation catalysts. J Phys Chem B 100:9929–993410.1021/jp960593t ↗
36. Wang GQ, Xing W, Zhuo SP (2013) Nitrogen-doped graphene as low-cost counter electrode for high-efficiency dye-sensitized solar cells. Electrochim Acta 92:269–27510.1016/j.electacta.2013.01.034 ↗
37. Persson I, Näslund L, Halim J, Barsoum MW, Darakchieva V, Palisaitis J, Rosen J (2018) P.O.Å. Persson, On the organization and thermal behavior of functional groups on Ti3C2 MXene surfaces in vacuum. 2D Mater 5:15002–1501110.1088/2053-1583/aa89cd ↗
38. Guo DM, An QD, Xiao ZY, Zhai SR, Yang DJ (2018) Efficient removal of Pb(II), Cr(VI) and organic dyes by polydopamine modified chitosan aerogels. Carbohyd Polym 202:306–31410.1016/j.carbpol.2018.08.140 ↗
39. Rangel-Mendeza JR, Monroy-Zepeda R, Leyva-Ramos E, Diaz-Flores PE, Shirai K (2009) Chitosan selectivity for removing cadmium (II), copper (II), and lead (II) from aqueous phase: pH and organic matter effect. J Hazard Mater 162:503–51110.1016/j.jhazmat.2008.05.073 ↗
40. Repo E, Warchol JK, Kurniawan TA, Sillanpää MET (2010) Adsorption of Co(II) and Ni(II) by EDTA- and/or DTPA-modified chitosan: kinetic and equilibrium modeling. Chem Eng J 161:73–8210.1016/j.cej.2010.04.030 ↗
41. Anush SM, Vishalakshi B, Chandan HR, Geetha BR (2018) Heterocyclic modification of chitosan for the adsorption of Cu (II) and Cr(VI) ions. Sep Sci Technol 53:1979–199010.1080/01496395.2018.1442859 ↗
42. Dong ZH, Wang D, Liu X, Pei XF, Chen LW, Jin J (2014) Bio-inspired surface-functionalization of grapheme oxide for the adsorption of organic dyes and heavy metal ions with a super high capacity. J. Mater. Chem. A 2:5034–504010.1039/C3TA14751G ↗
43. Niu YL, Li K, Ying D, Wang Y, Jia J (2017) Novel recyclable adsorbent for the removal of copper (II) and lead (II) from aqueous solution. Bioresource Technol. 229:63–6810.1016/j.biortech.2017.01.007 ↗
44. Li YH, Di Z, Ding J, Wu D, Luan Z, Zhu Y (2005) Adsorption thermodynamic, kinetic and desorption studies of Pb2+ on carbon nanotubes. Water Res 39:605–60910.1016/j.watres.2004.11.004 ↗
45. Zhou Q, Luo WJ, Zhang X (2017) Ingenious route for ultraviolet-induced graft polymerization achieved on inorganic particle: fabricating magnetic poly(acrylic acid) densely grafted nanocomposites for Cu2+ removal. Appl Surf Sci 413:181–19010.1016/j.apsusc.2017.04.033 ↗